The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF...The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF3(M=K,Cs)systems with molar ratios<1 were studied by in-situ Raman spectroscopy and molecular simulation.The results show that,in addition to AlF6^(3-),AlF5^(2-),and AlF4^-,the systems also contained Al2F-7^-.The characteristic bands in the Raman spectra belonging to Al2F-7^-were located at about 225 cm^-1,315 cm^-1,479 cm^-1,and 720 cm^-1.There are two possible structures of Al2F-7^-,which belong to the D3d and D3hpoint groups.Both of these structures are linear,and their single-point energies were found to differ by only 0.31 kcal/mol.展开更多
Understanding electronic structure is crucial to enhance the battery performance. Soft X-ray spectroscopy(SXS) is one of the most effective methods to provide direct probe of electronic states. Here, spectroscopic mea...Understanding electronic structure is crucial to enhance the battery performance. Soft X-ray spectroscopy(SXS) is one of the most effective methods to provide direct probe of electronic states. Here, spectroscopic measurements of transition metal 3 d and oxygen 2 p states are simply reviewed. Then, we mainly focus on the perspective of the development direction of modern SXS techniques. Although the true power of recently developed high efficiency mapping of resonant inelastic X-ray scattering(m RIXS) has been apparent for materials and chemistry studies, great challenges remain for mRIXS spectroscopic interpretation, and the understanding of the battery materials on novel redox activities remains elusive.展开更多
为研究新型闭口型压型钢板Econdek65-675组合板的破坏、挠曲、端部滑移特性及纵向承载能力,根据欧洲规范对4对18块组合板进行试验而获得相关系数m,k。制作的18个试件分别为115 mm、150 mm、200 mm 3种厚度3组,每组由3块短板与3块长板组...为研究新型闭口型压型钢板Econdek65-675组合板的破坏、挠曲、端部滑移特性及纵向承载能力,根据欧洲规范对4对18块组合板进行试验而获得相关系数m,k。制作的18个试件分别为115 mm、150 mm、200 mm 3种厚度3组,每组由3块短板与3块长板组成。试验结果发现3组试件都发生明显的端部滑移,呈现过早的纵向剪切破坏。将试验结果与欧洲规范和美国规范进行对比,结果表明欧洲规范更为准确。同时,给出了该种组合板纵向承载力计算公式及相关曲线,并与类似的其他组合板进行对比,结果显示Econdek65-675组合板具有较可靠的组合效率。展开更多
基金the National Natural Science Foundation of China(grant no.51474060)the National Key R&D Program of China(grant no.2017 YFC0805100)+1 种基金the National Natural Science Foundation of Liaoning Province(China)(grant no.2019-MS-129)the Fundamental Research Funds for the Central Universities of China(grant no.N162502002).
文摘The molten mixtures of alkali metal fluorides and aluminum fluoride are applied as aluminum electrolytes or brazing fluxes.However,the presence of Al2F-7^-in such molten systems is disputed.In the present study,MF-AlF3(M=K,Cs)systems with molar ratios<1 were studied by in-situ Raman spectroscopy and molecular simulation.The results show that,in addition to AlF6^(3-),AlF5^(2-),and AlF4^-,the systems also contained Al2F-7^-.The characteristic bands in the Raman spectra belonging to Al2F-7^-were located at about 225 cm^-1,315 cm^-1,479 cm^-1,and 720 cm^-1.There are two possible structures of Al2F-7^-,which belong to the D3d and D3hpoint groups.Both of these structures are linear,and their single-point energies were found to differ by only 0.31 kcal/mol.
文摘Understanding electronic structure is crucial to enhance the battery performance. Soft X-ray spectroscopy(SXS) is one of the most effective methods to provide direct probe of electronic states. Here, spectroscopic measurements of transition metal 3 d and oxygen 2 p states are simply reviewed. Then, we mainly focus on the perspective of the development direction of modern SXS techniques. Although the true power of recently developed high efficiency mapping of resonant inelastic X-ray scattering(m RIXS) has been apparent for materials and chemistry studies, great challenges remain for mRIXS spectroscopic interpretation, and the understanding of the battery materials on novel redox activities remains elusive.
文摘为研究新型闭口型压型钢板Econdek65-675组合板的破坏、挠曲、端部滑移特性及纵向承载能力,根据欧洲规范对4对18块组合板进行试验而获得相关系数m,k。制作的18个试件分别为115 mm、150 mm、200 mm 3种厚度3组,每组由3块短板与3块长板组成。试验结果发现3组试件都发生明显的端部滑移,呈现过早的纵向剪切破坏。将试验结果与欧洲规范和美国规范进行对比,结果表明欧洲规范更为准确。同时,给出了该种组合板纵向承载力计算公式及相关曲线,并与类似的其他组合板进行对比,结果显示Econdek65-675组合板具有较可靠的组合效率。
