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Regulating interfacial chemistry and kinetic behaviors of F/Mo co-doping Ni-rich layered oxide cathode for long-cycling lithium-ion batteries over-20°C-60°C
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作者 Siqi Guan Lin Tao +9 位作者 Pei Tang Ruopian Fang Huize Wu Nan Piao Huicong Yang Guangjian Hu Xin Geng Lixiang Li Baigang An Feng Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期449-457,共9页
Ni-rich layered oxide cathodes have shown promise for high-energy lithium-ion batteries(LIBs)but are usually limited to mild environments because of their rapid performance degradation under extreme temperature condit... Ni-rich layered oxide cathodes have shown promise for high-energy lithium-ion batteries(LIBs)but are usually limited to mild environments because of their rapid performance degradation under extreme temperature conditions(below0°C and above 50 °C).Here,we report the design of F/Mo co-doped LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(FMNCM)cathode for high-performance LIBs from-20 to 60°C.F^(-) doping with high electronegativity into the cathode surface is found to enhance the stability of surface lattice structure and protect the interface from side reactions with the electrolyte by generating a LiF-rich surface layer.Concurrently,the Mo^(6+) doping suppresses phase transition,which blocks Li^(+)/Ni^(2+) mixing,and stabilizes lithium-ion diffusion pathway.Remarkably,the FMNCM cathode demonstrates excellent cycling stability at a high cutoff voltage of 4.4 V,even at 60°C,maintaining 90.6%capacity retention at 3 C after 150 cycles.Additionally,at temperatures as low as-20°C,it retains 77.1%of its room temperature capacity,achieving an impressive 97.5%capacity retention after 500 cycles.Such stable operation under wide temperatures has been further validated in practical Ah-level pouch-cells.This study sheds light on both fundamental mechanisms and practical implications for the design of advanced cathode materials for wide-temperature LIBs,presenting a promising path towards high-energy and long-cycling LIBs with temperatureadaptability. 展开更多
关键词 Anion-cation co-doping Wide temperature operation Ni-richlayered cathode Phase transition Surface/interface
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A bi-functional strategy involving surface coating and subsurface gradient co-doping for enhanced cycle stability of LiCoO_(2) at 4.6 V 被引量:2
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作者 Yun He Xiaoliang Ding +7 位作者 Tao Cheng Hongyu Cheng Meng Liu Zhijie Feng Yijia Huang Menghan Ge Yingchun Lyu Bingkun Guo 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第2期553-560,I0014,共9页
Layered LiCoO_(2)(LCO)acts as a dominant cathode material for lithium-ion batteries(LIBs)in 3C products because of its high compacted density and volumetric energy density.Although improving the high cutoff voltage is... Layered LiCoO_(2)(LCO)acts as a dominant cathode material for lithium-ion batteries(LIBs)in 3C products because of its high compacted density and volumetric energy density.Although improving the high cutoff voltage is an effective strategy to increase its capacity,such behavior would trigger rapid capacity decay due to the surface or/and structure degradation.Herein,we propose a bi-functional surface strategy involving constructing a robust spinel-like phase coating layer with great integrity and compatibility to LiCoO_(2) and modulating crystal lattice by anion and cation gradient co-doping at the subsurface.As a result,the modified LiCoO_(2)(AFM-LCO)shows a capacity retention of 80.9%after 500 cycles between 3.0and 4.6 V.The Al,F,Mg enriched spinel-like phase coating layer serves as a robust physical barrier to effectively inhibit the undesired side reactions between the electrolyte and the cathode.Meanwhile,the Al,F,Mg gradient co-doping significantly enhances the surficial structure stability,suppresses Co dissolution and oxygen release,providing a stable path for Li-ions mobility all through the long-term cycles.Thus,the surface bi-functional strategy is an effective method to synergistically improve the electrochemical performances of LCO at a high cut-off voltage of 4.6 V. 展开更多
关键词 Lithium-ion batteries 4.6 V-LiCoO_(2) Surface modification Gradient co-doping Interfacial stability
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Integration of pore structure modulation and B,N co-doping for enhanced capacitance deionization of biomass-derived carbon
