The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)...The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)and phenol(PhOH)were used to prepare a novel class of deep eutectic solvents(DESs)with multiple active sites and low viscosities.The NH_(3) separation performance of EtOHACl+PhOH DESs was analyzed completely.It is figured out that the NH_(3) absorption rates in EtOHACl+PhOH DESs are very fast.The NH_(3) absorption capacities are very high and reach up to 5.52 and 10.74 mol·kg1 at 11.2 and 100.4 kPa under 298.2 K,respectively.In addition,the EtOHACl+PhOH DESs present highly selective absorption of NH_(3) over N_(2) and H_(2) and good regenerative properties after seven cycles of absorption/desorption.The intrinsic separation mechanism of NH_(3) by EtOHACl+PhOH DESs was further revealed by spectroscopic analysis and quantum chemistry calculations.展开更多
The clinical effects of two different methods–high-viscosity cement percutaneous vertebroplasty（PVP） and low-viscosity cement percutaneous kyphoplasty（PKP） in the treatment of osteoporotic vertebral compression f...The clinical effects of two different methods–high-viscosity cement percutaneous vertebroplasty（PVP） and low-viscosity cement percutaneous kyphoplasty（PKP） in the treatment of osteoporotic vertebral compression fractures（OVCFs） were investigated. From June 2010 to August 2013, 98 cases of OVCFs were included in our study. Forty-six patients underwent high-viscosity PVP and 52 patients underwent low-viscosity PKP. The occurrence of cement leakage was observed. Pain relief and functional activity were evaluated using the Visual Analog Scale（VAS） and Oswestry Disability Index（ODI）, respectively. Restoration of the vertebral body height and angle of kyphosis were assessed by comparing preoperative and postoperative measurements of the anterior heights, middle heights and the kyphotic angle of the fractured vertebra. Nine out of the 54 vertebra bodies and 11 out of the 60 vertebra bodies were observed to have cement leakage in the high-viscosity PVP and low-viscosity PKP groups, respectively. The rate of cement leakage, correction of anterior vertebral height and kyphotic angles showed no significant differences between the two groups（P〉0.05）. Low-viscosity PKP had significant advantage in terms of the restoration of middle vertebral height as compared with the high-viscosity PVP（P〈0.05）. Both groups showed significant improvements in pain relief and functional capacity status after surgery（P〈0.05）. It was concluded that high-viscosity PVP and low-viscosity PKP have similar clinical effects in terms of the rate of cement leakage, restoration of the anterior vertebral body height, changes of kyphotic angles, functional activity, and pain relief. Low-viscosity PKP is better than high-viscosity PVP in restoring the height of the middle vertebra.展开更多
Low temperature fluidity of gear oils is an important fluid property as it directly impacts the useful life of a gear set.This paper compares low temperature fluidity measurement precision of ASTM D6821 and ASTM D2983...Low temperature fluidity of gear oils is an important fluid property as it directly impacts the useful life of a gear set.This paper compares low temperature fluidity measurement precision of ASTM D6821 and ASTM D2983.Both tests are identical in the way they thermally condition the sample prior to viscosity measurement.While ASTM D2983 is cited in many current specifications,ASTM D6821 offers users and formulators a more accurate estimate of gear oil low temperature fluidity.The primary benefit in using ASTM D6821 is better precision.ASTM D6821 accomplishes this by automating the steps from prior to preheat through to viscosity measurement at end of test.展开更多
This study focused on the development of a new low viscosity automatic transmission fluid(ATF) with enhanced friction durability to meet the needs of new step type automatic transmissions.Recent high fuel prices encou...This study focused on the development of a new low viscosity automatic transmission fluid(ATF) with enhanced friction durability to meet the needs of new step type automatic transmissions.Recent high fuel prices encourage increased efficiency in the driveline,including the transmission.Reduction in fluid viscosity and wider use of slip control in torque converter clutches are two ways to practically improve fuel efficiency.Increased torque and more shifting is seen with a variety of new transmission hardware platforms,such as wet starting clutches,dual clutches and seven-or eight-speed ATs.This suggests the need for enhanced levels of friction durability from the ATF.The new challenge from this hardware for the ATF formulator lies in the need to simultaneously meet the wear,friction durability and torque capacity requirements at low viscosity in a cost-effective manner.This report introduced a new low viscosity fluid that represents a different commercial ATF formulation style.The new chemistry employs a low viscosity for increased fuel economy,while easily doubling the friction durability of current conventional ATFs and offering higher torque and better EP.展开更多
基金supported by the National Natural Science Foundation of China(22221005 and 22008033).
