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Quantum Spin Exchange Interactions to Accelerate the Redox Kinetics in Li–S Batteries
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作者 Yu Du Weijie Chen +4 位作者 Yu Wang Yue Yu Kai Guo Gan Qu Jianan Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期370-383,共14页
Spin-engineering with electrocatalysts have been exploited to suppress the“shuttle effect”in Li–S batteries.Spin selec-tion,spin-dependent electron mobility and spin potentials in activation barriers can be optimiz... Spin-engineering with electrocatalysts have been exploited to suppress the“shuttle effect”in Li–S batteries.Spin selec-tion,spin-dependent electron mobility and spin potentials in activation barriers can be optimized as quantum spin exchange interactions lead-ing to a significant reduction of the electronic repulsions in the orbitals of catalysts.Herein,we anchor the MgPc molecules on fluorinated carbon nanotubes(MgPc@FCNT),which exhibits the single active Mg sites with axial displacement.According to the density functional theory calculations,the electronic spin polarization in MgPc@FCNT not only increases the adsorption energy toward LiPSs intermediates but also facilitates the tunneling process of electron in Li–S batter-ies.As a result,the MgPc@FCNT provides an initial capacity of 6.1 mAh cm^(-2) even when the high sulfur loading is 4.5 mg cm^(-2),and still maintains 5.1 mAh cm^(-2) after 100 cycles.This work provides a new perspective to extend the main group single-atom catalysts enabling high-performance Li–S batteries. 展开更多
关键词 Metal phthalocyanines spin polarization ELECTROCATALYsIs lis batteries
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Mechanochemical strategy assisted morphology recombination of COFs for promoted kinetics and LiPS transformation in Li-S batteries
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作者 Yunchen Ge Yan Meng +3 位作者 Lin Liu Jianming Li Xuechun Huang Dan Xiao 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第12期1822-1834,共13页
A covalent organic frameworks(COFs)material with regular pores and stable structure can be used as the host of lithium-sulfur batteries to improve battery kinetics and polysulfides conversion.Herein,we designed and sy... A covalent organic frameworks(COFs)material with regular pores and stable structure can be used as the host of lithium-sulfur batteries to improve battery kinetics and polysulfides conversion.Herein,we designed and synthesized two kinds of rod-liked bulk COFs by adjusting different pore sizes(COF-BTD and COF-TFB),unfortunately,the active sites masking and sluggish kinetics have not met our expectations.Generally,the available layered COFs prepared from mechanochemical can expose abundant active sites and favorable kinetics than bulk COFs.Thus,simple mechanical ball milling is applied to activate the above COFs(M-COFs group).It is worth noting that layered R-COF-BTD is directly synthesized from rod-liked precursors by simple morphological reconstruction.A series of characterization methods are used to systematically explore the advantages of the group of M-COFs@S electrodes in the cycling process,including the effects of specific morphology on the kinetics and transformation of polysulfides.Our research provides a feasible plan for the development and selection of the host material of lithium-sulfur batteries. 展开更多
关键词 Covalent organic frameworks Ball milling Recombination of morphology lis batteries
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Refuting the Misconception:Li Bai as an Impolite Person
