采用固相反应制备了Ni O-La Co O3催化剂,考察了焙烧温度以及Ni含量对催化剂的CO和丙烷氧化活性的影响。用X射线粉末衍射、H2-程序升温还原等技术对催化剂进行了表征。结果表明,在焙烧温度为700-1000℃时,焙烧温度越高,催化剂的丙烷和C...采用固相反应制备了Ni O-La Co O3催化剂,考察了焙烧温度以及Ni含量对催化剂的CO和丙烷氧化活性的影响。用X射线粉末衍射、H2-程序升温还原等技术对催化剂进行了表征。结果表明,在焙烧温度为700-1000℃时,焙烧温度越高,催化剂的丙烷和CO氧化性能越差,其中700℃焙烧后的10Ni O-La Co O3催化剂的效果最好。助剂Ni能有效提高La Co O3催化剂的丙烷和CO氧化性能,其中Ni含量为7.5%的7.5Ni O-La Co O3催化剂氧化性能最佳。研究发现催化剂的CO和丙烷氧化活性与催化剂中氧活动性具有相关性。展开更多
Catalytic direct decomposition of NO by perovskite-type catalysts has attracted much attention for the various possible components and the unique structure. LaCoO_3 nanoparticles were precipitated on a-Al_2O_3 micro p...Catalytic direct decomposition of NO by perovskite-type catalysts has attracted much attention for the various possible components and the unique structure. LaCoO_3 nanoparticles were precipitated on a-Al_2O_3 micro powders by rotary chemical vapor deposition（rotary CVD） and its catalytic performance for the decomposition of NO was investigated. LaCoO_3 nano-particles with 100 nm in average diameter and 1.5% in mass were uniformly dispersed on a-Al_2O_3 powder. The conversion of NO increased with increasing temperature from 400 to 950 ℃, and reached 28.7% at 950 ℃. The gas velocity of transformed NO on LaCoO_3 nano-particles catalyst per mass unit was 7.7 mL/（g min）, showing a good catalytic activity over the calculated results of pure catalysts. After five times of aging performance experiments, the NO conversion kept the same value, showing a good aging performance and thermal stability.展开更多
Summary of main observation and conclusion A series of electrospun LaCoO3 perovskites derived from CoX2 (X =CH3COO-,NO3-) were prepared and investigated for total propane oxidation.It is shown that pure rhombohedral p...Summary of main observation and conclusion A series of electrospun LaCoO3 perovskites derived from CoX2 (X =CH3COO-,NO3-) were prepared and investigated for total propane oxidation.It is shown that pure rhombohedral perovskite LaCoO3 from Co(CH3COO)2 can be obtained at a relatively low temperature,400 ℃,benefitting from the complexation effect of CH3COO-.On the other hand,CH3COO-can accelerate the complete decomposition of polymer.The low-temperature process can protect LaCoO3 nanoparticles from growing up.展开更多
文摘采用固相反应制备了Ni O-La Co O3催化剂,考察了焙烧温度以及Ni含量对催化剂的CO和丙烷氧化活性的影响。用X射线粉末衍射、H2-程序升温还原等技术对催化剂进行了表征。结果表明,在焙烧温度为700-1000℃时,焙烧温度越高,催化剂的丙烷和CO氧化性能越差,其中700℃焙烧后的10Ni O-La Co O3催化剂的效果最好。助剂Ni能有效提高La Co O3催化剂的丙烷和CO氧化性能,其中Ni含量为7.5%的7.5Ni O-La Co O3催化剂氧化性能最佳。研究发现催化剂的CO和丙烷氧化活性与催化剂中氧活动性具有相关性。
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.21033006, No.21133004, and No.21373167） and the Ministry of Science and Technology （No.2010CB732303）.
文摘在房间温度结构(293 K ) 的 perovskite LaCoO3 的电子结构被使用 PBE， PBE+U 和 HSE 计算。不同旋转配置被考虑了。我们的计算证明在在 HSE 的 DFT+U 和混合因素的 Hubbard U 参数的选择显著地象相对精力一样影响了乐队差距。因为旋转退出了状态，为 U 的最佳的价值并且是 3.0 eV 并且 0.05 分别地。当时，我们的计算也强调了那 U5.0 eV， PBE+U 将导致无理的电子结构和精力顺序。
基金Funded by the National Natural Science Foundation of China(Nos.51372188 and 51521001)the 111 Project(B13035)+3 种基金the International Science&Technology Cooperation Program of China(2014DFA53090)the Natural Science Foundation of Hubei Province,China(2016CFA006)the National Key Research and Development Program of China(2017YFB0310400)the Fundamental Research Funds for the Central Universities(WUT:2017II43GX,2017III032)
文摘Catalytic direct decomposition of NO by perovskite-type catalysts has attracted much attention for the various possible components and the unique structure. LaCoO_3 nanoparticles were precipitated on a-Al_2O_3 micro powders by rotary chemical vapor deposition（rotary CVD） and its catalytic performance for the decomposition of NO was investigated. LaCoO_3 nano-particles with 100 nm in average diameter and 1.5% in mass were uniformly dispersed on a-Al_2O_3 powder. The conversion of NO increased with increasing temperature from 400 to 950 ℃, and reached 28.7% at 950 ℃. The gas velocity of transformed NO on LaCoO_3 nano-particles catalyst per mass unit was 7.7 mL/（g min）, showing a good catalytic activity over the calculated results of pure catalysts. After five times of aging performance experiments, the NO conversion kept the same value, showing a good aging performance and thermal stability.
基金the National Natural Science Foundation of China(Nos.21875037,21407025)the National Science Foundation of Fujian Province(No.2016J01047)the New Century Talent Project of Fujian Province.
文摘Summary of main observation and conclusion A series of electrospun LaCoO3 perovskites derived from CoX2 (X =CH3COO-,NO3-) were prepared and investigated for total propane oxidation.It is shown that pure rhombohedral perovskite LaCoO3 from Co(CH3COO)2 can be obtained at a relatively low temperature,400 ℃,benefitting from the complexation effect of CH3COO-.On the other hand,CH3COO-can accelerate the complete decomposition of polymer.The low-temperature process can protect LaCoO3 nanoparticles from growing up.