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作者 Yao Qiu Chunjie Zhang +7 位作者 Rui Zhang Zhiyuan Liu Huazeng Yang Shuai Qi Yongzhao Hou Guangwu Wen Jilei Liu Dong Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2023年第5期1488-1500,共13页
Biomass-derived carbon has demonstrated great potentials as advanced electrode for capacitive deionization(CDI),owing to good electroconductivity,easy availability,intrinsic pores/channels.However,conventional simple ... Biomass-derived carbon has demonstrated great potentials as advanced electrode for capacitive deionization(CDI),owing to good electroconductivity,easy availability,intrinsic pores/channels.However,conventional simple pyrolysis of biomass always generates inadequate porosity with limited surface area.Moreover,biomass-derived carbon also suffers from poor wettability and single physical adsorption of ions,resulting in limited desalination performance.Herein,pore structure optimization and element co-doping are integrated on banana peels(BP)-derived carbon to construct hierarchically porous and B,N co-doped carbon with large ions-accessible surface area.A unique expansionactivation(EA)strategy is proposed to modulate the porosity and specific surface area of carbon.Furthermore,B,N co-doping could increase the ions-accessible sites with improved hydrophilicity,and promote ions adsorption.Benefitting from the synergistic effect of hierarchical porosity and B,N co-doping,the resultant electrode manifest enhanced CDI performance for NaCl with large desalination capacity(29.5 mg g^(-1)),high salt adsorption rate(6.2 mg g^(-1)min^(-1)),and versatile adsorption ability for other salts.Density functional theory reveals the enhanced deionization mechanism by pore and B,N co-doping.This work proposes a facile EA strategy for pore structure modulation of biomass-derived carbon,and demonstrates great potentials of integrating pore and heteroatoms-doping on constructing high-performance CDI electrode. 展开更多
关键词 Capacitive deionization Biomass-derived carbon Pore structure B N co-doping Desalination performance
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Vacancy defect MoSeTe embedded in N and F co-doped carbon skeleton for high performance sodium ion batteries and hybrid capacitors
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作者 Dehui Yang Wentao Guo +6 位作者 Fei Guo Jiaming Zhu Gang Wang Hui Wang Guanghui Yuan Shenghua Ma Beibei Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期652-664,I0014,共14页
Sodium-ion batteries(SIBs) and hybrid capacitors(SIHCs) have garnered significant attention in energy storage due to their inherent advantages,including high energy density,cost-effectiveness,and enhanced safety.Howev... Sodium-ion batteries(SIBs) and hybrid capacitors(SIHCs) have garnered significant attention in energy storage due to their inherent advantages,including high energy density,cost-effectiveness,and enhanced safety.However,developing high-performance anode materials to improve sodium storage performa nce still remains a major challenge.Here,a facile one-pot method has been developed to fabricate a hybrid of MoSeTe nanosheets implanted within the N,F co-doped honeycomb carbon skeleton(MoSeTe/N,F@C).Experimental results demonstrate that the incorporation of large-sized Te atoms into MoSeTe nanosheets enlarges the layer spacing and creates abundant anion vacancies,which effectively facilitate the insertion/extraction of Na^(+) and provide numerous ion adsorption sites for rapid surface capacitive behavior.Additionally,the heteroatoms N,F co-doped honeycomb carbon skeleton with a highly conductive network can restrain the volume expansion and boost reaction kinetics within the electrode.As anticipated,the MoSeTe/N,F@C anode exhibits high reversible capacities along with exceptional cycle stability.When coupled with Na_(3)V_(2)(PO_(4))_(3)@C(NVPF@C) to form SIB full cells,the anode delivers a reversible specific capacity of 126 mA h g^(-1) after 100 cycles at 0.1 A g^(-1).Furthermore,when combined with AC to form SIHC full cells,the anode demonstrates excellent cycling stability with a reversible specific capacity of50 mA h g^(-1) keeping over 3700 cycles at 1.0 A g^(-1).In situ XRD,ex situ TEM characterization,and theoretical calculations(DFT) further confirm the reversibility of sodium storage in MoSeTe/N,F@C anode materials during electrochemical reactions,highlighting their potential for widespread practical application.This work provides new insights into the promising utilization of advanced transition metal dichalcogenides as anode materials for Na^(+)-based energy storage devices. 展开更多
关键词 MoSeTe N F co-doped honeycomb carbon skeleton Sodium-ion batteries Sodium-ion hybrid capacitor
