Thin polymer electrolyte with MXene functional layer for uniform Li^(+) deposition in all-solid-state lithium battery

Solid polymer electrolyte(SPE) shows great potential for all-solid-state batteries because of the inherent safety and flexibility;however, the unfavourable Li+deposition and large thickness hamper its development and application. Herein, a laminar MXene functional layer-thin SPE layer-cathode integration(MXene-PEO-LFP) is designed and fabricated. The MXene functional layer formed by stacking rigid MXene nanosheets imparts higher compressive strength relative to PEO electrolyte layer. And the abundant negatively-charged groups on MXene functional layer effectively repel anions and attract cations to adjust the charge distribution behavior at electrolyte–anode interface. Furthermore,the functional layer with rich lithiophilic groups and outstanding electronic conductivity results in low Li nucleation overpotential and nucleation energy barrier. In consequence, the cell assembled with MXene-PEO-LFP, where the PEO electrolyte layer is only 12 μm, much thinner than most solid electrolytes, exhibits uniform, dendrite-free Li+deposition and excellent cycling stability. High capacity(142.8 mAh g-1), stable operation of 140 cycles(capacity decay per cycle, 0.065%), and low polarization potential(0.5 C) are obtained in this Li|MXene-PEO-LFP cell,which is superior to most PEO-based electrolytes under identical condition. This integrated design may provide a strategy for the large-scale application of thin polymer electrolytes in all-solid-state battery.

In Situ Polymer Gel Electrolyte in Boosting Scalable Fibre Lithium Battery Applications

The poor interfacial stability not only deteriorates fibre lithium-ion batteries(FLBs)performance but also impacts their scalable applications.To efficiently address these challenges,Prof.Huisheng Peng team proposed a generalized channel structures strategy with optimized in situ polymerization technology in their recent study.The resultant FLBs can be woven into different-sized powering textiles,providing a high energy density output of 128 Wh kg^(-1) and simultaneously demonstrating good durability even under harsh conditions.Such a promising strategy expands the horizon in developing FLB with particular polymer gel electrolytes,and significantly ever-deepening understanding of the scaled wearable energy textile system toward a sustainable future.

Review on current development of polybenzimidazole membrane for lithium battery

With the rapid development of portable technology,lithium batteries have emerged as potential candidates for high-performance energy storage systems owing to their high energy density and cycling stability.Among the key components of a lithium battery system,the separator plays a critical role as it directly influences the battery performance benchmark(cycling performance and safety).However,traditional polyolefin separators(polypropylene/polyethylene)are unable to meet the demands of highperformance and safer battery systems due to their poor electrolyte compatibility,thermal runaways,and ultimate growth of dendrites.In contrast,membranes fabricated using polybenzimidazole(PBI)exhibit excellent electrolyte wettability and outstanding thermal dimensional stability,thus holding great potential as separators for high-performance and high-safety batteries.In this paper,we present a comprehensive review of the general requirements for separators,synthesis technology for separators,and research trends focusing PBI membranes in lithium batteries to alleviate the current commercial challenges faced by conventional polyolefin separators.In addition,we discuss the future development direction for PBI battery separators by considering various factors such as production cost,ecological footprint,preparation technology,and battery component compatibility.By exploring these perspectives,we aim to promote the continued application and exploration of PBI-based materials to advance lithium battery technology.

Laminar Composite Solid Electrolyte with Poly(Ethylene Oxide)-Threaded Metal-Organic Framework Nanosheets for High-Performance All-Solid-State Lithium Battery

