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Incorporating empirical knowledge into data-driven variable selection for quantitative analysis of coal ash content by laser-induced breakdown spectroscopy 被引量:1
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作者 吕一涵 宋惟然 +1 位作者 侯宗余 王哲 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期148-156,共9页
Laser-induced breakdown spectroscopy(LIBS)has become a widely used atomic spectroscopic technique for rapid coal analysis.However,the vast amount of spectral information in LIBS contains signal uncertainty,which can a... Laser-induced breakdown spectroscopy(LIBS)has become a widely used atomic spectroscopic technique for rapid coal analysis.However,the vast amount of spectral information in LIBS contains signal uncertainty,which can affect its quantification performance.In this work,we propose a hybrid variable selection method to improve the performance of LIBS quantification.Important variables are first identified using Pearson's correlation coefficient,mutual information,least absolute shrinkage and selection operator(LASSO)and random forest,and then filtered and combined with empirical variables related to fingerprint elements of coal ash content.Subsequently,these variables are fed into a partial least squares regression(PLSR).Additionally,in some models,certain variables unrelated to ash content are removed manually to study the impact of variable deselection on model performance.The proposed hybrid strategy was tested on three LIBS datasets for quantitative analysis of coal ash content and compared with the corresponding data-driven baseline method.It is significantly better than the variable selection only method based on empirical knowledge and in most cases outperforms the baseline method.The results showed that on all three datasets the hybrid strategy for variable selection combining empirical knowledge and data-driven algorithms achieved the lowest root mean square error of prediction(RMSEP)values of 1.605,3.478 and 1.647,respectively,which were significantly lower than those obtained from multiple linear regression using only 12 empirical variables,which are 1.959,3.718 and 2.181,respectively.The LASSO-PLSR model with empirical support and 20 selected variables exhibited a significantly improved performance after variable deselection,with RMSEP values dropping from 1.635,3.962 and 1.647 to 1.483,3.086 and 1.567,respectively.Such results demonstrate that using empirical knowledge as a support for datadriven variable selection can be a viable approach to improve the accuracy and reliability of LIBS quantification. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) coal ash content quantitative analysis variable selection empirical knowledge partial least squares regression(PLSR)
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Ultrafast dynamics of femtosecond laser-induced high spatial frequency periodic structures on silicon surfaces 被引量:2
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作者 Ruozhong Han Yuchan Zhang +6 位作者 Qilin Jiang Long Chen Kaiqiang Cao Shian Zhang Donghai Feng Zhenrong Sun Tianqing Jia 《Opto-Electronic Science》 2024年第3期33-46,共14页
Femtosecond laser-induced periodic surface structures(LIPSS)have been extensively studied over the past few decades.In particular,the period and groove width of high-spatial-frequency LIPSS(HSFL)is much smaller than t... Femtosecond laser-induced periodic surface structures(LIPSS)have been extensively studied over the past few decades.In particular,the period and groove width of high-spatial-frequency LIPSS(HSFL)is much smaller than the diffraction limit,making it a useful method for efficient nanomanufacturing.However,compared with the low-spatial-frequency LIPSS(LSFL),the structure size of the HSFL is smaller,and it is more easily submerged.Therefore,the formation mechanism of HSFL is complex and has always been a research hotspot in this field.In this study,regular LSFL with a period of 760 nm was fabricated in advance on a silicon surface with two-beam interference using an 800 nm,50 fs femtosecond laser.The ultrafast dynamics of HSFL formation on the silicon surface of prefabricated LSFL under single femtosecond laser pulse irradiation were observed and analyzed for the first time using collinear pump-probe imaging method.In general,the evolution of the surface structure undergoes five sequential stages:the LSFL begins to split,becomes uniform HSFL,degenerates into an irregular LSFL,undergoes secondary splitting into a weakly uniform HSFL,and evolves into an irregular LSFL or is submerged.The results indicate that the local enhancement of the submerged nanocavity,or the nanoplasma,in the prefabricated LSFL ridge led to the splitting of the LSFL,and the thermodynamic effect drove the homogenization of the splitting LSFL,which evolved into HSFL. 展开更多
关键词 laser-induced periodic surface structures(LIPSS) local field enhancement collinear pump-probe imaging silicon high spatial frequency periodic structures