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作者 HE Xiangjun 《Cultural and Religious Studies》 2024年第10期635-640,共6页
This essay endeavors to dispel the lingering misconception that Li Bai,the celebrated Tang Dynasty poet,was a man devoid of propriety.Through a meticulous examination of historical records,literary works,and contempor... This essay endeavors to dispel the lingering misconception that Li Bai,the celebrated Tang Dynasty poet,was a man devoid of propriety.Through a meticulous examination of historical records,literary works,and contemporary interpretations,this study presents a nuanced portrait of Li Bai as a poet who,despite his eccentricities and wanderlust,possessed a profound sense of etiquette and respect for societal norms.This essay argues that his unique personality in life and free expression in poetry are all driven by the need for artistic creation,rather than challenging for ancient propriety. 展开更多
关键词 li Bai propriety culture rituals Great Preface poetry expresses aspirations
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Rebellious Spirit in Shelley’s Poetry
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作者 李蓉 《文山师范高等专科学校学报》 2003年第3期186-190,共5页
雪莱的诗歌反映了他争取平等和自由的反叛思想。诗歌中揭示了他对上层阶级的诅咒 。
关键词 雪莱诗歌 反叛思想 平等 自由
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The Influence of Miao Nationality’s Culture in Yuan Xiang Region on the Later Poetry Creation of Qu Yuan
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作者 GUO Xiaochun 《Cultural and Religious Studies》 2020年第8期467-472,共6页
Miao culture is one of the minority cultures in China.It also has a certain impact on the development of Chinese literature and poetry.Chu ci is a new poetic style created by Qu Yuan,an ancient poet in China.It is the... Miao culture is one of the minority cultures in China.It also has a certain impact on the development of Chinese literature and poetry.Chu ci is a new poetic style created by Qu Yuan,an ancient poet in China.It is the first collection of romantic poetry in the history of Chinese literature.Qu Yuan’s poetry creation is related to his life experience.Qu Yuan was exiled to Yuan Xiang region,and he had been in contact with the Miao ancestors in Yuan Xiang area during the exile.Therefore,the Miao land culture in Yuan Xiang area has a profound influence on Qu Yuan’s later poetry creation.This paper,taking Qu Yuan’s later poetry as an example,analyzes the influence of Miao culture on Chu ci in Yuan Xiang area,introduces Qu Yuan’s life and how to contact Miao culture,and probes into the influence of Miao nationality’s religious thought,customs,language and culture,oral folk song and pan song on the later poetry creation of Qu Yuan. 展开更多
关键词 Miao nationality’s culture the songs of Chu influence Qu Yuan’s poetry Yuan Xiang region
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Boundary of Domestication:Christianized Imagery in English Translations of Mao Zedong’s Poetry
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作者 LI Dong-lin 《Journal of Literature and Art Studies》 2022年第10期1021-1030,共10页
