Based on the MAP-CGE model,this paper simulated the impacts on the output,energy consumption and pollutant emissions of different cement production processes when implementing a low carbon cement standard in China.It ...Based on the MAP-CGE model,this paper simulated the impacts on the output,energy consumption and pollutant emissions of different cement production processes when implementing a low carbon cement standard in China.It also calculated the impacts on the marginal abatement cost and equilibrium price of the cement industry,and analyzed the co-abatement effects of different pollutants.The results showed that implementing the low carbon cement standard will be beneficial in promoting an upgrading of cement production processes,and strengthening the energy conservation and emission reduction in the cement industry.If there is no change in the existing technology,the cement industry will reduce SO2emissions by 1.17 kg and NOxemissions by 4.44 kg per ton of CO2emission reduction.Implementing low carbon cement standard can also promote NOxabatement in the cement industry.However,the cement industry will bear the abatement costs,and their equilibrium price will increase slightly.展开更多
This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of he...This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.展开更多
This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial eq...This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=(14674.69±17.49)J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-(32374.25±12.93)J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -(4445.47 ± 1.77) kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm(C8H11NO, s)=-(274.68 ±2.06) kJ·mol^-1, in accordance with Hess law.展开更多
The city of Lisbon, like many others in the EU region, introduced a Low Emission Zone (LEZ) as a tool for improving air quality in its city centre. This kind of emission reduction schemes is always controversial since...The city of Lisbon, like many others in the EU region, introduced a Low Emission Zone (LEZ) as a tool for improving air quality in its city centre. This kind of emission reduction schemes is always controversial since it might lead to significant changes in the daily behaviours of its inhabitants. In order to evaluate the effects of the measure, an estimation of the impact of the introduction of the Lisbon LEZ was performed. Real traffic counting and fleet characterization combined with CORINAR-based emission inventory methodology allowed to estimate the impacts of three different scenarios applied to the “business as usual” condition (current vehicle fleet) ranging from “no circulation from non- compliant vehicles” to an “aggressive fleet renewal”. Results highlight the high percentage of atmospheric emissions of PM10 and NOx that might result from certain fleets like taxis and buses, especially because there was an emphasis in standardized/normalized estimations (emissions per 1000 vehicles) in order to allow different strategic approaches. The total reduction of PM10 emissions associated to each scenario vary between 6 ton.year-1 (scenario 2) and 8 ton.year-1 (scenario 1), or 25% and 34% less emissions. In terms of NOxemission reductions vary between 6 ton.year-1 (scenario 2) and 57 ton.year-1 (scenario 1), or 1% and 7% less emissions. The Lisbon LEZ is therefore much more efficient in reducing PM10 emissions compared to NOx. Major reduction in PM10 and NOx emissions are to be expected with a moderate intervention in the (relatively old) taxi fleet in Lisbon while for passenger cars the impact is limited. However in absolute terms and due to its urban mileage passenger cars should also continue being included in Lisbon LEZ. Simultaneously, an effort in the increase of dedicated lanes for public transport should be made, for further reductions in PM10 and NOx emissions.展开更多
Objectives: To challenge the expiry dates of low concentration high purity mycotoxins standards. Literature Review: Aflatoxins (AFs) and Ochratoxin A (OTA) are persistent mycotoxins with adverse effects on humans. Myc...Objectives: To challenge the expiry dates of low concentration high purity mycotoxins standards. Literature Review: Aflatoxins (AFs) and Ochratoxin A (OTA) are persistent mycotoxins with adverse effects on humans. Mycotoxins standards are purchased to determine mycotoxin concentrations in food and may be stocked in some laboratories beyond expiry dates causing laboratories financial losses. Methods: Certified mycotoxins standards were purchased over the years from the same supplier at times and at other times from two different suppliers for quality control purposes. For AFs, six chromatographic runs for each of the mycotoxins standards were done to compare the difference among these standards having the following expiry dates (2008, 2012, 2013 and 2018). AFs standards