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Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation
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作者 Haixu Li Haobo He +7 位作者 Tiannan Jiang Yunfei Du Zhichen Wu Liang Xu Xinjie Wang Xiaoguang Liu Wanhua Yu Wendong Xue 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期169-181,共13页
S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB... S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)degradation.The effects of two different mixing routes were identified on the MB degradation performance.Particularly,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with Co-S.Furthermore,the degradation parameters,including pH and MOF-AEP dosage,were investigated.Finally,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB. 展开更多
关键词 advanced oxidation process alcohol solvent evaporation hydrogen bond S and Co co-doped carbon catalysts wastewater remediation
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Interconnected carbon nanocapsules with high N/S co-doping as stable and high-capacity potassium-ion battery anode 被引量:6
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作者 Honghui Bi Xiaojun He +3 位作者 Lei Yang Hongqiang Li Biyu Jin Jieshan Qiu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第3期195-204,I0007,共11页
Carbonaceous materials have drawn much attention in potassium-ion batteries (PIBs) due to their low price and superior physicochemical properties. However, the application of carbonaceous materials in PIB anodes is hi... Carbonaceous materials have drawn much attention in potassium-ion batteries (PIBs) due to their low price and superior physicochemical properties. However, the application of carbonaceous materials in PIB anodes is hindered by sluggish kinetics and large volume expansion. Herein, N/S co-doped carbon nanocapsule (NSCN) is constructed for superior K+ storage. The NSCN possesses 3D nanocapsule framework with abundant meso/macropores, which guarantees structural robustness and accelerates ions/electrons transportation. The high-level N/S co-doping in carbon matrix not only generates ample defects and active sites for K+ adsorption, but also expands interlayer distance for facile K+ intercalation/deintercalation. As a result, the NSCN electrode delivers a high reversible capacity (408 mAh g^(−1) at 0.05 A g^(−1)), outstanding rate capability (149 mAh g^(−1) at 5 A g^(−1)) and favorable cycle stability (150m Ah g^(−1) at 2 A g^(−1) after 2000 cycles). Ex situ TEM, Raman and XPS measurements demonstrate the excellent stability and reversibility of NSCN electrode during potassiation/depotassiation process. This work provides inspiration for the optimization of energy storage materials by structure and doping engineering. 展开更多
关键词 3D Carbon nanocapsules N/S co-doping Carbon anode Potassium-ion battery
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First-principles investigation of N-Ag co-doping effect on electronic properties in p-type ZnO 被引量:2
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作者 左春英 温静 柏跃磊 《Chinese Physics B》 SCIE EI CAS CSCD 2010年第4期328-334,共7页
The geometric structure, band structure and density of states of pure, Ag-doped, N-doped, and N-Ag codoped wurtzite ZnO have been investigated by the first-principles ultra-soft pseudopotential method based on the den... The geometric structure, band structure and density of states of pure, Ag-doped, N-doped, and N-Ag codoped wurtzite ZnO have been investigated by the first-principles ultra-soft pseudopotential method based on the density functional theory. The calculated results show that the carrier concentration is increased in the ZnO crystal codoped by N and Ag, and the codoped structure is stable and is more in favour of the formation of p-type ZnO. 展开更多
关键词 FIRST-PRINCIPLES co-doping ZNO electronic properties
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Interior and Exterior Decoration of Transition Metal Oxide Through Cu^(0)/Cu^(+) Co-Doping Strategy for High-Performance Supercapacitor 被引量:5
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作者 Weifeng Liu Zhi Zhang +4 位作者 Yanan Zhang Yifan Zheng Nishuang Liu Jun Su Yihua Gao 《Nano-Micro Letters》 SCIE EI CAS CSCD 2021年第4期96-109,共14页
