Layered injection technology for chemical flooding of Class-Ⅲ oil reservoirs in the Daqing Oil Fields complex,Songliao Basin,Northeast China

The Class-Ⅲ oil reservoirs of Lasaxing oilfield in the Daqing Oil Fields complex have geological oil reserves of 1.86 billion tonnes,an oil recovery of 39%,with remaining reserves accounting for more than 45%of the total geological reserves of the oilfield.Therefore,they have considerable potential for future oil production.The current layered injection technologies fail to achieve effective control over the low single-layer injection rates since they can only produce low throttle differential pressure under low injection rates(5-20 m^(3)/d).In this study,a symmetrically-structured double-offset-hole injection allocator and a novel throttling component were developed.Their spatial layout was constructed and mechanical parameters were optimized using finite element analysis,which allows for expanding the flow rate range at low injection rates.According to experimental results,the throttle differential pressure increased from 0.2 MPa to 0.8 MPa at an injection rate of 5 m^(3)/d,and the range of the single-layer flow rates expanded from 20-70 m^(3)/d to 5-70 m3/d.The field test results show that the effective production of oil layers with medium and low permeability was achieved and that the ratio of producing oil layer thickness to the total reservoir thickness increased by 9.7%on average.Therefore,this study provides valuable technical support for the effective chemical-flooding-based development of Class-Ⅲ oil reservoirs.

Simulation study of blue InGaN multiple quantum well light-emitting diodes with different hole injection layers

InGaN-based light-emitting diodes with p-GaN and p-A1GaN hole injection layers are numerically studied using the APSYS simulation software. The simulation results indicate that light-emitting diodes with p-A1GaN hole injection layers show superior optical and electrical performance, such as an increase in light output power, a reduction in current leakage and alleviation of efficiency droop. These improvements can be attributed to the p-A1GaN serving as hole injection layers, which can alleviate the band bending induced by the polarization field, thereby improving both the hole injection efficiency and the electron blocking efficiency.

Performance improvement of GaN-based light-emitting diode with a p-InAlGaN hole injection layer

The characteristics of a blue light-emitting diode （LED） with a p-InA1GaN hole injection layer （HIL） is analyzed numerically. The simulation results indicate that the newly designed structure presents superior optical and electrical performance such as an increase in light output power, a reduction in current leakage and alleviation of efficiency droop. These improvements can be attributed to the p-InA1GaN serving as hole injection layers, which can alleviate the band bending induced by the polarization field, thereby improving both the hole injection efficiency and the electron blocking efficiency.

Improvement of electron injection of organic light-emitting devices by inserting a thin aluminum layer into cesium carbonate injection layer

We investigate the electron injection effect of inserting a thin aluminum（Al） layer into cesium carbonate（Cs2CO3）injection layer. Two groups of organic light-emitting devices（OLEDs） are fabricated. For the first group of devices based on Alq3, we insert a thin Al layer of different thickness into Cs2CO3 injection layer, and the device＇s maximum current efficiency of 6.5 cd/A is obtained when the thickness of the thin Al layer is 0.4 nm. However, when the thickness of Al layer is 0.8 nm, the capacity of electron injection is the strongest. To validate the universality of this approach, then we fabricate another group of devices based on another blue emitting material. The maximum current efficiency of the device without and with a thin Al layer is 4.51 cd/A and 4.84 cd/A, respectively. Inserting a thin Al layer of an appropriate thickness into Cs2CO3 layer can result in the reduction of electron injection barrier, enhancement of the electron injection, and improvement of the performance of OLEDs. This can be attributed to the mechanism that thermally evaporated Cs2CO3 decomposes into cesium oxides, the thin Al layer reacts with cesium oxides to form Al–O–Cs complex, and the amount of the Al–O–Cs complex can be controlled by adjusting the thickness of the thin Al layer.

Improvement of Performance of Organic Light-Emitting Diodes with Both a MoO3 Hole Injection Layer and a MoO3 Doped Hole Transport Layer

We improve the performance of organic light-emitting diodes （OLEDs） with both a MoO3 hole injection layer （HIL） and a MoO3 doped hole transport layer （HTL）, and present a systematical and comparative investigation on these devices. Compared with OLEDs with only MoO3 HIL or MoO3 doped HTL, OLEDs with both MoO3 HIL and MoO3 doped HTL show superior performance in driving voltage, power efficiency, and stability. Based on the typical NPB/Alq3 heterojunction structure, OLEDs with both MoO3 HIL and MoO3 doped HTL show a driving voltage of 5.4 V and a power efficiency of 1.41 lm/W for 1000 cd/m2, and a lifetime of around 0. 88 h with an initial luminance of 5268 cd/m2 under a constant current of 190 mA/cm2 operation in air without encapsulation. While OLEDs with only MoO3 HIL or MoO3 doped HTL show higher driving voltages of 6.4 V or 5.8 V and lower power efficiencies of 1.201m/W or 1.341m/W for 1000cd/m2, and a shorter lifetime of 0.33 or 0.60h with an initial luminance of around 5122 or 5300cd/m2 under a constant current of 200 or 216mA/cm2 operation. Our results demonstrate clearly that using both MoO3 HIL and MoO3 doped HTL is a simple and effective approach to simultaneoasly improve both the hole injection and transport efficiency, resulting from the lowered energy barrier at the anode interface and the increased hole carrier density in MoO3 doped HTL.