purchased/obtained from two different suppliers in 2016 and expiring in 2018 were also compared. For OTA, the difference of concentration obtained between two years (2010 and 2018) was tested. All samples were run on a HPLC equipped with a fluorescence detector. Linearity of calibration curves and the points of lowest detection were determined for AFs components and for OTA from the unexpired mycotoxins standards. Results: At a 0.05 significance level and using non parametric tests, the statistical test revealed a p of 0.166, 0.153, 0.358 and 0.03 for B1, G1, B2 and G2 respectively among years for standards from same supplier and 0.037, 0.109, 0.182 and 0.182 for B1, G1, B2 and G2 respectively for unexpired standards from two different suppliers. For OTA, a p of 0.109 was obtained for standards of different expiry dates purchased from different suppliers. Conclusion: High purity low concentration mycotoxin standards purchased a decade ago (i.e. expired) did not differ from those purchased this current year (still valid). Hence, the expiry date can be renewed reducing the laboratories expenses. Manufacturers are urged to reconsider the expiry dates.展开更多
目的探讨发病4.5~9.0 h的急性缺血性脑卒中(acute ischemic stroke,AIS)患者经多模式CT筛选下超时间窗应用小剂量或标准剂量阿替普酶静脉溶栓的有效性和安全性。方法回顾性分析2021年1月—2023年1月在临沂市中心医院卒中中心就诊的发病...目的探讨发病4.5~9.0 h的急性缺血性脑卒中(acute ischemic stroke,AIS)患者经多模式CT筛选下超时间窗应用小剂量或标准剂量阿替普酶静脉溶栓的有效性和安全性。方法回顾性分析2021年1月—2023年1月在临沂市中心医院卒中中心就诊的发病时间在4.5~9.0 h的104例AIS患者。均完善一站式多模式CT检查,采用F-stroke软件处理分析脑CT灌注成像,存在核心/灌注不匹配者,给予阿替普酶静脉溶栓,并按照采用剂量大小分为小剂量组(0.6 mg/kg体质量,n=53)与标准剂量组(0.9 mg/kg体质量,n=54)。通过对比改良RanKin评分量表(modified RanKin scale,mRS)、美国国立卫生研究院卒中量表(the National Institutes of Health stroke scale,NIHSS)评分评估临床有效性,通过比较出血性转化(hemorrhagic transformation,HT)率、症状性颅内出血(symptomatic intracranial hemorrhage,SICH)率、泌尿道出血率、消化道出血率、病死率评估临床安全性。结果小剂量组预后良好率为58.49%(31/53),标准剂量组预后良好率为59.26%(32/54),差异无统计学意义(P>0.05)。2组溶栓后7 d NIHSS评分低于基线NIHSS评分,溶栓后90 d mRS评分低于入院时mRS评分,差异有统计学意义(P<0.05)。2组溶栓后7 d NIHSS评分、溶栓后90 d mRS评分比较,差异无统计学意义(P>0.05)。小剂量组24 h HT发生率、24 h SICH发生率、泌尿道出血发生率、消化道出血发生率、90 d病死率分别为1.89%(1/53)、1.89%(1/53)、3.77%(2/53)、1.89%(1/53)、1.89%(1/53),标准剂量组分别为9.26%(5/54)、7.41%(4/54)、1.85%(1/54)、5.56%(3/54)、1.85%(1/54),差异无统计学意义(P>0.05)。结论多模式CT筛选指导下发病在4.5~9.0 h的AIS患者超时间窗应用小剂量和标准剂量阿替普酶静脉溶栓有相似的临床疗效,小剂量更安全。展开更多
基金supported by the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(No.14XNJ008)
文摘Based on the MAP-CGE model,this paper simulated the impacts on the output,energy consumption and pollutant emissions of different cement production processes when implementing a low carbon cement standard in China.It also calculated the impacts on the marginal abatement cost and equilibrium price of the cement industry,and analyzed the co-abatement effects of different pollutants.The results showed that implementing the low carbon cement standard will be beneficial in promoting an upgrading of cement production processes,and strengthening the energy conservation and emission reduction in the cement industry.If there is no change in the existing technology,the cement industry will reduce SO2emissions by 1.17 kg and NOxemissions by 4.44 kg per ton of CO2emission reduction.Implementing low carbon cement standard can also promote NOxabatement in the cement industry.However,the cement industry will bear the abatement costs,and their equilibrium price will increase slightly.
基金Project supported by the National Natural Science Foundations of China (Grant Nos.20673050 and 20973089)
文摘This paper reports that the low-temperature heat capacities of pyridine-2,6-dicarboxylic acid were measured by a precision automatic calorimeter over a temperature range from 78 K to 380 K. A polynomial equation of heat capacities as a function of temperature was fitted by the least-squares method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 K were calculated and tabulated at intervals of 5 K. The constant-volume energy of combustion of the compound was determined by means of a precision rotating-bomb combustion calorimeter. The standard molar enthalpy of combustion of the compound was derived from the constant-volume energy of combustion. The standard molar enthalpy of formation of the compound was calculated from a combination of the datum of the standard molar enthalpy of combustion of the compound with other auxiliary thermodynamic quantities through a Hess thermochemical cycle.
基金supported by the National Natural Science Foundation of China (Grant No 20673050)
文摘This paper reports that low-temperature heat capacities of 4-(2-aminoethyl)-phenol (C8H11NO) are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=(14674.69±17.49)J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-(32374.25±12.93)J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -(4445.47 ± 1.77) kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm(C8H11NO, s)=-(274.68 ±2.06) kJ·mol^-1, in accordance with Hess law.
