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南海陆坡中新世以来沉积物特性与气体水合物分布初探 被引量:63
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作者 苏新 陈芳 +1 位作者 于兴河 黄永样 《现代地质》 CAS CSCD 北大核心 2005年第1期1-13,共13页
通过对南海陆坡地区中新世以来沉积物的一些属性和特征的研究, 获得了下面的初步认识: (1)南海陆坡有几个沉积速率较高的地区, 如东沙一带、西沙海槽、中建南地区, 以及南沙西南部和西北部 (曾母、万安盆地 ); (2)大洋钻探钻井资料的研... 通过对南海陆坡地区中新世以来沉积物的一些属性和特征的研究, 获得了下面的初步认识: (1)南海陆坡有几个沉积速率较高的地区, 如东沙一带、西沙海槽、中建南地区, 以及南沙西南部和西北部 (曾母、万安盆地 ); (2)大洋钻探钻井资料的研究表明, 中新世与早上新世为高碳酸盐比值的低速堆积期, 而近 200万a以来为低碳酸盐比值的高速堆积期, 上新世晚期至全新世沉积物以粘土质粉砂和粉砂质粘土为最主要成分; (3)南海不同时期的沉积速率不同, 全新世为沉积速率最高的时期, 其次为更新世; 上新世和中新世为沉积速率较低的时期。南海利于气体水合物存藏的沉积可能为全新世和更新世的沉积; ( 4 )对南海晚第四纪以来沉积物的综合研究表明南海陆坡的A区 (东沙附近 )、B区(西沙海槽)、D区 (南海西部、越南以东 ) 等地区可能利于气体水合物的形成和分布; 而E区 (南沙西南部 )、F区(南沙中上部) 和G区 (南沙海槽) 则是气体水合物调查值得关注的地区。 展开更多
关键词 气体水合物 沉积物属性 沉积组分 南海陆坡 中新世 ODP 184航次
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深水沉积物波及其在南海研究之现状 被引量:39
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作者 钟广法 李前裕 +1 位作者 郝沪军 王嘹亮 《地球科学进展》 CAS CSCD 北大核心 2007年第9期907-913,共7页
深水沉积物波的研究始于20世纪50年代。根据成因和结构特征,可以将深水沉积物波划分为细粒底流、细粒浊流、粗粒底流和粗粒浊流等类型。不同类型的沉积物波具有不同的形态、物质组成及分布特征。已提出的深水沉积物波的形成模式主要有... 深水沉积物波的研究始于20世纪50年代。根据成因和结构特征,可以将深水沉积物波划分为细粒底流、细粒浊流、粗粒底流和粗粒浊流等类型。不同类型的沉积物波具有不同的形态、物质组成及分布特征。已提出的深水沉积物波的形成模式主要有背流波模式、逆行沙波模式、内波模式及底形和斜坡失稳混合模式等。1994年太阳号95航次和1999年ODP184航次揭示并证实,南海北部东沙岸外1144站所处的深水陆坡区发育有一高速沉积物牵引体。根据最新的地震资料分析发现,该牵引体实际上由一系列逆陆坡向上倾方向迁移的沉积物波组成,这一发现对于南海北部大陆边缘古海洋、古环境和古气候研究,以及南海深水油气勘探具有重要意义。 展开更多
关键词 深水沉积物波 底流沉积 浊流沉积 沉积物牵引体 南海 ODP 184航次
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寻求深海碳酸盐沉积含量的物理标志 被引量:7
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作者 黄维 刘志飞 +1 位作者 陈晓良 汪品先 《地球科学(中国地质大学学报)》 EI CAS CSCD 北大核心 2003年第2期157-162,共6页
运用岩心物理性质求取深海碳酸盐沉积的相对含量 ,是古海洋学研究中一种“多快好省”的办法 ,在低分辨率研究中取得成功 ,但在较高分辨率的研究中精度问题十分突出 .采用大洋钻探 (ODP) 184航次船上颜色反射率和磁化率数据 ,结合实验室... 运用岩心物理性质求取深海碳酸盐沉积的相对含量 ,是古海洋学研究中一种“多快好省”的办法 ,在低分辨率研究中取得成功 ,但在较高分辨率的研究中精度问题十分突出 .采用大洋钻探 (ODP) 184航次船上颜色反射率和磁化率数据 ,结合实验室碳酸盐化学分析实测结果 ,运用最小二乘法等数理分析方法 ,分别建立颜色反射率和磁化率与碳酸盐含量之间的拟合方程 ,估算碳酸盐含量 .结果表明 ,根据颜色反射率蓝色光波段值及其平方作为控制变量来拟合的碳酸盐含量 ,同实测值具有较高的一致性 ,误差较小 ;但是 ,用磁化率推算的碳酸盐含量同实测值比较则误差相当大 .用岩心物理性质推测的拟合方程是在开展一定量实测分析的基础上建立的 ,不同站位的这种拟合关系不能套用 ,只有当其他影响成分含量相当稳定或有规律变化时 ,运用岩心物理性质求取深海碳酸盐沉积含量的方法才具有相当高的应用价值 . 展开更多
关键词 碳酸盐 颜色反射率 磁化率 南海 大洋钻探 最小二乘法
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中更新世气候转型时期南海生态环境的南北差异 被引量:4
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作者 李前裕 汪品先 +6 位作者 陈木宏 郑范 王汝建 孙湘君 刘传联 成鑫荣 翦知湣 《地球科学进展》 CAS CSCD 北大核心 2006年第8期781-792,共12页
