Late Paleozoic Fluid Systems and Their Ore-forming Effects in the Yuebei Basin,Northern Guangdong,China

Based on detailed and systematic researches of the geology of ore deposits, fluid inclusions and isotope geochemistry etc., and regarding the Late Paleozoic fluid system of the Yuebei Basin as an integrated object in this paper, we have revealed the temporo-spatial evolution law of the basin＇s fluid system and discussed its ore-forming effects by simulating and analyzing the distribution of ore-forming elements, the fluid thermodynamics and dynamics of evolution processes of this basin. The results show that Late Paleozoic ore-forming fluid systems of the Yuebei Basin include four basic types as follows. （1） The sea floor volcanic-exhalation system developed during the rapid basin slip-extension stage in the Mid-Late Devonian, which affected the Dabaoshan region. It thus formed the Dabaoshan-type Cu-Pb-Zn-Fe sea floor volcanic-exhalation sedimentary deposits. （2） The compaction fluid system developed during the stable spreading and thermal subsidence-compression stage of the basin in the Mid-Late Devonian. The range of its effects extended all over the whole basin. It resulted in filling-metasomatic deposits, such as the Hongyan-type pyrite deposits and pyrite sheet within the Fankou-type Cu-Pb-Zn-S deposits. （3） The hot water circulation system of sea floor developed during the stage of basin uplifting and micro-aulacogen from the late Late Carboniferous to Middle Carboniferous. The range of its effects covered the Fankou region. It thus formed MVT deposits, such as the main orebody of the Fankou-type Pb-Zn-S deposits. （4） The gravity fluid system developed during the stage of fold uplifting and the basin closed from Middle Triassic to Jurassic, forming groundwater hydrothermal deposits, e.g. the veinlet Pb-Zn-calcite orebodies of the Fankou-type Pb-Zn- S deposits. Migration and concentration of the ore-forming fluids were constrained by the state of temporo-spatial distribution of its fluid potential. Growth faults not only converged the fluids and drove them to move upwards, but also the fluids often crossed the faults to the edges of the basin at the bottom of these faults and the lithologic interfaces, and even migrated to the basin＇s edges from top to bottom along the faults, which may be one of the basic reasons for the stratabound deposits to cluster mainly along the contemporaneous faults on the inner border of the basin. The superposed mineralization resulting from the multi-stage activity of contemporaneous faults and ore-forming fluid systems in the basin may be one of the key factors for forming superlarge ore deposits.

Tectonic Framework of Late Paleozoic Intrusions in Xingxingxia： Implications for Final Closure of South Tianshan Ocean in East Tianshan

This work carried out systematic geological field investigation, petrography observation, zircon geochronology and whole rock geochemistry on Late Paleozoic intrusions in the Xingxingxia region near the Xinjiang-Gansu provincial boundary, western China, aiming to constrain the Late Paleozoic tectonic framework of the Xingxingxia region and the final closure time of South Tianshan Ocean in the East Tianshan. The Xingxingxia area is located in the east part of the Tianshan orogen, and adjacent to the north of the Tarim Basin. The Late Paleozoic magma activities in the Xingxingxia region can be mainly divided into three stages. The first stage includes intrusive magma activities under a collision setting between Late Ordovician to the Late Devonian. The second stage is intrusive magma activities under a subduction setting during（304±3）–（278±3） Ma, and the third stage involves intrusive magma activities under a collision and post-collision setting during（268±5）–（259.9±2.6） Ma. The final suture zone of South Tianshan Ocean should be between the Central Tianshan Block and South Tianshan accretionary complex. Based on previous work, both the first stage magma activities（i.e., intrusive magmatic activities between the Late Ordovician to Late Devonian） and the Hongliuhe ophiolitic complex indicate a close event between Central Tianshan Block and South Tianshan Accretionary Complex. The 304±3 Ma dioritic metamorphic gneiss of the XingX ingxia complex and the 278±3 Ma diorite are all island arc calc-alkaline rocks, the 289±3 Ma gabbro is island arc tholeiitic gabbro formed by magma from metasomatic enrichment mantle. All these results indicate that the second stage of magmatic activities is under a subduction setting. The third stage magma activities i.e. the granitic magma activities of（268±5）–（259.9±2.6） Ma occurred at a transitional setting from compressional to post-collision extensional tectonic setting. Thus, around（268±5）–（260±3） Ma, the final closure of the South Tianshan Ocean occurred and the Tianshan orogen shifted into the intracontinental evolution stage. During and after the closure process, a wide range of metamorphism and large dextral strike-slip faults developed.