Although CoO is a promising electrode material for supercapacitors due to its high theoretical capacitance,the practical applications still suffering from inferior electrochemical activity owing to its low electrical ... Although CoO is a promising electrode material for supercapacitors due to its high theoretical capacitance,the practical applications still suffering from inferior electrochemical activity owing to its low electrical conductivity,poor structural stability and inefficient nanostructure.Herein,we report a novel Cu0/Cu+co-doped CoO composite with adjustable metallic Cu0 and ion Cu+via a facile strategy.Through interior(Cu+)and exterior(Cu0)decoration of CoO,the electrochemical performance of CoO electrode has been significantly improved due to both the beneficial flower-like nanostructure and the synergetic effect of Cu0/Cu+co-doping,which results in a significantly enhanced specific capacitance(695 F g^(-1) at 1 A g^(-1))and high cyclic stability(93.4%retention over 10,000 cycles)than pristine CoO.Furthermore,this co-doping strategy is also applicable to other transition metal oxide(NiO)with enhanced electrochemical performance.In addition,an asymmetric hybrid supercapacitor was assembled using the Cu0/Cu+co-doped CoO electrode and active carbon,which delivers a remarkable maximal energy density(35 Wh kg^(-1)),exceptional power density(16 kW kg^(-1))and ultralong cycle life(91.5%retention over 10,000 cycles).Theoretical calculations further verify that the co-doping of Cu^(0)/Cu^(+)can tune the electronic structure of CoO and improve the conductivity and electron transport.This study demonstrates a facile and favorable strategy to enhance the electrochemical performance of transition metal oxide electrode materials. 展开更多
关键词 Cu^(0)/Cu^(+)co-doping HETEROSTRUCTURE Transition metal oxide SUPERCAPACITOR
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Enhancement of photoluminescence of Ba_2SiO_4:Eu^(2+) by co-doping of La^(3+) or Y^(3+) 被引量:5
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作者 胡小野 李振华 +1 位作者 徐欣 李永绣 《Journal of Rare Earths》 SCIE EI CAS CSCD 2009年第1期47-49,共3页
Green light-emitting Ba2SiO4:Eu^2+ phosphors co-doped with La or Y were synthesized by conventional solid-state reaction technique in reductive atmosphere(a mixture of 5% H2 and 95% N2).The results showed that the... Green light-emitting Ba2SiO4:Eu^2+ phosphors co-doped with La or Y were synthesized by conventional solid-state reaction technique in reductive atmosphere(a mixture of 5% H2 and 95% N2).The results showed that the co-doping of La and Y could greatly enhance the fluorescence intensity of Ba2SiO4:Eu2+ phosphors.The optimum doping concentration expressed by the x value in(Ba0.985-1.5xREx)2SiO4:0.03Eu^2+(RE=La or Y) was determined to be of 0.05.The excitation and emission peaks of all as-synthesized phosphors were wide bands.The excitation bands ranged from 250 to 400 nm, which matched well with the wavelength of near ultraviolet white light-emitting diodes(LED) chip and could be used as a potential candidate for the fabrication of white LED.The emission bands from 450 to 550 nm were typical 5d-4f transition emission of Eu^2+ and displayed un-symmetry profiles because of the two substitution sites of Ba^2+ with Eu^2+. 展开更多
关键词 Ba2SiO4:Eu^2+ phosphor co-doping white light-emitting diodes
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Boosting electrocatalytic activity for CO_(2) reduction on nitrogen-doped carbon catalysts by co-doping with phosphorus 被引量:2
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作者 Shuo Chen Tianfu Liu +4 位作者 Samson O.Olanrele Zan Lian Chaowei Si Zhimin Chen Bo Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2021年第3期143-150,共8页
Electrochemical reduction of CO_(2)(CERR)to value-added chemicals is an attractive strategy for greenhouse gas mitigation,and carbon recycles utilization.Conventional metal catalysts suffered from low durability and s... Electrochemical reduction of CO_(2)(CERR)to value-added chemicals is an attractive strategy for greenhouse gas mitigation,and carbon recycles utilization.Conventional metal catalysts suffered from low durability and sluggish kinetics impede the practical application.On the other hand,doped carbon materials recently demonstrate superior catalytic performance in CERR,which shows the potential to diminish the problems of metal catalysts to some extent.Herein,we present the design and fabrication of nitrogen(N),phosphorus(P)co-doped metal-free carbon materials as an efficient and stable electrocatalyst for reduction of CO_(2) to CO,which exhibits an excellent performance with a high faradaic efficiency of 92%(-0.55 V vs.RHE)and up to 24 h stability.A series of characterizations including TEM and XPS verified that nitrogen and phosphorous are successfully incorporated into the carbon matrix.Moreover,the comparisons between co-doping and single doping catalysts reveal that co-doping can significantly increase CERR performance.The improved catalytic activity is attributed