In this study, Pb was separated and used to prepare BaPbO3 conductive ceramics from leaded waste.The experimental results show that BaPbO3 powder synthesized at 700 °C has particle size of 2–5 lm. The powders we...In this study, Pb was separated and used to prepare BaPbO3 conductive ceramics from leaded waste.The experimental results show that BaPbO3 powder synthesized at 700 °C has particle size of 2–5 lm. The powders were densified by sintering at 1,000 °C for 2 h in the air.Synthesized BaPbO3 ceramics have high Curie temperature and high-temperature positive temperature coefficient(PTC) resistivity characteristics. Electrical resistivity of BaPbO3 compact increases from 5 × 10^-6Ω·m at room temperature to 4 × 10^-4Ω·m at 750 °C. Compared with the one prepared by pure chemical reagents, the BaPbO3 prepared from leaded waste has the similar characteristics of high Curie temperature and PTC resistivity.展开更多
基金financially supported by the Beijing Nova Program (No.Z141103001814006)the National Key Technology R&D Program (Nos. 2012BAC12B05 and 2012BAC02B01)+1 种基金the National Natural Science Foundation of China (Nos. 51174247 and U1360202)the National High-Tech Research and the Development Program of China (No. 2012AA063202)
文摘In this study, Pb was separated and used to prepare BaPbO3 conductive ceramics from leaded waste.The experimental results show that BaPbO3 powder synthesized at 700 °C has particle size of 2–5 lm. The powders were densified by sintering at 1,000 °C for 2 h in the air.Synthesized BaPbO3 ceramics have high Curie temperature and high-temperature positive temperature coefficient(PTC) resistivity characteristics. Electrical resistivity of BaPbO3 compact increases from 5 × 10^-6Ω·m at room temperature to 4 × 10^-4Ω·m at 750 °C. Compared with the one prepared by pure chemical reagents, the BaPbO3 prepared from leaded waste has the similar characteristics of high Curie temperature and PTC resistivity.