Developing laminar composite solid electrolyte with ultrathin thickness and continuous conduction channels in vertical direction holds great promise for all-solid-state lithium batteries.Herein,a thin,laminar solid electrolyte is synthesized by filtrating–NH 2 functionalized metal-organic framework nanosheets and then being threaded with poly(ethylene oxide)chains induced by the hydrogen-bonding interaction from–NH_(2) groups.It is demonstrated that the threaded poly(ethylene oxide)chains lock the adjacent metal-organic framework nanosheets,giving highly enhanced structural stability(Young’s modulus,1.3 GPa)to 7.5-μm-thick laminar composite solid electrolyte.Importantly,these poly(ethylene oxide)chains with stretching structure serve as continuous conduction pathways along the chains in pores.It makes the non-conduction laminar metal-organic framework electrolyte highly conductive:3.97×10^(−5) S cm^(−1) at 25℃,which is even over 25 times higher than that of pure poly(ethylene oxide)electrolyte.The assembled lithium cell,thus,acquires superior cycling stability,initial discharge capacity(148 mAh g^(−1) at 0.5 C and 60℃),and retention(94% after 150 cycles).Besides,the pore size of nanosheet is tailored(24.5–40.9˚A)to evaluate the mechanisms of chain conformation and ion transport in confined space.It shows that the confined pore only with proper size could facilitate the stretching of poly(ethylene oxide)chains,and meanwhile inhibit their disorder degree.Specifically,the pore size of 33.8˚A shows optimized confinement effect with trans-poly(ethylene oxide)and cis-poly(ethylene oxide)conformation,which offers great significance in ion conduction.Our design of poly(ethylene oxide)-threaded architecture provides a platform and paves a way to the rational design of next-generation high-performance porous electrolytes.

Bayesian framework for satellite rechargeable lithium battery synthesizing bivariate degradation and lifetime data

Reliability and remaining useful life(RUL)estimation for a satellite rechargeable lithium battery(RLB)are significant for prognostic and health management(PHM).A novel Bayesian framework is proposed to do reliability analysis by synthesizing multisource data,including bivariate degradation data and lifetime data.Bivariate degradation means that there are two degraded performance characteristics leading to the failure of the system.First,linear Wiener process and Frank Copula function are used to model the dependent degradation processes of the RLB's temperature and discharge voltage.Next,the Bayesian method,in combination with Markov Chain Monte Carlo(MCMC)simulations,is provided to integrate limited bivariate degradation data with other congeneric RLBs'lifetime data.Then reliability evaluation and RUL prediction are carried out for PHM.A simulation study demonstrates that due to the data fusion,parameter estimations and predicted RUL obtained from our model are more precise than models only using degradation data or ignoring the dependency of different degradation processes.Finally,a practical case study of a satellite RLB verifies the usability of the model.

LiNbO3-coated LiNi0.8Co0.1Mn0.1O2 cathode with high discharge capacity and rate performance for all-solid-state lithium battery

In order to obtain high power density,energy density and safe energy storage lithium ion batteries(LIB)to meet growing demand for electronic products,oxide cathodes have been widely explored in all-solidstate lithium batteries(ASSLB)using sulfide solid electrolyte.However,the electrochemical performances are still not satisfactory,due to the high interfacial resistance caused by severe interfacial instability between sulfide solid electrolyte and oxide cathode,especially Ni-rich oxide cathodes,in charge-discharge process.Ni-rich LiNi0.8Co0.1Mn0.1O2(NCM811)material at present is one of the most key cathode candidates to achieve the high energy density up to 300 Wh kg^-1 in liquid LIB,but rarely investigated in ASSLB using sulfide electrolyte.To design the stable interface between NCM811 and sulfide electrolyte should be extremely necessary.In this work,in view of our previous work,LiNbO3 coating with about 1 wt% content is adopted to improve the interfacial stability and the electrochemical performances of NCM811 cathode in ASSLB using Li10GeP2S12 solid electrolyte.Consequently,LiNbO3-coated NCM811 cathode displays the higher discharge capacity and rate performance than the reported oxide electrodes in ASSLB using sulfide solid electrolyte to our knowledge.

