Wetting front migration model of ion-adsorption rare earth during the multi-hole unsaturated liquid injection

In the process of ion-adsorption rare earth ore leaching,the migration characteristics of the wetting front in multi-hole injection holes and the influence of wetting front intersection effect on the migration distance of wetting fronts are still unclear.Besides,wetting front migration distance and leaching time are usually required to optimize the leaching process.In this study,wetting front migration tests of ionadsorption rare earth ores during the multi-hole fluid injection(the spacing between injection holes was 10 cm,12 cm and 14 cm)and single-hole fluid injection were completed under the constant water head height.At the pre-intersection stage,the wetting front migration laws of ion-adsorption rare earth ores during the multi-hole fluid injection and single-hole fluid injection were identical.At the postintersection stage,the intersection accelerated the wetting front migration.By using the Darcy’s law,the intersection effect of wetting fronts during the multi-hole liquid injection was transformed into the water head height directly above the intersection.Finally,based on the Green-Ampt model,a wetting front migration model of ion-adsorption rare earth ores during the multi-hole unsaturated liquid injection was established.Error analysis results showed that the proposed model can accurately simulate the infiltration process under experimental conditions.The research results enrich the infiltration law and theory of ion-adsorption rare earth ores during the multi-hole liquid injection,and this study provides a scientific basis for optimizing the liquid injection well pattern parameters of ion-adsorption rare earth in situ leaching in the future.

FLOW DYNAMICS OF GAS-SOLID FLUIDIZED BEDS WITH EVAPORATIVE LIQUID INJECTION

The electrical capacitance tomography （ECT） with neural network multi-criteria image reconstruction technique （NN-MOIRT） is developed for real time imaging of a gas-solid fluidized bed using FCC particles with evaporative liquid injection. Some aspects of the fundamental characteristics of the gas-solid flow with evaporative liquid injection including real time and time averaged cross-sectional solids concentration distributions, the cross-sectional solids concentration fluctuations and the quasi-3D flow structures are studied. A two-region model and a direct image calculation are proposed to describe the dynamic behavior in both the bubble/void phase and the emulsion phase based on the tomographic images. Comparisons are made between the fundamental behaviors of the gas-solid flows with and without evaporative liquid injection for various gas velocities ranging from bubbling to turbulent fluidization regimes. Significant differences are observed in the behavior of the gas-solid flow with the evaporative liquid injection compared to the fluidized bed without liquid injection.

Experimental analysis of volatile liquid injection into a fluidized bed

Experiments were conducted on a lab-scale fluidized bed to study the distribution of liquid ethanol injected into fluidized catalyst particles. Electrical capacitance measurements were used to study the liquid distribution inside the bed, and a new method was developed to determine the liquid content inside fluidized beds of fluid catalytic cracking particles. The results shed light on the complex liquid injection region and reveal the strong effect of superficial gas velocity on liquid distribution inside the fluidized bed, which is also affected by the imbibition of liquid inside particle pores. Particle internal porosity was found to play a major role when the changing mass of liquid in the bed was monitored. The results also showed that the duration of liquid injection affected liquid-solid contact inside the bed and that liouid-solid mixin~ was not homogeneous durin~ the limited liouid injection time.

Three-dimensional simulation of liquid injection,film formation and transport,in fluidized beds

Liquid injection, and film formation and transport in dense-phase gas-solids fluidized beds are numerically simulated in three dimensions using a collisional exchange model that is based on the mechanism that collisions cause transfer of liquid mass, momentum, and energy between particles. In the model, each of the particles is represented by a solid core and a liquid film surrounding the core. The model is incorporated in the framework of the commercial code Barracuda developed by CPFD Software. The commercial software is an advanced CFD-based computational tool where the particles are treated as discrete entities, calculated by the MP-PIC method, and tracked using the Lagrangian method. Details of the collisional liquid transfer model have been previously presented in O＇Rourke, Zhao, and Snider （2009）; this paper presents new capabilities and proof-testing of the collision model and a new method to better quantify the penetration length. Example calculations of a fluidized bed without liquid injection show the expected effect of collisions on the reduction of granular temperature （fluctuational kinetic energy） of the bed. When applied to liquid injection into a dense-phase fluidized bed under different conditions, the model predicts liquid penetration lengths comparable to the experiments. In addition, the simulation reveals for the first time the dynamic mixing of the liquid droplets with the bed particles and the transient distribution of the droplets inside the bed.