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Effect of matrix thermal properties on laser-induced plasma
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作者 Yuheng Shan An Li +4 位作者 Xinyu Zhang Wen Yi Ying Zhang Xiaodong Liu Ruibin Liu 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第10期331-336,共6页
The matrix thermal properties have an important impact on laser-induced plasma,as the thermal effect dominates the interaction between ns-pulsed laser and matter,especially in metals.We used a series of pure metals an... The matrix thermal properties have an important impact on laser-induced plasma,as the thermal effect dominates the interaction between ns-pulsed laser and matter,especially in metals.We used a series of pure metals and aluminum alloys to measure plasma temperature and electron density through laser-induced breakdown spectroscopy,in order to investigate the effect of matrix thermal properties on laser-induced plasma.In pure metals,a significant negative linear correlation was observed between the matrix thermal storage coefficient and plasma temperature,while a weak correlation was observed with electron density.The results indicate that metals with low thermal conductivity or specific heat capacity require less laser energy for thermal diffusion or melting and evaporation,resulting in higher ablation rates and higher plasma temperatures.However,considering ionization energy,thermal effects may be a secondary factor affecting electron density.The experiment of aluminum alloy further confirms the influence of thermal conductivity on plasma temperature and its mechanism explanation. 展开更多
关键词 laser-induced plasma thermal properties matrix effect thermal storage coefficient plasma temperature
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Femtosecond laser-induced nanoparticle implantation into flexible substrate for sensitive and reusable microfluidics SERS detection
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作者 Yongxiang Hu Yu Zhou +2 位作者 Guohu Luo Dege Li Minni Qu 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第4期262-274,共13页
Surface-enhanced Raman spectroscopy(SERS)microfluidic system,which enables rapid detection of chemical and biological analytes,offers an effective platform to monitor various food contaminants and disease diagnoses.Th... Surface-enhanced Raman spectroscopy(SERS)microfluidic system,which enables rapid detection of chemical and biological analytes,offers an effective platform to monitor various food contaminants and disease diagnoses.The efficacy of SERS microfluidic systems is greatly dependent on the sensitivity and reusability of SERS detection substrates to ensure repeated use for prolonged periods.This study proposed a novel process of femtosecond laser nanoparticle array(NPA)implantation to achieve homogeneous forward transfer of gold NPA on a flexible polymer film and accurately integrated it within microfluidic chips for SERS detection.The implanted Au-NPA strips show a remarkable electromagnetic field enhancement with the factor of 9×108 during SERS detection of malachite green(MG)solution,achieving a detection limit lower than 10 ppt,far better than most laser-prepared SERS substrates.Furthermore,Au-NPA strips show excellent reusability after several physical and chemical cleaning,because of the robust embedment of laser-implanted NPA in flexible substrates.To demonstrate the performance of Au-NPA,a SERS microfluidic system is built to monitor the online oxidation reaction between MG/NaClO reactants,which helps infer the reaction path.The proposed method of nanoparticle implantation is more effective than the direct laser structuring technique.It provides better performance for SERS detection,robustness of detection,and substrate flexibility and has a wider range of applications for microfluidic systems without any negative impact. 展开更多
关键词 femtosecond laser-induced transfer nanoparticle array surface-enhanced Raman spectrum microfluidic system
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Towards a new avenue for rapid synthesis of electrocatalytic electrodes via laser-induced hydrothermal reaction for water splitting
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作者 Yang Sha Menghui Zhu +6 位作者 Kun Huang Yang Zhang Francis Moissinac Zhizhou Zhang Dongxu Cheng Paul Mativenga Zhu Liu 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第1期340-351,共12页