Simulation of second-order RC equivalent circuit model of lithium battery based on variable resistance and capacitance

With the rise of the electric vehicle industry,as the power source of electric vehicles,lithium battery has become a research hotspot.The state of charge(SOC)estimation and modelling of lithium battery are studied in this paper.The ampere-hour(Ah)integration method based on external characteristics is analyzed,and the open-circuit voltage(OCV)method is studied.The two methods are combined to estimate SOC.Considering the accuracy and complexity of the model,the second-order RC equivalent circuit model of lithium battery is selected.Pulse discharge and exponential fitting of lithium battery are used to obtain corresponding parameters.The simulation is carried out by using fixed resistance capacitance and variable resistance capacitor respectively.The accuracy of variable resistance and capacitance model is 2.9%,which verifies the validity of the proposed model.

Discovery and design of lithium battery materials via high-throughput modeling

This paper reviews the rapid progress in the field of high-throughput modeling based on the Materials Genome Initiative, and its application in the discovery and design of lithium battery materials. It offers examples of screening, optimization and design of electrodes, electrolytes, coatings, additives, etc. and the possibility of introducing the machine learning method into material design. The application of the material genome method in the development of lithium battery materials provides the possibility to speed up the upgrading of new candidates in the discovery of lots of functional materials.

High-throughput theoretical design of lithium battery materials

The rapid evolution of high-throughput theoretical design schemes to discover new lithium battery materials is re- viewed, including fiigh-capacity cathodes, low-strain cathodes, anodes, solid state eleclrolytes, and electrolyte additives. With tfie development of efficient theoretical methods and inexpensive computers, high-throughput theoretical calculations have played an increasingly important role in the discovery of new malerials. With the help of automatic simnlation flow, many types of materials can be screened, optimized and designed from a structural database according to specific search criteria. In advanced cell technology, new materials for next generation lithium batteries are of great significance to achieve perlbmmnce, and some representative criteria are： higher energy density, better safety, and faster charge/discharge speed.

Novel Nanosized Adsorbing Composite Cathode Materials for the Next Generational Lithium Battery

A novel carbon-sulfur nano-composite material was synthesized by heating sublimed sulfur and high surface area activated carbon （HSAAC） under certain conditions. The physical and chemical per- formances of the novel carbon-sulfur nano-composite were characterized by scanning electron microscopy （SEM）, Brunauer-Emmett-Teller （BET） and X-ray diffraction （XRD）. The electrochemical performances of nano-composite were characterized by charge-discharge characteristic, cyclic voltammetry and electrochemical impendence spectroscopy （EIS）. The experimental results indicate that the electrochemical capability of nano- composite material was superior to that of traditional S-containing composite material. The cathode made by carbon-sulfur nano-composite material shows a good cycle ability and a high specific charge-discharge capacity. The HSAAC shows a vital role in adsorbing sublimed sulfur and the polysulfides within the cathode and is an excellent electric conductor for a sulfur cathode and prevents the shuttle behavior of the lithium-sulfur battery.

Lithium battery state of charge and state of health prediction based on fuzzy Kalman filtering

This paper presents a more accurate battery state of charge(SOC)and state of health(SOH)estimation method.A lithium battery is represented by a nonlinear two-order resistance-capacitance equivalent circuit model.The model parameters are estimated by searching least square error optimization algorithm.Precisely defined by this method,the model parameters allow to accurately determine the capacity of the battery,which in turn allows to specify the SOC prediction value used as a basis for the SOH value.Application of the extended Kalman filter(EKF)removes the need of prior known initial SOC,and applying the fuzzy logic helps to eliminate the measurement and process noise.Simulation results obtained during the urban dynamometer driving schedule(UDDS)test show that the maximum error in estimation of the battery SOC is 0.66%.Battery capacity is estimate by offline updated Kalman filter,and then SOH will be predicted.The maximum error in estimation of the battery capacity is 1.55%.

