Thermal properties of AlN-Si-Al composites produced by pressureless melt infiltration of Al/Al alloys into porous a-Si3N4 preforms were investigated in a temperature range of 50-300 °C. SEM and TEM investigations...Thermal properties of AlN-Si-Al composites produced by pressureless melt infiltration of Al/Al alloys into porous a-Si3N4 preforms were investigated in a temperature range of 50-300 °C. SEM and TEM investigations revealed that the grain size of AlN particles was less than 1 μm. In spite of sub-micron grain size, composites showed relatively high thermal conductivity (TC), 55-107 W/(m·K). The thermal expansion coefficient (CTE) of the composite produced with commercial Al source, which has the highest TC of 107 W/(m·K), was 6.5×10-6 K-1. Despite the high CTE of Al (23.6×10-6 K-1), composites revealed significantly low CTE through the formation of Si and AlN phases during the infiltration process.展开更多
Magnesium and calcium phosphates composites are promising biomaterials to create biodegradable load-bearing implants for bone regeneration. The present investigation is focused on the design of an interpenetrated magn...Magnesium and calcium phosphates composites are promising biomaterials to create biodegradable load-bearing implants for bone regeneration. The present investigation is focused on the design of an interpenetrated magnesium- tricalcium phosphate (Mg-TCP) composite and its evaluation under immersion test. In the study, TCP porous preforms were fabricated by robocasting to have a prefect control of porosity and pore size and later infiltrated with pure commercial Mg through current-assisted metal infiltration (CAMI) technique. The microstructure, composition, distribution of phases and degradation of the composite under physiological simulated conditions were analysed by scanning electron microscopy, elemental chemical analysis and X-ray diffraction. The results revealed that robocast TCP preforms were full infiltrated by magnesium through CAMI, even small pores below 2 μm have been filled with Mg, giving to the composite a good interpenetration. The degradation rate of the Mg-TCP composite displays lower value compared to the one of pure Mg during the first 24 h of immersion test.展开更多
Porous metals are a class of cellular materials with lightweight and unique mechanical,electrical,thermal,physical and acoustic characteristics.Magnesium and magnesium alloy foams have exhibited excellent advantages.I...Porous metals are a class of cellular materials with lightweight and unique mechanical,electrical,thermal,physical and acoustic characteristics.Magnesium and magnesium alloy foams have exhibited excellent advantages.In particular,open-cell Mg-based foams(porous Mg/Mg alloy foams)have been used for bioresorbable implants,CO_(2)trapping systems,filters,heat exchangers,absorbent panels and many other applications.While significant progress has been taken in producing porous Mg-based foams with good structure-property relations,but with a large number of different processing parameters,different mechanical properties and pore morphologies of each porous Mg-based foam,it is essential to understand the individual effects of each aspect of the parameters.Therefore,the present article summarized the effects of available processing parameters on the structure and mechanical properties of the porous Mg-based foams.Finally,the future perspectives to enhance the structure and properties of porous Mg/Mg alloy foams were discussed.展开更多
基金The Foundation for Scientific Research Projects of Mugla Sitki Kocman University(Project No.10/30)The Scientific&Technological Research Council of Turkey(TUBITAK,Project No:108M194)for funding the present work
文摘Thermal properties of AlN-Si-Al composites produced by pressureless melt infiltration of Al/Al alloys into porous a-Si3N4 preforms were investigated in a temperature range of 50-300 °C. SEM and TEM investigations revealed that the grain size of AlN particles was less than 1 μm. In spite of sub-micron grain size, composites showed relatively high thermal conductivity (TC), 55-107 W/(m·K). The thermal expansion coefficient (CTE) of the composite produced with commercial Al source, which has the highest TC of 107 W/(m·K), was 6.5×10-6 K-1. Despite the high CTE of Al (23.6×10-6 K-1), composites revealed significantly low CTE through the formation of Si and AlN phases during the infiltration process.
基金funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curieco-financed by the South Moravian Region under Grant No.665860+2 种基金the project CEITEC 2020(LQ1601) with financial support from the Ministry of Education,Youth and Sports of the Czech Republic under the National Sustainability Program Ⅱfounded by the Brno City Municipalitythe project CB.177700,and COFAA-IPN(SIP project 20144443)
文摘Magnesium and calcium phosphates composites are promising biomaterials to create biodegradable load-bearing implants for bone regeneration. The present investigation is focused on the design of an interpenetrated magnesium- tricalcium phosphate (Mg-TCP) composite and its evaluation under immersion test. In the study, TCP porous preforms were fabricated by robocasting to have a prefect control of porosity and pore size and later infiltrated with pure commercial Mg through current-assisted metal infiltration (CAMI) technique. The microstructure, composition, distribution of phases and degradation of the composite under physiological simulated conditions were analysed by scanning electron microscopy, elemental chemical analysis and X-ray diffraction. The results revealed that robocast TCP preforms were full infiltrated by magnesium through CAMI, even small pores below 2 μm have been filled with Mg, giving to the composite a good interpenetration. The degradation rate of the Mg-TCP composite displays lower value compared to the one of pure Mg during the first 24 h of immersion test.
基金supported by the Natural Science Foundation of Jiangsu Province of China(Grant No.BK20171437)Key R&D Program of Jiangsu Province of China(Grant No.BE2018044)+2 种基金the Guiding Captital for Industry Development Project of Suqian of China(Grant No.H201714)the Basic Science Research Project of Nantong of China(Grant No.JC2021190)the Natural Science Foundation of China(Grant No.12072105).
文摘Porous metals are a class of cellular materials with lightweight and unique mechanical,electrical,thermal,physical and acoustic characteristics.Magnesium and magnesium alloy foams have exhibited excellent advantages.In particular,open-cell Mg-based foams(porous Mg/Mg alloy foams)have been used for bioresorbable implants,CO_(2)trapping systems,filters,heat exchangers,absorbent panels and many other applications.While significant progress has been taken in producing porous Mg-based foams with good structure-property relations,but with a large number of different processing parameters,different mechanical properties and pore morphologies of each porous Mg-based foam,it is essential to understand the individual effects of each aspect of the parameters.Therefore,the present article summarized the effects of available processing parameters on the structure and mechanical properties of the porous Mg-based foams.Finally,the future perspectives to enhance the structure and properties of porous Mg/Mg alloy foams were discussed.