End Late Paleozoic tectonic stress field in the southern edge of Junggar Basin

This paper presents the end Late Paleozoic tectonic stress field in the southern edge of Junggar Basin by interpreting stress-response structures （dykes, folds, faults with slickenside and conjugate joints）. The direction of the maximum principal stress axes is interpreted to be NW-SE （about 325°）, and the accommodated motion among plates is assigned as the driving force of this tectonic stress field. The average value of the stress index Rt is about 2.09, which indicates a variation from strike-slip to compressive tectonic stress regime in the study area during the end Late Paleozoic period. The reconstruction of the tectonic field in the southern edge of Junggar Basin provides insights into the tectonic deformation processes around the southern Junggar Basin and contributes to the further understanding of basin evolution and tectonic settings during the culmination of the Paleo- zoic.

Late Paleozoic Sequence-Stratigraphic Frameworks and Sea Level Changes in Dianqiangui Basin and Its Adjacent Areas with Systematic Revision of Regional Unconformities

The formation process of the Dianqiangui basin, a special basin, occurred after the Caledonian orogeny, in the south of Guizhou, the west of Guangxi and the southeast of Yunnan, experienced three periods: it began in the Devonian, persisted in the Carboniferous, and became fiercer in the Permian. Controlled by syndepositional fault-zones, varieties of isolated carbonate platforms, large and small, were developed in the background of a deep-water basin, namely, an inter-platform ditch. And a special paleogeographical Late Paleozoic pattern marked by “platform-basin-hill-trough” was produced in both the Dianqiangui basin and its adjacent areas. Affected by regional tectonic activities and the global changes in the sea level, the platform carbonates and coal measures superimposed each other cyclically on the attached platform. The reef-building on the isolated platform and the margin of the attached platform corresponds to the development of the shale succession in the deep-water basin. All of these elementary characteristics reflect a regular and sophisticated filling succession of the Dianqiangui basin, a result of the dual controls of the regionally tectonic activities and the eustacy. Based on the two elementary features of the third-order sequences, i.e. the regularity of sedimentary-facies succession in space and the simultaneity of environmental changes in time, 25 third-order sequences could be discerned in the Upper Paleozoic strata in the Dianqiangui basin and its adjacent areas. On the basis of the two kinds of facies-changing surfaces and the two kinds of diachronisms in stratigraphic records, the regional Late Paleozoic sequence-stratigraphic framework in the Dianqiangui basin and its adjacent areas can be established. There are two types of facies-changing surfaces and two types of diachronisms in stratigraphic records: the static type, a result of the change in sedimentary facies in space, and the dynamic type, a result of the change in time. These two types of facies-changing surfaces led to the generation of the two types of diachronisms: the diachronism of facies-changing surfaces that was formed by the static facies-changing surfaces, and the diachronism of punctuated surfaces that was formed by the dynamic facies-changing surfaces. The two types of facies-changing surfaces and the two types of diachronisms in stratigraphic records are the key to the establishment of the sequence-stratigraphic framework. The sequence boundaries could be divided geologically into four types: tectonic unconformity, sedimentary unconformity, drowned unconformity and their correlative surfaces. All of these four types can be further grouped into exposed punctuated surfaces and deepened punctuated surfaces. The tectonic unconformity is similar to Type Ⅰ sequence boundary, and the sedimentary unconformity is similar to Type Ⅱ sequence boundary defined by Vail et al.. In terms of sequence stratigraphy, the tectonic unconformities of the Ziyun movement, the Qiangui epeirogeny and the Dongwu revolution as well as the drowned unconformity in the transitional period from the Permian to the Triassic can be systematically defined and their geological characteristics are briefly presented.