Electrochemical production of hydrogen from water requires the development ofelectrocatalysts that are active,stable,and low-cost for water splitting.To address these challenges,researchers are increasingly exploring ... Electrochemical production of hydrogen from water requires the development ofelectrocatalysts that are active,stable,and low-cost for water splitting.To address these challenges,researchers are increasingly exploring binder-free electrocatalytic integratedelectrodes (IEs) as an alternative to conventional powder-based electrode preparation methods,for the former is highly desirable to improve the catalytic activity and long-term stability for large-scale applications of electrocatalysts.Herein,we demonstrate a laser-inducedhydrothermal reaction (LIHR) technique to grow NiMoO4nanosheets on nickel foam,which is then calcined under H2/Ar mixed gases to prepare the IE IE-NiMo-LR.This electrode exhibits superior hydrogen evolution reaction performance,requiring overpotentials of 59,116 and143 mV to achieve current densities of 100,500 and 1000 mA·cm-2.During the 350 h chronopotentiometry test at current densities of 100 and 500 m A·cm-2,the overpotentialremains essentially unchanged.In addition,NiFe-layered double hydroxide grown on Ni foam is also fabricated with the same LIHR method and coupled with IE-NiMo-IR to achieve water splitting.This combination exhibits excellent durability under industrial current density.The energy consumption and production efficiency of the LIHR method are systematicallycompared with the conventional hydrothermal method.The LIHR method significantly improves the production rate by over 19 times,while consuming only 27.78%of the total energy required by conventional hydrothermal methods to achieve the same production. 展开更多
关键词 electrocatalytic electrode laser-induced hydrothermal reaction NiFe layered double hydroxides hydrogen evolution reaction water splitting energy consumption production rate
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Characteristics of laser-induced breakdown spectroscopy of liquid slag
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作者 董长言 于洪霞 +4 位作者 孙兰香 李洋 刘修业 周平 黄少文 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第2期86-93,共8页
Rapid online analysis of liquid slag is essential for optimizing the quality and energy efficiency of steel production. To investigate the key factors that affect the online measurement of refined slag using laser-ind... Rapid online analysis of liquid slag is essential for optimizing the quality and energy efficiency of steel production. To investigate the key factors that affect the online measurement of refined slag using laser-induced breakdown spectroscopy(LIBS), this study examined the effects of slag composition and temperature on the intensity and stability of the LIBS spectra. The experimental temperature was controlled at three levels: 1350℃, 1400℃, and 1450℃. The results showed that slag composition and temperature significantly affected the intensity and stability of the LIBS spectra. Increasing the Fe content and temperature in the slag reduces its viscosity, resulting in an enhanced intensity and stability of the LIBS spectra. Additionally, 42 refined slag samples were quantitatively analyzed for Fe, Si, Ca, Mg, Al, and Mn at 1350℃, 1400℃, and 1450℃.The normalized full spectrum combined with partial least squares(PLS) quantification modeling was used, using the Ca Ⅱ 317.91 nm spectral line as an internal standard. The results show that using the internal standard normalization method can significantly reduce the influence of spectral fluctuations. Meanwhile, a temperature of 1450℃ has been found to yield superior results compared to both 1350℃ and 1400℃, and it is advantageous to conduct a quantitative analysis of the slag when it is in a “water-like” state with low viscosity. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) SLAG temperature COMPOSITION VISCOSITY internal standard normalization partial least squares(PLS)
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Estimating the yield stress of soft materials via laser-induced breakdown spectroscopy
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作者 龚书航 李亚举 +7 位作者 钱东斌 叶晋瑞 赵扣 曾强 陈良文 张少锋 杨磊 马新文 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第3期428-432,共5页
Taking three typical soft samples prepared respectively by loose packings of 77-,95-,and 109-μm copper grains as examples,we perform an experiment to investigate the energy-dependent laser-induced breakdown spectrosc... Taking three typical soft samples prepared respectively by loose packings of 77-,95-,and 109-μm copper grains as examples,we perform an experiment to investigate the energy-dependent laser-induced breakdown spectroscopy(LIBS)of soft materials.We discovered a reversal phenomenon in the trend of energy dependence of plasma emission intensity:increasing initially and then decreasing separated by a well-defined critical energy.The trend reversal is attributed to the laser-induced recoil pressure at the critical energy just matching the sample's yield strength.As a result,a one-to-one correspondence can be well established between the samples'yield stress and the critical energy that is easily obtainable from LIBS measurements.This allows us to propose an innovative method for estimating the yield stress of soft materials via LIBS with attractive advantages including in-situ remote detection,real-time data collection,and minimal destructive to sample. 展开更多
关键词 laser-induced breakdown spectroscopy soft materials yield stress
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Research on a deconvolution algorithm for laser-induced fluorescence diagnosis based on the maximum entropy principle
