Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping

Electrocatalytic hydrogen production from seawater holds enormous promise for clean energy generation.Nevertheless,the direct electrolysis of seawater encounters significant challenges due to poor anodic stability caused by detrimental chlorine chemistry.Herein,we present our recent discovery that the incorporation of Ce into Ni Fe layered double hydroxide nanosheet array on Ni foam(Ce-Ni Fe LDH/NF)emerges as a robust electrocatalyst for seawater oxidation.During the seawater oxidation process,CeO_(2)is generated,effectively repelling Cl^(-)and inhibiting the formation of Cl O-,resulting in a notable enhancement in the oxidation activity and stability of alkaline seawater.The prepared Ce-Ni Fe LDH/NF requires only overpotential of 390 m V to achieve the current density of 1 A cm^(-2),while maintaining long-term stability for 500 h,outperforming the performance of Ni Fe LDH/NF(430 m V,150 h)by a significant margin.This study highlights the effectiveness of a Ce-doping strategy in augmenting the activity and stability of materials based on Ni Fe LDH in seawater electrolysis for oxygen evolution.

Lamellar water induced quantized interlayer spacing of nanochannels walls

The nanoscale confinement is of great important for the industrial applications of molecular sieve,desalination,and also essential in bio-logical transport systems.Massive efforts have been devoted to the influence of restricted spaces on the properties of confined fluids.However,the situation of channel-wall is crucial but attracts less attention and remains unknown.To fundamentally understand the mechanism of channel-walls in nanoconfinement,we investigated the interaction between the counter-force of the liquid and interlamellar spacing of nanochannel walls by considering the effect of both spatial confinement and surface wettability.The results reveal that the nanochannel stables at only a few discrete spacing states when its confinement is within 1.4 nm.The quantized interlayer spacing is attributed to water molecules becoming laminated structures,and the stable states are corresponding to the monolayer,bilayer and trilayer water configurations,respectively.The results can potentially help to understand the characterized interlayers spacing of graphene oxide membrane in water.Our findings are hold great promise in design of ion filtration membrane and artificial water/ion channels.

Values of macular ganglion cell-inner plexiform layer and 10-2 visual field measurements in detecting and evaluating glaucoma

AIM:To assess the performance of macular ganglion cell-inner plexiform layer thickness(mGCIPLT)and 10-2 visual field(VF)parameters in detecting early glaucoma and evaluating the severity of advanced glaucoma.METHODS:Totally 127 eyes from 89 participants(36 eyes of 19 healthy participants,45 eyes of 31 early glaucoma patients and 46 eyes of 39 advanced glaucoma patients)were included.The relationships between the optical coherence tomography(OCT)-derived parameters and VF sensitivity were determined.Patients with early glaucoma were divided into eyes with or without central 10°of the VF damages(CVFDs),and the diagnostic performances of OCT-derived parameters were assessed.RESULTS:In early glaucoma,the mGCIPLT was significantly correlated with 10-2 VF pattern standard deviation(PSD;with average mGCIPLT:β=-0.046,95%CI,-0.067 to-0.024,P<0.001).In advanced glaucoma,the mGCIPLT was related to the 24-2 VF mean deviation(MD;with average mGCIPLT:β=0.397,95%CI,0.199 to 0.595,P<0.001),10-2 VF MD(with average mGCIPLT:β=0.762,95%CI,0.485 to 1.038,P<0.001)and 24-2 VF PSD(with average mGCIPLT:β=0.244,95%CI,0.124 to 0.364,P<0.001).Except for the minimum and superotemporal mGCIPLT,the decrease of mGCIPLT in early glaucomatous eyes with CVFDs was more severe than that of early glaucomatous eyes without CVFDs.The area under the curve(AUC)of the average mGCIPLT(AUC=0.949,95%CI,0.868 to 0.982)was greater than that of the average circumpapillary retinal nerve fiber layer thickness(cpRNFLT;AUC=0.827,95%CI,0.674 to 0.918)and rim area(AUC=0.799,95%CI,0.610 to 0.907)in early glaucomatous eyes with CVFDs versus normal eyes.CONCLUSION:The 10-2 VF and mGCIPLT parameters are complementary to 24-2 VF,cpRNFLT and ONH parameters,especially in detecting early glaucoma with CVFDs and evaluating the severity of advanced glaucoma in group level.