中更新世气候转型在南海浮游有孔虫、氧同位素和其它生物记录上主要反映在900kaBP前后发生高频率变化,特别是指示表层水骤然降温。北部冬季表层水温从24~25℃降至17~28℃,而南部也从26~27℃降至23~24℃。总的降温趋势与开放西太... 中更新世气候转型在南海浮游有孔虫、氧同位素和其它生物记录上主要反映在900kaBP前后发生高频率变化,特别是指示表层水骤然降温。北部冬季表层水温从24~25℃降至17~28℃,而南部也从26~27℃降至23~24℃。总的降温趋势与开放西太平洋一致,直接反映了西太平洋暖池在900kaBP之后MIS22期间有明显的减弱。表层水大幅度降温还发生在后继的MIS20、18、16几太冰期,说明主要冰期旋回周期由4lka转变为100ka经历了长达400ka的过渡时期,并且冬季风增强也在过渡时期的后半段最明显。南海南北生物组合和δ18O值的差异,突出了中更新世气候转型期边缘海区南北气候梯度反差和冬季风在冰期增强的讯号。结论是:生态环境系统反应总体表现与冰期旋回一致的同时。还包含了独特的地区性系统演变特征。但是,南海一西太平洋地区在0.9MaBP前后表层海水盐度因东亚冬季风和海平面下降的定量变化,以及这些变化对气候转型时期海-气耦合过程和生态环境系统的影响,尚缺乏足够的资料和证据。 展开更多
关键词 冰期旋回 中更新世 气候转型 季风 氧同位素 微体化石 南海 ODPl84航次
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利用地震资料反演地层的碳酸盐含量 被引量:3
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作者 熊艳 钟广法 +3 位作者 李前裕 吴能友 李学杰 马在田 《地球科学(中国地质大学学报)》 EI CAS CSCD 北大核心 2006年第6期851-856,共6页
基于碳酸盐含量与地层速度、密度之间的关系,在井资料约束下,使用人工神经网络方法反演高分辨率地震资料所反映的地层碳酸盐含量,并应用于南海北部陆坡ODP184航次1146和1148孔区,取得较好效果.方法的关键是从井旁地震道中提取多种属性,... 基于碳酸盐含量与地层速度、密度之间的关系,在井资料约束下,使用人工神经网络方法反演高分辨率地震资料所反映的地层碳酸盐含量,并应用于南海北部陆坡ODP184航次1146和1148孔区,取得较好效果.方法的关键是从井旁地震道中提取多种属性,利用逐步回归法,确定6种与碳酸盐含量相关性最好的地震属性,分别是平均频率、道积分绝对振幅、主频、时间、道微分瞬时振幅和瞬时频率,然后进行地层碳酸盐含量反演.反演结果相对于岩心分析的碳酸盐含量的误差大多在±5%之内,较为精确地揭示了地震地层剖面上碳酸盐含量的分布. 展开更多
关键词 碳酸盐含量反演 地震资料 人工神经网络 ODP184航次 南海北部
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Exploring Physical Indicators for Carbonate Contents in Deep Sea Sediments 被引量:1
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作者 Huang Wei Liu Zhifei Chen Xiaoliang Wang Pinxian Laboratory of Marine Geology, Tongji University, Shanghai200092 《Journal of China University of Geosciences》 SCIE CSCD 2003年第4期300-305,共6页
To determine carbonate contents of deep sea sediments using physical properties is an enjoyable and efficient paleoceanographic way, which has been processed successfully in many studies based on a low resolution, but... To determine carbonate contents of deep sea sediments using physical properties is an enjoyable and efficient paleoceanographic way, which has been processed successfully in many studies based on a low resolution, but rather than a high one. A series of mathematical methods including the least square method were used in this study to build multiple regression equations between color reflectance and carbonate content, and between magnetic susceptibility and carbonate content, based on the data of color reflectance and magnetic susceptibility collected via the ODP Leg 184 cruise, as well as measured carbonate contents. We found that percent carbonate estimated with diffuse reflectance is closer to the measured one than that estimated with magnetic susceptibility, and the multiple regression equation is varied in different sites. 展开更多
关键词 CARBONATE color reflectance magnetic susceptibility South China Sea ODP leg 184.
