A novel nonlinear multi-input multi-output MIMO detection algorithm is proposed which is referred to as an ordered successive noise projection cancellation OSNPC algorithm. It is capable of improving the computation p...A novel nonlinear multi-input multi-output MIMO detection algorithm is proposed which is referred to as an ordered successive noise projection cancellation OSNPC algorithm. It is capable of improving the computation performance of the MIMO detector with the conventional ordered successive interference cancellation OSIC algorithm. In contrast to the OSIC in which the known interferences in the input signal vector are successively cancelled the OSNPC successively cancels the known noise projections from the decision statistic vector. Analysis indicates that the OSNPC is equivalent to the OSIC in error performance but it has significantly less complexity in computation.Furthermore when the OSNPC is applied to the MIMO detection with the preprocessing of dual lattice reduction DLR the computational complexity of the proposed OSNPC-based DLR-aided detector is further reduced due to the avoidance of the inverse of the reduced basis of the dual lattice in computation compared to that of the OSIC-based one. Simulation results validate the theoretical conclusions with regard to both the performance and complexity of the proposed MIMO detection scheme.展开更多
The development of electrocatalysts for the oxygen reduction reaction(ORR) that bears high selectivity,exceptional activity,and long-term stability is crucial for advancing various green energy technologies.Intermetal...The development of electrocatalysts for the oxygen reduction reaction(ORR) that bears high selectivity,exceptional activity,and long-term stability is crucial for advancing various green energy technologies.Intermetallics composed of platinum and transition metals are considered to be promising candidates for this purpose.However,they typically face challenges such as unfavorable intrinsic activity and a propensity for particle aggregation,diminishing their ORR performance.Against this backdrop,we present our findings on a N-doped carbon confined Pt_(3)Co intermetallic doped with p-block metal tin(Pt_(3)Co_(x)Sn_(1-x)/NC).The introduction of Sn induces lattice strain due to its larger atomic size,which leads to the distortion of the Pt_(3)Co lattice structure,while the coupling of carbon polyhedra inhibits the particle aggregation.The optimized Pt_(3)Co_(0.8)Sn_(0.2)/NC catalyst demonstrates an impressive half-wave potential of 0.86 V versus RHE,surpassing both Pt_(3)Co/NC and Pt_(3)Sn/NC catalysts.Moreover,the Pt_(3)Co_(0.8)Sn_(0.2)/NC exhibits a mass-specific activity as high as 1.4 A mg_(Pt)^(-1),ranking it in the top level among the intermetallicsbased ORR electrocatalysts.When further employed as a cathode material in a self-assembled zinc-air battery,it shows stable operation for over 80 h.These results underscore the significant impact of lattice strain engineering through the strategic doping of p-block metal in the carbon-confined Pt_(3)Co intermetallic,thereby enhancing the catalytic efficiency for the ORR.展开更多
Efficient massive MIMO detection for practical deployment, which is with spatially correlated channel and high-order modulation, is a challenging topic for the fifth generation mobile communication(5 G). In this paper...Efficient massive MIMO detection for practical deployment, which is with spatially correlated channel and high-order modulation, is a challenging topic for the fifth generation mobile communication(5 G). In this paper, we propose a lattice reduction aided expectation propagation(LRA-EP) algorithm for massive MIMO detection. LRA-EP applies expectation propagation in lattice reduced MIMO system to approach the distribution of lattice reduced constellation point by iterative refinement on its parameters(mean and covariance). The parameter refinement is based on the lattice reduced, well-conditioned MIMO channel. Numerical result shows that LRA-EP outperforms classic EP based MIMO detection(EPD) with 5～7 dB in terms of required signalto-noise ratio(SNR) for 1% packet error rate in spatially correlated channel for 256-QAM. We also show that LRA-EP has lower computation complexity than EPD.展开更多
The lattice-reduction （LR） has been developed to im- prove the performance of the zero-forcing （ZF） precoder in multiple input multiple output （MIMO） systems. Under the assumptions of uncorrelated flat fading ch...The lattice-reduction （LR） has been developed to im- prove the performance of the zero-forcing （ZF） precoder in multiple input multiple output （MIMO） systems. Under the assumptions of uncorrelated flat fading channel model and perfect channel state information at the transmitter （CSIT）, an LR-aided ZF precoder is able to collect the full transmit diversity. With the complex Lenstra- Lenstra-Lov^sz （LLL） algorithm and limited feedforward structure, an LR-aided linear minimum-mean-square-error （LMMSE） pre- coder for spatial correlated MIMO channels and imperfect CSIT is proposed to achieve lower bit error rate （BER）. Assuming a time division duplexing （TDD） MIMO system, correlated block flat fad- ing channel and LMMSE uplink channel estimator, it is proved that the proposed LR-aided LMMSE precoder can also obtain the full transmit diversity through an analytical approach. Furthermore, the simulation results show that with the quadrature phase shift keying （QPSK） modulation at the transmitter, the uncoded and coded BERs of the LR-aided LMMSE precoder are lower than that of the traditional LMMSE precoder respectively when Eb-No is greater than 10 dB and 12 dB at all correlation coefficients.展开更多
