Primary Results of Lithium Coating for the Improvement of Plasma Performance in EAST

First lithium coating associated with ion cyclotron range of frequency （ICRF） plasma was performed successfully in EAST. Results in reduction of both residual impurity and deuterium in the vacuum vessel were obtained. Particularly the partial pressure of deuterium after the lithium coating was reduced by about a factor of 5. Impurity radiation in the plasma was reduced and electron temperature increased by about 50%. Moreover, reproducible plasma discharges with high parameters, such as higher plasma current and density, could be easily obtained. These results showed that plasma performance was improved. Even though only 2 g of lithium were injected, the effective lifetime of the Li film was raised up to 40 shots.

Stabilized cobalt-free lithium-rich cathode materials with an artificial lithium fluoride coating

Iron-substituted cobalt-free lithium-rich manganese-based materials,with advantages of high specific capacity,high safety,and low cost,have been considered as the potential cathodes for lithium ion batteries.However,challenges,such as poor cycle stability and fast voltage fade during cycling under high potential,hinder these materials from commercialization.Here,we developed a method to directly coat LiF on the particle surface of Li_(1.2)Ni_(0.15)Fe_(0.1)Mn_(0.55O2).A uniform and flat film was successfully formed with a thickness about 3 nm,which can effect-ively protect the cathode material from irreversible phase transition during the deintercalation of Li^(+).After surface coating with 0.5wt%LiF,the cycling stability of Li_(1.2)Ni_(0.15)Fe_(0.1)Mn_(0.55O2) cycled at high potential was significantly improved and the voltage fade was largely suppressed.

Spectroscopic Measurements of Impurity Spectra on the EAST Tokamak

Ultraviolet （UV） and visible impurity spectra （200-750 nm） are commonly used to study plasma and wall interactions in magnetic fusion plasmas. Two optical multi-channel analysis （OMA） systems have been installed for the UV-visible spectrum measurement on EAST. These two OMA systems are both equipped with the Czerny-Turner （C-T） type spectrometer. The upper vacuum vessel and inner divertor baffle can be viewed simultaneously through two optical lenses. The OMA1 system is mainly used for multi-impurity lines radiation measurement. A 280 nm wavelength range can be covered by a 300 mm focal length spectrometer equipped with a 300 grooves/mm grating. The Da/Ha line shapes can be resolved by the OMA2 system. The focal length is 750 mm. The spectral resolution can be up to 0.01 nm using a 1800 grooves/mm grating. The impurity behaviour and hydrogen ratio evolution after boroniztion, lithium coating, and siliconization are compared. Lithium coating has shown beneficial effects on the reduction of edge recycling and low Z impurity （C, O） influx. The impurity expelling effect of the divertor configuration is also briefly discussed through multi-channels observation of OMA1 system.

Forming solid electrolyte interphase in situ in an ionic conducting Li_(1.5)Al_(0.5)Ge_(1.5)(PO_4)_3-polypropylene(PP) based separator for Li-ion batteries

A new concept of forming solid electrolyte interphases（SEI） in situ in an ionic conducting Li（1.5）Al（0.5）Ge（1.5）（PO4）3-polypropylene（LAGP-PP） based separator during charging and discharging is proposed and demonstrated. This unique structure shows a high ionic conductivity, low interface resistance with electrode, and can suppress the growth of lithium dendrite. The features of forming the SEI in situ are investigated by scanning electron microscopy（SEM） and x-ray photoelectron spectroscopy（XPS）. The results confirm that SEI films mainly consist of lithium fluoride and carbonates with various alkyl contents. The cell assembled by using the LAGP-coated separator demonstrates a good cycling performance even at high charging rates, and the lithium dendrites were not observed on the lithium metal electrode. Therefore, the SEI-LAGP-PP separator can be used as a promising flexible solid electrolyte for solid state lithium batteries.

Sub-100 nm hollow SnO_2@C nanoparticles as anode material for lithium ion batteries and significantly enhanced cycle performances

Rational designing and controlling of nanostructures is a key factor in realizing appropriate properties required for the high-performance energy fields. In the present study, hollow Sn O2@C nanoparticles（NPs） with a mean size of 50 nm have been synthesized in large-scale via a facile hydrothermal approach.The morphology and composition of as-obtained products were studied by various characterized techniques. As an anode material for lithium ion batteries（LIBs）, the as-prepared hollow Sn O2@C NPs exhibit significant improvement in cycle performances. The discharge capacity of lithium battery is as high as 370 m Ah g 1, and the current density is 3910 m A g 1（5 C） after 573 cycles. Furthermore, the capacity recovers up to 1100 m Ah g 1at the rate performances in which the current density is recovered to 156.4 m A g 1（0.2 C）. Undoubtedly, sub-100 nm Sn O2@C NPs provide significant improvement to the electrochemical performance of LIBs as superior-anode nanomaterials, and this carbon coating strategy can pave the way for developing high-performance LIBs.