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南海东沙陆坡1144站沉积牵引体的地震层序框架及沉积演化
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作者 王长势 钟广法 +1 位作者 施和生 王嘹亮 《海洋地质与第四纪地质》 CAS CSCD 北大核心 2011年第6期55-63,共9页
以高分辨率二维地震资料为主,结合ODP184航次1144站位的钻井和测井资料,应用地震地层学原理,对南海北部东沙陆坡1144站所在沉积牵引体的形态、规模、内部结构及沉积演化进行研究,识别出了7个全区分布的不整合型层序界面。1144站合成记... 以高分辨率二维地震资料为主,结合ODP184航次1144站位的钻井和测井资料,应用地震地层学原理,对南海北部东沙陆坡1144站所在沉积牵引体的形态、规模、内部结构及沉积演化进行研究,识别出了7个全区分布的不整合型层序界面。1144站合成记录层位标定表明,除最底部的层序界面外,其余6个界面的地质年代自下而上分别约为1.09、0.88、0.65、0.30、0.13和0.02Ma;以上述7个不整合面及海底为边界,划分出了7个地震层序,自下而上依次为层序1~7。其中,层序1以杂乱的弱振幅反射为特征,解释为沉积牵引体发育前的滑塌或碎屑流沉积;层序2~7以平行—波状的连续中强振幅反射为特征,解释为沉积牵引体的主体,由此推测该沉积牵引体主要形成于约1.09Ma以来的中—晚更新世。编制了各层序的等T0厚度图,发现不同层序发育时期沉积厚度的横向变化较大,其沉积中心大致沿陆坡走向发生过4次比较明显的迁移。该沉积牵引体总体沿陆坡走向呈北东—南西向的不规则带状分布,保守估计其面积约为1 100km2,厚度为280~520m。 展开更多
关键词 沉积牵引体 地震层序分析 ODP184航次1144站 东沙陆坡 南海北部
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Stratal Carbonate Content Inversion Using Seismic Data and Its Applications to the Northern South China Sea
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作者 熊艳 钟广法 +3 位作者 李前裕 吴能友 李学杰 马在田 《Journal of China University of Geosciences》 SCIE CAS CSCD 2006年第4期320-325,354,共7页
On the basis of the relationship between the carbonate content and the stratal velocity and density, an exercise has been attempted using an artificial neural network on high-resolution seismic data for inversion of c... On the basis of the relationship between the carbonate content and the stratal velocity and density, an exercise has been attempted using an artificial neural network on high-resolution seismic data for inversion of carbonate content with limited well measarements as a control. The method was applied to the slope area of the northern South China Sea near ODP Sites 1146 and 1148, and the results are satisfaetory. Before inversion calculation, a stepwise regression method was applied to obtain six properties related most closely to the carbonate content variations among the various properties on the seismic profiles across or near the wells. These include the average frequency, the integrated absolute amplitude, the dominant frequency, the reflection time, the derivative instantaneous amplitude, and the instantaneous frequency. The results, with carbonate content errors of mostly ±5 % relative to those measured from sediment samples, show a relatively accurate picture of carbonate distribution along the slope profile. This method pioneers a new quantitative model to acquire carbonate content variations directly from high-resolution seismic data. It will provide a new approach toward obtaining substitutive high-resolution sediment data for earth system studies related to basin evolution, especially in discussing the coupling between regional sedimentation and climate change. 展开更多
关键词 carbonate content inversion seismic data artificial neural network ODP leg 184 northern South China Sea.