A lattice reduction aided (LRA) minimum mean square error (MMSE) Tomlinson-Harashima pre-coding (THP) was proposed based on vertical Bell Labs layered space time (VBLAST) algorithm for multiple input multiple output (...A lattice reduction aided (LRA) minimum mean square error (MMSE) Tomlinson-Harashima pre-coding (THP) was proposed based on vertical Bell Labs layered space time (VBLAST) algorithm for multiple input multiple output (MIMO) systems. The extended channel was used to provide optimal tradeoff between residual interference and noise amplification. The processing based on lattice reduction method helps achieve maximal diversity order. The VBLAST algorithm was applied to get the optimal processing ordering for successive interference cancellation (SIC) at transmitter. Simulation results show that the proposed algorithm outperforms conventional THP and the LRA zero-forcing (ZF) THP with full diversity order.展开更多
A computationally efficient soft-output detector with lattice-reduction （LR） for the multiple-input multiple-output （MIMO） systems is proposed. In the proposed scheme, the sorted QR de- composition is applied on t...A computationally efficient soft-output detector with lattice-reduction （LR） for the multiple-input multiple-output （MIMO） systems is proposed. In the proposed scheme, the sorted QR de- composition is applied on the lattice-reduced equivalent channel to obtain the tree structure. With the aid of the boundary control, the stack algorithm searches a small part of the whole search tree to generate a handful of candidate lists in the reduced lattice. The proposed soft-output algorithm achieves near-optimal perfor- mance in a coded MIMO system and the associated computational complexity is substantially lower than that of previously proposed methods.展开更多
The relations of variation of lattice stress to shape, peak concentrations of the P atom depth profile and Sb doses of P+Sb dual implantation were studied in high energy P implantation silicon. The experimental result...The relations of variation of lattice stress to shape, peak concentrations of the P atom depth profile and Sb doses of P+Sb dual implantation were studied in high energy P implantation silicon. The experimental results show that the lattice stress in P-implanted silicon obviously increases with increasing ion dose. The stress of P-implanted silicon with the dose of 2×1013/cm2 is 2.2 times greater than at a dose of 3.6×1012/cm2. The stress decreases rapidly as the annealing time increases.It is very interesting that the stress has a negative value when the concentration of P atoms in the implanted layer is below 6×1016/cm3, whereas the stress becomes positive when the concentration is greater than 6×16/cm3. The stress increases rapidly with increasing Sb ion dose after P implantation. The stress has a positive value before annealing. If the Sb dose is below 1 ×1016/cm2, the stress is negative after annealing,and it is positive when the Sb dose is higher than 1×1016/cm2. The stress is close to zero for a Sb implantation dose of 1×1016/cm2. The best compensation dose of Sb to P implantation dose of 3×1016/cm2 is 1×1016/cm2.展开更多
Electrochemical carbon dioxide reduction reaction(CO_(2)RR)can produce value-added hydrocarbons from renewable electricity,providing a sustainable and promising approach to meet dual-carbon targets and alleviate the e...Electrochemical carbon dioxide reduction reaction(CO_(2)RR)can produce value-added hydrocarbons from renewable electricity,providing a sustainable and promising approach to meet dual-carbon targets and alleviate the energy crisis.However,it is still challenging to improve the selectivity and stability of the products,especially the C^(2+) products.Here we propose to modulate the electronic structure of copper oxide(CuO)through lattice strain construction by zinc(Zn)doping to improve the selectivity of the catalyst to ethylene.Combined performance and in situ characterization analyses show that the compressive strain generated within the CuO lattice and the electronic structure modulation by Zn doping enhances the adsorption of the key intermediate*CO,thereby increasing the intrinsic activity of CO_(2)RR and inhibiting the hydrogen precipitation reaction.Among the best catalysts had significantly improved ethylene selectivity of 60.5%and partial current density of 500 mA·cm^(–2),and the highest C^(2+) Faraday efficiency of 71.47%.This paper provides a simple idea to study the modulation of CO_(2)RR properties by heteroatom doped and lattice strain.展开更多
基金The National Science and Technology Major Project(No.2012ZX03004005-003)the National Natural Science Foundation of China(No.61171081,61201175)the Innovation Technology Fund of Jiangsu Province(No.BC2012006)
文摘A novel nonlinear multi-input multi-output MIMO detection algorithm is proposed which is referred to as an ordered successive noise projection cancellation OSNPC algorithm. It is capable of improving the computation performance of the MIMO detector with the conventional ordered successive interference cancellation OSIC algorithm. In contrast to the OSIC in which the known interferences in the input signal vector are successively cancelled the OSNPC successively cancels the known noise projections from the decision statistic vector. Analysis indicates that the OSNPC is equivalent to the OSIC in error performance but it has significantly less complexity in computation.Furthermore when the OSNPC is applied to the MIMO detection with the preprocessing of dual lattice reduction DLR the computational complexity of the proposed OSNPC-based DLR-aided detector is further reduced due to the avoidance of the inverse of the reduced basis of the dual lattice in computation compared to that of the OSIC-based one. Simulation results validate the theoretical conclusions with regard to both the performance and complexity of the proposed MIMO detection scheme.