Plate tectonics in the late Paleozoic

As the chronicle of plate motions through time, paleogeography is fundamental to our understanding of plate tectonics and its role in shaping the geology of the present-day. To properly appreciate the history of tectonics--and its influence on the deep Earth and climate-it is imperative to seek an accurate and global model of paleogeography. However, owing to the incessant loss of oceanic lithosphere through subduction, the paleogeographic reconstruction of ＇full-plates＇ （including oceanic lithosphere） becomes increasingly challenging with age. Prior to 150 Ma ~60% of the lithosphere is missing and re- constructions are developed without explicit regard for oceanic lithosphere or plate tectonic principles; in effect, reflecting the earlier mobilistic paradigm of continental drift. Although these ＇continental＇ re- constructions have been immensely useful, the next-generation of mantle models requires global plate kinematic descriptions with full-plate reconstructions. Moreover, in disregarding （or only loosely applying） plate tectonic rules, continental reconstructions fail to take advantage of a wealth of additional information in the form of practical constraints. Following a series of new developments, both in geo- dynamic theory and analytical tools, it is now feasible to construct full-plate models that lend themselves to testing by the wider Earth-science community. Such a model is presented here for the late Paleozoic （410-250 Ma） together with a review of the underlying data. Although we expect this model to be particularly useful for numerical mantle modeling, we hope that it will also serve as a general framework for understanding late Paleozoic tectonics, one on which future improvements can be built and further tested.

On Geodynamic Evolution of Simao Region (Southwestern Yunnan, China) during Late Paleozoic and Triassic

Over the last years, the Simao region, southwestern Yunnan, China, turned out to be a very promising target to elucidate plate tectonic processes around the Permian Triassic boundary within the Tethyan domain of Asia. New data from this area reveal that Upper Paleozoic compressional deformations occurred along the Lancangjiang and in areas to the east. Along Lancangjiang, an angular unconformity is exposed, which separates quartz phyllites—formed during a Carboniferous tectono metamorphic event—from Triassic red beds to roofing rhyolites. The acidic volcanics were often said to be remnants of a volcanic arc that was active during the Triassic subduction and closure of an oceanic realm along the Lancangjiang zone. According to our new data, however, these volcanics indicate most probably an Upper Triassic stage of rifting. In the Yunxian anticline (NW of Simao), an angular unconformity of intra Permian age is exposed where Carboniferous to lower Middle Permian strata, which were deposited in a rather deep basin, are unconformably overlain by a shallow marine sequence of upper Middle to Upper Permian sediments. The angular unconformity is of the same age as the syn orogenous sediments first described and dated from the Phetchabun region in Thailand and hence a convincing argument for a Late Variscan orogeny forming an extensive zone of mountain building that can be traced through the central parts of mainland Southeast Asia.

Late Paleozoic to Mesozoic extension in southwestern Fujian Province, South China： Geochemical, geochronological and Hf isotopic constraints from basic-intermediate dykes

The tectonic evolution of SE China block since late Paleozoic remains debated. Here we present a new set of zircon U-Pb geochronological, Lu-Hf isotopic data and whole-rock geochemistry for two stages of basicintermediate dykes from the southwestern Fujian. The samples were collected from the NE-trending （mainly diabases） and NW-trending （mainly diabasic diorites） dykes and yielded zircon U-Pb ages of 315 and 141 Ma, with eHf（t） values of -8.90 to 7.49 and -23.39 to -7.15 （corresponding to TDM2 values of 850 to 1890 Ma and 737 to 2670 Ma）, respectively. Geochemically these rocks are characterized by low TiO2 （0.91-1.73 wt.%） and MgO （3.04-7.96 wt.%）, and high A1203 （12.5-16.60 wt.%） and K20 （0.60-3.63 wt.%）. Further they are enriched in LREEs and LILEs （Rb, Ba, Th and K）, but depleted in HFSEs （Nb, Ta and Zr）. The tectonic discrimination analysis revealed that the dykes were formed in an intraplate extensional envi- ronment. However, the NW trending dykes show crust-mantle mixed composition, which indicate an extensional tectonic setting with evidence for crustal contamination. The SE China block experienced two main stages of extensional tectonics from late Carboniferous to early Cretaceous. The tectonic evolution of the SE China block from late Devonian to Cretaceous is also evaluated.