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中国加入国际大洋钻探计划的4年回顾 被引量:2
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作者 China Ocean Drilling Academic Committee 《海洋地质动态》 2002年第5期1-6,1,共6页
国际大洋钻探计划 ( ODP,1 985-2 0 0 3 )及其前身深海钻探计划 ( DSDP,1 968-1 983 ) ,是 2 0世纪地球科学规模最大、历时最久的国际合作研究计划 ,3 0余年来一直是推动学科发展的前沿 ,导致了学科的一场革命。我国经国务院领导批准于 ... 国际大洋钻探计划 ( ODP,1 985-2 0 0 3 )及其前身深海钻探计划 ( DSDP,1 968-1 983 ) ,是 2 0世纪地球科学规模最大、历时最久的国际合作研究计划 ,3 0余年来一直是推动学科发展的前沿 ,导致了学科的一场革命。我国经国务院领导批准于 1 998年春正式加入大洋钻探计划 ,年付 50万美金 ,成为第一个“参与成员”( Associated Member)。 4年来 ,已经取得重大进展。( 1 )成功地在南海实施了 ODP1 84航次。这次在我国科学家建议、设计和主持下的航次在南海二、三千米深水区的 6个站位取岩心 50 0 0多米 ,实现了中国海大洋钻探零的突破 ,使我国一举进入国际深海研究的前沿。在航次结束后的研究中 ,我国取得的成果也遥遥领先 ,不仅在不同时间尺度上取得了西太平洋区迄今为止最佳的深海沉积记录 ,而且在气候演变周期性、亚洲季风变迁和南海盆地演化等方面也获得了大量创新成果 ,其中包括学术上的突破性进展 ,目前正在逐步向国际学术界展示中。( 2 )促进了我国深海基础研究及其基地建设。加入 ODP4年来 ,我国深海基础研究迅速发展 ,继国家自然科学基金重大项目 (东亚古季风的海洋记录 )后 ,又于 2 0 0 0年底启动了国家重点基础研究规划项目 (地球圈层相互作用中的深海过程和深海记录 ) ,并实现了深海“973”项目? 展开更多
关键词 深海研究 南海 中国 国际大钻探计划
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Thirty million year deep-sea records in the South China Sea 被引量:43
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作者 WANGPinxian ZHAOQuanhong +7 位作者 JIANZhimin CHENGXinrong HUANGWei TIANJun WANGJiliang LIQianyu LIBaohua SUXin 《Chinese Science Bulletin》 SCIE EI CAS 2003年第23期2524-2535,共12页
In the spring of 1999 the Ocean Drilling Pro-gram (ODP) Leg 184 Shipboard Party cored 17 holes at 6 deep water sites in the northern and southern parts of the South China Sea (SCS). Chinese scientists actively partici... In the spring of 1999 the Ocean Drilling Pro-gram (ODP) Leg 184 Shipboard Party cored 17 holes at 6 deep water sites in the northern and southern parts of the South China Sea (SCS). Chinese scientists actively partici-pated in the entire process of this first deep-sea drilling leg off China, from proposal to post-cruise studies. More than 30 categories of analyses have been conducted post-cruise in various Chinese laboratories on a large number of core sam-ples, and the total number of analyses exceeded 60 thousand. The major scientific achievements of the Leg 184 studies are briefly reported in three successive papers, with the first one presented here dealing with deep-sea stratigraphy and evolu-tion of climate cycles. This ODP leg has established the best deep-sea stratigraphic sequences in the Western Pacific: the 23-Ma isotope sequence from the Dong-Sha area is unique worldwide because of its continuity; the last 5-Ma sequence from the Nansha area represents one of the best 4 ODP sites worldwide with the highest time-resolution for that time in-terval, and the sequences of physical properties enable a de-cadal-scale time resolution. All these together have provided for the first time high-quality marine records for paleoenvi-ronmental studies in the Asian-Pacific region. This new set of stratigraphic records has revealed changes in climate cyclic-ity over the last 20 Ma with the fluctuating power of the 100 ka, 400 ka, 2000 ka eccentricity cycles, indicating the evolv-ing response of the climate system to orbital forcing along with the growth of the Antarctic and Northern Hemisphere ice sheets. 展开更多
关键词 南中国海 海洋钻探工程 深海沉积 ODP SCS 轨道循环
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Grain-size records at ODP Site 1146 from the northern South China Sea: Implications on the East Asian monsoon evolution since 20 Ma 被引量:11
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作者 Jan-Berend W. STUUT 《Science China Earth Sciences》 SCIE EI CAS 2007年第10期1536-1547,共12页