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作者 雷清雲 杨雄 +4 位作者 程谋森 张帆 郭大伟 李小康 肖文杰 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第7期93-107,共15页
Laser-induced fluorescence(LIF)spectroscopy is employed for plasma diagnosis,necessitating the utilization of deconvolution algorithms to isolate the Doppler effect from the raw spectral signal.However,direct deconvol... Laser-induced fluorescence(LIF)spectroscopy is employed for plasma diagnosis,necessitating the utilization of deconvolution algorithms to isolate the Doppler effect from the raw spectral signal.However,direct deconvolution becomes invalid in the presence of noise as it leads to infinite amplification of high-frequency noise components.To address this issue,we propose a deconvolution algorithm based on the maximum entropy principle.We validate the effectiveness of the proposed algorithm by utilizing simulated LIF spectra at various noise levels(signal-to-noise ratio,SNR=20–80 d B)and measured LIF spectra with Xe as the working fluid.In the typical measured spectrum(SNR=26.23 d B)experiment,compared with the Gaussian filter and the Richardson–Lucy(R-L)algorithm,the proposed algorithm demonstrates an increase in SNR of 1.39 d B and 4.66 d B,respectively,along with a reduction in the root-meansquare error(RMSE)of 35%and 64%,respectively.Additionally,there is a decrease in the spectral angle(SA)of 0.05 and 0.11,respectively.In the high-quality spectrum(SNR=43.96 d B)experiment,the results show that the running time of the proposed algorithm is reduced by about98%compared with the R-L iterative algorithm.Moreover,the maximum entropy algorithm avoids parameter optimization settings and is more suitable for automatic implementation.In conclusion,the proposed algorithm can accurately resolve Doppler spectrum details while effectively suppressing noise,thus highlighting its advantage in LIF spectral deconvolution applications. 展开更多
关键词 maximum entropy spectral deconvolution laser-induced fluorescence spectrum
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Two-dimensional investigation of characteristic parameters and their gradients for the self-generated electric and magnetic fields of laser-induced zirconium plasma
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作者 Tayyaba SAJID Shazia BASHIR +2 位作者 Mahreen AKRAM Maira RAZZAQ Khaliq MAHMOOD 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第5期138-155,共18页
Two-dimensional diagnosis of laser-induced zirconium(Zr)plasma has been experimentally performed using the time-of-flight method by employing Faraday cups in addition to electric and magnetic probes.The characteristic... Two-dimensional diagnosis of laser-induced zirconium(Zr)plasma has been experimentally performed using the time-of-flight method by employing Faraday cups in addition to electric and magnetic probes.The characteristic parameters of laser-induced Zr plasma have been evaluated as a function of different laser irradiances ranging from 4.5 to 11.7 GW cm-2 at different axial positions of 1–4 cm with a fixed radial distance of 2 cm.A well-supporting correlation between the plume parameters and the laser-plasma-produced spontaneous electric and magnetic(E and B)fields was established.The measurements of the characteristic parameters and spontaneously induced fields were observed to have an increasing trend with the increasing laser irradiance.However,when increasing the spatial distance in both the axial and radial directions,the plasma parameters(electron/ion number density,temperature and kinetic energy)did not show either continuously increasing or decreasing trends due to various kinetic and dynamic processes during the spatial evolution of the plume.However,the E and B fields were observed to be always diffusing away from the target.The radial component of electron number densities remained higher than the axial number density component,whereas the axial ion number density at all laser irradiances and axial distances remained higher than the radial ion number density.The higher axial self-generated electric field(SGEF)values than radial SGEF values are correlated with the effective charge-separation mechanism of electrons and ions.The generation of a self-generated magnetic field is observed dominantly in the radial direction at increasing laser irradiance as compared to the axial one due to the deflection of fast-moving electrons and the persistence of two-electron temperature on the radial axis. 展开更多
关键词 Faraday cup axial and radial expansion space-charge effect laser-induced zirconium plasma two-electron temperature distribution self-generated electric and magnetic fields
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Laser-induced breakdown spectroscopy as a method for millimeter-scale inspection of surface flatness
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作者 Jinrui YE Yaju LI +8 位作者 Zhao ZHANG Xinwei WANG Kewei TAO Qiang ZENG Liangwen CHEN Dongbin QIAN Shaofeng ZHANG Lei YANG Xinwen MA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第9期148-155,共8页