Sedimentology and sequence stratigraphy of the mixed clastic-carbonate deposits in the Late Paleozoic icehouse period:A case study from the northern Qaidam Basin

The widely-developed,mixed clastic-carbonate succession in the northern Qaidam Basin records the paleo-environment changes under the glacial activity during the Late Paleozoic icehouse period in the context of regional tectonic stability,however,the depositional environment and sequence stratigraphy characteristics of the mixed deposits is rarely reported and still not clear.Combined the latest drilling wells data,we analyzed the sedimentary and stratigraphic characterization of the mixed strata via detailed field outcrops and core observations and thin section microscopic observations and recognized three depositional systems,including progradational coastal system,incised valley system,and carbonate-dominated marine shelf system,and identified four third-order sequences,SQ1,SQ2,SQ3 and SQ4,consisting of LST,TST,and HST.The depositional environment is overall belonged to marine-continental transition context and shifted from marine to continental environment frequently,showing an evolutionary pattern from marine towards terrestrial-marine transition and then back into the marine environment again in the long-term,which was controlled by the regional tectonic subsidence and the high-frequency and large-amplitude sea-level changes due to the Late Paleozoic glacial activity.The result is of significance in understanding the evolution of the Qinghai-Tibet Plateau and the sedimentation-climate response.

Geothermal Field and Tectono-Thermal Evolution since the Late Paleozoic of the Qaidam Basin,Western China

The Qaidam basin is the largest intermountain basin inside Tibet, and is one of the three major petroliferous basins in western China. This study discussed the geothermal field and tectono-thermal evolution of the basin, in an effort to provide evidence for intracontinental or intraplate continental dynamics and basin dynamics, petroleum resources assessment, and to serve petroleum production.

Detrital zircon constraints on late Paleozoic tectonism of the Bogda region(NW China)in the southern Central Asian Orogenic Belt

The Chinese North Tianshan(CNTS)in the southern part of the Central Asian Orogenic Belt(CAOB)has undergone multistage accretion-collision processes during Paleozoic time,which remain controversial.This study addresses this issue by tracing the provenance of Late Paleozoic sedimentary successions from the Bogda Mountain in the eastern CNTS through U-Pb dating and Lu-Hf isotopic analyses of detrital zircons.New detrital zircon U-Pb ages(N=519)from seven samples range from 261±4 Ma to 2827±32 Ma.The most prominent age peak is at 313 Ma and subordinate ages vary from 441 Ma to 601 Ma,with some Precambrian detrital zircon ages(~7%)lasting from 694 Ma to 1024 Ma.The youngest age components in each sample yielded weighted mean ages ranging from 272±9 Ma to 288±5 Ma,representing the maximum depositional ages.These and literature data indicate that some previously-assumed"Carboniferous"strata in the Bogda area were deposited in the Early Permian,including the Qijiaojing,Julideneng,Shaleisaierke,Yangbulake,Shamaershayi,Liushugou,Qijiagou,and Aoertu formations.The low maturity of the sandstones,zircon morphology and provenance analyses indicate a proximal sedimentation probably sourced from the East Junggar Arc and the Harlik-Dananhu Arc in the CNTS.The minor Precambrian detrital zircons are interpreted as recycled materials from the older strata in the Harlik-Dananhu Arc.Zircon EHf(t)values have increased since^408 Ma,probably reflecting a tectonic transition from regional compression to extension.This event might correspond to the opening of the Bogda intraarc/back arc rift basin,possibly resulting from a slab rollback during the northward subduction of the North Tianshan Ocean.A decrease of zirconεHf(t)values at^300 Ma was likely caused by the cessation of oceanic subduction and subsequent collision,which implies that the North Tianshan Ocean closed at the end of the Late Carboniferous.