The abundant imagery in Mao Zedong’s poetry is of great political and cultural significance and its English translation plays a major role in spreading New China’s influences worldwide.Comparison reveals that,in tra... The abundant imagery in Mao Zedong’s poetry is of great political and cultural significance and its English translation plays a major role in spreading New China’s influences worldwide.Comparison reveals that,in translations of a particular kind of imagery with supernatural meanings,some translators took a domesticating stance and Christianized some images with supernatural connotations,adding to them strong Western mythological features.It misinterprets the political and cultural connotations of the original,which is harmful to establish a proper political image and cultural confidence,and violates Mao’s translation thoughts and expectations.Christianization and its causes should be critically investigated.New boundaries should be set for foreignization and domestication methods.By viewing the relationships between the translator’s subjectivity and the author’s will,as well as the pursuit of translation effect and the defence of ideological security,new discourse will be explored to tell the Chinese stories with profound political and cultural thoughts in Mao’s poetry in a correct and well-accepted way. 展开更多
关键词 Mao Zedong’s poetry imagery translation Christianization DOMEsTICATION
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Poetry Translation and Cultural Transmission——the English Version of the Classical Chinese Poem “Bring in the Wine”
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作者 刘圆圆 《海外英语》 2019年第14期45-46,共2页
This article,based on the English version of Li Bai's Classical Chinese Poem“Bring in the Wine”,explores the important position of cultural transmission in the English translation of the Classical Chinese Poem t... This article,based on the English version of Li Bai's Classical Chinese Poem“Bring in the Wine”,explores the important position of cultural transmission in the English translation of the Classical Chinese Poem through the comparison of the cultural translation,and finally draws the rationality and feasibility of the creative translation techniques in the English translation of the Classical Chinese Poems.It points out that the alienation of the Chinese culture's external communication has ignored the reader's cultural acceptance ability and position of the western countries and regions dominated by the foreign countries.It is believed that in a long period of time,Chinese culture needs the translation of Chinese translators to dissimilation,the translation of foreign sinologists,domestication,and alienation,to meet the needs of different types of readers and to promote the Chinese culture to go out. 展开更多
关键词 English TRANsLATION of classical poetry cultural transmission li Bai “Bring in the Wine” creative TRANsLATION FOREIGNIZATION DOMEsTICATION
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A Survey of English Translation Studies of Lu You’s Poetry Based on the Data Analysis of Domestic Academic Journals (2001-2022)
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作者 Dongfang Chen Jiesen Ma 《Open Journal of Applied Sciences》 2023年第6期847-857,共11页
This article presents a comprehensive analysis of the current state of research on the English translation of Lu You’s poetry, utilizing a data sample comprising research papers published in the CNKI Full-text Databa... This article presents a comprehensive analysis of the current state of research on the English translation of Lu You’s poetry, utilizing a data sample comprising research papers published in the CNKI Full-text Database from 2001 to 2022. Employing rigorous longitudinal statistical methods, the study examines the progress achieved over the past two decades. Notably, domestic researchers have displayed considerable interest in the study of Lu You’s English translation works since 2001. The research on the English translation of Lu You’s poetry reveals a diverse range of perspectives, indicating a rich