文摘The efficient separation and collection of ammonia(NH_(3))during NH_(3) synthesis process is essential to improve the economic efficiency and protect the environment.In this work,ethanolammonium hydrochloride(EtOHACl)and phenol(PhOH)were used to prepare a novel class of deep eutectic solvents(DESs)with multiple active sites and low viscosities.The NH_(3) separation performance of EtOHACl+PhOH DESs was analyzed completely.It is figured out that the NH_(3) absorption rates in EtOHACl+PhOH DESs are very fast.The NH_(3) absorption capacities are very high and reach up to 5.52 and 10.74 mol·kg1 at 11.2 and 100.4 kPa under 298.2 K,respectively.In addition,the EtOHACl+PhOH DESs present highly selective absorption of NH_(3) over N_(2) and H_(2) and good regenerative properties after seven cycles of absorption/desorption.The intrinsic separation mechanism of NH_(3) by EtOHACl+PhOH DESs was further revealed by spectroscopic analysis and quantum chemistry calculations.
基金supported by Development Center for Medical Science and Technology,National Health and Family Planning Commission of China(No.W2012ZT15)
文摘The clinical effects of two different methods–high-viscosity cement percutaneous vertebroplasty（PVP） and low-viscosity cement percutaneous kyphoplasty（PKP） in the treatment of osteoporotic vertebral compression fractures（OVCFs） were investigated. From June 2010 to August 2013, 98 cases of OVCFs were included in our study. Forty-six patients underwent high-viscosity PVP and 52 patients underwent low-viscosity PKP. The occurrence of cement leakage was observed. Pain relief and functional activity were evaluated using the Visual Analog Scale（VAS） and Oswestry Disability Index（ODI）, respectively. Restoration of the vertebral body height and angle of kyphosis were assessed by comparing preoperative and postoperative measurements of the anterior heights, middle heights and the kyphotic angle of the fractured vertebra. Nine out of the 54 vertebra bodies and 11 out of the 60 vertebra bodies were observed to have cement leakage in the high-viscosity PVP and low-viscosity PKP groups, respectively. The rate of cement leakage, correction of anterior vertebral height and kyphotic angles showed no significant differences between the two groups（P〉0.05）. Low-viscosity PKP had significant advantage in terms of the restoration of middle vertebral height as compared with the high-viscosity PVP（P〈0.05）. Both groups showed significant improvements in pain relief and functional capacity status after surgery（P〈0.05）. It was concluded that high-viscosity PVP and low-viscosity PKP have similar clinical effects in terms of the rate of cement leakage, restoration of the anterior vertebral body height, changes of kyphotic angles, functional activity, and pain relief. Low-viscosity PKP is better than high-viscosity PVP in restoring the height of the middle vertebra.
文摘Low temperature fluidity of gear oils is an important fluid property as it directly impacts the useful life of a gear set.This paper compares low temperature fluidity measurement precision of ASTM D6821 and ASTM D2983.Both tests are identical in the way they thermally condition the sample prior to viscosity measurement.While ASTM D2983 is cited in many current specifications,ASTM D6821 offers users and formulators a more accurate estimate of gear oil low temperature fluidity.The primary benefit in using ASTM D6821 is better precision.ASTM D6821 accomplishes this by automating the steps from prior to preheat through to viscosity measurement at end of test.
文摘This study focused on the development of a new low viscosity automatic transmission fluid(ATF) with enhanced friction durability to meet the needs of new step type automatic transmissions.Recent high fuel prices encourage increased efficiency in the driveline,including the transmission.Reduction in fluid viscosity and wider use of slip control in torque converter clutches are two ways to practically improve fuel efficiency.Increased torque and more shifting is seen with a variety of new transmission hardware platforms,such as wet starting clutches,dual clutches and seven-or eight-speed ATs.This suggests the need for enhanced levels of friction durability from the ATF.The new challenge from this hardware for the ATF formulator lies in the need to simultaneously meet the wear,friction durability and torque capacity requirements at low viscosity in a cost-effective manner.This report introduced a new low viscosity fluid that represents a different commercial ATF formulation style.The new chemistry employs a low viscosity for increased fuel economy,while easily doubling the friction durability of current conventional ATFs and offering higher torque and better EP.
