The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming f...The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H20-NaCI-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The oreforming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep.展开更多
1 Geological Background of Minerlization or Geologic Setting The northeast of Yunnan1 Pb-Zn-Ag-Ge polymetallic ore district is an important part of the southwestern margin of the Yangtze block Sichuan-Yunnan-Guizhou
1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this ...1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this paper,展开更多
1 Introduction The Lehonglead-zincdeposit is a large-sized Pb-Zn depositnewly found in recent years in the Sichuan-Yunnan-Guizhou Lead-zinc Poly-metallic Mineralization Area,which occurrenceis strictly
The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covere...The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covered by eluvial-deluvial lateritic layer, without any mineralized outcrops. The main concealed orebody V3 is buffed in the depth of 300-500m. The orebodies are controlled by certain stratigraphic horizons, and most are cut by strata with a high angle, while a few occur along the strata. The direct wall rocks are calcisiltite, calclithite, bioclastic calcarenite,展开更多
1 Introduction The Wuzhishan lead-zinc ore-concentrated area in Puding is located in the east of the Sichuan,Guizhou and Yunnan lead-zinc metallogenic domain,with the Youjiang-Nanpan River metallogenic province to the
Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide m...Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.展开更多
Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological resea...Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological research and mineral exploration(Li Bile et al., 2015). The Qimantag Mountain is located in middle segment of the EKO, which has experienced the Early Paleozoic and Late Paleozoic–Early展开更多
Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimen...Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimental Investigation of Integrated Prospecting Technology for Concealed Carbonate-Type Lead-Zinc Deposits in the Region of Sichuan, Yunnan and Guizhou Provinces". This project has been implemented by the Chengdu Center of China Geological Survey since 2013, and the project has run for 3 years. The general objective of this project is to establish an effective and adaptable integrated prospecting methodology (including geological, geophysical and geochemical techniques) in search for deep concealed lead-zinc deposits.展开更多
Nineteen volcanic and magmatic rock samples were collected from the Jinding lead-zinc deposit and its surrounding areas in Yunnan. The ICP and AES analyses, referred to the previous results, show that the metal minera...Nineteen volcanic and magmatic rock samples were collected from the Jinding lead-zinc deposit and its surrounding areas in Yunnan. The ICP and AES analyses, referred to the previous results, show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ΣREE from the early to late stages of mineralization, and similarities in REE distribution patterns, indicating that the ore fluids are characterized by high LREE enrichment, markedly negative δCe anomaly and slight δEu anomaly. These REE distribution patterns exhibit striking similarities to those of the Pliocene trachyte in the study area, both of which are similar in ΣREE, LREE/HREE ratio, δEu and δCe. The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.展开更多
Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered...Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volcanism. In order to lay the foundation on studying its diagenesis and mineralization ages,the detailed studies were carried out by dating the host rocks( i. e. rhyolitic lithic-crystal tuffs) using zircon LA-ICP-MS U-Pb method.The dating results show three groups of ages. The first group is the captured zircons( the weighted mean ^(206)Pb /^(238) U age as 175. 6 ± 2. 3 Ma,MSWD = 0. 70,n = 3). The second group can be regarded as the rockforming age( the weighted mean ^(206)Pb /^(238) U age as 165. 3 ± 1. 9 Ma,MSWD = 2. 40,n = 14). The third group should represent the late stage of the magmatic evolution( the weighted mean ^(206)Pb /^(238) U age as 161. 0 ± 3. 1Ma,MSWD = 0. 86,n = 4). According to the ages and the crystal form or CL image characteristics of zircons,it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geochronological research,the acidic pyroclastic rocks are space accompaniment and time connection with the Tamulangou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver,lead and zinc mineralization in this area.展开更多
Qinling-type Pb-Zn deposits are located in the Qinling fold belt, occurring in the fine-clastic and carbonate rocks of the Devonian marine facies. They are reformed sedimentary deposits originating from hydrothermal w...Qinling-type Pb-Zn deposits are located in the Qinling fold belt, occurring in the fine-clastic and carbonate rocks of the Devonian marine facies. They are reformed sedimentary deposits originating from hydrothermal waters, and may be subdivided into 2 subtypes: hydrothermal sedimentary deposits (Changba subtype) and reformed hydrothermal sedimentary deposits (Bijiashan-Qiandongshan subtype). In comparison with some of the famous Palaeozoic Pb-Zn deposits in the world, the Qinling-type Pb-Zn deposits constitute an independent type, which possesses some characteristics of both hydrothermal sedimentary deposits (Meggen type) and reformed hydrothermal deposits (Mississippi Valley type).展开更多
An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits a...An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits association and zoning laws.展开更多