文摘The city of Lisbon, like many others in the EU region, introduced a Low Emission Zone (LEZ) as a tool for improving air quality in its city centre. This kind of emission reduction schemes is always controversial since it might lead to significant changes in the daily behaviours of its inhabitants. In order to evaluate the effects of the measure, an estimation of the impact of the introduction of the Lisbon LEZ was performed. Real traffic counting and fleet characterization combined with CORINAR-based emission inventory methodology allowed to estimate the impacts of three different scenarios applied to the “business as usual” condition (current vehicle fleet) ranging from “no circulation from non- compliant vehicles” to an “aggressive fleet renewal”. Results highlight the high percentage of atmospheric emissions of PM10 and NOx that might result from certain fleets like taxis and buses, especially because there was an emphasis in standardized/normalized estimations (emissions per 1000 vehicles) in order to allow different strategic approaches. The total reduction of PM10 emissions associated to each scenario vary between 6 ton.year-1 (scenario 2) and 8 ton.year-1 (scenario 1), or 25% and 34% less emissions. In terms of NOxemission reductions vary between 6 ton.year-1 (scenario 2) and 57 ton.year-1 (scenario 1), or 1% and 7% less emissions. The Lisbon LEZ is therefore much more efficient in reducing PM10 emissions compared to NOx. Major reduction in PM10 and NOx emissions are to be expected with a moderate intervention in the (relatively old) taxi fleet in Lisbon while for passenger cars the impact is limited. However in absolute terms and due to its urban mileage passenger cars should also continue being included in Lisbon LEZ. Simultaneously, an effort in the increase of dedicated lanes for public transport should be made, for further reductions in PM10 and NOx emissions.
文摘Objectives: To challenge the expiry dates of low concentration high purity mycotoxins standards. Literature Review: Aflatoxins (AFs) and Ochratoxin A (OTA) are persistent mycotoxins with adverse effects on humans. Mycotoxins standards are purchased to determine mycotoxin concentrations in food and may be stocked in some laboratories beyond expiry dates causing laboratories financial losses. Methods: Certified mycotoxins standards were purchased over the years from the same supplier at times and at other times from two different suppliers for quality control purposes. For AFs, six chromatographic runs for each of the mycotoxins standards were done to compare the difference among these standards having the following expiry dates (2008, 2012, 2013 and 2018). AFs standards purchased/obtained from two different suppliers in 2016 and expiring in 2018 were also compared. For OTA, the difference of concentration obtained between two years (2010 and 2018) was tested. All samples were run on a HPLC equipped with a fluorescence detector. Linearity of calibration curves and the points of lowest detection were determined for AFs components and for OTA from the unexpired mycotoxins standards. Results: At a 0.05 significance level and using non parametric tests, the statistical test revealed a p of 0.166, 0.153, 0.358 and 0.03 for B1, G1, B2 and G2 respectively among years for standards from same supplier and 0.037, 0.109, 0.182 and 0.182 for B1, G1, B2 and G2 respectively for unexpired standards from two different suppliers. For OTA, a p of 0.109 was obtained for standards of different expiry dates purchased from different suppliers. Conclusion: High purity low concentration mycotoxin standards purchased a decade ago (i.e. expired) did not differ from those purchased this current year (still valid). Hence, the expiry date can be renewed reducing the laboratories expenses. Manufacturers are urged to reconsider the expiry dates.
文摘目的探讨发病4.5~9.0 h的急性缺血性脑卒中(acute ischemic stroke,AIS)患者经多模式CT筛选下超时间窗应用小剂量或标准剂量阿替普酶静脉溶栓的有效性和安全性。方法回顾性分析2021年1月—2023年1月在临沂市中心医院卒中中心就诊的发病时间在4.5~9.0 h的104例AIS患者。均完善一站式多模式CT检查,采用F-stroke软件处理分析脑CT灌注成像,存在核心/灌注不匹配者,给予阿替普酶静脉溶栓,并按照采用剂量大小分为小剂量组(0.6 mg/kg体质量,n=53)与标准剂量组(0.9 mg/kg体质量,n=54)。通过对比改良RanKin评分量表(modified RanKin scale,mRS)、美国国立卫生研究院卒中量表(the National Institutes of Health stroke scale,NIHSS)评分评估临床有效性,通过比较出血性转化(hemorrhagic transformation,HT)率、症状性颅内出血(symptomatic intracranial hemorrhage,SICH)率、泌尿道出血率、消化道出血率、病死率评估临床安全性。结果小剂量组预后良好率为58.49%(31/53),标准剂量组预后良好率为59.26%(32/54),差异无统计学意义(P>0.05)。2组溶栓后7 d NIHSS评分低于基线NIHSS评分,溶栓后90 d mRS评分低于入院时mRS评分,差异有统计学意义(P<0.05)。2组溶栓后7 d NIHSS评分、溶栓后90 d mRS评分比较,差异无统计学意义(P>0.05)。小剂量组24 h HT发生率、24 h SICH发生率、泌尿道出血发生率、消化道出血发生率、90 d病死率分别为1.89%(1/53)、1.89%(1/53)、3.77%(2/53)、1.89%(1/53)、1.89%(1/53),标准剂量组分别为9.26%(5/54)、7.41%(4/54)、1.85%(1/54)、5.56%(3/54)、1.85%(1/54),差异无统计学意义(P>0.05)。结论多模式CT筛选指导下发病在4.5~9.0 h的AIS患者超时间窗应用小剂量和标准剂量阿替普酶静脉溶栓有相似的临床疗效,小剂量更安全。