An attempt was made to extend mild combustion to forward flow furnace, such as the refinery and petrochemical tube furnace. Three dimensional numerical simulation was carried out to study the performance of this furna...An attempt was made to extend mild combustion to forward flow furnace, such as the refinery and petrochemical tube furnace. Three dimensional numerical simulation was carried out to study the performance of this furnace. The Eddy Dissipation Concept(EDC) model coupled with the reaction mechanism DRM-19 was used. The prediction showed a good agreement with the measurement. The effect of air nozzle circle(D), air nozzle diameter(d), air nozzle number(N), and air preheating temperature(Tair) on the flow, temperature and species fields, and the CO and NO emissions was investigated. The results indicate that there are four zones in the furnace, viz.: a central jet zone, an ignition zone, a combustion reaction zone, and a flue gas zone, according to the distribution profiles of H_2 CO and OH. The central jet entrains more flue gas in the furnace upstream with an increasing D while the effect of D is negligible in the downstream. The air jet momentum increases with a decreasing d or an increasing Tair, and entrains more flue gas. The effect of N is mainly identified near the burner exit. More heat is absorbed in the radiant section and less heat is discharged to the atmosphere with a decreasing d and an increasing N as evidenced by the flue gas temperature. The CO and NO emissions are less than 50 μL/L and 10 μL/L, respectively, in most of conditions.展开更多
This work concerns the study of HSs (Hybrid Systems) that are made up of the integration of M-HTFC (Medium and High Temperature Fuel Cell) and MGT (Micro-Gas-Turbine). Different typologies of hybrid systems are ...This work concerns the study of HSs (Hybrid Systems) that are made up of the integration of M-HTFC (Medium and High Temperature Fuel Cell) and MGT (Micro-Gas-Turbine). Different typologies of hybrid systems are taken into account, which differ from each other in their plant layouts. The plants are considered in cogenerative arrangement. The aim of this study is to carry out an energetic analysis of the HS considered to obtain an analytical expression to depict the system operating in cogenerative arrangement. An energetic comparison among the systems analyzed based on some indexes is effected, which allows an evaluation of the plants performances in cogenerative arrangement. An energetic analysis is carried out, which is based on a "black box" depiction of the plant in which the components and the mutual interactions are highlighted. The fuel cell component of the plant is not analyzed as a black box, but each element that constitutes it, is elaborated as a subsystem.展开更多
The Shanghai Meishan Iron and Steel Co., Ltd. has a large supply of coke oven gas (COG) and has the potential to develop and apply the spraying of COG on the surface of a sinter bed. The effects of the amount of COG, ...The Shanghai Meishan Iron and Steel Co., Ltd. has a large supply of coke oven gas (COG) and has the potential to develop and apply the spraying of COG on the surface of a sinter bed. The effects of the amount of COG, the spraying time, and the spraying distribution with the process on the quantity and quality indexes of sinter were investigated in the laboratory experi-ments. The results showed that the COG spraying can improve the sinter indexes to a large extent if appropriate parameters were used. It was found that an appropriate amount of COG, a relatively long spraying time, and a decreasing distribution of the COG amount with the spraying process all help to obtain a better performance for sinter quantity and quality indexes. When the COG spraying was applied to the No. 3 sintering machine, the sinter tumbler index increased by 0.45%, the overall finished product rate increased by 0.72%, the solid fuel consumption decreased by 4.06kg/t, the reducibility increased by 3.89%, and the cost of iron decreased by 5.29 CNY/t, and the CO2, SO2 and Nox emissions also decreased, thus proving the feasibility of this technology. Therefore, COG spraying provides a new way to improve sinter and also decrease the energy consumption and pollution.展开更多
This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin follo...This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin followed by dissolution of lignin using a recyclable ethanol/acetic acid/water solvent system.Then,pure cellulose was produced using a four-step refining process,including chelating,O_(3),H_(2)O_(2),and xylanase treatments.Finally,MCC was obtained through hydrolysis,drying,and mechanical treatments.The effects of acetic acid,O_(3),H_(2)O_(2),NaOH,pretreatment time,and temperature on the properties of wheat straw cellulose(including Kappa number,yield,α-cellulose content,crystallinity,KMnO4 value,degree of polymerization(DP),and brightness)were investigated.The results showed that the addition of acetic acid enhanced lignin removal and hemicellulose degradation,improving the purity of the raw cellulose.The optimized acetic acid dosage in the wheat straw thermal decomposition step was 2%(w/w).The optimized O_(3)dosage was 1.2%(w/w).The optimized conditions for H_(2)O_(2)treatment were found to be 3%(w/w)H_(2)O_(2)and 1.8%(w/w)NaOH at 70°C for 120 min.The KMnO4 value was 2.0,brightness was 84.1%ISO,the viscosity was 934 mL/g,and the DP was 626 for refined cellulose.Xylanase effectively improved theα-cellulose content of wheat straw cellulose.With an optimized xylanase dosage of 1.5 IU/g,theα-cellulose content was 94.7%,the brightness was 85.6%ISO,and the DP was 615 for wheat straw cellulose.展开更多
基金supported by the technology development fund of China Petroleum & Chemical Corporation (Sinopec 312016 and 314054)
文摘An attempt was made to extend mild combustion to forward flow furnace, such as the refinery and petrochemical tube furnace. Three dimensional numerical simulation was carried out to study the performance of this furnace. The Eddy Dissipation Concept(EDC) model coupled with the reaction mechanism DRM-19 was used. The prediction showed a good agreement with the measurement. The effect of air nozzle circle(D), air nozzle diameter(d), air nozzle number(N), and air preheating temperature(Tair) on the flow, temperature and species fields, and the CO and NO emissions was investigated. The results indicate that there are four zones in the furnace, viz.: a central jet zone, an ignition zone, a combustion reaction zone, and a flue gas zone, according to the distribution profiles of H_2 CO and OH. The central jet entrains more flue gas in the furnace upstream with an increasing D while the effect of D is negligible in the downstream. The air jet momentum increases with a decreasing d or an increasing Tair, and entrains more flue gas. The effect of N is mainly identified near the burner exit. More heat is absorbed in the radiant section and less heat is discharged to the atmosphere with a decreasing d and an increasing N as evidenced by the flue gas temperature. The CO and NO emissions are less than 50 μL/L and 10 μL/L, respectively, in most of conditions.