Kalman Filter Estimation of Lithium Battery SOC Based on Model Capacity Updating

High-precision estimation of lithium battery SOC can effectively optimize vehicle energy management,improve lithium battery safety protection,extend lithium battery cycle life,and reduce new energy vehicle costs.Based on the forgetting factor recursive least square method(FFRLS),Thevenin equivalent circuit model and Singular Value Decomposition-Unscented Kalman Filter(SVD-UKF),the SVD-UKF combined lithium battery SOC estimation algorithm with model capacity update is proposed,aiming at further improving the SOC estimation accuracy of lithium battery.The parameter identification of Thevenin model is studied by using the forgetting factor recursive least square method.To overcoming the shortcomings of Kalman filter linearization error and non-positive definite covariance matrix,the singular value decomposition unscented Kalman filter algorithm is proposed.It is worth mentioning that in order to consider the impact of battery available capacity attenuation on the estimation of lithium battery SOC,the model capacity update algorithm is used to optimize the model parameters and state joint estimation algorithm based on FFRLS&SVD-UKF.Verified by simulation and lithium battery test,the results show that the SVD-UKF algorithm based on model capacity update can accurately estimate the SOC of lithium battery in real time with the available capacity of lithium battery continuous attenuation.The purpose of improving the accuracy of SOC estimation of lithium batteries is achieved.

Electrochemical performance of Klason lignin as a low-cost cathode-active material for primary lithium battery

A few classes of organic compounds are promising electrode-active materials due to their high power and energy densities,low cost,environmental friendliness,and functionality.In the present work,the possibility of using Klason lignin extracted from buckwheat husks as a cathode-active material for a primary lithium battery has been investigated for the first time.The reaction mechanism in the lithium/lignin electrochemical cell was suggested based on the deep galvanostatic discharge（up to 0.005 V） data and cyclic voltammetry results.The dependence of the electrochemical behavior of the Klason lignin on the milling degree was evaluated.The maximum specific capacity of the lignin is equal to 600 m Ah g-1at a discharge current density of 75 μA cm-2.Beneficial effect of the thermal treatment of the Klason lignin cathode at250°C on the cell performance was established.It was found that the discharge capacity of the cell increased by 30% in the range from 3.3 to0.9 V for the treated cathode material.These results demonstrate the prospects of using Klason lignin-based electrochemical cells as low-rate primary power sources.

THE ELECTROCHEMICAL BEHAVIOUR OF THE NEW VANADIUM BRONZE (Li_3V_5O_(15)) CATHODE IN SECONDARY LITHIUM BATTERY

A new kind of vanadium bronze with rich lithium (Li_5V_5O_(15))was prepared from Li_2CO_3 and V_2O_5 at 680℃ for 24 hrs. The charge and discharge curves of bronze electrode were determined in organic electrolyte. One mole of this material could be incorporated up to 4 mole lithium at 0.2mA/cm^2 and 1.0V cut-off voltage, corresponding capacity about 340Ah/kg. Compared with the cell of Li/Li_(1+x)V_3O_5 the cell of Li/new bronze had higher capacity, smoother discberge curve, but lower plateau voltage (about 1.8V). The cycling behaviour of this material was good. The electrode insertion reaction was controlled by the lithium diffusion process in the bronze. This new bronze could be used for low voltage rechargeable lithium battery.

HIGH TEMPERATURE SUPERCONDUCTOR YBa_2CuaO_(7-x) AS A LITHIUM BATTERY CATHODE

Superconductor YBa_2Cu_3O_(7-x) used as a material for lithium battery was examined in 1NLiClO_4 propylene carbonate/1,2-dimethoxyethane (1:1) solution. YBa_2Cu_3O_(7-x) exhibited 150 mAh/g of discharge capacity at 250 uA/cm^2 discharge current. An ac impedance measurements was carried out, the results have shown that the electrode reaction has low charge-transfer resistance and the chemical diffusion coeffic ient of Li^+ has a value of 10^(-11) cm^2/sec.