基金Natural Science Foundation of Jiangsu Province (BK20210735)National Natural Science Foundation of China (52201269, 52302296)+4 种基金Collaborative Innovation Center of Suzhou Nano Science and Technologythe 111 Projectthe Suzhou Key Laboratory of Functional Nano and Soft MaterialsJiangsu Key Laboratory for Carbon-Based Functional Materials & Devicesthe funding from the Gusu leading talent plan for scientific and technological innovation and entrepreneurship (ZXL2022487)。
文摘The development of electrocatalysts for the oxygen reduction reaction(ORR) that bears high selectivity,exceptional activity,and long-term stability is crucial for advancing various green energy technologies.Intermetallics composed of platinum and transition metals are considered to be promising candidates for this purpose.However,they typically face challenges such as unfavorable intrinsic activity and a propensity for particle aggregation,diminishing their ORR performance.Against this backdrop,we present our findings on a N-doped carbon confined Pt_(3)Co intermetallic doped with p-block metal tin(Pt_(3)Co_(x)Sn_(1-x)/NC).The introduction of Sn induces lattice strain due to its larger atomic size,which leads to the distortion of the Pt_(3)Co lattice structure,while the coupling of carbon polyhedra inhibits the particle aggregation.The optimized Pt_(3)Co_(0.8)Sn_(0.2)/NC catalyst demonstrates an impressive half-wave potential of 0.86 V versus RHE,surpassing both Pt_(3)Co/NC and Pt_(3)Sn/NC catalysts.Moreover,the Pt_(3)Co_(0.8)Sn_(0.2)/NC exhibits a mass-specific activity as high as 1.4 A mg_(Pt)^(-1),ranking it in the top level among the intermetallicsbased ORR electrocatalysts.When further employed as a cathode material in a self-assembled zinc-air battery,it shows stable operation for over 80 h.These results underscore the significant impact of lattice strain engineering through the strategic doping of p-block metal in the carbon-confined Pt_(3)Co intermetallic,thereby enhancing the catalytic efficiency for the ORR.
文摘Efficient massive MIMO detection for practical deployment, which is with spatially correlated channel and high-order modulation, is a challenging topic for the fifth generation mobile communication(5 G). In this paper, we propose a lattice reduction aided expectation propagation(LRA-EP) algorithm for massive MIMO detection. LRA-EP applies expectation propagation in lattice reduced MIMO system to approach the distribution of lattice reduced constellation point by iterative refinement on its parameters(mean and covariance). The parameter refinement is based on the lattice reduced, well-conditioned MIMO channel. Numerical result shows that LRA-EP outperforms classic EP based MIMO detection(EPD) with 5～7 dB in terms of required signalto-noise ratio(SNR) for 1% packet error rate in spatially correlated channel for 256-QAM. We also show that LRA-EP has lower computation complexity than EPD.
基金supported by the National Science Fund for Distinguished Young Scholars (60725105)the National Basic Research Program of China (2009CB320404)+4 种基金the Program for Changjiang Scholars and Innovative Research Team in University (IRT0852)the 111 Project(B08038)the National Natural Science Foundation of China (60702057)the Special Research Fund of State Key Laboratory (ISN1102003)the National Science and Technology Major Project (2011ZX03001-007-01)
文摘The lattice-reduction （LR） has been developed to im- prove the performance of the zero-forcing （ZF） precoder in multiple input multiple output （MIMO） systems. Under the assumptions of uncorrelated flat fading channel model and perfect channel state information at the transmitter （CSIT）, an LR-aided ZF precoder is able to collect the full transmit diversity. With the complex Lenstra- Lenstra-Lov^sz （LLL） algorithm and limited feedforward structure, an LR-aided linear minimum-mean-square-error （LMMSE） pre- coder for spatial correlated MIMO channels and imperfect CSIT is proposed to achieve lower bit error rate （BER）. Assuming a time division duplexing （TDD） MIMO system, correlated block flat fad- ing channel and LMMSE uplink channel estimator, it is proved that the proposed LR-aided LMMSE precoder can also obtain the full transmit diversity through an analytical approach. Furthermore, the simulation results show that with the quadrature phase shift keying （QPSK） modulation at the transmitter, the uncoded and coded BERs of the LR-aided LMMSE precoder are lower than that of the traditional LMMSE precoder respectively when Eb-No is greater than 10 dB and 12 dB at all correlation coefficients.