Boundary layer flow over a moving surface in a nanofluid with suction or injection

An analysis is performed to study the heat transfer characteristics of steady two-dimensional boundary layer flow past a moving permeable flat plate in a nanofluid. The effects of uniform suction and injection on the flow field and heat transfer characteristics are numerically studied by using an implicit finite difference method. It is found that dual solutions exist when the plate and the free stream move in the opposite directions. The results indicate that suction delays the boundary layer separation, while injection accelerates it.

Effects of multiple intravitreal anti-VEGF injections on retinal nerve fiber layer and intraocular pressure: a comparative clinical study

Dear Sir,Ifound the article by Sobac1etal[1]very interesting.The authors concluded that repeated intravitreal injection(IVI)of ranibizumab or bevacizumab didn’t seem have adverse effects on retinal nerve fiber layer(RNFL)thickness in wet age-related macular degeneration(AMD)patients.

Accelerating directional charge separation via built-in interfacial electric fields originating from work-function differences

In this work,a hierarchical porous SnS_(2)/rGO/TiO_(2)hollow sphere heterojunction that allows highly-efficient light utilization and shortening distance of charge transformation is rationally designed and synthesized.More importantly,an rGO interlayer is successfully embedded between the TiO_(2)hollow sphere shells and outermost SnS_(2)nanosheets.This interlayer functions as a bridge to connect the two light-harvesting semiconductors and acts as a hole injection layer in the tandem heterojunction.The induced built-in electric fields on both sides of the interface precisely regulate the spatial separation and directional migration of the photo-generated holes from the light-harvesting semiconductor to the rGO hole injection interlayer.These synergistic effects greatly prolong the lifetime of the photo-induced charge carriers.The optimized tandem heterojunction with a 2 wt%rGO loading demonstrate enhanced visible-light-driven photocatalytic activity for Rhodamine B(RhB)dye degradation(removal rate:97.3%)and Cr(VI)reduction(removal rate:97.09%).This work reveals a new strategy for the rational design and assembly of hollow-structured photocatalytic materials with spatially separated reduction and oxidation surfaces to achieve excellent photocatalytic performance.

Polymer light-emitting devices using poly(ethylene oxide) as an electron injecting layer

The performance of polymer light emitting devices(PLEDs)based on polyvinyl carbazole(PVK)is improved by introducing a nanoscale interfacial thin layer,made of poly(ethylene oxide)(PEO),between the calcium cathode and the PVK emissive layer.It is believed that the PEO layer plays a key role in enhancing the device performance.In comparison to the device with Ca/Al as the cathode,the performance of the PLED with PEO/Ca/Al cathode,including the driving voltage,luminance efficiency is significantly improved.These improvements are attributed to the introduction of a thin layer of PEO that can lower the interfacial barrier and facilitate electron injection.

Geology and development of geothermal field in Neogene Guantao Formation in northern Bohai Bay Basin: A case of the Caofeidian geothermal heating project in Tangshan, China

Taking the Gaoshangpu-Liuzan geothermal field in the Nanpu sag of the Bohai Bay Basin as the research object, this paper discusses the geological conditions and potential of the geothermal resources of the Guantao Formation in the study area, and introduces the development practice of geothermal energy heating in Caofeidian. The average buried depth of the Guantao Formation is 1500–2500 m, the lithology is dominated by sandy conglomerate, and the average thickness of thermal reservoir is 120–300 m. The average porosity of thermal reservoir is 28%–35%, the permeability is(600–2000)×10^(-3) μm^(2), and the temperature of thermal reservoir is 70–110 ℃. The formation has total geothermal resources of 13.79×10^(18) J, equivalent to 4.70×10^(8) t of standard coal. Based on a large amount of seismic and drilling data from oil and gas exploration, this study carried out high quality target area selection, simulation of sandstone thermal reservoir, and production and injection in the same layer. The geothermal heating project with distributed production and injection well pattern covering an area of 230×10^(4) m^(2) was completed in the new district of Caofeidian in 2018. The project has been running steadily for two heating seasons, with an average annual saving of 6.06×10^(4) t of standard coal and a reduction of 15.87×10^(4) t of carbon dioxide, achieving good economic and social benefits. This project has proved that the Neogene sandstone geothermal reservoir in eastern China can achieve sustainable large-scale development by using the technology of "balanced production and injection in the same layer". It provides effective reference for the exploration and development of geothermal resource in oil and gas-bearing basins in eastern China.

Increased work function in PEDOT:PSS film under ultraviolet irradiation

An increase of work function （0.3 eV） is achieved by irradiating poly（3,4-ethylenedioxythiophene）：poly（styrene sul- fonate） （PEDOT：PSS） film in vacuum with 254-nm ultraviolet （UV） light. The mechanism for such an improvement is investigated by photoelectron yield spectroscopy, X-ray photo electron energy spectrum, and field emission technique. Sur- face oxidation and composition change are found as the reasons for work function increase. The UV-treated PEDOT：PSS film is used as the hole injection layer in a hole-only device. Hole injection is improved by UV-treated PEDOT：PSS film without baring the enlargement of film resistance. Our result demonstrates that UV treatment is more suitable for modifying the injection barrier than UV ozone exposure.