The diffusion of La in ε-Fe 2～3N(ε)and γ′-Fe 4N (γ′)phases produced by plasma nitriding was studied. It is found that with increasing nitriding time, the ε phase continuously decomposes into γ′ one under...The diffusion of La in ε-Fe 2～3N(ε)and γ′-Fe 4N (γ′)phases produced by plasma nitriding was studied. It is found that with increasing nitriding time, the ε phase continuously decomposes into γ′ one under employed experimental conditions and compared with γ′ phase or ε+γ′ ones, the mono one ε has an impedient effect on depth of La diffusion. The growth of La layer in dual phases and mono one follows an approximate exponential law and a parabolic one, respectively, and this kinetics law does not change with increasing temperature. The effect of increasing temperature in the range of 520 to 560 ℃ on La diffusion depth is less than that of phase constitution change such as the decomposition of ε phase into γ′ one.展开更多
The as-sintered sinter skin and the polished section of WC-11Co-0.4Cr 3 C 2-0.3VC-0.2RE（RE=mischmetal with La/Ce ratio of 0.65） alloy were analyzed.It was shown that the microstructures on the skin and in the inner ...The as-sintered sinter skin and the polished section of WC-11Co-0.4Cr 3 C 2-0.3VC-0.2RE（RE=mischmetal with La/Ce ratio of 0.65） alloy were analyzed.It was shown that the microstructures on the skin and in the inner part of the alloy were all characterized with a WC＋β＋M structure,where β was a cobalt-based binder phase and M represented a RE-containing phase.There existed an inward diffusion of S atoms,which caught and fixed the Ce atoms in the alloy and an outward diffusion of La atoms during the sintering process.Consequently,the M phase was characterized with the decreased La/Ce ratio（0.59） in the inner part and the increased La/Ce ratio（1.01） on the skin.The M phase on the skin was characterized with a γ-Ce 2 S 3 type structure.To suppress the long range migration of rare earth to the skin,S in the sintering atmosphere had to be eliminated.展开更多
文摘The diffusion of La in ε-Fe 2～3N(ε)and γ′-Fe 4N (γ′)phases produced by plasma nitriding was studied. It is found that with increasing nitriding time, the ε phase continuously decomposes into γ′ one under employed experimental conditions and compared with γ′ phase or ε+γ′ ones, the mono one ε has an impedient effect on depth of La diffusion. The growth of La layer in dual phases and mono one follows an approximate exponential law and a parabolic one, respectively, and this kinetics law does not change with increasing temperature. The effect of increasing temperature in the range of 520 to 560 ℃ on La diffusion depth is less than that of phase constitution change such as the decomposition of ε phase into γ′ one.
基金supported by National Natural Science Foundation of China (51074189,50823006)Science and Technology Planning Project Founda-tion of Hunan Province,China (2010FJ2006)+1 种基金Research Foundation for the Doctoral Program of Higher Education of China (20100162110001)the National Science & Technology Special Foundation of China (2011BAE09B02,2012ZX04003021)
文摘The as-sintered sinter skin and the polished section of WC-11Co-0.4Cr 3 C 2-0.3VC-0.2RE（RE=mischmetal with La/Ce ratio of 0.65） alloy were analyzed.It was shown that the microstructures on the skin and in the inner part of the alloy were all characterized with a WC＋β＋M structure,where β was a cobalt-based binder phase and M represented a RE-containing phase.There existed an inward diffusion of S atoms,which caught and fixed the Ce atoms in the alloy and an outward diffusion of La atoms during the sintering process.Consequently,the M phase was characterized with the decreased La/Ce ratio（0.59） in the inner part and the increased La/Ce ratio（1.01） on the skin.The M phase on the skin was characterized with a γ-Ce 2 S 3 type structure.To suppress the long range migration of rare earth to the skin,S in the sintering atmosphere had to be eliminated.