Summary of the Performance of V_(2)O_(5)Materials as Lithium Battery Cathode

Lithium battery has recently gained more and more attention worldwide.It has wide usage that range from toys to electric cars.Choosing a suitable material that best fits the overall performance as electrode for the battery is very essential.For cathode material,apart from the traditional and widely-used LiCoCO_(2),LiFePO_(4)and so on,there are innovations that include the use of V_(2)O_(5).Researches have been done focusing on how to further improve the performance for V_(2)O_(5)cathode in terms of different structure,forms or combination with other chemical molecules.This research paper will make a summary of the materials derived from traditional V_(2)O_(5)as well as their performances.

Advanced Nonflammable Localized High-Concentration Electrolyte For High Energy Density Lithium Battery

The key to realize long-life high energy density lithium batteries is to exploit functional electrolytes capable of stabilizing both high voltage cathode and lithium anode.The emergence of localized high-concentration electrolytes(LHCEs)shows great promise for ameliorating the above-mentioned interfacial issues.In this work,a lithium difluoro(oxalate)borate(LiDFOB)based nonflammable dual-anion LHCE is designed and prepared.Dissolving in the mixture of trimethyl phosphate(TMP)/1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)),the continuously consumption of LiDFOB is suppressed by simply introducing lithium nitrate(LiNO_(3)).Meantime,as most of the TMP molecular are coordinated with Li^(+),the electrolyte does not show incompatibility issue between neither metal lithium nor graphite anode.Therefore,it demonstrates excellent capability in stabilizing the interface of Ni-rich cathode and regulating lithium deposition morphology.The Li||LiNi_(0.87)Co_(0.08)Mn_(0.05)O_(2)(NCM87)batteries exhibit high capacity retention of more than 90%after 200 cycles even under the high cutoff voltage of 4.5 V,1 C rate.This study offers a prospective method to develop safe electrolytes suitable for high voltage applications,thus providing higher energy densities.

Application of Nonlinear Triangular Fuzzy Fault Tree Algorithm in Predicting Lithium Battery Air Transport Accidents

The traditional triangular fuzzy fault tree prediction model adopts the linear approximation method.Therefore,the accident prediction error is large.Based on the analysis of the error sources and the fuzzy set,the precise calculation method of the event at the top of the fault tree is given.By using the numerical calculation software,an accurate calculation method of nonlinear triangular fuzzy accident prediction was adopted to predict lithium battery air transport fire accidents,and the fuzzy importance of the cause event was calculated.

Numerical Simulation of Thermal Management of Lithium Battery Based on Air Cooled Heat Dissipation

In recent years,due to the rapid increase in the number of vehicles in the world,the traditional vehicles using gasoline or diesel as energy have led to serious air pollution and energy depletion.It is urgent to develop practical clean energy vehicles.The performance of electric vehicle depends on the power battery pack.The working temperature of the battery pack has a great impact on the performance of the battery,so it is necessary to carry out thermal management on the battery pack.Taking a lithium-ion battery as the research object,the temperature field of the battery pack in the charge and discharge state is simulated and analyzed by using CFD simulation software in the way of air cooled heat dissipation,so as to understand the influencing factors of uneven temperature field.At the same time,the development trend of battery temperature can be well predicted through simulation,so as to provide theoretical basis for the design of battery pack.

Regulating electrochemical performances of lithium battery by external physical field

Lithium batteries have always played a key role in the field of new energy sources.However,non-controllable lithium dendrites and volume dilatation of metallic lithium in batteries with lithium metal as anodes have limited their development.Recently,a large number of studies have shown that the electrochemical performances of lithium batteries can be enhanced through the regulation of external physical fields.Especially,it significantly hinders the growth of lithium dendrites and promoting the reaction kinetics.This review summarizes recent innovations in the investigation of various physical fields of lithium batteries.The application of magnetic field in the synthesis of lithium battery electrode materials is introduced.The influence factors and regulation mechanism of various physical fields on the electrochemical performance of lithium batteries are reviewed emphatically.In addition,the current research status and existing challenges,along with future directions for the evolution of lithium batteries,are minutely discussed and prospected.New strategies for the further evolution of lithium batteries have also been provided.