to the synergetic effects between nitrogen and phosphorous dopants,which effectively modulate properties of the active site.The density functional theory(DFT)calculations were also performed to understand the synergy effects of dopants.It is revealed that the phosphorous doping can significantly lower the Gibbs free energy of COOH^(*)formation.Moreover,the introduction of the second dopants phosphorous can reduce the reaction barrier along the reaction path and cause polarization of density of states at the Fermi level.These changes can greatly enhance the activity of the catalysts.From a combined experimental and computational exploration,current work provides valuable insights into the reaction mechanism of CERR on N,P co-doped carbon catalysts,and the influence from synergy effects between dopants,which paves the way for the rational design of novel metal-free catalysts for CO2 electro-reduction. 展开更多
关键词 Metal-free catalyst CO_(2)reduction co-doping DFT
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First-principles study of metallic carbon nanotubes with boron/nitrogen co-doping 被引量:1
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作者 陈灵娜 马松山 +2 位作者 欧阳芳平 肖金 徐慧 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第1期541-547,共7页
Using the first-principles calculations, we investigate the electronic band structure and the quantum transport properties of metallic carbon nanotubes (MCNTs) with B/N pair co-doping. The results about formation en... Using the first-principles calculations, we investigate the electronic band structure and the quantum transport properties of metallic carbon nanotubes (MCNTs) with B/N pair co-doping. The results about formation energy show that the B/N pair co-doping configuration is a most stable structure. We find that the electronic structure and the transport properties are very sensitive to the doping concentration of the B/N pairs in MCNTs, where the energy gaps increase with doping concentration increasing both along the tube axis and around the tube, because the mirror symmetry of MCNT is broken by doping B/N pairs. In addition, we discuss conductance dips of the transmission spectrum of doped MCNTs. These unconventional doping effects could be used to design novel nanoelectronic devices. 展开更多
关键词 metallic carbon nanotube B/N pairs co-doping energy gap FIRST-PRINCIPLES
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Tungsten and phosphate polyanion co-doping of Ni-ultrahigh cathodes greatly enhancing crystal structure and interface stability 被引量:1
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作者 Huawei Zhu Haifeng Yu +2 位作者 Zhaofeng Yang Hao Jiang Chunzhong Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2021年第9期144-151,共8页
The Ni-ultrahigh cathode material is one of the best choices for further increasing energy-density of lithium-ion batteries(LIBs),but they generally suffer from the poor structure stability and rapid capacity fade.Her... The Ni-ultrahigh cathode material is one of the best choices for further increasing energy-density of lithium-ion batteries(LIBs),but they generally suffer from the poor structure stability and rapid capacity fade.Herein,the tungsten and phosphate polyanion co-doped LiNi_(0.9)Co_(0.1)O_(2)cathode materials are successfully fabricated in terms of Li(Ni_(0.9)Co_(0.7))_(1-x)W_(x)O_(2-4y)(PO_(4))_(y) by the precursor modification and subsequent annealing.The higher bonding energy of W—O(672 kJ·mol^(-1))can extremely stabilize the lattice oxygen of Ni-rich oxides compared with Ni—O(391.6 kJ·mol^(-1))and Co—O(368 kJ·mol^(-1)).Meanwhile,the stronger bonding of Ni—(PO_(4)^(3-))vs.Ni—O could fix Ni cations in the transition metal layer,and hence suppressing the Li/Ni disorder during the charge/discharge process.Therefore,the optimized Li(Ni_(0.9)Co_(0.1))_(0.99)W_(0.01)O_(1.96)(PO_4)_(0.01)delivers a remarkably extended cycling life with 95.1%retention of its initial capacity of 207.4 mA·h·g^(-1)at 0.2 C after 200 cycles.Meantime,the heteroatoms doping does not sacrifice the specific capacity even at different rates. 展开更多
关键词 LiNi_(0.9)Co_(0.1)O_(2) co-doping Crystal stability Cycling life Li-ion batteries
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Ultralong nitrogen/sulfur Co-doped carbon nano-hollowsphere chains with encapsulated cobalt nanoparticles for highly efficient oxygen electrocatalysis 被引量:6
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作者 Wei Zhang Xingmei Guo +6 位作者 Cong Li Jiang-Yan Xue Wan-Ying Xu Zheng Niu Hongwei Gu Carl Redshaw Jian-Ping Lang 《Carbon Energy》 SCIE CSCD 2023年第8期15-30,共16页