Organic matter, associated with ores, host rocks, ore source rocks and present in fluid inclusions in the Qixiashan lead zinc polymetallic deposit hosted in Upper Carboniferous dolomites and limestones in East China,...Organic matter, associated with ores, host rocks, ore source rocks and present in fluid inclusions in the Qixiashan lead zinc polymetallic deposit hosted in Upper Carboniferous dolomites and limestones in East China, was systematically analyzed using Fourier transform infrared spectroscopy, gas chromatography (GC), GC/mass spectrometry and proton induced X ray emission. The biomarker ratios of n C - 21 / n C + 22 alkanes, C 23 tricyclic/C 30 hopane and the tricyclic terpane parameters including C 21 /C 23 , C 19-20 /C 21-29 and C 19-25 /C 26-29 can effectively discriminate ores from host rocks. Extractable organic matter present in fluid inclusions displays similarities to those enclosed in the ore source rocks in the biomarker ratios, suggesting that a proportion of organic matter was introduced into the deposit from the ore source strata. The presence of copper and zinc in stage Ⅱ pyrobitumen indicates that some metals may have been transported by an organic fluid or removed from an aqueous fluid by organic matter.展开更多
Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin...Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.展开更多
As part of the hydro geological study of the Kherzet Youcef deposit, a drilling battery was carried out. The objective of this achievement is the satisfaction of the water needs of the city of Ain Azel (drinking water...As part of the hydro geological study of the Kherzet Youcef deposit, a drilling battery was carried out. The objective of this achievement is the satisfaction of the water needs of the city of Ain Azel (drinking water supply, irrigation and industrial water supply) and even the transfer to other municipalities suffering by the lack of water and the resumption of mining activity at the deposit of Kherzet Youcef. This water table is located in carbonate formations of Paleo-Neogene age linked to lead-zinc mineralization. Knowledge of water quality and its suitability for human consumption is an obligation. These metals have adverse health effects. We used the results of Sonarem’s analyses from 1973 to 1979. In addition, we carried out two analyses, during two years 2015-2016, on five boreholes. The parameters analyzed are major elements, physical parameters and trace metal elements (Zn, Pb and Fe). The analyses were done by ICP-AES. In our work, it has been shown that waste water is suitable for use in agriculture. For this we used the electrical conductivity at 25°C and those of the sodium adsorption ratio (SAR). For drinking water supply, monitoring the change in trace metal element (Zn, Pb and Fe) for two years has allowed us to conclude that groundwater in the groundwater table east of the Kherzet Youcef fault is generally acceptable. They are eligible by the quality standard set by Algerian regulations. However, they exceed the world health organization (WHO) standards, especially for lead. We recommend a revision of drinking water quality standards set by Algerian regulations, rigorous monitoring of TME content variation and water treatment before distribution.展开更多
The Longtang Pb-Zn deposit occurs in the Upper Sinian Guanyinyan Formation. The host rocks include sandy shale, cherty limestone and dolomitic limestone.The deposit is a typical one of thallogen origin.The mineral ass...The Longtang Pb-Zn deposit occurs in the Upper Sinian Guanyinyan Formation. The host rocks include sandy shale, cherty limestone and dolomitic limestone.The deposit is a typical one of thallogen origin.The mineral assemblage in the ore is made up of sphalerite, galena, pyrite, enargite,tennantite, seligmannite, asphalt, etc. The ore-forming process is possessed of multiepisode and multi-stage characters. Generally sphalerites exhibit algal stromatolitic, bacterial and algal colloidal textures, providing evidence for the direct involvement of algaeand bacteria in mineralization of ore-forming elements during sedimentary diagenesis.This is the first transmingration of ore-forming elements. However, pyrite embracing bacteria and galena replacing/filling trichomes are typical organic textures, which are relatedto organic carbon and bitumen that can adsorb or reduce ore-forming elements. This is anindirect process of organic mineralization, i.e., the second transmigration of ore-formingelements. δ34S values are all greater than 5%o, indicating the dominance of the heavysulfur isotopes. The ore-forming temperature deduced from fluid inclusions ranges from100℃ to 150℃±. All this goes to show that the Longtang Pb-Zn deposit is of thallogenorlgin.展开更多
Tumor deposits(TDs)are defined as discrete,irregular clusters of tumor cells lying in the soft tissue adjacent to but separate from the primary tumor,and are usually found in the lymphatic drainage area of the primary...Tumor deposits(TDs)are defined as discrete,irregular clusters of tumor cells lying in the soft tissue adjacent to but separate from the primary tumor,and are usually found in the lymphatic drainage area of the primary tumor.By definition,no residual lymph node structure should be identified in these tumor masses.At present,TDs are mainly reported in colorectal cancer,with a few reports in gastric cancer.There are very few reports on breast cancer(BC).For TDs,current dominant theories suggest that these are the result of lymph node metastasis of the tumor with complete destruction of the lymph nodes by the tumor tissue.Even some pathologists classify a TD as two lymph node metastases for calculation.Some pathologists also believe that TDs belong to the category of disseminated metastasis.Therefore,regardless of the origin,TDs are an indicator of poor prognosis.Moreover,for BC,sentinel lymph node biopsy is generally used at present.Whether radical axillary lymph node dissection should be adopted for BC with TDs in axillary lymph nodes is still inconclusive.The present commentary of this clinical issue has certain guiding significance.It is aimed to increase the awareness of the scientific community towards this under-recognized problem in BC pathology.展开更多
基金This research is supported by the National Natural Science Foundation of China (No. 40672061) ; 'National Science Support Plan Program' (2006BAB01A06) ; 'National Basic Research Program of China' (No.2007CB411304 No. 2001 CB409806).