Extended finite element-based cohesive zone method for modeling simultaneous hydraulic fracture height growth in layered reservoirs

In this study,a fully coupled hydromechanical model within the extended finite element method(XFEM)-based cohesive zone method(CZM)is employed to investigate the simultaneous height growth behavior of multi-cluster hydraulic fractures in layered porous reservoirs with modulus contrast.The coupled hydromechanical model is first verified against an analytical solution and a laboratory experiment.Then,the fracture geometry(e.g.height,aperture,and area)and fluid pressure evolutions of multiple hydraulic fractures placed in a porous reservoir interbedded with alternating stiff and soft layers are investigated using the model.The stress and pore pressure distributions within the layered reservoir during fluid injection are also presented.The simulation results reveal that stress umbrellas are easily to form among multiple hydraulic fractures’tips when propagating in soft layers,which impedes the simultaneous height growth.It is also observed that the impediment effect of soft layer is much more significant in the fractures suppressed by the preferential growth of adjoining fractures.After that,the combined effect of in situ stress ratio and fracturing spacing on the multi-fracture height growth is presented,and the results elucidate the influence of in situ stress ratio on the height growth behavior depending on the fracture spacing.Finally,it is found that the inclusion of soft layers changes the aperture distribution of outmost and interior hydraulic fractures.The results obtained from this study may provide some insights on the understanding of hydraulic fracture height containment observed in filed.

Dual-function protective layer for highly reversible Zn anode

The thermodynamic instability of zinc anodes in aqueous electrolytes leads to issues such as corrosion,hydrogen evolution reactions(HER), and dendrite growth, severely hindering the practical application of zinc-based aqueous energy storage devices. To address these challenges, this work proposes a dualfunction zinc anode protective layer, composed of Zn-Al-In layered double oxides(ILDO) by rationally designing Zn-Al layered double hydroxides(Zn-Al LDHs) for the first time. Differing from previous works on the LDHs coatings, firstly, the ILDO layer accelerates zinc-ion desolvation and also captures and anchors SO_(4)^(2-). Secondly, the in-situ formation of the Zn-In alloy phase effectively lowers the nucleation energy barrier, thereby regulating zinc nucleation. Consequently, the zinc anode with the ILDO protective layer demonstrates long-term stability exceeding 1900 h and low voltage hysteresis of 7.5 m V at 0.5 m A cm^(-2) and 0.5 m A h cm^(-2). Additionally, it significantly enhances the rate capability and cycling performance of Zn@ILDO//MnO_(2) full batteries and Zn@ILDO//activated carbon zinc-ion hybrid capacitors.This simple and effective dual-function protective layer strategy offers a promising approach for achieving high-performance zinc-ion batteries.

热储特征对砂岩热储采灌井距的影响-以济阳坳陷为例

水热型地热资源的回灌式开采是公认的地热可持续开采方式,而采灌井距是地热项目中需要着重关注的问题,以避免开采井中的热突破现象。回灌水在热储中的运移取决于热储特征,也就是储层的透水能力,主要指热储的孔隙度、渗透率及砂泥岩组合关系等参数。基于济阳坳陷典型地热田的储层数据,采用Tough2为核心的Petrasim软件建立数值模型,系统研究了储层孔隙度、渗透率及单砂体厚度对热储中回灌水的运移以及温度场的影响。模拟结果显示:(1)储层孔隙度对回灌压力与采灌井距几乎没有影响;(2)储层渗透率对采灌率和采灌压力影响较大,控制着热储的回灌能力,但对采灌井距没有影响;(3)多次叠置的薄砂层热储中的泥岩隔层影响回灌水运移,在多层薄砂叠置的热储中回灌水水平运移距离远,温度影响范围更大,应扩大采灌井距。该研究对地热开发项目的可持续运行具有指导意义。

