A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfoni...A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.展开更多
A selective and sensitive method for determination of platinum and palladium(II) in an aqueous solution simultaneously by laser thermal lens spectrometry, based on the complex reaction of 2-(3,5-dichloropyridylazo)-5-...A selective and sensitive method for determination of platinum and palladium(II) in an aqueous solution simultaneously by laser thermal lens spectrometry, based on the complex reaction of 2-(3,5-dichloropyridylazo)-5-dimethylaminoamiline (3,5-diCl-PA^D~MA) with platinum and palladium, has been developed. It is shown that the palladium complex can be formed at room temperature, while the platinum complex can be only formed after being heated in a boiling water bath. By using this difference of reaction temperature and the characteristic of the complexes mentioned above, the method for simultaneous determination of platinum and palladium was established in an aqueous solution without a pre-separation. The results show that the dynamic linear ranges of determination for platinum and palladium are 0.005- 0.04 μg/mL and 0.005- 0.25 μg/mL respectively, and that the detection limits are both 0.002 μg/mL. The method has been applied to the determination of platinum and palladium simultaneously in alloy and catalyst samples with satisfactory results.展开更多
The curvature type of the thermal lens generated in a zigzag slab laser is numerically analysed. It is found that the curvature type of the thermal lens varies alternatively between the convex and the concave lenses w...The curvature type of the thermal lens generated in a zigzag slab laser is numerically analysed. It is found that the curvature type of the thermal lens varies alternatively between the convex and the concave lenses with the number of bounces of light within the slab, which can be well explained by the trace of the zigzag propagation. In addition, we conclude that the beamlet with a larger number of bounces experiences weaker thermal lensing but more serious wavefront deformation due to the large side lobe portion in the curve of optical path difference.展开更多
In this work, the thermal characterization of continuously pumped passively Q-switched laser is quantitatively represented. The system under investigation is end-pumped Yb:YAG passively Q-switched by Cr4+:YAG as satur...In this work, the thermal characterization of continuously pumped passively Q-switched laser is quantitatively represented. The system under investigation is end-pumped Yb:YAG passively Q-switched by Cr4+:YAG as saturable absorber. The rate equations describing the dynamics of laser action are numerically solved simultaneously with the temperature conductivity heat equation to depict the transient temperature distribution. The study has been performed in the cylindrical coordinates to characterize the temperature distribution in the axial and radial directions. The thermal transient time in both directions as well as the thermal focal length are calculated. The temporal behavior of the temperature distribution has been illustrated in a 3-dimensional diagram.展开更多
A comparative study on the laser performance between bonding and non-bonding Er,Pr:GYSGG rods side-pumped by 970-nm laser diodes(LDs) is conducted for the thermal lensing compensation. The analyses of the thermal dist...A comparative study on the laser performance between bonding and non-bonding Er,Pr:GYSGG rods side-pumped by 970-nm laser diodes(LDs) is conducted for the thermal lensing compensation. The analyses of the thermal distribution and thermal focal length show that the bonding rod possesses a high cooling efficiency and weak thermal lensing effect compared with the conventional Er,Pr:GYSGG rod. Moreover, the laser characteristics of maximum output power, slope efficiency, and laser beam quality of the bonding rod with concave end-faces operated at 2.79 μm are improved under the high-repetition-rate operation. A maximum output power of 13.96 W is achieved at 150-Hz and 200-μs pulse width,corresponding to a slope efficiency of 17.7% and an electrical-to-optical efficiency of 12.9%. All results suggest that the combination of thermal bonding and concave end-face is a suitable structure for thermal lensing compensation.展开更多
文摘A novel method for the determination of cationic surfactant by laser thermal lens spectrometry was developed. It was based on the reaction between 1-hydroxy-2-(5-nitro-2-Pyri- dylazo)-8-aminonaphthalene-3,6-disulfonic acid (5-NO2-PAH) and cationic surfactant to form 1:2 ionic association complex in a weakly basic medium (pH 9.44). The determination conditions and the mechanism were discussed. The method has been applied to the analysis of wastewater and moat water samples.
基金ProjectsupportedbytheNaturalScienceFoundationofShaanxiProvinceofChina (No .97H0 1) .
文摘A selective and sensitive method for determination of platinum and palladium(II) in an aqueous solution simultaneously by laser thermal lens spectrometry, based on the complex reaction of 2-(3,5-dichloropyridylazo)-5-dimethylaminoamiline (3,5-diCl-PA^D~MA) with platinum and palladium, has been developed. It is shown that the palladium complex can be formed at room temperature, while the platinum complex can be only formed after being heated in a boiling water bath. By using this difference of reaction temperature and the characteristic of the complexes mentioned above, the method for simultaneous determination of platinum and palladium was established in an aqueous solution without a pre-separation. The results show that the dynamic linear ranges of determination for platinum and palladium are 0.005- 0.04 μg/mL and 0.005- 0.25 μg/mL respectively, and that the detection limits are both 0.002 μg/mL. The method has been applied to the determination of platinum and palladium simultaneously in alloy and catalyst samples with satisfactory results.
基金supported by the National Natural Science Foundation of China(Grant Nos.50721004 and 60978032)
文摘The curvature type of the thermal lens generated in a zigzag slab laser is numerically analysed. It is found that the curvature type of the thermal lens varies alternatively between the convex and the concave lenses with the number of bounces of light within the slab, which can be well explained by the trace of the zigzag propagation. In addition, we conclude that the beamlet with a larger number of bounces experiences weaker thermal lensing but more serious wavefront deformation due to the large side lobe portion in the curve of optical path difference.
文摘In this work, the thermal characterization of continuously pumped passively Q-switched laser is quantitatively represented. The system under investigation is end-pumped Yb:YAG passively Q-switched by Cr4+:YAG as saturable absorber. The rate equations describing the dynamics of laser action are numerically solved simultaneously with the temperature conductivity heat equation to depict the transient temperature distribution. The study has been performed in the cylindrical coordinates to characterize the temperature distribution in the axial and radial directions. The thermal transient time in both directions as well as the thermal focal length are calculated. The temporal behavior of the temperature distribution has been illustrated in a 3-dimensional diagram.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51872290,51702322,and 51802307)the National Key Research and Development Program of China(Grant No.2016YFB1102301)
文摘A comparative study on the laser performance between bonding and non-bonding Er,Pr:GYSGG rods side-pumped by 970-nm laser diodes(LDs) is conducted for the thermal lensing compensation. The analyses of the thermal distribution and thermal focal length show that the bonding rod possesses a high cooling efficiency and weak thermal lensing effect compared with the conventional Er,Pr:GYSGG rod. Moreover, the laser characteristics of maximum output power, slope efficiency, and laser beam quality of the bonding rod with concave end-faces operated at 2.79 μm are improved under the high-repetition-rate operation. A maximum output power of 13.96 W is achieved at 150-Hz and 200-μs pulse width,corresponding to a slope efficiency of 17.7% and an electrical-to-optical efficiency of 12.9%. All results suggest that the combination of thermal bonding and concave end-face is a suitable structure for thermal lensing compensation.
文摘基于对LD端面泵浦Yb∶KGW激光晶体工作特点的分析,建立了符合条件的激光晶体热模型.考虑晶体侧面的热对流,运用MATLAB和FORTRAN软件,通过有限差分法求解各向异性介质热传导方程,得到了该晶体的温度场分布、端面热形变分布和不同泵浦功率下的热焦距.结果表明:在泵浦功率为14 W时,泵浦面最高温度达272.8℃、最大形变为0.48μm,光斑附近的热焦距为4.8 cm.