Geochemistry of Sulfur and Hazardous Elements in Late Paleozoic Coals and Partings from Taozao Coalfield, Shandong Province, China

The analyses of different sulfur forms, the trace elements in pyrites using electron microprobe and the trace elements in coal using INAA (instrumental neutron activation analysis) of the Late Paleozoic coals from the Taozao coalfield in Shandong Province, China, conclude that most sulfur (>75 %) in high-sulfur coal of Taiyuan Formation occurred as pyrite, in which many hazardous elements co-existed and their concentrations varied with their geological origin. The concentrations of hazardous elements in high-sulfur coals from Taiyuan Formation, composing mainly of Cu, As, U, Pb, Mo and Co, are much higher than those in the low-sulfur coals from Shanxi Formation and Shihezi Formation, because the influence of seawater during and after coal accumulation in Taiyuan Formation is stronger than those in Shanxi and Shihezi formations. Moreover, the element As is related to Fe, and both elements exist mainly in the form of pyrite. The element U is richer in the coal influenced by seawater. In addition, the coal affected by the magmatism contains more U, too. When high-sulfur coals are processed with heavy media washing to remove sulfur and minerals, the majority of hazardous elements will also be removed from the coals.

Late Paleozoic alkaline magmatism in Western Transbaikalia,Russia:Implications for magma sources and tectonic settings

This paper presents the results of geochronological(40Ar-39Ar,U-Pb SHRIMP Ⅱ),petrological and geochemical studies of the Late Paleozoic complexes of alkaline rocks(Zimovechinsky,Tuchinsky and Koma) located within the Vitim Plateau(the western part of the Mongol-Okhotsk Orogenic Belt).The rocks were formed at 310-280 Ma.It is coeval with Late Paleozoic magmatism within the Central Asian Orogenic Belt.The εNd(T) values show large variations from-2.1 to +3.3 as well as the initial Sr(I) isotopic ratios from 0.7042 to 0.7138,that demonstrate strong isotopic heterogeneity of the magmatic source.The geochemical characteristics of the rocks show pronounced positive Pb and negative Ti,Zr-Hf anomalies that can be explained by involvement of the subducted component in primary melts.The rocks intruded in a setting of extension at the active continental margin of the Siberian Craton during subduction of Mongol-Okhotsk oceanic crust under the Siberian Craton.

Lithospheric dripping in a soft collision zone:Insights from late Paleozoic magmatism suites of the eastern Central Asian Orogenic Belt

The closure of Paleo-Asian Ocean is considered to have occurred along the Solonker Suture in the southernmost segment of the Central Asian Orogenic Belt(CAOB),the largest Phanerozoic accretionary orogen on the globe.The suture branches to the east to form the northern Hegenshan-Heihe Suture and the southern Solonker-Changchun Suture.The Hegenshan-Heihe Suture is an ideal natural laboratory for studying the post-collisional geodynamic processes operating in a soft collision zone driven by divergent double-sided subduction.Here we report results from an integrated study of the petrology,geochronology,geochemistry,and Sr-Nd-Hf isotopic compositions of the Early Carboniferous-Early Permian mag-matic suite in the Hailar Basin of the Xing'an-Erguna Block.The Early Carboniferous igneous rocks are represented by 356-349 Ma andesitic tuffs,exhibiting typical subduction-related features,such as enrichment in large-ion lithophile elements and depletion in high-field-strength elements.These features,together with the relatively depleted Sr-Nd-Hf isotopic compositions,constant Nb/Y values,but highly variable Rb/Y and Ba values indicate that these rocks were generated by partial melting of a depleted mantle wedge metasomatized by slab-derived fluids.The Late Carboniferous-Early Permian magmatic suite(317-295 Ma)is characterized by high Sr contents(313-1080 ppm)and low Y contents(5-13 ppm),and these can be subdivided into calc-alkaline adakitic rocks and high-K calc-alkaline adakitic rocks.The calc-alkaline adakitic rocks have higher values of Sr/Y,(Sm/Yb)_(source normalized),and Mg#,and lower values of Y,_(Ybsource normalized),and K_(2)O/Na_(2)O than the high-K calc-alkaline adakitic rocks,which suggests that the former was generated by partial melting of foundered lower continental crust and the latter by partial melting of normal lower continental crust.Based on our new data,in conjunction with those in previous studies,we conclude that the tectonic evolution of the Hegenshan-Heihe Suture involved Early Carboniferous double-sided subduction of the Nenjiang Ocean,latest Early Carboniferous soft collision between the Xing'an-Erguna and Songliao blocks,and Late Carboniferous-Early Permian post-collisional extension.We also propose a new geodynamic scenario in which removal of the lithospheric root might have occurred in a soft collision zone during the post-collision period via repeated and localized lithospheric dripping,which results from combined effects of hydration weakening of the lithosphere caused by pre-collision subduction and asthenospheric stirring triggered by slab break-off.