2.5D scattering of incident plane SV waves by a canyon in layered half-space

This paper presents a 2.5D scattering of incident plane SV waves by a canyon in a layered half-space by using the indirect boundary element method （IBEM）. A free field response analysis is performed to provide the displacements and stresses on the boundary of the canyon where fictitious uniform moving loads are applied to calculate the Green＇s fi.mctions for the displacements and stresses. The amplitudes of the loads are determined by the boundary conditions. The free field displacements are added to the fictitious uniform moving loads induced displacements and the total response is obtained. Numerical calculations are performed for a canyon with homogenous and in one layer over bedrock. The effects of the thickness and stiffness of the layer on the amplification are studied and discussed.

Green's function of multi-layered poroelastic half-space for models of ground vibration due to railway traffic

This study proposes a Green＇s function, an essential representation of water-saturated ground under moving excitation, to simulate ground borne vibration from trains. First, general solutions to the governing equations of poroelastic medium are derived by means of integral transform. Secondly, the transmission and reflection matrix approach is used to formulate the relationship between displacement and stress of the stratified ground, which results in the matrix of the Green＇s function. Then the Green＇s function is combined into a train-track-ground model, and is verified by typical examples and a field test. Additional simulations show that the computed ground vibration attenuates faster in the immediate vicinity of the track than in the surrounding area. The wavelength of wheel-rail unevenness has a notable effect on computed displacement and pore pressure. The variation of vibration intensity with the depth of ground is significantly influenced by the layering of the strata soil. When the train speed is equal to the velocity of the Rayleigh wave, the Mach cone appears in the simulated wave field. The proposed Green＇s function is an appropriate representation for a layered ground with shallow ground water table, and will be helpful to understand the dynamic responses of the ground to complicated moving excitation.

Seismogram Synthesis in Multi-layered Half-space Part Ⅰ. Theoretical Formulations

In the past two decades numerous studies were made to develop and improve the theory and practical computation techniques of synthesizing theoretical seismograms for the model of multi-layered half-space. Today, synthesizing theoretical seismograms in multi-layered half-space is an important tool for understanding the structure of the Earth’s interior as well as the seismic source process from well-recorded seismograms data. As part of a review of the state-of-the-art, in this article I shall present a systematic and self-contained theory of elastic waves in multi-layered half-space media based on the developments in the past two decades.

In-plane dynamic Green's functions for inclined and uniformly distributed loads in a multi-layered transversely isotropic half-space

The dynamic stiffness method combined with the Fourier transform is utilized to derive the in-plane Green’s functions for inclined and uniformly distributed loads in a multi-layered transversely isotropic（TI）half-space.The loaded layer is fixed to obtain solutions restricted in it and the corresponding reactions forces,which are then applied to the total system with the opposite sign.By adding solutions restricted in the loaded layer to solutions from the reaction forces,the global solutions in the wavenumber domain are obtained,and the dynamic Green’s functions in the space domain are recovered by the inverse Fourier transform.The presented formulations can be reduced to the isotropic case developed by Wolf（1985）,and are further verified by comparisons with existing solutions in a uniform isotropic as well as a layered TI halfspace subjected to horizontally distributed loads which are special cases of the more general problem addressed.The deduced Green’s functions,in conjunction with boundary element methods,will lead to significant advances in the investigation of a variety of wave scattering,wave radiation and soil-structure interaction problems in a layered TI site.Selected numerical results are given to investigate the influence of material anisotropy,frequency of excitation,inclination angle and layered on the responses of displacement and stress,and some conclusions are drawn.

