Relationship between Multi-Phase Formation and Molecular Structure for Liquid Crystal System

4 mechanical model of liquid crystals （ LCs ） was used to explain the phase formation and thermal properties . The LC plusses in the model are micro- machine systems consisting of an ensemble of molecular rotors, and some dynamie parameters in a semi-experiment molecular orbit method. A novel explanation on the multi-phase formation of LC system is obtained. It is found that the value of the critical rotational velueity is a key parameter for the characterization of each homologous series. The dipole moment of the molecules was also discussed.

Mechanical model study of relationship of molecular configuration and multiphase in liquid crystal materials

A mechanical model of liquid crystals （LCs） is applied to study the polymorphism of homologous series of terphenyl compounds. With a senti-experimental molecular orbit method, we calculate the moment of inertia which represents the rotation state to describe the phase transition temperature obtained from experimental data. We propose a novel explanation of the phase sequence or polymorphism of LC materials using the two key parameters, the moment of inertia and critical rotational velocity. The effect of molecular polarity on the appearance of liquid crystalline is also discussed.

Bichromatic coherent random lasing from dye-doped polymer stabilized blue phase liquid crystals controlled by pump light polarization

In this paper,we investigate the bichromatic coherent random lasing actions from the dye-doped polymer stabilized blue phase liquid crystals.Two groups of lasing peaks,of which the full widith at half maximum is about 0.3 nm,are clearly observed.The shorter-and longer-wavelength modes are associated with the excitation of the single laser dye（DCM） monomers and dimers respectively.The experimental results show that the competition between the two groups of the lasing peaks can be controlled by varying the polarization of the pump light.When the polarization of the pump light is rotated from 0？to 90？,the intensity of the shorter-wavelength lasing peak group reduces while the intensity of the longer-wavelength lasing peak group increases.In addition,a red shift of the longer-wavelength modes is also observed and the physical mechanisms behind the red-shift phenomenon are discussed.

Electrically tunable holographic polymer templated blue phase liquid crystal grating

In this paper, we demonstrate an alternative approach to fabricating an electrically tunable holographic polymer tem- plated blue phase liquid crystal grating. This grating is obtained by preforming a polymer template comprised of periodic fringes, and then refilling it with a blue phase liquid crystal. Compared with conventional holographic polymer dispersed liquid crystal gratings, our grating can remarkably reduce its switching voltage from 200 V to 43 V while maintaining a sub-millisecond response time. The holographic polymer templated blue phase liquid crystal （HPTBPLC） grating is free from electrode patterning, thus leading to a lower cost and more flexible applications.

Microstructure - properties relationship of transient liquid phase diffusion bonded a third generation single crystal super alloy joint

Microstructure of transient liquid phase( TLP) diffusion bonded a third generation single crystal superalloy joint was investigated using scanning electron microscopy( SEM),and mechanical properties test of joint was carried out,for obtaining relationship between microstructure and mechanical properties of joint. The results showed that the joint contained bonding zone and base metal. The diffusion zone was obviously observed. When it was not finished for isothermal solidification process,the bonding zone would contain isothermal solidification zone and rapid solidification zone. Metallographic examination revealed that isothermal solidification zone was consisted of γ and γ' phase. Rapid solidification zone was consisted of two different structures,which were ternary eutectic of borides,γ and γ' phase developing at the edge of joint,binary eutectic of γ and γ' phase appearing in the portion of joint. When it was not enough for homogenization process under the condition of finishing isothermal solidification process,the bonding zone would contain isothermal solidification zone and borides at the interface. Under the conditions of relatively high welding temperature and long welding time,average tensile strength of joint was equivalent to that of parent material.