A non-contact method for millimeter-scale inspection of material surface flatness via Laser-Induced Breakdown Spectroscopy(LIBS)is investigated experimentally.The experiment is performed using a planished surface of a... A non-contact method for millimeter-scale inspection of material surface flatness via Laser-Induced Breakdown Spectroscopy(LIBS)is investigated experimentally.The experiment is performed using a planished surface of an alloy steel sample to simulate its various flatness,ranging from 0 to 4.4 mm,by adjusting the laser focal plane to the surface distance with a step length of 0.2 mm.It is found that LIBS measurements are successful in inspecting the flatness differences among these simulated cases,implying that the method investigated here is feasible.It is also found that,for achieving the inspection of surface flatness within such a wide range,when univariate analysis is applied,a piecewise calibration model must be constructed.This is due to the complex dependence of plasma formation conditions on the surface flatness,which inevitably complicates the inspection procedure.To solve the problem,a multivariate analysis with the help of Back-Propagation Neural Network(BPNN)algorithms is applied to further construct the calibration model.By detailed analysis of the model performance,we demonstrate that a unified calibration model can be well established based on BPNN algorithms for unambiguous millimeter-scale range inspection of surface flatness with a resolution of about 0.2 mm. 展开更多
关键词 laser-induced breakdown spectroscopy machine learning surface flatness
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Estimating the grain size of microgranular material using laser-induced breakdown spectroscopy combined with machine learning algorithms
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作者 张朝 李亚举 +9 位作者 杨光辉 曾强 李小龙 陈良文 钱东斌 孙对兄 苏茂根 杨磊 张少锋 马新文 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第5期129-137,共9页
Recent work has validated a new method for estimating the grain size of microgranular materials in the range of tens to hundreds of micrometers using laser-induced breakdown spectroscopy(LIBS).In this situation,a piec... Recent work has validated a new method for estimating the grain size of microgranular materials in the range of tens to hundreds of micrometers using laser-induced breakdown spectroscopy(LIBS).In this situation,a piecewise univariate model must be constructed to estimate grain size due to the complex dependence of the plasma formation environment on grain size.In the present work,we tentatively construct a unified calibration model suitable for LIBS-based estimation of those grain sizes.Specifically,two unified multivariate calibration models are constructed based on back-propagation neural network(BPNN)algorithms using feature selection strategies with and without considering prior information.By detailed analysis of the performances of the two multivariate models,it was found that a unified calibration model can be successfully constructed based on BPNN algorithms for estimating the grain size in the range of tens to hundreds of micrometers.It was also found that the model constructed with a priorguided feature selection strategy had better prediction performance.This study has practical significance in developing the technology for material analysis using LIBS,especially when the LIBS signal exhibits a complex dependence on the material parameter to be estimated. 展开更多
关键词 laser-induced breakdown spectroscopy machine learning randomly packed microgranular materials
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The recent progress of laser-induced graphene based device applications 被引量:3
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作者 Liqiang Zhang Ziqian Zhou +1 位作者 Xiaosong Hu Liaoyong Wen 《Journal of Semiconductors》 EI CAS CSCD 2023年第3期29-42,共14页
Laser writing is a fast and efficient technology that can produce graphene with a high surface area,whereas laser-induced graphene(LIG)has been widely used in both physics and chemical device application.It is necessa... Laser writing is a fast and efficient technology that can produce graphene with a high surface area,whereas laser-induced graphene(LIG)has been widely used in both physics and chemical device application.It is necessary to update this important progress because it may provide a clue to consider the current challenges and possible future directions.In this review,the basic principles of LIG fabrication are first briefly described for a detailed understanding of the lasing process.Sub-sequently,we summarize the physical device applications of LIGs and describe their advantages,including flexible electronics and energy harvesting.Then,chemical device applications are categorized into chemical sensors,supercapacitors,batteries,and electrocatalysis,and a detailed interpretation is provided.Finally,we present our vision of future developments and challenges in this exciting research field. 展开更多