基金The National Natural Science Foundation of China (No. 60772100) The Science and Technology Committee of Shanghai (No. 060215013)
文摘A lattice reduction aided (LRA) minimum mean square error (MMSE) Tomlinson-Harashima pre-coding (THP) was proposed based on vertical Bell Labs layered space time (VBLAST) algorithm for multiple input multiple output (MIMO) systems. The extended channel was used to provide optimal tradeoff between residual interference and noise amplification. The processing based on lattice reduction method helps achieve maximal diversity order. The VBLAST algorithm was applied to get the optimal processing ordering for successive interference cancellation (SIC) at transmitter. Simulation results show that the proposed algorithm outperforms conventional THP and the LRA zero-forcing (ZF) THP with full diversity order.
文摘A computationally efficient soft-output detector with lattice-reduction （LR） for the multiple-input multiple-output （MIMO） systems is proposed. In the proposed scheme, the sorted QR de- composition is applied on the lattice-reduced equivalent channel to obtain the tree structure. With the aid of the boundary control, the stack algorithm searches a small part of the whole search tree to generate a handful of candidate lists in the reduced lattice. The proposed soft-output algorithm achieves near-optimal perfor- mance in a coded MIMO system and the associated computational complexity is substantially lower than that of previously proposed methods.
文摘The relations of variation of lattice stress to shape, peak concentrations of the P atom depth profile and Sb doses of P+Sb dual implantation were studied in high energy P implantation silicon. The experimental results show that the lattice stress in P-implanted silicon obviously increases with increasing ion dose. The stress of P-implanted silicon with the dose of 2×1013/cm2 is 2.2 times greater than at a dose of 3.6×1012/cm2. The stress decreases rapidly as the annealing time increases.It is very interesting that the stress has a negative value when the concentration of P atoms in the implanted layer is below 6×1016/cm3, whereas the stress becomes positive when the concentration is greater than 6×16/cm3. The stress increases rapidly with increasing Sb ion dose after P implantation. The stress has a positive value before annealing. If the Sb dose is below 1 ×1016/cm2, the stress is negative after annealing,and it is positive when the Sb dose is higher than 1×1016/cm2. The stress is close to zero for a Sb implantation dose of 1×1016/cm2. The best compensation dose of Sb to P implantation dose of 3×1016/cm2 is 1×1016/cm2.
基金supported by the National Natural Science Foundation of China(Nos.52072152 and 51802126)the Jiangsu University Jinshan Professor Fund,the Jiangsu Specially-Appointed Professor Fund,Open Fund from Guangxi Key Laboratory of Electrochemical Energy Materials,Zhenjiang“Jinshan Talents”Project 2021,China PostDoctoral Science Foundation(No.2022M721372)+2 种基金“Doctor of Entrepreneurship and Innovation”in Jiangsu Province(No.JSSCBS20221197)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_3645)Key Research and Development Program of Zhenjiang City(No.CG2023004).
文摘Electrochemical carbon dioxide reduction reaction(CO_(2)RR)can produce value-added hydrocarbons from renewable electricity,providing a sustainable and promising approach to meet dual-carbon targets and alleviate the energy crisis.However,it is still challenging to improve the selectivity and stability of the products,especially the C^(2+) products.Here we propose to modulate the electronic structure of copper oxide(CuO)through lattice strain construction by zinc(Zn)doping to improve the selectivity of the catalyst to ethylene.Combined performance and in situ characterization analyses show that the compressive strain generated within the CuO lattice and the electronic structure modulation by Zn doping enhances the adsorption of the key intermediate*CO,thereby increasing the intrinsic activity of CO_(2)RR and inhibiting the hydrogen precipitation reaction.Among the best catalysts had significantly improved ethylene selectivity of 60.5%and partial current density of 500 mA·cm^(–2),and the highest C^(2+) Faraday efficiency of 71.47%.This paper provides a simple idea to study the modulation of CO_(2)RR properties by heteroatom doped and lattice strain.