Geochemistry of the Late Paleozoic cherts in the Youjiang Basin:Implications for the basin evolution

We analyzed the major and rare earth element compositions of siliceous deposits from the Upper Devonian Liujiang Formation,Lower Carboniferous Luzhai Formation,Lower-Middle Permian Sidazhai Formation and Tapi Formation,which are widely distributed as bedded cherts in the interplatform basinal successions of the Youjiang Basin.The Liujiang Formation and Luzhai Formation cherts generally have high Al/(Al+Fe+Mn) values(0.38-0.94) and are non-hydrothermal cherts.These cherts are generally characterized by moderately negative Ce anomalies and high Y/Ho values relatived to PAAS,indicating that the Youjiang Basin might have evolved into an open rift basin during the Late Devonian-Early Carboniferous.The Sidazhai Formation cherts from Ziyun generally have high Al/(Al+Fe+Mn) values(0.60-0.78),suggesting negligible contribution from a hydrothermal component.The Sidazhai Formation cherts from Hechi and the Tapi Formation cherts from Malipo generally have low Al/(Al+Fe+Mn) values(0.09-0.41),indicating an intense hydrothermal input.Relatived to the Sidazhai Formation cherts,the Tapi Formation cherts have higher Ce/Ce*values(0.68±0.19) and lower Y/Ho values(41.83±13.27),which may be affected by the terrigenous input from the Vietnam Block.The Sidazhai Formation cherts from Ziyun and Hechi exhibit negative Ce anomalies(0.43±0.12,0.33±0.17,respectively) with high Y/Ho values(57.44±16.20,46.02±4.27,respectively),resembling the geochemical characteristics of open-ocean basin cherts.These cherts were deposited on a passive continental margin adjacent to the Babu branch ocean,which may have contributed to upwelling.Detailed spatial studies on geochemical characteristics of the Late Paleozoic cherts can unravel the evolution of the Youjiang Basin.

Variabilities of carbonateδ13C signal in response to the late Paleozoic glaciations,Long’an,South China

An integrated study of biostratigraphy,microfacies,and stable carbon isotope stratigraphy was carried out on the late Famennian–early Asselian carbonates of the Long’an section in Guangxi,South China.Stable carbon isotope studies in the Long’an section have revealed four major positive shifts ofδ13C values in the Carboniferous strata in South China.The first shift occurred in the Siphonodella dasaibaensia zone in the Tournaisian,with an amplitude of 4.19‰.The second shift occurred near the Visean/Serpukhovian boundary,with an amplitude of 2.63‰.The third shift occurred in the Serpukhovian,with an amplitude of 3.95‰.The fourth shift occurred in the Kasimovian,with an amplitude of 3.69‰.Furthermore,there were several brief positiveδ13C shifts during the late Famennian to early Tournaisian.All of these shifts can be well correlated globally,and each corresponds to sea-level regressions in South China and Euro-America,indicating increases in ocean primary productivity and global cooling events.Chronologically,the four major positive excursions ofδ13C,together with several brief positiveδ13C shifts that were observed during the late Famennian to the early Tournaisian,correspond to the well-accepted Glacial I,II,and III events.

Late Carboniferous-Early Permian Sequence Stratigraphy and Depositional Evolution in the Northeast Ordos Basin,North China

Sequence stratigraphical analysis was applied to the Upper Carboniferous-Lower Permian sedimentary succession of the northeastern Ordos Basin, north China based on data acquired from ten entire logging curves and eight outcrops. The facies framework of the lithostratigraphical unit, the Taiyuan Formation comprises seven facies in two facies associations, varying from fluvio-delta to shelf-barrier islands. The facies are presented within a chronostratigraphical framework, linked by systems tract, which in turn are limited by flooding surfaces and sequence boundaries. Six third-order depositional sequences are recognised, bounded by six type 2 unconformities. An upwards-shallowing epicontinental sea sedimentary model is created, which consists of a sandstone, coal seam and carbonate succession.