关键词 laser-induced graphene flexible electronics energy harvesting chemical sensors SUPERCAPACITORS ELECTROCATALYSIS
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Two-dimensional laser-induced periodic surface structures formed on crystalline silicon by GHz burst mode femtosecond laser pulses 被引量:3
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作者 Shota Kawabata Shi Bai +2 位作者 Kotaro Obata Godai Miyaji Koji Sugioka 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2023年第1期212-220,共9页
Femtosecond laser pulses with GHz burst mode that consist of a series of trains of ultrashort laser pulses with a pulse interval of several hundred picoseconds offer distinct features in material processing that canno... Femtosecond laser pulses with GHz burst mode that consist of a series of trains of ultrashort laser pulses with a pulse interval of several hundred picoseconds offer distinct features in material processing that cannot be obtained by the conventional irradiation scheme of femtosecond laser pulses(single-pulse mode).However,most studies using the GHz burst mode femtosecond laser pulses focus on ablation of materials to achieve high-efficiency and high-quality material removal.In this study,we explore the ability of the GHz burst mode femtosecond laser processing to form laser-induced periodic surface structures(LIPSS)on silicon.It is well known that the direction of LIPSS formed by the single-pulse mode with linearly polarized laser pulses is typically perpendicular to the laser polarization direction.In contrast,we find that the GHz burst mode femtosecond laser(wavelength:1030 nm,intra-pulse duration:220 fs,intra-pulse interval time(intra-pulse repetition rate):205 ps(4.88 GHz),burst pulse repetition rate:200 kHz)creates unique two-dimensional(2D)LIPSS.We regard the formation mechanism of 2D LIPSS as the synergetic contribution of the electromagnetic mechanism and the hydrodynamic mechanism.Specifically,generation of hot spots with highly enhanced electric fields by the localized surface plasmon resonance of subsequent pulses in the bursts within the nanogrooves of one-dimensional LIPSS formed by the preceding pulses creates 2D LIPSS.Additionally,hydrodynamic instability including convection flow determines the final structure of 2D LIPSS. 展开更多
关键词 GHz burst laser-induced periodic surface structures(LIPSS) surface nanostructuring 2D nanostructures
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Electronic and thermal properties of Ag-doped single crystal zinc oxide via laser-induced technique 被引量:1
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作者 邢欢 王惠琼 +5 位作者 宋廷鲁 李纯莉 戴扬 傅耿明 康俊勇 郑金成 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第6期44-51,共8页
The doping of ZnO has attracted lots of attention because it is an important way to tune the properties of ZnO.Postdoping after growth is one of the efficient strategies.Here,we report a unique approach to successfull... The doping of ZnO has attracted lots of attention because it is an important way to tune the properties of ZnO.Postdoping after growth is one of the efficient strategies.Here,we report a unique approach to successfully dope the single crystalline ZnO with Ag by the laser-induced method,which can effectively further post-treat grown samples.Magnetron sputtering was used to coat the Ag film with a thickness of about 50 nm on the single crystalline ZnO.Neodymium-doped yttrium aluminum garnet(Nd:YAG)laser was chosen to irradiate the Ag-capped ZnO samples,followed by annealing at700℃for two hours to form ZnO:Ag.The three-dimensional(3D)information of the elemental distribution of Ag in ZnO was obtained through time-of-flight secondary ion mass spectrometry(TOF-SIMS).TOF-SIMS and core-level x-ray photoelectron spectroscopy(XPS)demonstrated that the Ag impurities could be effectively doped into single crystalline ZnO samples as deep as several hundred nanometers.Obvious broadening of core level XPS profiles of Ag from the surface to depths of hundred nms was observed,indicating the variance of chemical state changes in laser-induced Ag-doped ZnO.Interesting features of electronic mixing states were detected in the valence band XPS of ZnO:Ag,suggesting the strong coupling or interaction of Ag and ZnO in the sample rather than their simple mixture.The Ag-doped ZnO also showed a narrower bandgap and a decrease in thermal diffusion coefficient compared to the pure ZnO,which would be beneficial to thermoelectric performance. 展开更多
关键词 zinc oxide Ag-doping laser-induced technique XPS SIMS thermal diffusivity
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A data selection method for matrix effects and uncertainty reduction for laser-induced breakdown spectroscopy 被引量:1
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作者 龙杰 宋惟然 +1 位作者 侯宗余 王哲 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第7期82-89,共8页
Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superp... Severe matrix effects and high signal uncertainty are two key bottlenecks for the quantitative performance and wide applications of laser-induced breakdown spectroscopy(LIBS).Based on the understanding that the superposition of both matrix effects and signal uncertainty directly affects plasma parameters and further influences spectral intensity and LIBS quantification performance,a data selection method based on plasma temperature matching(DSPTM)was proposed to reduce both matrix effects and signal uncertainty.By selecting spectra with smaller plasma temperature differences for all samples,the proposed method was able to build up the quantification model to rely more on spectra with smaller matrix effects and signal uncertainty,therefore improving final quantification performance.When applied to quantitative analysis of the zinc content in brass alloys,it was found that both accuracy and precision were improved using either a univariate model or multiple linear regression(MLR).More specifically,for the univariate model,the root-mean-square error of prediction(RMSEP),the determination coefficients(R^(2))and relative standard derivation(RSD)were improved from 3.30%,0.864 and 18.8%to 1.06%,0.986 and 13.5%,respectively;while for MLR,RMSEP,R^(2)and RSD were improved from 3.22%,0.871 and 26.2%to 1.07%,0.986 and 17.4%,respectively.These results prove that DSPTM can be used as an effective method to reduce matrix effects and improve repeatability by selecting reliable data. 展开更多
关键词 laser-induced breakdown spectroscopy(LIBS) quantification UNCERTAINTY univariate/multivariate analysis matrix effects temperature matching
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Self-absorption effects of laser-induced breakdown spectroscopy under different gases and gas pressures 被引量:1
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作者 王崧宁 张殿鑫 +6 位作者 陈楠 何亚雄 张红 柯川 许涛 陈永亮 赵勇 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第2期155-162,共8页
The self-absorption effect is one of the main factors affecting the quantitative analysis accuracy of laser-induced breakdown spectroscopy.In this paper,the self-absorption effects of laserinduced 7050 Al alloy plasma... The self-absorption effect is one of the main factors affecting the quantitative analysis accuracy of laser-induced breakdown spectroscopy.In this paper,the self-absorption effects of laserinduced 7050 Al alloy plasma under different pressures in air,Ar,and N2have been studied.Compared with air and N2,Ar significantly enhances the spectral signal.Furthermore,the spectral self-absorption coefficient is calculated to quantify the degree of self-absorption,and the influences of gas species and gas pressure on self-absorption are analyzed.In addition,it is found that the spectral intensity fluctuates with the change of pressure of three gases.It can also be seen that the fluctuation of spectral intensity with pressure is eliminated after correcting,which indicates that the self-absorption leads to the fluctuation of spectral intensity under different pressures.The analysis shows that the evolution of optical thin spectral lines with pressure in different gases is mainly determined by the gas properties and the competition between plasma confinement and Rayleigh–Taylor instability. 展开更多
关键词 self-absorption coefficient ambient gases gas pressure laser-induced breakdown spectroscopy
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The comparison of manganese spectral lines for self-absorption reduction in LIBS using laser-induced fluorescence 被引量:1
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作者 唐云 李菁锋 +5 位作者 马世祥 胡桢麟 彭旭翔 周伟平 袁晓 沈萌 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第6期82-87,共6页
The detection of manganese(Mn)in steel by laser-induced breakdown spectroscopy(LIBS)provides essential information for steelmaking.However,self-absorption greatly disrupts the LIBS spectral lines of Mn with high conte... The detection of manganese(Mn)in steel by laser-induced breakdown spectroscopy(LIBS)provides essential information for steelmaking.However,self-absorption greatly disrupts the LIBS spectral lines of Mn with high content.In this study,to minimize self-absorption for Mn spectral lines in LIBS,laser-induced fluorescence(LIF)was applied.Compared with conventional LIBS,the self-absorption factors(α)of Mn I 403.08,403.31,and 403.45 nm lines were reduced by 90%,88%,and 88%,respectively;the root mean square errors of crossvalidation were decreased by 88%,85%,and 87%,respectively;the average relative errors were reduced by 93%,90%,and 91%,respectively;and average relative standard deviations were decreased by 29%,32%,and 33%,respectively.The LIBS-LIF was shown to successfully minimize the self-absorption effect and spectral intensity fluctuation and improve detection accuracy. 展开更多
关键词 laser-induced breakdown spectroscopy SELF-ABSORPTION LIBS-LIF
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Laser-Induced Graphene Conductive Fabric Decorated with Copper Nanoparticles for Electromagnetic Interference Shielding Application 被引量:1
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作者 刘琬玲 陈春晖 +6 位作者 海文清 毕思伊 蒋金华 邵慧奇 邵光伟 付少举 陈南梁 《Journal of Donghua University(English Edition)》 CAS 2023年第6期571-579,共9页