The development of simple and effective strategies to prepare electrocatalysts,which possess unique and stable structures comprised of metal/nonmetallic atoms for oxygen reduction reaction(ORR)and oxygen evolution rea... The development of simple and effective strategies to prepare electrocatalysts,which possess unique and stable structures comprised of metal/nonmetallic atoms for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),is currently an urgent issue.Herein,an efficient bifunctional electrocatalyst featured by ultralong N,S-doped carbon nano-hollow-sphere chains about 1300 nm with encapsulated Co nanoparticles(Co-CNHSCs)is developed.The multifunctional catalytic properties of Co together with the heteroatom-induced charge redistribution(i.e.,modulating the electronic structure of the active site)result in superior catalytic activities toward OER and ORR in alkaline media.The optimized catalyst Co-CNHSC-3 displays an outstanding electrocatalytic ability for ORR and OER,a high specific capacity of 1023.6 mAh gZn^(-1),and excellent reversibility after 80 h at 10mA cm^(-2)in a Zn-air battery system.This work presents a new strategy for the design and synthesis of efficient multifunctional carbon-based catalysts for energy storage and conversion devices. 展开更多
关键词 Co nanoparticles N S co-doping oxygen electrocatalysts rechargeable Zn-air batteries ultralong carbon nano-hollow-sphere chains
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Rationally designed hollow carbon nanospheres decorated with S,P co-doped NiSe_(2) nanoparticles for high-performance potassium-ion and lithium-ion batteries 被引量:3
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作者 Jiajia Ye Zizhong Chen +4 位作者 Zhiqiang Zheng Zhanghua Fu Guanghao Gong Guang Xia Cheng Hu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第3期401-411,I0011,共12页
Hollow nanostructures with external shells and inner voids have been proved to greatly shorten the transport distance of ions/electrons and buffer volume change,especially for the large-sized potassium-ions in seconda... Hollow nanostructures with external shells and inner voids have been proved to greatly shorten the transport distance of ions/electrons and buffer volume change,especially for the large-sized potassium-ions in secondary batteries.In this work,hollow carbon(HC) nanospheres embedded with S,P co-doped NiSe_(2)nanoparticles are fabricated by "drop and dry" and "dissolving and precipitation" processes to form Ni(OH)2nanocrystals followed by annealing with S and P dopants to form nanoparticles.The resultant S,P-NiSe_(2)/HC composite exhibits excellent cyclic performance with 131.6 mA h g^(-1)at1000 mA g^(-1)after 3000 cycles for K^(+)storage and a capacity of 417.1 mA h g^(-1)at 1000 mA g^(-1)after1000 cycles for Li^(+)storage.K-ion full cells are assembled and deliver superior cycling stability with a ca pacity of 72.5 mA h g^(-1)at 200 mA g^(-1)after 500 cycles.The hollow carbon shell with excellent electrical conductivity effectively promotes the transporta tion and tolerates large volume variation for both K^(+)and Li^(+).Density functional theory calculations confirm that the S and P co-doping NiSe_(2) enables stronger adsorption of K^(+)ions and higher electrical conductivity that contributes to the improved electrochemical performance. 展开更多
关键词 S P co-doping NiSe_(2)nanoparticles Hollow carbon nanospheres Potassium-ion batteries Lithium-ion batteries
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Nitrogen and phosphorus co-doped activated carbon induces high density Cu^(+)active center for acetylene hydrochlorination 被引量:1
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作者 Fei Li Xuemei Wang +3 位作者 Pengze Zhang Qinqin Wang Mingyuan Zhu Bin Dai 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第7期193-199,共7页
This work aims to solve the problems of low reaction activity of Cu-based catalysts and agglomeration of active centers in acetylene hydrochlorination.Cu-based catalysts supported by NAP co-doped activated carbon(AC)w... This work aims to solve the problems of low reaction activity of Cu-based catalysts and agglomeration of active centers in acetylene hydrochlorination.Cu-based catalysts supported by NAP co-doped activated carbon(AC)with different content(mCu-xNP/AC)were manufactured and applied in the acetylene hydrochlorination reaction.It was found that the doping of carriers N and P induced the transformation of Cu^(2+)to Cu^(+),and the catalytic activity was markedly improved.Under the optimal reaction temperature of 220℃,the gas hourly space velocity(GHSV)of C_(2)H_(2)was 90 h^(-1)and V_(HCl):V_(C_(2)H_(2))was 1.15.The initial activity of the 5%Cu-30 NP/AC catalyst reached 95.59%.Through some characterization methods showed the addition of N and P improved the dispersion of Cu in carbon,which increased the ratio of Cu^+/Cu^(2+).The measurement results confirmed that the chemisorption capacity of mCu-xNP/AC for C_(2)H_(2)decreased slightly,and the chemisorption capacity for HCl increased significantly,which was the reason for the increased activity of the catalyst.The conclusion provides a reference for the development of acetylene hydrochlorination Cu catalyst. 展开更多