Zircon SHRIMP U–Pb geochronology,geochemistry,and geological significance of dacite in the Zhesang gold district,southeast Yunnan Province,China

The Late Paleozoic and Mesozoic tectonic framework of the Nanpanjiang Basin has much been disputed.Herein,the middle-acid volcanic rock,dacite,exposed to the Zhesang gold district,southeast Yunnan Province,has been analyzed.The results show that the dacite belongs to a calc-alkaline series,SiO_(2)contents range from 62.79 to 76.66 wt%.Zircon SHRIMP U–Pb dating of dacite demonstrates that they were formed in the Early Triassic(247.8±1.7 Ma,MSWD=1.2).All samples exhibit enrichment in LILE(e.g.Rb,K,Th,and U),and depletion in HFSE(e.g.Nb,Ta,and Ti),which has the geochemical affinity of I-type granite.La–La/Sm and La–La/Yb discrimination diagrams show that the partial melting,mainly of the mafic lower crust,of rocks,plays a major role in the formation process.The dacite has low initial ^(87)Sr/^(86)Sr ratios(0.706954 to 0.708589)and negative ε_(Nd)(t)values(-11.77 to-10.88).Zircons in dacite have ε_(Hf)(t)values of-16.2 to-8.3,and the two-stage Hf model ages are 1799–2301 Ma,mostly concentrated between 1800 and 1900 Ma,indicating that the magma source area is the reconstructed ancient lower crust mixed with some mantle materials,and crystal fractionation process underwent in the late stage of magma migration.This study reveals that the arc-volcanic rocks of the Early Triassic in the southern margin of the Nanpanjiang Basin were formed by the subduction of the Late Paleozoic ocean basin within the border region between China and Vietnam.

Geochemistry,Nd Isotopic Characteristics of Metamorphic Complexes in Northern Hebei:Implications for Crustal Accretion

The middle segment of the northern margin of the North China Craton （NCC） consists mainly of metamorphosed Archean Dantazi Complex, Paleoproterozoic Hongqiyingzi Complex and unmetamorphosed gabbro-anorthosite-meta-alkaline granite, as well as metamorphosed Late Paleozoic mafic to granitoid rocks in the Damiao-Changshaoying area. The -2.49 Ga Dantazi Complex comprises dioritic-trondhjemitic-granodoritic-monzogranitic gneisses metamorphosed in amphibolite to granulite facies. Petrochemical characteristics reveal that most of the rocks belong to a medium- to high-potassium calc-alkaline series, and display Mg^# less than 40, right-declined REE patterns with no to obviously positive Eu anomalies, evidently negative Th, Nb, Ta and Ti anomalies in primitive mantlenormalized spider diagrams, εNd（t）=＋0.65 to -0.03, and depleted mantle model ages TDM=2.78-2.71 Ga. Study in petrogenesis indicates that the rocks were formed from magmatic mixing between mafic magma from the depleted mantle and granitoid magma from partial melting of recycled crustal mafic rocks in a continental margin setting. The 2.44-2.41 Ga Hongqiyingzi Complex is dominated by metamorphic mafic-granodioritic-monzogranitic gneisses, displaying similar petrochemical features to the Dantazi Complex, namely medium to high potassium calc-alkaline series, and the mafic rocks show evident change in LILEs, negative Th, Nb, Ta, Zr anomalies and positive P anomalies. And the other granitiod samples also exhibit negative Th, Nb, Ta, P and Ti anomalies. All rocks in the Hongqiyingzi Complex show right-declined REE patterns without Eu anomaly. The metamorphic mafic rocks with εNd（t） = -1.64 may not be an identical magmatic evolution series with granitoids that have εNd（t） values of ＋3.19 to ＋1.94 and TDM ages of 2.55-2.52 Ga. These granitic rocks originated from hybrid between mafic magma from the depleted mantle and magma from partial melting of juvenile crustal mafic rocks in an island arc setting. All the -311 Ma Late Paleozoic metamorphic mafic rocks and related granitic rocks show a medium-potassium calc-alkaline magmatic evolution series, characterized by high Mg^#, obviously negative Th, Nb, Ta anomalies and positive Sr anomalies, from no to strongly negative Ti anomalies and flat REE patterns with εNd（t） = ＋8.42, implying that the maflc magma was derived from the depleted mantle. However the other granitic rocks are characterized by right-declined REE patterns with no to evidently positive Eu anomalies, significantly low εNd（t） = -13.37 to -14.04, and TDM=1.97-1.96 Ga, revealing that the granitoid magma was derived from hybrid between maflc magma that came from -311 Ma depleted mantle and granitoid magma from Archean to Early Paleoproterozoic ancient crustal recycling. The geochemistry and Nd isotopic characteristics as well as the above geological and geochronological results indicate that the middle segment of the northern margin of the NCC mainly experienced four crustal growth episodes from Archean to Late Paleozoic, which were dominated by three continental marginal arc accretions （-2.49, -2.44 and 311 Ma）, except the 1.76-1.68 Ga episode related to post-collisional extension, revealing that the crustal accretion of this segment was chiefly generated from arc accretion and amalgamation to the NCC continental block.

