MgxNi1-xFe_(2)O_(4)(x=0,0.25,0.5,0.75,1)spinel ferrite material was analyzed to determine its magnetic properties and structure.X-ray diffraction(XRD),Mössbauer spectroscopy,and vibrating sample magnetometer(VSM)...MgxNi1-xFe_(2)O_(4)(x=0,0.25,0.5,0.75,1)spinel ferrite material was analyzed to determine its magnetic properties and structure.X-ray diffraction(XRD),Mössbauer spectroscopy,and vibrating sample magnetometer(VSM)characterization were performed on the samples prepared using the sol-gel method.The results from XRD confirmed the existence of the single-phase cubic spinel structures Fd3m,as well as the evolution of the crystalline size(D),the lattice parameter(a)and cell volume in compounds.The Mössbauer spectra showed the distribution of cations and changes in the magnetic properties of the sample.VSM measurement revealed that the samples were room-temperature ferromagnetic.Moreover,the saturation magnetization(Ms)of the samples changed with the Mg^(2+)ion content x,and a maximum occured at x=0.5.Doping with Mg^(2+)ions increased the transfer of Ni^(2+)ions to tetrahedral sites,thus increasing the magnetic moment difference between tetrahedral(A)and octahedral(B)sites.Specifically,doping NiFe_(2)O_(4) with Mg^(2+)ions can enhance its magnetic properties and enhance its saturation magnetization.展开更多
Determination of Fe^(2+)/Fe^(3+) ratios from metallogenic belts to explore controlling physical and chemical conditions of rock formation is of great significance.In order to explore magnetite Fe^(2+)/Fe^(3+) ratios o...Determination of Fe^(2+)/Fe^(3+) ratios from metallogenic belts to explore controlling physical and chemical conditions of rock formation is of great significance.In order to explore magnetite Fe^(2+)/Fe^(3+) ratios of the Qimantag metallogenic belt,part of the Eastern Kunlun orogenic belt in the northeastern margin of the Qinghai–Tibetan plateau,western Central Orogenic Belt of China,and overcome the limitation of the traditional electronic probe,five different measurement methods are proposed and their respective advantages and disadvantages evaluated,with the composition data of the magnetite obtained using electron probe microanalysis(EPMA).The direct oxygen measurement method has a significant impact on the determination results of FeO and Fe2O3,but the accuracy and uniformity of the results are low.The valence method(Flank method)based on the spectral intensity ratio of Lαto Lβfor iron is also unreliable for FeO and Fe_(2)O^(3) measurements because it is difficult to establish a relationship between Lβ/Lα,the spectral intensity ratio,and the Fe^(2+)/Fe^(3+) content ratio.In comparison,the charge difference method,the surplus-oxygen method and the Mössbauer spectrum method are still the most favorable.Mössbauer spectroscopy,with its isomer movement particularly sensitive to the oxidation state of iron,yields results closer to 0.5,which is relatively reliable.Earlier magnetite deposits are located in intrusions or contact zones and formed by magmatic fluids with high Fe2+/Fe3+ratios,whereas later magnetite deposits are farther away from intrusions and have low Fe^(2+)/Fe^(3+) ratios.The transformation mechanism of hematite and magnetite in the Qimantage metallogenic belt is also studied.No large volume changes,such as pore filling and shrinkage fracture,were detected in the metallogenic belt,and the transformation mechanism is more similar to a reoxidation and reduction mechanism.展开更多
利用透射电子显微镜、X射线衍射分析和穆斯堡尔谱分析技术研究了快凝Al Fe V Si Nd纳米晶薄带在疲劳过程中微结构变化 ,结果发现 :固溶元素自α Al晶内析出产生偏聚体 ,同时 ,X射线衍射谱出现一个额外的衍射峰。穆斯堡尔谱分析表明 :X...利用透射电子显微镜、X射线衍射分析和穆斯堡尔谱分析技术研究了快凝Al Fe V Si Nd纳米晶薄带在疲劳过程中微结构变化 ,结果发现 :固溶元素自α Al晶内析出产生偏聚体 ,同时 ,X射线衍射谱出现一个额外的衍射峰。穆斯堡尔谱分析表明 :X射线衍射谱中额外的衍射峰是由于疲劳过程中析出相 (Al8Fe4 Nd1 相 )展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No.11447231)the National Undergraduate Innovation and Entrepreneurship Training Program Support Projects of China+2 种基金the Natural Science Foundation of Hunan Province,China (Grant No.2020JJ4517)the Research Foundation of the Education Bureau of Hunan Province,China (Grant Nos.19A434,19A433,and 19C1621)the Opening Project of the Cooperative Innovation Center for Nuclear Fuel Cycle Technology and Equipment,University of South China (Grant Nos.2019KFY10 and 2019KFY09)。