Optical simulation of in-plane-switching blue phase liquid crystal display using the finite-difference time-domain method

The finite-difference time-domain method is used to simulate the optical characteristics of an in-plane switching blue phase liquid crystal display.Compared with the matrix optic methods and the refractive method,the finite-difference timedomain method,which is used to directly solve Maxwell＇s equations,can consider the lateral variation of the refractive index and obtain an accurate convergence effect.The simulation results show that e-rays and o-rays bend in different directions when the in-plane switching blue phase liquid crystal display is driven by the operating voltage.The finitedifference time-domain method should be used when the distribution of the liquid crystal in the liquid crystal display has a large lateral change.

Synthesis and Characterization of Liquid Crystal with Lower Temperature of Phase Change of meso-tetra-(4-n-lauroyloxyphenyl)porphyrin

The synthesis and characterization of meso-tetra (4-n-lauroyloxy phenyl) porphyrin with long ester chains are reported. The domains of stability and the structure of the liquid crystalline phases are determined by optical microscopy and differential scanning calorimerials (DSC).

Fast generation of controllable equal-intensity four beams based on isosceles triangle multilevel phase grating realized by liquid crystal spatial light modulator

Liquid crystal spatial light modulator （LCSLM） realizing equal-intensity multiple beams often has some features, i.e., phase valley between two adjacent pixels, flybaek region when phase decreases immediately from 2~r to 0, and inevitable backplane curvature, which are different from those of most conventional diffractive optical elements （DOEs）, such as static DOEs. For optimal intensity uniformity, equal-intensity multi-beam generation must be considered for these artifacts. We present a tunable-grating method in which the intensity uniformity can be improved by considering the LCSLM artifacts. For instance, tuning phase modulation depth of the grating, called isosceles triangle multilevel phase grating （ITMPG）, can be used not only to improve the intensity uniformity, but also to fast steer four beams with narrow beamwidths, determined by the same effective aperture of ITMPG. Improved intensity uniformity and high relative diffraction efficiency are demonstrated through experiments with phase-only LCSLM.

Relaxation process and phase transition of lanthanide liquid crystalline complexes by photoacoustic spectroscopy

Lanthanide-containing liquid crystals exhibiting smectic A phase close to room temperature were obtained. Photoacoustic （PA） spectroscopy was used to study the spectral properties and phase transitions of liquid crystalline metal complexes. It was found that PA intensity of the ligand had a relationship with the probability of nonradiative transitions, which increased in the order of Eu（tta）3L2〈La（tta）3L2〈 Tb（tta）3L2〈Er（tta）3L2. The relaxation processes of the complexes were studied in depth from two aspects： radiative and non-radiative processes, combining with their fluorescence spectra. Phase transitions of europium（m） and erbium（m） complexes, in the temperature range of 383-358 K, could be clearly monitored by both PA amplitude and PA phase signals. As the temperature crossed the transition point, PA amplitude showed a minimum and PA phase a maximum. The results indicated that PA technique could serve as a new tool for investigating the physicochemical properties of liquid crystals containing metal ions.

Adaptive modulation system for liquid crystal phase modulator

An adaptive modulation system for a liquid crystal（LC） phase modulator is demonstrated. The phase retardation may be modulated by resetting the driving voltage automatically by matching the measured and ideal transmittance of an LC cell sandwiched by crossed polarizers. By using this system, an LC phase modulator can get a low error function of 0.25% in a short modulation time, which is less than the 10% obtained using a conventional modulation method.

Asymmetric dynamic phase holographic grating in nematic liquid crystal

A new scheme for recording a dynamic phase grating with an asymmetric profile in C60-doped homeotropically aligned nematic liquid crystal（NLC） was presented.An oblique incidence beam was used to record the thin asymmetric dynamic phase holographic grating.The diffraction efficiency we achieved is more than 40%,exceeding the theoretical limit for symmetric profile gratings.Both facts can be explained by assuming that a grating with an asymmetric saw-tooth profile is formed in the NLC.Finally,physical mechanism and mathematical model for characterizing the asymmetric phase holographic grating were presented,based on the photo-refractive-like（PR-like） effect.