273 samples from Ocean Drilling Program (ODP) Site 1146 in the northern South China Sea (SCS) were analyzed for grain-size distributions using grain-size class vs. standard deviation method and end-member modeling alg... 273 samples from Ocean Drilling Program (ODP) Site 1146 in the northern South China Sea (SCS) were analyzed for grain-size distributions using grain-size class vs. standard deviation method and end-member modeling algorithm (EMMA) in order to investigate the evolution of the East Asian monsoon since about 20 Ma. 10–19 μm/1.3–2.4 μm, the ratio of two grain-size populations with the highest variability through time was used to indicate East Asian winter monsoon intensity relative to summer monsoon. The mass accumulation rate of the coarsest end member EM1 (eolian), resulting from EMMA, can be used as a proxy of winter monsoon strength and Asian inland aridity, and the ratio of EM1/(EM2+EM3) as a proxy of winter monsoon intensity relative to summer monsoon. The combined proxies show that a profound enhancement of East Asian winter monsoon strength and winter monsoon intensity relative to summer monsoon occurred at about 8 Ma, and it is possible that the summer monsoon simultaneously intensified with winter monsoon at 3 Ma. Our results are well consistent with the previous studies in loess, eolian deposion in the Pacifc, radiolarians and planktonic foraminifera in the SCS. The phased uplift of the Himalaya-Tibetan Plateau may have played a significant role in strengthening the Asian monsoon at 8 Ma and 3 Ma. 展开更多
关键词 grain size EOLIAN dust East Asian monsoon South China Sea ODP leg184
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Evolution of the South China Sea and monsoon history revealed in deep-sea records 被引量:36
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作者 WANGPinxian JIANZhimin +17 位作者 ZHAOQuanhong LIQianyu WANGRujian LIUZhifei WUGuoxuan SHAOLei WANGJiliang HUANGBaoqi FANGDianyong TIANJun LIJianru LIXianhua WEIGangjian SUNXiangjun LUOYunli SUXin MAOShaozhi CHENMuhong 《Chinese Science Bulletin》 SCIE EI CAS 2003年第23期2549-2561,共13页
As the third summary report of ODP Leg 184 to the South China Sea (SCS), this paper discusses the evolution of the East Asian monsoon and the SCS basin. A multi-proxy approach, involving geochemistry, micropaleontolog... As the third summary report of ODP Leg 184 to the South China Sea (SCS), this paper discusses the evolution of the East Asian monsoon and the SCS basin. A multi-proxy approach, involving geochemistry, micropaleontology, pollen and other analyses, was adopted for reconstructing the evolutionary history of the East Asian monsoon, which was characterized by a series of paleo-climate events especially at 8, 3.2, 2.2 and 0.4 Ma. The new record indicates similar stages in the development of the East and South Asian monsoons, with an enhanced winter monsoon over East Asia being the major difference. The rich spectrums of monsoon variability from the southern SCS also reveal other characteristic features of the low latitude ocean. Evidence for the evolution of the SCS includes the hemipelagic Oligocene sediments, implying the existence of deep water environments during the early seafloor spreading stage of the SCS basin. The four major unconformities and some remarkable diagenetic features in upper Oligocene deposits indicate the strongest tectonic events in the region. From a careful comparison of lithologies and sedimentation rates, we conclude that the prominent differences in sedimentary environments between the southern and northern SCS were established only by ~3 Ma. 展开更多
关键词 南中国海 深海沉积 ODP 海洋钻探工程 东亚季风
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Exploring cyclic changes of the ocean carbon reservoir 被引量:17
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作者 WANG Pinxian, TIAN Jun, CHENG Xinrong, LIU Quanlian & XU Jian Key Laboratory of Marine Geology, Ministry of Education, Tongji Uni-versity, Shanghai 200092, China 《Chinese Science Bulletin》 SCIE EI CAS 2003年第23期2536-2548,共13页
A 5-Ma record from ODP Site 1143 has re-vealed the long-term cycles of 400—500 ka in the carbon isotope variations. The periodicity is correlatable all over the global ocean and hence indicative of low-frequency chan... A 5-Ma record from ODP Site 1143 has re-vealed the long-term cycles of 400—500 ka in the carbon isotope variations. The periodicity is correlatable all over the global ocean and hence indicative of low-frequency changes in the ocean carbon reservoir. As the same periodicity is also found in carbonate and eolian dust records in the tropical ocean, it may have been caused by such low-latitude proc-esses