Advances in low-temperature extraction of natural resources using liquefied dimethyl ether

This review summarized the valuable works on the extraction technologies using pure liquefied dimethyl ether(DME)as the organic solvent.DME is a colorless gas with a slight ether-like fragrance at room temperature and pressure.Due to some special properties,such as the strong ability for extracting organic compounds and water,high extraction rate,cheap price,low extraction temperature,and energy consumption,environmental friend-liness,safety,and good compressibility,the application of liquefied DME to the extraction process shows many advantages and has strong potential market competitiveness.On the other hand,the drawbacks of liquefied DME extraction technology were also revealed,mainly on fire hazards,solvent loss,and lack of large-scale application.Furthermore,the previous studies on the application of liquefied DME extraction technology were divided into three parts based on the extracts(water,lipid/oil,and specific ingredients)and listed one by one.The research of the liquefied DME extraction process is still in development.In the future,it is expected that this technology can be continuously improved and optimized in both lab and industrial scales,together with the extension of its application range to more various natural resources.

RNA Extraction from Herba Violae Roots with Low-temperature Sectioning Method

[ Objective ] This study aimed to investigate the optimal method for extracting RNA from roots of medicinal plant herba violae by comparing the effects of liquid nitrogen grinding method and low-temperature sectioning method on RNA extraction. [ Method] Roots of herba violae were respectively crushed by using liquid nitrogen grinding method and low-temperature sectioning method to extract RNA. The extraction effects of these two methods were compared based on detec- tion of RNA concentration, purity and integrity and amplification of GAPDH gene by RT-PCR. [Result] The concentration of RNA extracted by liquid nitrogen grinding method and low-temperature sectioning method was 1.21 and 3.57 p^g/~, respectively. Both RNA extracted by these two methods showed two distinct bands after agarose gel electrophoresis. The ratio of brightness of the 28S rRNA to the 18S rRNA bands was greater than 1. PCR amplification showed that the length of GAPDH gene was about 230 bp, which was consistent with the expected result. [ Conclusion ] The experimental results indicated that using low-tempera ture sectioning method to crush the roots of herba violae can meet the needs of most molecular biological experiments including gene cloning and expression analysis, which is an effective and simple method for extracting RNA from plant roots.

Effect of Temperature on Phase and Alumina Extraction Efficiency of the Product from Sintering Coal Fly Ash with Ammonium Sulfate

A new developed technology for extracting alumina from coal fly ash was studied in this paper. In this technology, coal fly ash is first sintered with ammonium sulfate, forming ammonium aluminum sulfate in the resultant product, where alumina can be easily leached without using any strong acid or alkali. The products obtained under different sintering conditions were characterized by X-ray diffractometry. Alumina extraction efficiency of these products was also investigated. The results show that the sintering temperature and time substantially influence the phase composition and alumina extraction efficiency of sintered products, while the heating rate has little influence. The optimal sintering condition is 400 °C for 3 h in air with a heating rate of 6 °C·min-1.Under the optimal sintering condition, the alumina extraction efficiency from as-sintered coal fly ash can reach 85% or more.

The extraction of potassium from K-feldspar ore by low temperature molten salt method

The low temperature molten salt method was used to extract potassium from K-feldspar ore, and some related factors including mass ratio between NaNO_3, NaOH, H_2O and K-feldspar ore, particle size of K-feldspar ore,reaction temperature and time were investigated, respectively. In addition, the optimum condition for this method was determined by a series of condition experiments. What was more, the K-feldspar ore and the leach residue after reaction based on the above optimum condition were analyzed by XRD, SEM and EDS,separately. The results of which indicated that the mechanism of extraction of potassium for this method was according to the ion exchange reaction between sodium ion and potassium ion, and the extraction ratio of potassium had an obvious improvement than that of traditional methods, which could reach up to 96.25%.Therefore, this method can be a feasible solution to extract potassium from K-feldspar ore for its low energy consumption and high efficiency.

Cu(II) Extraction in Ionic Liquids and Chlorinated Solvents: Temperature Effect

Room temperature ionic liquids have been currently used in liquid/liquid extraction processes in order to substitute conventional organic solvents. In this paper, a series of chlorinated solvents and 1-alkyl-3-me- thylimidazolium-based ionic liquids were selected to study the extraction efficiency of a lipophilic polya- mine 1,1,7,7-tetraethyl-4-tetradecyldiethylenetriamine (TE14DT) towards the model ion Cu(II) in such dif-ferent media. The effect of temperature on the extraction efficiency was also investigated. The metal ion par-tition was found to be strongly dependent on both the nature of the solvent and on the working temperature. The viscosity of ionic liquids and the water content in ionic liquid were found to affect the extraction effi-ciency of TE14DT. The chemical nature of the cation of ionic liquids, and in particular the alkyl chain length on imidazolium ring, also seemed to be important in determining the efficiency of the extraction process. Finally, preliminary experiments on back-extraction of Cu(II) ions from ionic liquid also revealed interesting hints to the development of a continuous transport process.