Lyotropic Liquid Crystal Electrochemical Polymerization of Thiophene-Based Monomers: Polymerization in Cholesteric Liquid Crystal and Columnar Phase

Synthesis of conductive polymer poly([thiophene]-[benzo[1,2,3]thiadiazole] [thiophene]) (abbreviated as P(T-Btdaz-T)) was achieved by electrochemical polymerization in hydroxypropyl cellulose (HPC)/N,N-dimethylformamide (DMF) in liquid crystal state. The polymer thus obtained shows fingerprint texture, which is derived from helical structure of the HPC in cholesteric liquid crystal state. Fourier transform infrared spectroscopy measurements revealed that the polymer film is P(T-Btdaz-T)/HPC composite. Circular dichroism optical absorption spectroscopy measurements show that the polymer has the optical activity. Next, electrochemical polymerization of 3,4-ethylene-dioxythiophene (EDOT) was carried out in columnar phase liquid crystal. The polymer transcribes the columnar structure and shows optical structure resembling columnar liquid crystal electrolyte solution.

PHASE STRUCTURES AND TRANSITION BEHAVIORS OF A TRIPHENYLENE DISCOTIC LIQUID CRYSTAL

The phase behaviors and structures of a triphenylene-derived discotic liquid crystal （LC） hexa-n-octoxyl- triphenylene （C8HET） were studied using the combined techniques of differential scanning calorimetry （DSC）, wide angle X-ray diffraction （WAXD）, selected area electron diffraction （SAED） and polarized light microscopy （PLM）. Onedimensional （1D） powder WAXD results at different temperatures coupled with DSC and PLM observations revealed that the C8HET compound possessed an LC phase and three different crystalline （K3, K2 and K1） phases below the isotropic （I） melt. The I←→ LC phase transition was thermodynamically reversible and independent of the heating and cooling rates. The development and experimental observation of the three crystalline phases relied on different thermal histories. Among the three crystalline phases in CSHET, the K3 phase is the most stable phase, while the K2 and K1 phases are metastable. Note that the K1 phase only formed via a quenching process. Oh the basis of structure sensitive diffraction experiments such as 2D WAXD of oriented samples and SAED of single crystals, detailed structures and molecular packings of these four ordered phases were identified. The LC phase exhibited a hexagonal columnar phase with 2D lattice dimensions ofa = b = 2.38 nm and γ= 120°. All the three crystalline phases possess monoclinic unit cells, yet the y angle is not 90° in the cases of the K2 and the K3 phases, while in the case of the K1 phase the a angle is not 90°.

Studies on the Phase Behavior of Lyotropic Liquid Crystal in DAD/C_4OH/n-C_8H_(18)/D_2O System

The lytropic liquid crystals in dodecanic acid diethanolamine (DAD) /n-butanol (C4OH) /octane (n-C8H18) /deuteron (D2O) system were studied to determine the phase regions and were investigated by 2H-NMR spectroscopy,optical polarizing microscope and small-angle X-ray diffraction (SAXD) methods.The results indicate that the lamellar,hexagonal and cubic liquid crystals all exist in the above system.Keeping the weight ratio of DAD and C4OH constant,the microphase Structure,2H quadruple splitting and the interlayer spacing are all changed with the addition of deuteron.

Cellular Automata Simulation of Gap-Filler Dissolution during Transient Liquid Phase Bonding of Single Crystal Materials

A new numerical model is developed using a Cellular Automata (CA) method to study the liquid-phase dissolution behavior of gap-filler powder particles in interlayer powder mixture during transient liquid phase (TLP) bonding process. The model prediction of microstructural evolution in TLP joint between single crystal substrates show that formation of misoriented stray-grains results from incomplete liquation of the gap-filler powder particles. In contrast to what is generally assumed and reported, numerical calculations coupled with experimental verification show that under properly selected process parameters, complete melting of the gap-filler powder particles is possible. This is imperative to prevent the formation of misoriented stray-grains and maintain single crystallinity during TLP bonding of single crystal materials. The dependence of complete melting of the gap-filler particles on salient TLP bonding parameters are analyzed and discussed.