关键词 Acetylene hydrochlorination Cu-based catalysts Catalytic activity Heterogeneous catalysis N and P co-doped
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Effects of Sm Co-doping on Luminescent Properties of Sr4Al14O25:M (M=Mn4+, Cr3+) Phosphors
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作者 Yu-dong Xu Xu-dong Peng +4 位作者 Lei Wang Min Shi Yuan Zhang Quan Wang San Qi 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2015年第6期-,共6页
关键词 PHOSPHOR co-doping Strontium aluminates Energy transfer
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Theoretical study on the improvement of the doping efficiency of Al in 4H-SiC by co-doping group-IVB elements
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作者 Yuanchao Huang Rong Wang +3 位作者 Yixiao Qian Yiqiang Zhang Deren Yang Xiaodong Pi 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第4期512-517,共6页
The p-type doping efficiency of 4 H silicon carbide(4 H-SiC)is rather low due to the large ionization energies of p-type dopants.Such an issue impedes the exploration of the full advantage of 4 H-SiC for semiconductor... The p-type doping efficiency of 4 H silicon carbide(4 H-SiC)is rather low due to the large ionization energies of p-type dopants.Such an issue impedes the exploration of the full advantage of 4 H-SiC for semiconductor devices.In this study,we show that co-doping group-IVB elements effectively decreases the ionization energy of the most widely used p-type dopant,i.e.,aluminum(Al),through the defect-level repulsion between the energy levels of group-IVB elements and that of Al in 4 H-SiC.Among group-IVB elements Ti has the most prominent effectiveness.Ti decreases the ionization energy of Al by nearly 50%,leading to a value as low as~0.13 eV.As a result,the ionization rate of Al with Ti co-doping is up to~5 times larger than that without co-doping at room temperature when the doping concentration is up to 10^(18)cm^(-3).This work may encourage the experimental co-doping of group-IVB elements such as Ti and Al to significantly improve the p-type doping efficiency of 4 H-SiC. 展开更多
关键词 4H-SIC P-TYPE co-doping ab initio study
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Construction of N,O co-doped carbon anchored with Co nanoparticles as efficient catalyst for furfural hydrodeoxygenation in ethanol 被引量:1
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作者 Hui Yang Hao Chen +7 位作者 Wenhua Zhou Haoan Fan Chao Chen Yixuan Sun Jiaji Zhang Sifan Wang Teng Guo Jie Fu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第3期195-202,I0006,共9页
Hydrodeoxygenation of furfural(FF)into 2-methylfuran(MF)is a significant biomass utilization route.However,designing efficient and stable non-noble metal catalyst is still a huge challenge.Herein,we reported the N,O c... Hydrodeoxygenation of furfural(FF)into 2-methylfuran(MF)is a significant biomass utilization route.However,designing efficient and stable non-noble metal catalyst is still a huge challenge.Herein,we reported the N,O co-doped carbon anchored with Co nanoparticles(Co-SFB)synthesized by employing the organic ligands with the target heteroatoms.Raman,electron paramagnetic resonance(EPR),electrochemical impedance spectroscopy(EIS),and X-ray photoelectron spectroscopy(XPS)characterizations showed that the co-doping of N and O heteroatoms in the carbon support endows Co-SFB with enriched lone pair electrons,fast electron transfer ability,and strong metal-support interaction.These electronic properties resulted in strong FF adsorption as well as lower apparent reaction activation energy.At last,the obtained N,O co-doped Co/C catalyst showed excellent catalytic activity(nearly 100 mol%FF conversion and 94.6 mol%MF yield)and stability for in-situ dehydrogenation of FF into MF.This N,O co-doping strategy for the synthesis of highly efficient catalytic materials with controllable electronic state will provide an excellent opportunity to better understand the structure-function relationship. 展开更多
关键词 N O co-doped carbon Electronic properties FURFURAL 2-METHYLFURAN In-situ hydrodeoxygenation