body of scholarship. However, several challenges persist, including insufficient research, limited translation coverage, and a noticeable focus on specific poems such as “Phoenix Hairpin” in the realm of English translation research. Consequently, there is ample room for improvement in the quality of research output on the English translation of Lu You’s poems, as well as its recognition within the academic community. Building on these findings, it is argued that future investigations pertaining to the English translation of Lu You’s poetry should transcend the boundaries of textual analysis and encompass broader theoretical perspectives and research methodologies. By undertaking this shift, scholars will develop a more profound comprehension of Lu You’s poetic works and make substantive contributions to the field of translation studies. Thus, this article aims to bridge the gap between past research endeavors and future possibilities, serving as a guide and inspiration for scholars to embark on a more nuanced and enriching exploration of Lu You’s poetry as well as other Chinese literature classics. 展开更多
关键词 Lu You’s poetry English Translation studies Data Analysis Translation Criticism
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基于B/S模式的医学实验室信息平台(LIS)的设计与实现 被引量:10
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作者 贺建峰 宝媛媛 +3 位作者 张俊 胡杨升 张昊 张明军 《计算机应用与软件》 CSCD 2016年第3期83-86,共4页
随着医疗信息化的发展和对检验要求的提高,医学检验实现信息化管理已成为必然趋势,这也使得LIS在专业细分多、技术要素复杂的医学实验室信息管理中越来越重要。然而,传统的LIS大多基于C/S模式进行开发,这种模式开发的平台安装繁琐,扩展... 随着医疗信息化的发展和对检验要求的提高,医学检验实现信息化管理已成为必然趋势,这也使得LIS在专业细分多、技术要素复杂的医学实验室信息管理中越来越重要。然而,传统的LIS大多基于C/S模式进行开发,这种模式开发的平台安装繁琐,扩展性和分布能力差,实现维护和平台移植困难。针对这些问题,基于B/S模式,运用SSH框架和Ext JS技术对LIS平台进行研究并设计开发了一种医学实验室信息平台。结果表明,该平台有效地解决了传统LIS的许多不足,完成并实现了医学实验室的规范管理与信息融合,提高了工作效率。 展开更多
关键词 检验科 lis C/s B/s模式 ssH框架 ExtJs技术
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Li/S电池凝胶聚合物电解质的研究 被引量:7
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作者 马萍 徐宇虹 +2 位作者 张宝宏 殷金玲 孟祥利 《电池》 CAS CSCD 北大核心 2006年第6期426-428,共3页
通过溶液浇注和电解液吸收的方法,制备了PVDF-PEO类凝胶聚合物电解质膜,该膜有良好的透明性和柔韧性。PVDF-PEO凝胶聚合物电解质[n(PEO):n(PVDF)=0.5]在室温下的电导率最高可达7.03 mS/cm,吸液率达76.1%,电化学稳定窗口达4.1 V。将该电... 通过溶液浇注和电解液吸收的方法,制备了PVDF-PEO类凝胶聚合物电解质膜,该膜有良好的透明性和柔韧性。PVDF-PEO凝胶聚合物电解质[n(PEO):n(PVDF)=0.5]在室温下的电导率最高可达7.03 mS/cm,吸液率达76.1%,电化学稳定窗口达4.1 V。将该电解质[n(PEO)∶n(PVDF)]应用在Li/S电池上,经过15次充放电循环后,电池的放电比容量仍在400 mAh/g以上。 展开更多
关键词 凝胶聚合物电解质 PVDF PEO li/s电池
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软包装Li/S电池的性能研究 被引量:3
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作者 余仲宝 王维坤 +1 位作者 王安邦 杨裕生 《电池》 CAS CSCD 北大核心 2007年第4期247-249,共3页
应用软包装技术,用S-C复合材料作为Li/S电池的正极材料,组装了软包装Li/S电池。性能测试结果表明:120 mA首次放电容量达1700 mAh,比能量达300 Wh/kg;循环50次(100 mA)后的容量保持率约为60%。在0℃和-20℃下的放电容量(100 mA)分别达25... 应用软包装技术,用S-C复合材料作为Li/S电池的正极材料,组装了软包装Li/S电池。性能测试结果表明:120 mA首次放电容量达1700 mAh,比能量达300 Wh/kg;循环50次(100 mA)后的容量保持率约为60%。在0℃和-20℃下的放电容量(100 mA)分别达25℃下放电容量的90%和40%。电池在过充电和短路等滥用条件下,不燃烧、不爆炸。 展开更多
关键词 软包装 li/s电池 性能
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提高Li/S电池性能的研究进展 被引量:2
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作者 张勇 武行兵 +1 位作者 张爱勤 王力臻 《电池》 CAS CSCD 北大核心 2008年第4期257-259,共3页
综述了提高Li/S电池性能的研究进展,包括比容量、循环寿命、高功率性能和高低温性能;对研究方向作了简单的评述。
关键词 li/s电池 电化学性能 研究进展
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B/S结构LIS系统的应用体会 被引量:6
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作者 王会中 张金树 +1 位作者 孙宇 高德禄 《国际检验医学杂志》 CAS 2011年第5期621-622,共2页
当前,现代检验医学已步入了一个以自动化、信息化、网络化为主要特征的新时期。检验水平和检测手段日新月异,临床检验工作日趋自动化、规范化、信息化,因而建立一套功能强大的实验室信息系统(laboratory information system,LIS)... 当前,现代检验医学已步入了一个以自动化、信息化、网络化为主要特征的新时期。检验水平和检测手段日新月异,临床检验工作日趋自动化、规范化、信息化,因而建立一套功能强大的实验室信息系统(laboratory information system,LIS)是现代临床实验室必不可少的。如今的LIS已不仅仅局限于标本管理、数据采集、报告打印等简单的功能,信息技术的发展、医疗体制改革的要求以及各种严格的行业规范,将LIS推向了前所未有的高度。 展开更多
