In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer (Boltom-TM H30) to prepare a hyperbranched photosensitive polymer (H30-Ci). The polymer was characterized by UV absorp...In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer (Boltom-TM H30) to prepare a hyperbranched photosensitive polymer (H30-Ci). The polymer was characterized by UV absorption spectrum and 1H- NMR spectrum. After processed by Linearly Polarized Polymerization (LPP) method, the spin-coated films of H30-Ci were used as photo-alignment layers to assemble liquid crystal (LC) cells containing nematic liquid crystal (5CB). The observation by polarized microscope showed that the H30-Ci blended with a linear polymer (BP-AN-Ci) photo-alignment layers could align LC molecules in a very uniform way.展开更多
基金the National Natural Science Foundation of China (No. 50103005)Thanks for Professor Shi Wenfang of University of Science and Technology of China to supply the hyperbranched polymer(H30).
文摘In this work, 4-methoxylcinnamoyl chloride was reacted with a commercial hyperbranched polymer (Boltom-TM H30) to prepare a hyperbranched photosensitive polymer (H30-Ci). The polymer was characterized by UV absorption spectrum and 1H- NMR spectrum. After processed by Linearly Polarized Polymerization (LPP) method, the spin-coated films of H30-Ci were used as photo-alignment layers to assemble liquid crystal (LC) cells containing nematic liquid crystal (5CB). The observation by polarized microscope showed that the H30-Ci blended with a linear polymer (BP-AN-Ci) photo-alignment layers could align LC molecules in a very uniform way.