Research on Phase Detection of Liquid Crystal Optical Device

The technology for phase detection of liquid crystal optical device is a difficult research in current domestic and overseas. However, for the existing liquid crystal optical device, aiming at the poor anti-vibration capability and poor versatile of phase detection, the complexity of phase retrieval algorithm, we propose a new phase measurement principle and experimental methods of liquid crystal optical device. It is a phase measurement method based on the combination of phase- shifting interferometer and phase conjugation technology. The deflection characteristics of the liquid crystal device means the device can implement phase modulation to only one direction of polarized light while is completely transparent to orthogonal polarized light. We put forward the phase shift of the orthogonal polarization phase shift interferometer method, using phase shifting interference as well as the combination of phase conjugate means to achieve its phase measurement. So we can retrieves devices modulation phase simply and efficiently combines with phase- shifting interferometer technology.

SYNTHESIS AND CHARACTERIZATION OF NOVEL CHIRAL SMECTIC C(Sc~*) PHASE SHISH-KEBAB TYPE LIQUID CRYSTALLINE BLOCK COPOLYMERS

A new series of chiral shish-kebab type liquid crystal block copolymers that form the smectic C(Sc*) phase was synthesized by solution polycondensation. The copolymers were characterized by GPC, DSC, TG, POM, X-ray diffraction and polarimeter. The copolymers 7 entered into liquid crystal phase whin they were heated to their melting temperatures (T-m) and the copolymers 8 were in liquid crystal phase at room temperature with low viscosities. The smectic sanded texture or focal-conic texture were observed on POM. All the chiral block copolymers showed high optical activity. No racemization has happened. Temperature-variable X-ray diffraction study together with POM and polarimetric analysis realized that they are chiral smectic C(Sc*) phase. Thus we offer in this report the first example of shish-kebab type liquid crystal block copolymers that form a chiral smectic C(Sc*) phase. The variation of melting and isotropization temperatures with molecular structure was also discussed.

Electro-optical properties and(E,F) phase diagram of fluorinated chiral smectic liquid crystals

Fluorinated smectic liquid crystals each with a biphenyl benzoate rigid core are investigated. Molecular structures of the studied compounds have difference only in fluorine position and the length of the carbon chain. Dielectric relaxation study and electro-optical measurements are carried out with the classical SSFLC geometry. The field-induced phase transitions are studied and the（E,T） phase diagram is established.

Low voltage transflective blue-phase liquid crystal display with a non-uniform etching substrate

A transflective polymer-stabilized blue-phase liquid crystal display（BP-LCD） with a non-uniform etching substrate is proposed.In-plane switching（IPS） electrodes on the bottom substrate are put on the different gaps,and the bottom substrate between the electrodes is etched into different depths in transmissive（T） and reflective（R） regions.This structure can balance the optical phase retardation in the two regions and is helpful to achieve well-matched voltag-dependent transmittance and reflectance curves.This transflective display has high optical efficiency,a wide viewing angle,and low operating voltage（approximately 6 V）.

Kerr effect and Kerr constant enhancement in vertically aligned deformed helix ferroelectric liquid crystals

In this article,we review recently achieved Kerr effect progress in novel liquid crystal（LC） material：vertically aligned deformed helix ferroelectric liquid crystal（VADHFLC）.With an increasing applied electric field,the induced inplane birefringence of LCs shows quadratic nonlinearity.The theoretical calculations and experimental details are illustrated.With an enhanced Kerr constant to 130 nm/V2,this VADHFLC cell can achieve a 2π modulation by a small efficient electric field with a fast response around 100 μs and thus can be employed in both display and photonics devices.