3D scattering of obliquely incident plane SV waves by an alluvial valley embedded in a fluid-saturated, poroelastic layered half-space

The indirect boundary element method is used to study the 3D dynamic response of an infinitely long alluvial valley embedded in a saturated layered half-space for obli- quely incident SV waves. A wave-number transform is first applied along the valley＇s axis to reduce a 3D problem to a 2D plane strain problem. The problem is then solved in the section perpendicular to the axis of the valley. Finally, the 3D dynamic responses of the valley are obtained by an inverse wave-number transform. The validity of the method is con- firmed by comparison with relevant results. The differences between the responses around the valley embedded in dry and in saturated poroelastic medium are studied, and the effects of drainage conditions, porosity, soil layer stiffness, and soil layer thickness on the dynamic response are dis- cussed in detail resulting in some conclusions.

Dynamic soil-tunnel interaction in layered half-space for incident plane SH waves

The dynamic soil-tunnel interaction is studied by indirect boundary element method （IBEM）, using the model of a rigid tunnel in layered half-space, which is simplified to a single soil layer on elastic bedrock, subjected to incident plane SH waves. The accuracy of the results is verified through comparison with the analytical solution. It is shown that soil-tunnel interaction in layered half-space is larger than that in homogeneous half-space and this interaction mechanism is essentially different from that of soil-foundation-superstructure interaction.

基于特征工程的S-FCN火灾图像检测方法

针对复杂背景下火灾图像检测深度学习算法存在的计算复杂度高、检测实时性差等问题,提出一种基于特征工程的单隐层全连接网络(S-FCN)火灾图像检测方法。首先,从图像中提取多色彩空间颜色特征,并使用互信息量进行多色彩空间颜色特征降维;其次,简化深度学习模型的网络结构,将单隐层全连接网络作为其主干网络,其中,多色彩空间下的颜色特征能够更好地表征火灾烟雾与火焰,多色彩空间颜色特征降维能够有效降低输入特征的冗余度,单隐层全连接网络能够有效减少模型在传递过程中的参数数量;最后,将该方法在真实的复杂背景火灾图像数据集上进行试验评估。结果表明:所提方法取得的检测精度为93.83%,取得的检测实时性帧率为10869帧/s,能够实现复杂场景下高精度、高速度的火灾图像检测。

低能见度下GYOLOv5-SPD算法的车牌检测

车牌自动检测技术是构建智慧城市、加强交通管理等方面的重要内容。目前车牌检测技术正在逐步完善,但对于光照条件过低、雨天、雪天等能见度极低的气候环境下所拍摄的车牌照片,车牌检测技术还处于一个相对落后的水平。本文在中国城市停车数据集(CCPD)中能见度极低的车牌图像的基础上利用添加了伽玛(Gamma)变换的你只需看一次(YOLO)v5s模型与空间到深度层及无步长卷积层(SPD-Conv)进行融合用于车牌检测,将低能见度条件下的车牌视为小物体进行检测,目的是最大限度地识别其特征以提高精度。实验结果表明,本文用到的方法在车牌定位检测阶段达到了99.68%的召回率,在低能见度条件下对车牌的定位检测相较其他算法确实有一定的优势。

Dynamic soil-tunnel interaction in layered half-space for incident P-and SV-waves

The dynamic soil-tunnel interaction is studied by the model of a rigid tunnel embedded in layered half-space, which is simplified as a single soil layer on elastic bedrock to the excitation of P- and SV-waves. The indirect boundary element method is used, combined with the Green＇ s function of distributed loads acting on inclined lines. It is shown that the dynamic characteristics of soil-tunnel interaction in layered half-space are different much from that in homoge- neous half-space, and that the mechanism of soil-tunnel interaction is also different much from that of soil-founda- tion-superstructure interaction. For oblique incidence, the tunnel response for in-plane incident SV-waves is com- pletely different from that for incident SH-waves, while the tunnel response for vertically incident SV-wave is very similar to that of vertically incident SH-wave.