To meet the demands for flexible electromagnetic interference(EMI)shielding materials,a type of conductive fabric is prepared by generating three-dimensional(3D)porous laser-induced graphene(LIG)in situ on the surface... To meet the demands for flexible electromagnetic interference(EMI)shielding materials,a type of conductive fabric is prepared by generating three-dimensional(3D)porous laser-induced graphene(LIG)in situ on the surface of the aramid fabric(AF)and then electroless plating copper.After LIG treatment,the porous AF demonstrates admirable conductivity due to the generation of graphene.The superior surface resistance of the conductive fabric can reach 1.57Ω/sq after copper deposition,and the average EMI shielding effectiveness(SE)can reach 34.3 dB in a frequency range of 8.2 to 12.4 GHz,with the EMW absorption accounting for about 80%.The proposed technology provides a new idea for preparation of flexible EMI shielding materials. 展开更多
关键词 laser-induced graphene(LIG) electroless plating aramid fabric(AF) electromagnetic interference(EMI)
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Diagnostics of laser-induced plasma on carbon-based polymer material using atomic and molecular emission spectra
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作者 Jelena PETROVIC Dragan RANKOVIC +5 位作者 Miroslav KUZMANOVIC Jelena SAVOVIC Vasili KIRIS Alena NEVAR Mikhail NEDELKO Nikolai TARASENKO 《Plasma Science and Technology》 SCIE EI CAS CSCD 2023年第4期175-183,共9页
Time-integrated optical emission analysis of laser-induced plasma on Teflon is presented.Plasma was induced under atmospheric pressure air using transversely excited atmospheric CO_(2) laser pulses.Teflon is a C-based... Time-integrated optical emission analysis of laser-induced plasma on Teflon is presented.Plasma was induced under atmospheric pressure air using transversely excited atmospheric CO_(2) laser pulses.Teflon is a C-based polymer that is,among other things,interesting as a substrate for laser-induced breakdown spectroscopy analysis of liquid samples.This study aimed to determine the optimal experimental conditions for obtaining neutral and ionized C spectral lines and C2 and CN molecular band emission suitable for spectrochemical purposes.Evaluation of plasma parameters was done using several spectroscopic techniques.Stark profiles of appropriate C ionic lines were used to determine electron number density.The ratio of the integral intensity of ionic-to-atomic C spectral lines was used to determine the ionization temperature.A spectral emission of C2 Swan and CN violet bands system was used to determine the temperature of the colder,peripheral parts of plasma.We critically analyzed the use of molecular emission bands as a tool for plasma diagnostics and suggested methods for possible improvements. 展开更多
关键词 spectroscopy of laser-induced plasma laser-induced breakdown spectroscopy transversely excited atmospheric CO_(2)laser plasma diagnostics atomic and molecular emission spectra TEFLON
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Transmission effects of high energy nanosecond lasers in laser-induced air plasma under different pressures
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作者 胡蔚敏 尹凯欣 +4 位作者 王小军 杨晶 刘可 彭钦军 许祖彦 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第10期537-541,共5页
When a high energy nanosecond(ns)laser induces breakdown in the air,the plasma density generated in the rarefied atmosphere is much smaller than that at normal pressure.It is associated with a relatively lower absorpt... When a high energy nanosecond(ns)laser induces breakdown in the air,the plasma density generated in the rarefied atmosphere is much smaller than that at normal pressure.It is associated with a relatively lower absorption coefficient and reduces energy loss of the laser beam at low pressure.In this paper,the general transmission characterizations of a Joule level 10 ns 1064 nm focused laser beam are investigated both theoretically and experimentally under different pressures.The evolution of the electron density(n_(e)),the changes in electron temperature(T_(e))and the variation of laser intensity(I)are employed for numerical analyses in the simulation model.For experiments,four optical image transfer systems with focal length(f)of 200 mm are placed in a chamber and employed to focus the laser beam and produce plasmas at the focus.The results suggest that the transmittance increases obviously with the decreasing pressure and the plasma channels on the transmission path can be observed by the self-illumination.The simulation results agree well with the experimental data.The numerical model presents that the maximum n_e at the focus can reach 10^(19)cm^(-3),which is far below the critical density(n_(c)).As a result,the laser beam is not completely shielded by the plasmas. 展开更多
关键词 laser-induced plasma high energy nanosecond laser pulse rarefied atmosphere
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