like monsoon. According to the Quaternary records from Site 1143 and elsewhere, major ice-sheet expansion and major transition in glacial cyclicity (such as the Mid-Brunhes Event and the Mid-Pleistocene Revolution ) were all pre-ceded by reorganization in the ocean carbon reservoir ex-pressed as an episode of carbon isotope maximum (d 13Cmax), implying the role of carbon cycling in modulating the glacial periodicity. The Quaternary glacial cycles, therefore, should no more be ascribed to the physical response to insolation changes at the Northern Hemisphere high latitudes alone; rather, they have been driven by the 揹ouble forcing? a combination of processes at both high and low latitudes, and of processes in both physical (ice-sheet) and biogeochemical (carbon cycling) realms. As the Earth is now passing through a new carbon isotope maximum, it is of vital impor-tance to understand the cyclic variations in the ocean carbon reservoir and its climate impact. The Pre-Quaternary varia-tions in carbon and oxygen isotopes are characterized by their co-variations at the 400-ka eccentricity band, but the response of d 13C and d 18O to orbital forcing in the Quater-nary became diverged with the growth of the Arctic ice-sheet. The present paper is the second summary report of ODP Leg 184 to the South China Sea. 展开更多
关键词 海洋 ODP 海洋钻探工程 碳循环 南中国海 地层学
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Quaternary biogenic opal records in the South China Sea: Linkages to East Asian monsoon, global ice volume and orbital forcing 被引量:10
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作者 WANG RuJian JIAN ZhiMin +5 位作者 XIAO WenShen TIAN Jun LI JianRu CHEN RongHua ZHENG YuLong CHEN JianFang 《Science China Earth Sciences》 SCIE EI CAS 2007年第5期710-724,共15页
Particulate fluxes investigated in the central South China Sea (SCS) during 1993―1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary ... Particulate fluxes investigated in the central South China Sea (SCS) during 1993―1996 indicate that opal flux can be used to show primary productivity change, which provides a foundation for tracing the evolutionary relationship between the surface productivity and East Asian monsoon in the SCS during the late Quaternary glacial and interglacial periods. Based on the studies of opal % and their mass accumulation rates (MAR) at the six sites recovered from the SCS during the “Resolution” ODP Leg 184 and “Sonne” 95 cruise of the Sino-Germany cooperation, opal % and their MARs increased evidently in the northern sites since 470―900 ka, and they enhanced and reduced, respectively, during the glacial and interglacial periods. Whereas they increased obviously in the southern sites since 420―450 ka, and they augmented and declined, respectively, during the interglacial and glacial periods. The vari- ability in opal % and their MARs in the late Quaternary glacial cyclicity indicate the “seesaw” pattern of surface productivity in the SCS. The winter monsoon intensified during the glacial periods, surface productivity increased and decreased, respectively, in the northern and southern SCS. The summer monsoon strengthened during the interglacial periods, surface productivity increased and decreased, respectively, in the southern and northern SCS. The cross spectral analyses between the opal % in the northern and southern SCS during the Quaternary and global ice volume (δ 18O) and orbital forcing (ETP) indicate that the East Asian winter and summer monsoons could be ascribed to the different drive mechanisms. On the orbital time scale, the global ice volume change could be a dominant factor for the winter monsoon intension and temporal variations. As compared with the winter monsoon, the correlative summer solar radiation with the obliquity and precession in the Northern Hemisphere could be a mostly controlling factor for the summer monsoon intension and temporal variations. 展开更多
关键词 BIOGENIC OPAL surface productivity East Asian monsoon GLOBAL ice volume orbital FORCING ODP leg 184 QUATERNARY South China Sea
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