Co2＋-doped LiFePO4/C composite material was prepared by solid-state synthesis method using Fe2O3,Li2CO3 and NH4H2PO4 as the starting materials.The structures and elec-trochemical performance of samples were studied b...Co2＋-doped LiFePO4/C composite material was prepared by solid-state synthesis method using Fe2O3,Li2CO3 and NH4H2PO4 as the starting materials.The structures and elec-trochemical performance of samples were studied by XRD,SEM and constant current charge-discharge method.The results showed that the Co2＋ doping did not change the crystal structure of LiFePO4.The unit cell volume changed with the increase of Co2＋,and reached the maximum at x = 0.04.The LiFe0.96Co0.04PO4/C sample proved the best electrochemical properties.Its initial discharge capacity was 138.5 mA·h /g at 1 C rate.After 30 cycles,the capacity remained 127.7 mA·h /g,and the capacity retention rate was 92.2%.展开更多
The anoxic decomposition and influence of carbon precursors on the properties of LiFePO_4/C prepared by using Fe_2O_3 were investigated.X-ray powder diffractometry,Fourier transform infrared spectroscopy(FTIR),scannin...The anoxic decomposition and influence of carbon precursors on the properties of LiFePO_4/C prepared by using Fe_2O_3 were investigated.X-ray powder diffractometry,Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy(SEM) and carbon content and charge–discharge tests were applied to the characterization of the as-synthesized cathodes.Partial carbon is lost in the anaerobic decomposition of organic precursors and a high hydrogen content leads to a high residual carbon rate.Pyromellitic anhydride and citric acid participate in reactions before and in ball-milling.All the chosen carbon precursors are capable of producing LiFePO_4 with high degree of crystallinity and purity.The carbon derived from α-D-glucose,pyromellitic anhydride,soluble starch,citric acid and polyacrylamide has a loose and porous texture in LiFePO_4/C which forms conduction on and between LiFePO_4 particles.LiFePO_4/C prepared by using α-D-glucose,pyromellitic anhydride,citric acid and sucrose exhibits appreciable electrochemical performance.Graphite alone is able to enhance the electrochemical performance of LiFePO_4 to a limited extent but incapable of preparing practical cathode.展开更多
基金Sponsored by the Graduate Innovation Fund of Shaanxi University of Science and Technology
文摘Co2＋-doped LiFePO4/C composite material was prepared by solid-state synthesis method using Fe2O3,Li2CO3 and NH4H2PO4 as the starting materials.The structures and elec-trochemical performance of samples were studied by XRD,SEM and constant current charge-discharge method.The results showed that the Co2＋ doping did not change the crystal structure of LiFePO4.The unit cell volume changed with the increase of Co2＋,and reached the maximum at x = 0.04.The LiFe0.96Co0.04PO4/C sample proved the best electrochemical properties.Its initial discharge capacity was 138.5 mA·h /g at 1 C rate.After 30 cycles,the capacity remained 127.7 mA·h /g,and the capacity retention rate was 92.2%.
基金Project(2010ZC051)supported by Natural Science Foundation of Yunnan Province,ChinaProject(20140439)supported by Analysis and Testing Foundation of Kuming University of Science and Technology,ChinaProject(14118245)supported by the Starting Research Fund from Kunming University of Science and Technology,China
文摘The anoxic decomposition and influence of carbon precursors on the properties of LiFePO_4/C prepared by using Fe_2O_3 were investigated.X-ray powder diffractometry,Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy(SEM) and carbon content and charge–discharge tests were applied to the characterization of the as-synthesized cathodes.Partial carbon is lost in the anaerobic decomposition of organic precursors and a high hydrogen content leads to a high residual carbon rate.Pyromellitic anhydride and citric acid participate in reactions before and in ball-milling.All the chosen carbon precursors are capable of producing LiFePO_4 with high degree of crystallinity and purity.The carbon derived from α-D-glucose,pyromellitic anhydride,soluble starch,citric acid and polyacrylamide has a loose and porous texture in LiFePO_4/C which forms conduction on and between LiFePO_4 particles.LiFePO_4/C prepared by using α-D-glucose,pyromellitic anhydride,citric acid and sucrose exhibits appreciable electrochemical performance.Graphite alone is able to enhance the electrochemical performance of LiFePO_4 to a limited extent but incapable of preparing practical cathode.