文摘The Xitieshan lead-zinc deposit is located at the northern margin of the Qaidam Basin, Qinghai Province, China, and had developed a complete marine sedimentary-exhalative system. Our preliminary study of ore-forming fluids shows that fluid inclusions in quartz from altered stockwork rocks that represent the pipe facies have a wide range of temperature and salinity. The intense fluid activities are characteristics of the pipe facies of the exhalative system. Fluid inclusions in carbonates near the unstratified ore bodies hosted in the thick-bedded marble which represents vent-proximal facies are large in size and have moderate to high temperatures. They represent unerupted sub-seafloor fluid activity. Fluids in altered stockwork rocks and carbonates have similar H20-NaCI-CO2 system, both belonging to the sedimentary-exhalative system. The fluids migrate from the pipe facies to the unstratified ore bodies. Boiling of the fluids causes the separation of CO2 vapor and liquid H2O. When the fluids migrate into the unconsolidated thick-bedded marble, the escape of CO2, decreasing temperature and pressure as well as some involvement of seawater into the fluids result in the unmixing of fluids with high and low salinity and deposition of ore-forming materials. The two unmixed fluids were trapped in unconsolidated carbonates and the ore-forming materials were deposited in the unconsolidated carbonates to form the sedimentary-exhalative type unstratified ore bodies. The oreforming temperature of unstratified ore bodies is up to high temperature indicating that there is a huge ore-forming potential in its deep.
文摘1 Geological Background of Minerlization or Geologic Setting The northeast of Yunnan1 Pb-Zn-Ag-Ge polymetallic ore district is an important part of the southwestern margin of the Yangtze block Sichuan-Yunnan-Guizhou
基金financially supported by grants from the Commonweal Project from the Ministry of Land and Resources (No.201511015)China Geological Survey (No.DD2016027-2)
文摘1 Introduction The Longgen Lead-Zinc deposit is located in the southern Gangdise-Nyainqentantanglha plate and belongs to the western section of the Nyainqentantanglha copper-lead-zinc-silver metallogenic belt.In this paper,
基金supported by the Funds for the programs of the National Natural Science Foundation (Noes. 41572060, U1133602)Projects of YM Lab (2011)Innovation Team of Yunnan province and KMUST (2008,2012)
文摘1 Introduction The Lehonglead-zincdeposit is a large-sized Pb-Zn depositnewly found in recent years in the Sichuan-Yunnan-Guizhou Lead-zinc Poly-metallic Mineralization Area,which occurrenceis strictly
文摘The newly-discovered Xiyi lead-zinc deposit is a large deposit located in the north central Baoshan block of the southern Sanjiang metallogenic belt section, Southwest China.The surface of the deposit is mainly covered by eluvial-deluvial lateritic layer, without any mineralized outcrops. The main concealed orebody V3 is buffed in the depth of 300-500m. The orebodies are controlled by certain stratigraphic horizons, and most are cut by strata with a high angle, while a few occur along the strata. The direct wall rocks are calcisiltite, calclithite, bioclastic calcarenite,
基金funded by the national key basic research development program (2014 cb440905)key project of national natural science funds (41430315)
文摘1 Introduction The Wuzhishan lead-zinc ore-concentrated area in Puding is located in the east of the Sichuan,Guizhou and Yunnan lead-zinc metallogenic domain,with the Youjiang-Nanpan River metallogenic province to the
文摘Electron paramagnetic resonance spectra, absorption spectra, cathodoluminescence spectra and infrared spectra of sphalerite from the Lechang remoulded sedimentary lead-zinc deposit have been studied so as to provide microscopic evidence for the formation conditions and mineralization stages of the deposit as well as the geochemical processes of mineralization. On the basis of thermodynamic calculations, the stable fields of sphalerite from different mineralization stages were determined and are shown in logfs_2-logfo_2 diagrams; furthermore. the physico-chemical conditions of mineralization and the properties of mineralization solutions are discussed so that reliability of the genetic information provided by the spectroscopy of sphalerite may also be verified. It is suggested that the temperature and pH value of the mineralization system decrease, and so do the fugacities of O_2, S_2, H_2. and H_2S and the activities of HS^- and SO_4^(2-) from the early to late stages of minerahzation.