文摘MgxNi1-xFe_(2)O_(4)(x=0,0.25,0.5,0.75,1)spinel ferrite material was analyzed to determine its magnetic properties and structure.X-ray diffraction(XRD),Mössbauer spectroscopy,and vibrating sample magnetometer(VSM)characterization were performed on the samples prepared using the sol-gel method.The results from XRD confirmed the existence of the single-phase cubic spinel structures Fd3m,as well as the evolution of the crystalline size(D),the lattice parameter(a)and cell volume in compounds.The Mössbauer spectra showed the distribution of cations and changes in the magnetic properties of the sample.VSM measurement revealed that the samples were room-temperature ferromagnetic.Moreover,the saturation magnetization(Ms)of the samples changed with the Mg^(2+)ion content x,and a maximum occured at x=0.5.Doping with Mg^(2+)ions increased the transfer of Ni^(2+)ions to tetrahedral sites,thus increasing the magnetic moment difference between tetrahedral(A)and octahedral(B)sites.Specifically,doping NiFe_(2)O_(4) with Mg^(2+)ions can enhance its magnetic properties and enhance its saturation magnetization.
基金obtained grants from the National Key Research and Development Program Project"Enhanced Bioremediation Technology and Equipment for Chromium Residuation Site",the Scientific Research Project of Hunan Provincial Department of Education(Grant No.19C1178)the Construction Program for the First-Class Disciplines(Geography)of Hunan Province,China.The anonymous reviewers and editors are thanked for constructive suggestions on improving the quality of the manuscript.
文摘Determination of Fe^(2+)/Fe^(3+) ratios from metallogenic belts to explore controlling physical and chemical conditions of rock formation is of great significance.In order to explore magnetite Fe^(2+)/Fe^(3+) ratios of the Qimantag metallogenic belt,part of the Eastern Kunlun orogenic belt in the northeastern margin of the Qinghai–Tibetan plateau,western Central Orogenic Belt of China,and overcome the limitation of the traditional electronic probe,five different measurement methods are proposed and their respective advantages and disadvantages evaluated,with the composition data of the magnetite obtained using electron probe microanalysis(EPMA).The direct oxygen measurement method has a significant impact on the determination results of FeO and Fe2O3,but the accuracy and uniformity of the results are low.The valence method(Flank method)based on the spectral intensity ratio of Lαto Lβfor iron is also unreliable for FeO and Fe_(2)O^(3) measurements because it is difficult to establish a relationship between Lβ/Lα,the spectral intensity ratio,and the Fe^(2+)/Fe^(3+) content ratio.In comparison,the charge difference method,the surplus-oxygen method and the Mössbauer spectrum method are still the most favorable.Mössbauer spectroscopy,with its isomer movement particularly sensitive to the oxidation state of iron,yields results closer to 0.5,which is relatively reliable.Earlier magnetite deposits are located in intrusions or contact zones and formed by magmatic fluids with high Fe2+/Fe3+ratios,whereas later magnetite deposits are farther away from intrusions and have low Fe^(2+)/Fe^(3+) ratios.The transformation mechanism of hematite and magnetite in the Qimantage metallogenic belt is also studied.No large volume changes,such as pore filling and shrinkage fracture,were detected in the metallogenic belt,and the transformation mechanism is more similar to a reoxidation and reduction mechanism.
文摘利用透射电子显微镜、X射线衍射分析和穆斯堡尔谱分析技术研究了快凝Al Fe V Si Nd纳米晶薄带在疲劳过程中微结构变化 ,结果发现 :固溶元素自α Al晶内析出产生偏聚体 ,同时 ,X射线衍射谱出现一个额外的衍射峰。穆斯堡尔谱分析表明 :X射线衍射谱中额外的衍射峰是由于疲劳过程中析出相 (Al8Fe4 Nd1 相 )