Effect of kerosene injection states on mixing and combustion characteristics in a cavity-based supersonic combustor

It has been found that the static pressure distribution along the axial direction of liquid kerosene is lower than that of the gaseous kerosene under the same flow condition and overall equivalent ratio from previous studies.To further investigate this phenomenon,a compressible two-phase parallel simulation method is utilized to analyze the mixing and combustion characteristics of gaseous and liquid kerosene jets in a cavity-based supersonic combustor.The numerical results are consistent with the experiments and demonstrate that gaseous injection leads to a cavity shear layer that dives deeper into the cavity,forming two recirculation zones in the front and rear of the cavity.In contrast,the cavity shear layer is closer to the mainstream during liquid injection,and only a large recirculation zone is formed in the rear of the cavity.As a result of the cavity shear layer and the recirculating flow,the fuel vapor of gaseous injection accumulates in the front of the cavity,while for the liquid injection,the fuel vapor disperses in the cavity,cavity shear layer,and the region above,and the rear of the cavity has a higher fuel vapor concentration than the front.This unique fuel distribution causes the combustion area to be concentrated in the cavity during the gaseous injection but dispersed inside and downstream of the cavity during the liquid injection.As a result,forming a thermal throat under the same conditions is more challenging during liquid injection,and the generated static pressure distribution is lower than that during the gaseous injection.

Effect of successive sprays on liquid distribution in fluidized beds

In processes such as Fluid Coking^(™),agglomerate formation should be minimized since it reduces the yield of valuable products,and degrades operability because of the fouling of internals.An experimental model,consisting of an aqueous solution of gum arabic with a dye,has been successfully developed to simulate the formation of agglomerates in the Fluid Coking^(™)process,where bitumen is sprayed into a fluidized bed of coke particles The particles wetted by a spray could be predicted by assuming that all the particles in the wake of bubbles formed from the tip of the spray jet have been wetted by the injected liquid.The transfer of liquid from particles wetted with the spray to dry bed particles was relatively ineffective,as the number of wet particles increased by only 50%.With successive liquid injections,the proportion of the liquid trapped in agglomerates increases in latter injections:large agglomerates from earlier injections accumulate above the grid and are carried by gas bubbles into the spray jet cavity,where they seed fresh agglomerates.

Light propagation in the micro-size capillary injected by high temperature liquid

The high temperature liquid is injected into the micro-size capillary and its light propagation behavior is investigated. We focus on two different liquid pumping methods. The first method can pump the high temperature liquid tin into the micro-size capillary by using a high pressure difference system. After pumping, a single mode fiber(SMF) connected with the optical carrier based microwave interferometry(OCMI) system is used to measure different liquid tin levels in the micro-size capillary. The second method can pump the room temperature engine oil into the capillary by using a syringe pump. This method can avoid the air bubbles when the liquids are pumped into the capillary.

Sensitivity Analysis of Pollutants and Pattern Factor in a Gas Turbine Model Combustor due to Changes in Stabilizing Jets Characteristics

In the present paper,a sensitivity analysis of pollutants and pattern factor in a model combustor due to changes in the geometrical characteristics of stabilizing jets has been carried out.The exhaust pollutants including NO_(x),CO and soot have been chosen due to their harmful effect on the environment.The pattern factor has been also considered owing to its impact on turbine blades.The geometrical characteristics comprise diameter,angle and position of stabilizing jets.Eulerian-Lagrangian approach has been employed to model liquid fuel injection and distribution,breakup and evaporation of droplets.For the analysis of reactive-spray flow characteristics,RANS approach,realizable k-εturbulence model,discrete ordinates radiative heat transfer model and steady flamelet combustion model together with the chemical reaction mechanism of diesel fuel(C_(10)H_(22))have been applied.NO_(x) modeling has been performed via post-processing.Sensitivity analysis is such that by making variations in the problem inputs(diameter,angle and position of jets)in an organized manner,the effects on the outputs(NO_(x),CO,soot and pattern factor)are predicted.The number and order of simulations are predicted by design of experiments and full factorial model.Results have been analyzed using analysis of variance.It has been observed that if interactions among the characteristics of jets are considered,it is possible to analyze the exhaust pollutants more accurately.In fact,by using the interactions,it is likely to find a point where all output parameters are improved.Results show that by considering interactions of stabilizing jet characteristics,the maximum values of NO_(x),CO,soot and pattern factor change from 13.927 ppm,11.198%mole fraction,2.877 ppm and 0.043 to 26.233 ppm,14.693%mole fraction,142.357 ppm and 0.060,respectively.Furthermore,the minimum values change from 5.819 ppm,7.568%mole fraction,0.013 ppm and 0.029 to 6.098 ppm,5.987%mole fraction,0.002 ppm and 0.027,respectively.