文摘This work concerns the study of HSs (Hybrid Systems) that are made up of the integration of M-HTFC (Medium and High Temperature Fuel Cell) and MGT (Micro-Gas-Turbine). Different typologies of hybrid systems are taken into account, which differ from each other in their plant layouts. The plants are considered in cogenerative arrangement. The aim of this study is to carry out an energetic analysis of the HS considered to obtain an analytical expression to depict the system operating in cogenerative arrangement. An energetic comparison among the systems analyzed based on some indexes is effected, which allows an evaluation of the plants performances in cogenerative arrangement. An energetic analysis is carried out, which is based on a "black box" depiction of the plant in which the components and the mutual interactions are highlighted. The fuel cell component of the plant is not analyzed as a black box, but each element that constitutes it, is elaborated as a subsystem.
基金This work was supported by the National Natural Science Foundation of China(Grant Number 51804027)Fundamental Research Funds for the Central Universities(FRF-IC-18-010).
文摘The Shanghai Meishan Iron and Steel Co., Ltd. has a large supply of coke oven gas (COG) and has the potential to develop and apply the spraying of COG on the surface of a sinter bed. The effects of the amount of COG, the spraying time, and the spraying distribution with the process on the quantity and quality indexes of sinter were investigated in the laboratory experi-ments. The results showed that the COG spraying can improve the sinter indexes to a large extent if appropriate parameters were used. It was found that an appropriate amount of COG, a relatively long spraying time, and a decreasing distribution of the COG amount with the spraying process all help to obtain a better performance for sinter quantity and quality indexes. When the COG spraying was applied to the No. 3 sintering machine, the sinter tumbler index increased by 0.45%, the overall finished product rate increased by 0.72%, the solid fuel consumption decreased by 4.06kg/t, the reducibility increased by 3.89%, and the cost of iron decreased by 5.29 CNY/t, and the CO2, SO2 and Nox emissions also decreased, thus proving the feasibility of this technology. Therefore, COG spraying provides a new way to improve sinter and also decrease the energy consumption and pollution.
基金the Doctoral Program of Higher Education Projects(for the priority development areas)by Ministry of Education of China(Grant No.20126125130001)State Key Laboratory of Pulp and Paper Engineering open foundation(Grant No.201505)the Doctoral Scientific Research Foundation(Grant No.BJ13-02)by Shaanxi University of Science and Technology.
文摘This study focused on the manufacture of microcrystalline cellulose(MCC)from wheat straw using environmentally-friendly solvents.Raw cellulose was separated from wheat straw after thermal decomposition of lignin followed by dissolution of lignin using a recyclable ethanol/acetic acid/water solvent system.Then,pure cellulose was produced using a four-step refining process,including chelating,O_(3),H_(2)O_(2),and xylanase treatments.Finally,MCC was obtained through hydrolysis,drying,and mechanical treatments.The effects of acetic acid,O_(3),H_(2)O_(2),NaOH,pretreatment time,and temperature on the properties of wheat straw cellulose(including Kappa number,yield,α-cellulose content,crystallinity,KMnO4 value,degree of polymerization(DP),and brightness)were investigated.The results showed that the addition of acetic acid enhanced lignin removal and hemicellulose degradation,improving the purity of the raw cellulose.The optimized acetic acid dosage in the wheat straw thermal decomposition step was 2%(w/w).The optimized O_(3)dosage was 1.2%(w/w).The optimized conditions for H_(2)O_(2)treatment were found to be 3%(w/w)H_(2)O_(2)and 1.8%(w/w)NaOH at 70°C for 120 min.The KMnO4 value was 2.0,brightness was 84.1%ISO,the viscosity was 934 mL/g,and the DP was 626 for refined cellulose.Xylanase effectively improved theα-cellulose content of wheat straw cellulose.With an optimized xylanase dosage of 1.5 IU/g,theα-cellulose content was 94.7%,the brightness was 85.6%ISO,and the DP was 615 for wheat straw cellulose.