The Influence of Drying Temperature and Extraction Methods on a-Mangostin in Mangosteen Pericarp

The effects of drying temperature and extraction methods on α-mangostin content in mangosteen pericarp （Garcinia mangostana L.） powder were investigated. In the first part of experiment suitable drying temperature for retention α-mangostin content was determined. Three levels of drying temperatures （55, 65 and 75 ℃） were used in this study. The drying rates were increased with drying temperature. Room temperature extraction method was performed to investigate the effect of drying temperature on retention α-mangostin content in mangosteen pericarp. The α-mangostin content extracted at three different drying temperatures （55, 65 and 75 ℃） was 35.98 ± 0.49%, 40.32 ± 0.24%, and 37.79±0.34% w/w, respectively. The results showed that the suitable temperature for drying mangosteen pericarp was 65 ℃ that gave the highest of α-mangostin content. The second part of experiment was the comparison between extraction methods, such as shaking water bath extraction （SWE）, soxhlet extraction （SE） and microwave-assisted extraction （MAE）. The results show that MAE gave the highest extraction rate and α-mangostin content as compare to SWE and SE. The α-mangostin content extraction from SWE, SE and MAE are 45.83 ± 0.02, 34.82± 0.17 and 49.79 ± 0.15% w/w of crude extract, respectively.

Effect of Extractant and Temperature on Phenolic Compounds and Antioxidant Activity of Selected Spices

Ten spices marketed in Jordan, (Syzygium aromaticum L., Coriadrum sativum L., Cuminum cyminum L.,Zingiber officinale Rosc., Elettaria cardamomum, Curcuma longa, Rhus coriaria L., Cinnamomum zeylanicum Blume, Foeniculum vulgare Mill and Laurus nobilis L.) were investigated for their phenolic compounds and antioxidant activity. The influence of different extractants (methanol, ethanol and acetone) at different temperatures (20, 40 and 60°C) was examined. Results showed at 60°C using methanol, cloves had the highest level of total phenolics (781.0 mg GAE/100g using acetone). At 40°C, sumac and cloves had the highest amounts of total phenolics (343.9 mg/100g and 342 mg GAE/100g respectively). At 20°C, cloves continued to have the highest amount of total phenolics (394.7 mg/100g) using methanol as extactant. Ethanol as extractant, cloves gave the highest level of phenolics (548 mg GAE/100g, 493.4 mg GAE/100g) at 60°C, while at 20°C cloves and sumac showed the highest concentrations of phenolics (350.8 mg GAE/100g and 342.8 mg GAE/100g respectively). Acetone as extractant at 60°C, cloves had the highest levels of phenolics (781 mg GAE/100g) while at 40°C and at 20°C, sumac contributed the highest levels of total phenolics (583.2 mg GAE/100g and 754.5 mg GAE/100g). The total phenolics concentration varied significantly among the spices. Their values varied according to the extractant and extracting temperature. IC50 (radical scavenging activity) reflecting the antioxidant activity was presented. Results showed that cloves had the highest antioxidant activity while the cinnamon, turmeric and sumac had a appreciable level of antioxidant activity. Green cardamom and coriander had the lowest antioxidant activity. Antioxidant activity was positively correlated with total phenolic compounds content of the investigated spices.

Land-Cover Classification and its Impact on Peshawar’s Land Surface Temperature Using Remote Sensing