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Efficiently enhanced energy storage performance of Ba_(2)Bi_(4)Ti_(5)O_(18) film by co-doping Fe^(3+)and Ta^(5+)ion with larger radius
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作者 Qiong Wu Lei Zhao +1 位作者 Xinghao Chen Shifeng Zhao 《Chinese Physics B》 SCIE EI CAS CSCD 2022年第9期540-546,共7页
We present an efficient strategy,that is the co-substitution of Fe^(3+)and Ta^(5+)ions with large radius for Ti^(4+)ion,to enhance energy storage performance of Ba_(2)Bi_(4)Ti_(5)O_(18) film.For the films co-doped wit... We present an efficient strategy,that is the co-substitution of Fe^(3+)and Ta^(5+)ions with large radius for Ti^(4+)ion,to enhance energy storage performance of Ba_(2)Bi_(4)Ti_(5)O_(18) film.For the films co-doped with Fe^(3+)and Ta^(5+)ions,the maximum polarization under the same external electric field is improved because the radius of Fe^(3+)and Ta^(5+)ions is larger than that of Ti^(4+)ion.Moreover,due to the composition and chemical disorder,the relaxor properties are also slightly improved,which can not be achieved by the film doped with Fe^(3+)ions only.What is more,for the films doped with Fe^(3+)ion only,the leakage current density increases greatly due to the charge imbalance,resulting in a significant decrease in breakdown strength.It is worth mentioning that the breakdown strength of Fe^(3+)and Ta^(5+)ions co-doped film does not decrease due to the charge balance.Another important point is the recoverable energy storage density of the films co-doped with Fe^(3+)and Ta^(5+)ions has been greatly improved based on the fact that the maximum external electric field does not decrease and the maximum polarization under the same external electric field increases.On top of that,the hysteresis of the polarization has also been improved.Finally,the co-doped films with Fe^(3+)and Ta^(5+)ions have good frequency and temperature stability. 展开更多
关键词 Ba_(2)Bi_(4)Ti_(5)O_(18)film ferroelectrics energy storage co-doped RADIUS
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MnO_(2) nanosheet modified N, P co-doping carbon nanofibers on carbon cloth as lithiophilic host to construct high-performance anodes for Li metal batteries
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作者 Xiaoqiang Liu Qian Zhang +6 位作者 Yiru Ma Zhenzhen Chi Huixiang Yin Jie Liu Junfei Huang Ziyang Guo Lei Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2022年第6期270-281,I0008,共13页
Lithium (Li) metal batteries have attracted much attention owing to its ultra-high energy density.However,as important part of Li metal batteries,Li anodes still face many challenges,mainly including uncontrolled dend... Lithium (Li) metal batteries have attracted much attention owing to its ultra-high energy density.However,as important part of Li metal batteries,Li anodes still face many challenges,mainly including uncontrolled dendritic Li formation,dramatical volume variation and serious pulverization.Herein,manganese dioxide (MnO_(2)) nanosheet modified nitrogen (N),phosphorus (P) co-doping carbon nanofibers(NPC) on carbon cloth (CC)(MnO_(2)@NPC-CC) is successfully fabricated through electrodeposition approach and further treated with Li by the molten-infusion method to prepare Li based Mn@NPC-CC(Li-Mn@NPC-CC) electrode.The synergy of MnO_(2) and NPC obviously increases the reaction rate between MnO_(2)@NPC-CC and Li and guides even Li distribution over infusion process.Additionally,theoretical calculation,simulation and experimental results further indicate that N,P,Mn multi-doping effectively improves the superior lithiophilicity of Li-Mn@NPC-CC,which induces uniform Li deposition/dissolution to suppress dendrite growth over cycles.Moreover,conductive and porous NPC matrix not only effectively improves the stability of Li-Mn@NPC-CC,but also provides abundant spaces to accelerate the transfer of ion/electron and buffer electrode dimension variation during cycling.Hence,Li-Mn@NPC-CC-based symmetric cells exhibit extra-long cycling life (over 2200 h) with small hysteresis of 20 mV.When the LiMn@NPC-CC anode couples with air,Li iron phosphate (LiFePO_(4)),or hard carbon (C) cathode,the assembled full cells exhibit outstanding performance with low hysteresis and stable cycling properties.Especially,the corresponding pouch-typed Li–air cells also exhibit good performance at different bending angles and even power a series of electronic devices. 展开更多
关键词 N P co-doped carbon nanofibers on carbon cloth MnO_(2)nanosheet coating Molten-infusion method Li metal anodes Li metal batteries
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