Structural,Kinematic and Geochronological Study of the Main Tianshan Shear Zone in the Borohoro Ranges,NW China

The western segment of the Main Tianshan shear zone(MTSZ)branches into three major dextral strike-slip shear zones in the Borohoro Ranges,northwestern China.Mylonitic rocks within these zones exhibit vertical foliations,subhorizontal lineations,and dextral kinematics.The microstructures and CPO patterns of calcite and quartz in the tectonites suggest shearing at temperatures of 200℃ to 500℃ or above.The amount of dextral displacement along the zones is less than 100 km.LA-ICP-MS U-Pb dating of zircons from some pre-kinematic granites gave ages of 364-325 Ma and 316 Ma,and zircons from a syn-kinematic leucogranite gave an age of 291 Ma.We propose that dextral shearing along the MTSZ started in the earliest Permian.Our data indicate that collision between the Yili and Junggar plates might have finished before 325 Ma or 316 Ma,with a tectonic transformation from 325 Ma to 300 Ma,resulting in intracontinental transpression from 300 Ma or 291 Ma.We suggest that the formation of the Kazakhstan orocline(KO)took place in two stages,with the early stage of bending driven by convergence related to oblique subduction,and the late stage possibly associated with lateral disarticulation as a result of the dextral strike-slip shear zones.

Water-Flux Melting of Amphibolite in Paleozoic Leucogranite from the North Qinling,Central China:Implication for Post Collisional Setting

Paleozoic granites can provide important insights of crustal differentiation and collision process of the North Qinling terrane. The Dafanggou leucogranites that intruded in the Qinling Complex is a Paleozoic granite with zircon U-Pb age of 404±6.4 Ma(MSWD=0.13, n=9). The leucogranites display moderate SiO2(68.4 wt.% to 71.7 wt.%) content and high Na2O/K2O(1.07 to 2.74) and Sr/Y(42 to 65) ratios, and low A/CNK(1.04 to 1.08) and Rb/Sr(0.09 to 0.16) ratios. Combined with negative ε(Nd)(t)(-10.4) and ε(Hf)(t)(-9.35 to-0.25) values and ancient TDM2 ages(1.2 to 1.7 Ga), suggesting the leucogranite are derived from ancient amphibolitic crust in the Qinling Group. In addition, the absence of coeval mafic igneous rocks or mafic enclaves occurred in the Dafanggou pluton and the low T(Zrn)(~700 ℃) of leucogranites preclude that the leucogranites derived from high temperature dehydration melting of amphibolite. Thus, we propose that the occurrence of the Dafanggou leucogranite indicates that water-flux melting of middle-lower crust in postcollision setting may be a potential model for the genesis of granites in collisional orogenic belt.