基金financially supported by the Yunnan Copper (Group) Co., LTD (grant No.20150104)
文摘Object The Eastern Kunlun Orogen(EKO), An important part of the Tethyan orogenic belt in the northern margin of the Qinghai–Tibet Plateau(Li et al., 2014; Ren Haidong et al., 2016), is a key area for geological research and mineral exploration(Li Bile et al., 2015). The Qimantag Mountain is located in middle segment of the EKO, which has experienced the Early Paleozoic and Late Paleozoic–Early
基金granted by the China State Mineral Resources Investigation Program (Grant No.12120113050700)
文摘Mississippi-Valley's carbonate-type (MVT) lead-zinc deposits are the most important type of lead-zinc deposits in the southwest of China. In 2013, China Geological Survey Bureau deployed a project named "Experimental Investigation of Integrated Prospecting Technology for Concealed Carbonate-Type Lead-Zinc Deposits in the Region of Sichuan, Yunnan and Guizhou Provinces". This project has been implemented by the Chengdu Center of China Geological Survey since 2013, and the project has run for 3 years. The general objective of this project is to establish an effective and adaptable integrated prospecting methodology (including geological, geophysical and geochemical techniques) in search for deep concealed lead-zinc deposits.
文摘Nineteen volcanic and magmatic rock samples were collected from the Jinding lead-zinc deposit and its surrounding areas in Yunnan. The ICP and AES analyses, referred to the previous results, show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ΣREE from the early to late stages of mineralization, and similarities in REE distribution patterns, indicating that the ore fluids are characterized by high LREE enrichment, markedly negative δCe anomaly and slight δEu anomaly. These REE distribution patterns exhibit striking similarities to those of the Pliocene trachyte in the study area, both of which are similar in ΣREE, LREE/HREE ratio, δEu and δCe. The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.
基金Supported by National Natural Science Foundation of China(No.41390444)
文摘Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin,located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volcanism. In order to lay the foundation on studying its diagenesis and mineralization ages,the detailed studies were carried out by dating the host rocks( i. e. rhyolitic lithic-crystal tuffs) using zircon LA-ICP-MS U-Pb method.The dating results show three groups of ages. The first group is the captured zircons( the weighted mean ^(206)Pb /^(238) U age as 175. 6 ± 2. 3 Ma,MSWD = 0. 70,n = 3). The second group can be regarded as the rockforming age( the weighted mean ^(206)Pb /^(238) U age as 165. 3 ± 1. 9 Ma,MSWD = 2. 40,n = 14). The third group should represent the late stage of the magmatic evolution( the weighted mean ^(206)Pb /^(238) U age as 161. 0 ± 3. 1Ma,MSWD = 0. 86,n = 4). According to the ages and the crystal form or CL image characteristics of zircons,it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geochronological research,the acidic pyroclastic rocks are space accompaniment and time connection with the Tamulangou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver,lead and zinc mineralization in this area.
文摘Qinling-type Pb-Zn deposits are located in the Qinling fold belt, occurring in the fine-clastic and carbonate rocks of the Devonian marine facies. They are reformed sedimentary deposits originating from hydrothermal waters, and may be subdivided into 2 subtypes: hydrothermal sedimentary deposits (Changba subtype) and reformed hydrothermal sedimentary deposits (Bijiashan-Qiandongshan subtype). In comparison with some of the famous Palaeozoic Pb-Zn deposits in the world, the Qinling-type Pb-Zn deposits constitute an independent type, which possesses some characteristics of both hydrothermal sedimentary deposits (Meggen type) and reformed hydrothermal deposits (Mississippi Valley type).
文摘An attempt is made in this paper to describe the following laws governing the distribution of lead-zinc deposits in China: spatial distribution laws, temporal distribution laws, deep level control laws, and deposits association and zoning laws.