Spatial and temporal informationon urban infrastructure is essential and requires various land-cover/land-use planning and management applications.Besides,a change in infrastructure has a direct impact on other land-cover and climatic conditions.This study assessed changes in the rate and spatial distribution of Peshawar district’s infrastructure and its effects on Land Surface Temperature(LST)during the years 1996 and 2019.For this purpose,firstly,satellite images of bands7 and 8 ETM+(Enhanced Thematic Mapper)plus and OLI(Operational Land Imager)of 30 m resolution were taken.Secondly,for classification and image processing,remote sensing(RS)applications ENVI(Environment for Visualising Images)and GIS(Geographic Information System)were used.Thirdly,for better visualization and more in-depth analysis of land sat images,pre-processing techniques were employed.For Land use and Land cover(LU/LC)four types of land cover areas were identified-vegetation area,water cover,urbanized area,and infertile land for the years under research.The composition of red,green,and near infra-red bands was used for supervised classification.Classified images were extracted for analyzing the relative infrastructure change.A comparative analysis for the classification of images is performed for SVM(Support Vector Machine)and ANN(Artificial Neural Network).Based on analyzing these images,the result shows the rise in the average temperature from 30.04℃ to 45.25℃.This only possible reason is the increase in the built-up area from 78.73 to 332.78 Area km^(2) from 1996 to 2019.It has also been witnessed that the city’s sides are hotter than the city’s center due to the barren land on the borders.

A Comparative Study on Hemp(Cannabis sativa)Essential Oil Extraction Using Traditional and Advanced Techniques

A comparative study of Cannabis sativa(Hemp)essential constituents obtained by using Supercritical Fluid Extraction(SCFE),Steam Distillation(SD)and Hydrodistillation(HD)is presented here.The optimized extraction temperatures were 130,110and 50℃for hydrodistillation,steam distillation and supercritical fluid extraction respectively.The essential oil of C.sativa was analyzed by using Gas chromatography mass spectrometry(GC-MS).A total of 33,30and 31components have been identified in HD,SD and SCFE respectively.Yield of essential oil using SCFE(0.039%)was more than HD(0.025%)and SD(0.035%)extraction respectively.The main component of sesquiterpenes obtained by hydrodistillation at 130℃with their percentages included caryophyllene(40.58%),trans-α-bergamotene(5.41%),humulene(10.97%),cis-β-farnesene(8.53%)and monoterpenes includedα-pinene(2.13%),d-limonene(6.46%),p-cymol(0.65%)and cineole(2.58%)respectively.The main component of sesquiterpenes obtained by SD steam distillation at110℃including caryophyllene(38.60%)trans-α-bergamotene(4.22%),humulene(10.26%),cis-β-farnesene(6.67%)and monoterpenes includedα-pinene(3.21%),d-limonene(7.07%),p-cymol(2.59%)and cineole(3.88%)whereas the more percentages of major components were obtained by SCFE at 50℃included caryophyllene(44.31%),trans-α-bergamotene(6.79%),humulene(11.97%)cis-β-farnesene(9.71%)and monoterpenes includedα-pinene(0.45%),d-limonene(2.13%)p-cymol(0.19%)and cineole(1.38%)respectively.We found yield/efficiency,chemical composition,quality of the essential oils by supercritical fluid extraction superior in terms of modern,green,saving energy and a rapid approach as compared to traditional techniques.

Extraction of Yttrium (Ⅲ) into [C_8 mim][PF_6] Containing Cyanex 923

The extraction of Yttrium (Ⅲ) into [Cnmim][PF6] (n= 4, 6, 8) containing Cyanex 923 was studied in this paper. The mechanism of this extraction was indicated to be cation exchange. In addition, the extraction process is an endothermic reaction. The RTILs with shorter alkyl chain behave higher extraction efficiency during the extraction, however, which has also more loss to aqueous phase since the cation exchange mechanism.

Low Cost Process for Phenolic Compounds Extraction from Cabernet Sauvignon Grapes (<i>Vitis vinifera</i>L. cv. Cabernet Sauvignon). Optimization by Response Surface Methodology

Phenolic compounds are naturally extracted molecules used nowadays for several industrial applications such as food preservatives and neutraciticals;thus industrial needs are in constant growth. Optimization of phenolic compounds (PC) and monomeric anthocyanins (MA) extraction from grape berries using response surface methodology was here achieved. Cabernet Sauvignon (CS) wine grapes (Vitis vinifera L. cv. Cabernet Sauvignon) are a rich source of anti-radical phe- nols, extractable as dietary supplements. However, efficiency of extraction strongly depends on specific experimental conditions. In this work, the comparison between two extraction mixtures, Acetone/Water (A/W) and Methanol/Water (M/W) and the effects of three critical variables—Extraction Time (between 8 and 88 h), Extraction Temperature (between 1?C and 35?C) and Solvent Content (between 63% and 97%)—on Phenolic Compounds Yield (PCY) and Monomeric Anthocyanins Yield (MAY) were studied using Response Surface Methodology (RSM). Process conditions maximizing the PCY were found to be 87% A/W solvent content, after 88 h incubation at 26?C, and those of the MAY were found to be 97% M/W solvent content, after 8 h incubation at 1?C. In addition, chromatographic profiles of extracts showed very different affinities of the phenolic compounds families to the experimental conditions employed. This process advantages are: low percentage of organic solvent used, high quality of extracted molecules thanks to low temperature treatment, very low energy consumption and low cost of needed machinery. At industrial scale, it may be used as promising technique for the extraction of bioactive compounds from plant or byproduct material such as from wine or grape juice industries.