关键词 lis系统 B/s结构 实验室信息系统 临床实验室 应用 医疗体制改革 检验医学 检验工作
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电解质体系对FeS_2/LiSi热电池激活时间的影响研究 被引量:2
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作者 康博 邢永慧 +2 位作者 赵亚旭 曹军记 林海波 《电源技术》 CAS CSCD 北大核心 2015年第10期2153-2154,共2页
采用空载和带载两种放电方式,研究了热电池常用的二元和三元全锂电解质体系对Fe S2/Li Si热电池激活时间的影响。实验结果表明:空载放电时,二元电解质激活时间短;带载放电时,三元全锂电解质激活时间短。
关键词 电解质 FE s2/li si热电池 激活时间
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不同生物炭材料的制备及其在Li-S电池中的应用(英文) 被引量:7
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作者 李君涛 吴娇红 +1 位作者 张涛 黄令 《物理化学学报》 SCIE CAS CSCD 北大核心 2017年第5期968-975,共8页
通过可再生生物质制备的生物炭具有成本低、环保和资源可再生的优势。本研究以分布广泛的稻谷壳、芒草、杉木和柚子皮等生物质为原料,制备了4种不同类型生物炭,然后研究了其作为锂-硫电池硫/碳正极的载体的性能。研究表明由稻谷壳制备的... 通过可再生生物质制备的生物炭具有成本低、环保和资源可再生的优势。本研究以分布广泛的稻谷壳、芒草、杉木和柚子皮等生物质为原料,制备了4种不同类型生物炭,然后研究了其作为锂-硫电池硫/碳正极的载体的性能。研究表明由稻谷壳制备的硫/生物炭正极材料表现出最高的比容量和最优的循环稳定性。为了进一步改善其电性能,以SiO_2溶胶为模板制备了具有高孔隙率的稻谷壳生物炭,其多孔结构可有效抑制多硫化物的溶解。由此得到的硫/生物炭(硫含量为60%(w,质量分数))材料中的硫以无定型态均匀地分散在碳载体中。该材料表现出更优异的电化学性能:在0.2C(1C=1675 m A?g^(-1))倍率下,首周放电容量为1534.1 mAh?g^(-1),循环100周后仍可保持在783.7 mAh?g^(-1);倍率性能测试中,在2.0C倍率下,材料的可逆容量为485.3 mAh?g^(-1)。 展开更多
关键词 锂硫电池 复合物 稻壳 芒草 杉木 柚子皮
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SiCp/Al-Li复合材料的微观结构性能、及断裂特征 被引量:2
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作者 马宗义 毕敬 +2 位作者 吕毓雄 申红伟 高荫轩 《复合材料学报》 EI CAS CSCD 北大核心 1994年第1期43-47,共5页
本文对粉末冶金法制备的SiCp/Al-Li复合材料进行了不同温度的拉伸试验和透射电镜分析,结果表明,该复合材料具有高的室温强度和低的延伸率。在复合材料基体晶界和SiC颗粒界面处均存在一定宽度的无沉淀带。微裂纹常在基体... 本文对粉末冶金法制备的SiCp/Al-Li复合材料进行了不同温度的拉伸试验和透射电镜分析,结果表明,该复合材料具有高的室温强度和低的延伸率。在复合材料基体晶界和SiC颗粒界面处均存在一定宽度的无沉淀带。微裂纹常在基体晶界和SiC颗粒界面处形成。复合材料的断裂形貌为韧窝加沿晶断裂。 展开更多
关键词 复合材料 结构 性能
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S-Co复合掺杂LiMn_2O_4的合成与性能 被引量:4
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作者 夏君磊 赵世玺 +1 位作者 刘韩星 欧阳世翕 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2003年第4期942-946,共5页
为了扩大锂离子电池正极材料Li_xMn_2O_4的工作电压范围,在保证良好循环性能的基础上提高材料的容量,本文对S-Co复合掺杂LiMn_2O_4的合成工艺和电化学性能进行了研究。溶胶-凝胶法合成的各试样均为纯的立方尖晶石相,且结晶状态良好。S-C... 为了扩大锂离子电池正极材料Li_xMn_2O_4的工作电压范围,在保证良好循环性能的基础上提高材料的容量,本文对S-Co复合掺杂LiMn_2O_4的合成工艺和电化学性能进行了研究。溶胶-凝胶法合成的各试样均为纯的立方尖晶石相,且结晶状态良好。S-Co复合掺杂综合了S掺杂效应和Co掺杂效应,改善了LiMn_2O_4的电化学性能,在2.4~4.3V充放电压范围内,初始容量较高,达到170mAh/g,30次循环后容量不但没有衰减而且有一定增加。 展开更多
关键词 锂离子电池 正极材料 liMN2O4 s-Co复合掺杂
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6σ混料设计优选Li/S一次电池正极组分配比工艺 被引量:1
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作者 张勇 武行兵 +4 位作者 王力臻 张爱勤 冯辉 夏同驰 董会超 《郑州轻工业学院学报(自然科学版)》 CAS 2009年第1期46-49,共4页
采用混料实验设计,探讨了Li/S一次电池硫正极各组分的最优配比.响应优化预测结果显示,当m(S)∶m(SP)∶m(PVDF)=0.4∶0.43∶0.17时,电池放电比容量达到454 mAh/g.在此优化比例条件下实验验证结果为467 mAh/g.同时,电化学阻抗测试结果显示... 采用混料实验设计,探讨了Li/S一次电池硫正极各组分的最优配比.响应优化预测结果显示,当m(S)∶m(SP)∶m(PVDF)=0.4∶0.43∶0.17时,电池放电比容量达到454 mAh/g.在此优化比例条件下实验验证结果为467 mAh/g.同时,电化学阻抗测试结果显示,最优比例下的阻抗较小. 展开更多
关键词 混料设计 锂/硫电池 最优配比
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不同浓度Li_2SO_4水溶液结构的X射线衍射研究 被引量:1
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作者 房艳 房春晖 高世扬 《盐湖研究》 CSCD 2003年第2期41-45,共5页
用θ~ 2θ型粉末衍射仪反射法精确测量了不同浓度的Li2 SO4水溶液的衍射数据 ,通过数据处理给出了溶液的结构函数和径向分布函数 ,由几何结构模型的最小二乘法精修 ,得到了溶液中阳离子和阴离子第一、二水合层的结构参数。
关键词 li2s04水溶液结构 X射线衍射 数据处理 结构函数 径向分布函数 最小二乘法 硫酸锂 溶液配位化学
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Li/S电池电解质的研究进展与展望
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作者 翟丽娟 陈效华 +2 位作者 李燕 秦兆东 刘志远 《华南师范大学学报(自然科学版)》 CAS 北大核心 2009年第A02期96-97,110,共3页
综述了Li/S电池电解质的研究进展,并对发展前景做了展望.
关键词 li/s电池 电解质 研究进展
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