文摘Organic matter, associated with ores, host rocks, ore source rocks and present in fluid inclusions in the Qixiashan lead zinc polymetallic deposit hosted in Upper Carboniferous dolomites and limestones in East China, was systematically analyzed using Fourier transform infrared spectroscopy, gas chromatography (GC), GC/mass spectrometry and proton induced X ray emission. The biomarker ratios of n C - 21 / n C + 22 alkanes, C 23 tricyclic/C 30 hopane and the tricyclic terpane parameters including C 21 /C 23 , C 19-20 /C 21-29 and C 19-25 /C 26-29 can effectively discriminate ores from host rocks. Extractable organic matter present in fluid inclusions displays similarities to those enclosed in the ore source rocks in the biomarker ratios, suggesting that a proportion of organic matter was introduced into the deposit from the ore source strata. The presence of copper and zinc in stage Ⅱ pyrobitumen indicates that some metals may have been transported by an organic fluid or removed from an aqueous fluid by organic matter.
文摘Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.
文摘As part of the hydro geological study of the Kherzet Youcef deposit, a drilling battery was carried out. The objective of this achievement is the satisfaction of the water needs of the city of Ain Azel (drinking water supply, irrigation and industrial water supply) and even the transfer to other municipalities suffering by the lack of water and the resumption of mining activity at the deposit of Kherzet Youcef. This water table is located in carbonate formations of Paleo-Neogene age linked to lead-zinc mineralization. Knowledge of water quality and its suitability for human consumption is an obligation. These metals have adverse health effects. We used the results of Sonarem’s analyses from 1973 to 1979. In addition, we carried out two analyses, during two years 2015-2016, on five boreholes. The parameters analyzed are major elements, physical parameters and trace metal elements (Zn, Pb and Fe). The analyses were done by ICP-AES. In our work, it has been shown that waste water is suitable for use in agriculture. For this we used the electrical conductivity at 25°C and those of the sodium adsorption ratio (SAR). For drinking water supply, monitoring the change in trace metal element (Zn, Pb and Fe) for two years has allowed us to conclude that groundwater in the groundwater table east of the Kherzet Youcef fault is generally acceptable. They are eligible by the quality standard set by Algerian regulations. However, they exceed the world health organization (WHO) standards, especially for lead. We recommend a revision of drinking water quality standards set by Algerian regulations, rigorous monitoring of TME content variation and water treatment before distribution.
文摘The Longtang Pb-Zn deposit occurs in the Upper Sinian Guanyinyan Formation. The host rocks include sandy shale, cherty limestone and dolomitic limestone.The deposit is a typical one of thallogen origin.The mineral assemblage in the ore is made up of sphalerite, galena, pyrite, enargite,tennantite, seligmannite, asphalt, etc. The ore-forming process is possessed of multiepisode and multi-stage characters. Generally sphalerites exhibit algal stromatolitic, bacterial and algal colloidal textures, providing evidence for the direct involvement of algaeand bacteria in mineralization of ore-forming elements during sedimentary diagenesis.This is the first transmingration of ore-forming elements. However, pyrite embracing bacteria and galena replacing/filling trichomes are typical organic textures, which are relatedto organic carbon and bitumen that can adsorb or reduce ore-forming elements. This is anindirect process of organic mineralization, i.e., the second transmigration of ore-formingelements. δ34S values are all greater than 5%o, indicating the dominance of the heavysulfur isotopes. The ore-forming temperature deduced from fluid inclusions ranges from100℃ to 150℃±. All this goes to show that the Longtang Pb-Zn deposit is of thallogenorlgin.
文摘Tumor deposits(TDs)are defined as discrete,irregular clusters of tumor cells lying in the soft tissue adjacent to but separate from the primary tumor,and are usually found in the lymphatic drainage area of the primary tumor.By definition,no residual lymph node structure should be identified in these tumor masses.At present,TDs are mainly reported in colorectal cancer,with a few reports in gastric cancer.There are very few reports on breast cancer(BC).For TDs,current dominant theories suggest that these are the result of lymph node metastasis of the tumor with complete destruction of the lymph nodes by the tumor tissue.Even some pathologists classify a TD as two lymph node metastases for calculation.Some pathologists also believe that TDs belong to the category of disseminated metastasis.Therefore,regardless of the origin,TDs are an indicator of poor prognosis.Moreover,for BC,sentinel lymph node biopsy is generally used at present.Whether radical axillary lymph node dissection should be adopted for BC with TDs in axillary lymph nodes is still inconclusive.The present commentary of this clinical issue has certain guiding significance.It is aimed to increase the awareness of the scientific community towards this under-recognized problem in BC pathology.