Determination of 16 Species of OCPs in Water by Liquid-liquid Extraction-GC

[Objective] The research aimed to study the determination of 16 kinds of OCPs in water by liquid-liquid extraction -GC. [Method] The new method for determining 16 kinds of OCPs in water by liquid-liquid extraction -GC was established, and the influencing factors such as nitrogen pressure and water bath temperature were discussed. [ Result] Detection limit of the method was from 3.2 to 14.1 ng/L, the relative standard deviation was between 4.0% and 9.6%, and the average recovery ranged from 80.8% to 106.0%. By optimizing nitrogen pressure and water bath temperature in the sample pretreatment process, when nitrogen pressure was ＋0.087 kPa, and water bath temperature was ±36 ℃, recovery effect of this method was better. [ Conclusion] The determination method had accurate qualitative and quantitative results, and met detection requirement of 16 kinds of OCPs in water.

Antioxidants from Syrah Grapes (<i>Vitis vinifera L</i>.<i>cv</i>. <i>Syrah</i>). Extraction Process through Optimization by Response Surface Methodology

In this work, optimization of phenolic compounds (PC) and monomeric anthocyanins (MA) extraction from Syrah (Sy) wine grapes (Vitis vinifera L. cv. Syrah) using response surface methodology was conducted. The comparisons between two extraction mixtures, Acetone/Water (A/W) as well as Methanol/Water (M/W) and the effects of three critical variables, Extraction Time (between 8 and 88 h), Extraction Temperature (between 1℃ and 35℃) and Solvent Content (between 63% and 97%), on Phenolic Compounds Yield (PCY), Monomeric Anthocyanins Yield (MAY) and the DPPH Free Radical Inhibition Potential (DFRIP) were studied. The highest PCY was obtained in 63% A/W solvent content after 88 h incubation at 35℃. The highest MAY was acquired in 97% M/W solvent content after 8 h incubation at 17℃. The highest DFRIP of the extract was attained using 97% A/W solvent content after 16 h incubation at 35℃. The low cost of this process, on economic and environmental levels, could lead to interesting applications on an industrial scale. It could be used to obtain bioactive phytochemicals from direct material or byproducts for either therapeutic or nutritional purposes.

Survey of Intracellular Protein Extraction Methods from Pichia pastoris

The broken efficiency of cell wall and the release amount of Pichia pastoris intracellular protein under different cell breaking conditions were investigated in this paper. The results showed that broken efficiency using hot alkali combined with high-pressure homogenizing method was higher than that of enzyme hydrolysis, hot alkali treatment and high-pressure homogenation, respectively. Suspended medium had little effect on the broken efficiency of yeast cell, but had significant effect on the protein release yield. The results indicated that optimal condition for intracellular proteins extraction was 30% (wet weight, w/v) of yeast cells suspend in 50 mM phosphate buffer (pH 10.0), water bathed at 60?C for 2 hours, homogenized twice at 100 MPa pressure. The broken efficiency of Pichia pastoris cell could reach 87.6% and the protein yield was 35.48 g per 100 g cells.

Rail temperature variation under heavy haul operations

There currently does not exist in industry a reliable method for the detection of rail foot flaws.Like their head-based counterparts,foot flaws result in broken rail with potentially catastrophic consequences.A proposed area of research for the detection of these flaws is thermography,a non-contact method of measuring and analysing infrared emissions from an object under test.In industry,active excitation thermography is the most common,requiring an excitation source.This paper will present a temperature measurement system and a method of transient temperature extraction from the running rails for the effects of a passing train to evaluate heat transfer in the practical rail environment.The outcomes of these results will provide future direction in the development of a rail heat transfer model and determine if train passage provides enough active excitation for a thermography-based detection technique.