Space Charge Layer Eff ect in Sulfide Solid Electrolytes in All-Solid-State Batteries: In-situ Characterization and Resolution

All-solid-state lithium batteries(ASSLBs)have advantages of safety and high energy density,and they are expected to become the next generation of energy storage devices.Sulfide-based solid-state electrolytes(SSEs)with high ionic conduc-tivity and low grain boundary resistance exhibit remarkable practical application.However,the space charge layer(SCL)eff ect and high interfacial resistance caused by a mismatch with the current commercial oxide cathodes restrict the develop-ment of sulfide SSEs and ASSLBs.This review summarizes the research progress on the SCL eff ect of sulfide SSEs and oxide cathodes,including the mechanism and direct evidence from high performance in-situ characterizations,as well as recent progress on the interfacial modification strategies to alleviate the SCL eff ect.This study provides future direction to stabilize the high performance sulfide-based solid electrolyte/oxide cathode interface for state-of-the-art ASSLBs and future all-SSE storage devices.

A new layered space-time detection algorithm for frequency selective fading multiple-input multiple-output channels based on particle filter

In this paper, a new observation equation of non-Gaussian frequency selective fading Bell Labs layered space time （BLAST） architecture system is proposed, which is used for frequency selective fading channels and non-Gaussian noise in an application environment of BLAST system. With othogonal matrix triangularization （QR decomposition） of the channel matrix, the static observation equation of frequency selective fading BLAST system is transformed into a dynamic state space model, and then the particle filter is used for space-time layered detection. Making the full use of the finite alphabet of the digital modulation communication signal, the optimal proposal distribution can be chosen to produce particle and update the weight. Incorporated with current method of reducing error propagation, a new space-time layered detection algorithm is proposed. Simulation result shows the validity of the proposed algorithm.

Time domain method for calculating free field motion of a layered half-space subjected to obliquely incident body waves

In numerical simulation of wave scattering under oblique incident body waves using the finite element method, the free field motion at the incident lateral boundary induced by the background layered half-space complicates the computational area. In order to replace the complex frequency domain method, a time-domain method to calculate the free field motion of a layered half-space subjected to oblique incident body waves is developed in this paper. The new method decouples the equations of motion used in the finite element method and offers an interpolation formula of the free field motion. This formula is based on the fact that the apparent horizontal velocity of the free field motion is constant and can be calculated exactly. Both the theoretical analysis and numerical results demonstrate that the proposed method offers a high degree of accuracy.

3D Diffraction of obliquely incident SH waves by twin infinitely long cylindrical cavities in layered poroelastic half-space

Abstract This paper studies three-dimensional diffraction of obliquely incident plane SH waves by twin infinitely long cylindrical cavities in layered poroelastic half-space using indirect boundary element method. The approach is validated by comparison with the literature, and the effects of cavity interval, incident frequency, and boundary drainage condition on the diffraction are studied through numerical examples. It is shown that, the interaction between two cavities is significant and surface displacement peaks become large when two cavities are close, and the surface displacement may be significantly amplified by twin cavities, and the influence range with large amplification can be as wide as 40 times of the cavity radius. Surface displacements in dry poroelastic case and saturated poroelastic cases with drained and undrained boundaries are evidently different under certain circumstances, and the differences may be much larger than those in the free-field response.

AlLi-LDH中Al-O八面体环吸附锂的机制

采用共沉淀法合成铝锂层状双氢氧化物(AlLi-LDH)并进行提锂试验。AlLi-LDH的空间群为P32或C2/m,微观形貌呈直径为5~10μm的规则球形。AlLi-LDH吸附Li^(+)后,空间群转化为P32。当Li^(+)浓度为95.4 mg/L时,1 h后锂吸附量为8.98 mg/g;吸附48 h后,吸附量增加到16.50 mg/g;根据二级吸附模型预测Li^(+)吸附总量为17.57 mg/g。当Mg^(2+)/Li^(+)的质量比为1067时,Mg^(2+)/Li^(+)分离系数为29536。空间群为P32时,Li-O的相互作用强度变弱,且相互作用属于静电效应。具有P32空间基团的AlLi-LDH更容易吸附和解吸Li^(+)。