Separation and analysis of six fractions in low temperature coal tar by column chromatography

The low temperature coal tar(CT)is taken as the raw material,and the extraction and column chromatography are used for detailed and accurate characterization in this paper.The n-heptane soluble fraction(CT-HS)and insoluble fraction(CT-HI)were obtained by n-heptane Soxhlet extraction.The extraction rate of CT-HS reached 92.79%(mass),which indicated that there are few heavy compounds in it.Further,different solvents(methylbenzene,benzene,ethyl acetate,methylbenzene-ethanol)were used to elute CT-HS by chromatographic column to obtain five fractions(saturates,aromatics,heteroatoms,phenolics and resins,named CT-SA,CT-AR,CT-HE,CT-PH,CT-RE,respectively).The yields of CTSA,CT-AR,CT-HE,CT-PH,CT-RE are 42.12%,10.43%,2.19%,9.50%and 6.63%(mass),respectively.Gas chromatography-mass spectrometry analysis of eluting components show that alkanes are the main components in CT,followed by polycyclic aromatics,and the corresponding fractions are CT-SA and CT-AR,respectively.The relative content of aliphatics in CT-SA is 76.93%,and the relative content of aromatics in CT-AR is 75.05%.This separation technology effectively separates and enriches different components in CT,and the activation energy required for the pyrolysis process of a single eluting fraction is lower than that of CT,which is expected to provide an important reference for the separation,analysis and conversion of complex oil products such as coal-oil co-processing products,coal tar and other complex heavy carbon oil products.

An Idea of Extracting Fresh Water from the Atmosphere

Based on principles of vapor coagulation, a method of extracting fresh water from the atmosphere was put forward. Its principles are simple, and it is easy to make and install the equipment made cheaply. Moreover, there is no or much less energy consumed during the extraction process, so there is no environmental pollution. In a word, this method of extracting fresh water from the atmosphere is of great practical value.

城市浅层地热能开发地质环境问题研究

本文就浅层地热能开发利用过程中出现的生态环境和地质环境问题从客观因素和人为因素进行了详细的研究,借助土壤温度的测试和地层冷热平衡的监测,分析在地源热泵运行过程中造成的热污染、地下水位下降、地面沉降、地下水质恶化污染等问题。研究认为长期利用地源热泵开发利用系统,如设计不合理或地下水回灌率低,将破坏地层的冷热平衡。北方地区供暖期大于制冷期时,地层温度将逐年下降,N2O和CH4会集中释放,造成生物生长速度缓慢。地下水源热泵运行时,如地下水回灌困难,将导致地下水资源浪费、水位下降等生态环境问题以及路面塌陷、地面沉降等地质环境问题。供暖期、制冷期运行时间差别较大时,将导致地下水温度的变化,直接影响地下水中污染物的降解,间接影响地下水的水质。抽取、回灌地下水的过程会造成空气中的氧气随之溶解于水中,导致地下水质的变化。通过分析浅层地热能开发利用存在的突出问题和影响因素,可为其科学合理开发利用提供科学依据和技术支撑。

中深层水平连通地热井取热特性研究

高效取热技术是实现地热效益化开发的关键,建立了水平连通地热井数值仿真模型,计算了连续开采和间歇开采工况下的出口流体温度和换热量,研究了注入温度、注入流量、水平段长度对系统换热性能和岩层温度恢复能力的影响。结果表明,随着注入流量增加,地热井出口水温下降,但整个系统换热量提高;当注入温度较高时,可有效提高出口水温,但系统换热量降低较大;随着水平段长度增加,出口水温和换热量逐渐上升,换热性能提高;岩层温度恢复能力随注入流量和注入温度的增加而提高。综合考虑钻井成本、水泵功耗等因素,适量增加注入流量、降低注入温度、增加水平段长度能有效提高水平连通换热井的换热性能;虽然高的注入温度可提升岩层温度恢复能力,但不利于提高系统换热性能。

藏南高温地热水锂资源及其提取利用技术经济性探讨

这是一篇地球科学领域的论文。基于藏南高温地热水锂资源分布特征、成因机制、锂提取技术和经济性研究不足。本文通过板块构造分析、地热水组分测试、盐湖锂提取技术的适用性对比分析和建立地热水提取锂的经济评价模型,取得了如下成果:(1)藏南地热水锂主要分布在雅鲁藏布江深大断裂带两侧及其南部,富含锂花岗岩围岩淋滤和岩浆热液,为富锂地热水的形成提供了丰富的锂来源;(2)根据地热水锂具有低浓度和低镁/锂比的特性,选择了萃取法和沉淀法两种技术用来提取地热水锂元素;(3)以古堆地热田某地热井,其地热水锂浓度为23.5mg/L,采用萃取法工艺提锂为例,建立经济评价模型,采用现金流量法对经济性进行评估,经济评估结果表明,当碳酸锂价格不低于25万元/t情况下,地热水提锂项目具有良好的经济效益。