Metal Sm has been widely used in making Al–Sm magnet alloy materials. Conventional distillation technology to produce Sm has the disadvantages of low productivity, high costs, and pollution generation. The objective ...Metal Sm has been widely used in making Al–Sm magnet alloy materials. Conventional distillation technology to produce Sm has the disadvantages of low productivity, high costs, and pollution generation. The objective of this study was to develop a molten salt electrolyte system to produce Al–Sm alloy directly, with focus on the electrical conductivity and optimal operating conditions to minimize the energy consumption. The continuously varying cell constant(CVCC) technique was used to measure the conductivity for the Na3AlF6–AlF3–LiF–MgF2–Al2O3–Sm2O3electrolysis medium in the temperature range from 905 to 1055°C. The temperature(t) and the addition of Al2O3(W(Al2O3)), Sm2O3(W(Sm2O3)), and a combination of Al2O3and Sm2O3into the basic fluoride system were examined with respect to their effects on the conductivity(κ) and activation energy. The experimental results showed that the molten electrolyte conductivity increases with increasing temperature(t) and decreases with the addition of Al2O3or Sm2O3or both. We concluded that the optimal operation conditions for Al–Sm intermediate alloy production in the Na3AlF6–AlF3–LiF–MgF2–Al2O3–Sm2O3system are W(Al2O3) + W(Sm2O3) = 3wt%, W(Al2O3):W(Sm2O3) = 7:3, and a temperature of 965 to 995°C, which results in satisfactory conductivity, low fluoride evaporation losses, and low energy consumption.展开更多
The preparation techniques of Mg-mischmetal intermediate alloy and the effects of the mischmetal addition ranging from 0.45% to 1.04% on the microstructure and properties of AZ91D alloy prepared by die casting were in...The preparation techniques of Mg-mischmetal intermediate alloy and the effects of the mischmetal addition ranging from 0.45% to 1.04% on the microstructure and properties of AZ91D alloy prepared by die casting were investigated. The Mg-MM intermediate alloy was prepared by permanent mold casting and then was extruded into the bars. The microstructure and analytical studies were carried out using optical microscopy and differential scanning calorimetry (DSC). Testing results shows the Mg-MM intermediate alloy could melt easily down at die casting temperature of 680 ℃ that was lower than the melting point of lanthanum (918 ℃) and that of cerium (798 ℃). This was propitious to protection the alloy from the oxidation at high temperatures. Then magnesium alloy test bars were produced under conventional cold chamber die casting condition with addition of different weight of the Mg-MM intermediate alloy. Observation and analysis indicated that the microstructures of the alloy were refined and RE containing Al phase was formed with increasing RE addition. The data obtained by tensile tests showed that alloying with mischmetal improved the tensile property of the AZ91D magnesium die casting alloy at ambient temperature.展开更多
The standard heat treatment of cast nickel base superalloy K403 is the solid solution treatment of 1210℃/4h, air cooling. It is very difficult to meet the requirements of Aviation Standard HB5155, in which the stre...The standard heat treatment of cast nickel base superalloy K403 is the solid solution treatment of 1210℃/4h, air cooling. It is very difficult to meet the requirements of Aviation Standard HB5155, in which the stress rupture life at 750℃ and 645MPa is longer than 50h. The results showed that the intermediate temperature stress rupture properties impaired by treatment of 1210℃/4h were due to precipitation of too small γ′ phase(<0.2μm) in grains and absence of the secondary carbides at grain boundaries. Microstructure containing the intergranular M6C carbides with envelope of γ′ and the residual coarse γ′ was obtained by means of 1180℃/4h treatment, therefore the stress rupture life was obviously increased to meet the demand of HB5155. The effect of γ′ size was also discussed from the view point of deformation mechanism in this paper.展开更多
A TTT diagram for th ie precipitation formed at some intermediate temperatures through cooling from high lemperalure parenl phase in a Cu-27 27Zn-3.73Al allay is established by means of dilatormetric measurement.The m...A TTT diagram for th ie precipitation formed at some intermediate temperatures through cooling from high lemperalure parenl phase in a Cu-27 27Zn-3.73Al allay is established by means of dilatormetric measurement.The morphology and structure of transformation products formed at some intermediate tem peratures isothermally through cooling from high temperature parent phase and up-quenching from DO_(3) parent phase are studied by metallographic.X-ray and electron microscopy analyses.Three regions in the two separate C curves are obtained according to different morphology of precipitate:rod-like a,plate-like bainite and a rods,and bainite plates.Prolonged aging makes bainite plate change gradually into a whose lattice parameters are no different from that of a formed equilibriumly from parent phase.The structure is almost orthorhombic long period structure for bainites formed from B_(2) and DO_(3) parent phase,but monoclinic for martensite from DO_(3).They correspond to the overlapping and separating of(1210)and(2010)diffraction peaks respectively,showing the lower degree of ordering in bainite.展开更多
For the purpose of improving the defects of the conventional friction welding method, the new friction welding technology has been examined. That is, the aim of the study is producing the joint of dissimilar materials...For the purpose of improving the defects of the conventional friction welding method, the new friction welding technology has been examined. That is, the aim of the study is producing the joint of dissimilar materials evaluated to be difficult for friction welding and non-round shape joints. In this process, after the intermediate material generates the independent friction heat on every side of the specimens, it is removed instantaneously and upset process begins to weld the specimens for a joint. In this study, similar joint of A2017 aluminum alloy and one of S45C steel were examined. On the other hand, thermal elastic-plastic stress analysis by the finite element method was carried out using ANSYS mechanical.展开更多
铅铋快堆(lead-bismuth fast reactor,LFR)与超临界二氧化碳(supercritical CO_(2),S-CO_(2))循环耦合系统是提升核能利用效率,优化核能应用现状的突破性技术。为了准确把握该系统中耦合换热这一关键问题的发展动态与现状,从中间换热器...铅铋快堆(lead-bismuth fast reactor,LFR)与超临界二氧化碳(supercritical CO_(2),S-CO_(2))循环耦合系统是提升核能利用效率,优化核能应用现状的突破性技术。为了准确把握该系统中耦合换热这一关键问题的发展动态与现状,从中间换热器技术开发、印刷电路板式换热器(printed circuit board heat exchanger,PCHE)流道优化、液态铅铋合金(liquid lead bismuth eutectic,LBE)及S-CO_(2)流动传热机理研究、LBE及S-CO_(2)耦合对流换热机理研究等角度出发,全面归纳总结了相关的实验研究与数值模拟成果。研究结果表明,Z型PCHE加工难度适中,换热性能优秀,弯折处加入直道或弯弧可在传热速率略微下降的前提下大幅降低换热器内压降,明确该型换热器是目前主流选择,并给出了PCHE的结构优化设计思路;液态LBE流动传热实验研究存在边界条件范围窄的问题,对比已有的传热预测关联式,对棒束、圆管等不同条件给出相应的传热预测关联式;对比分析适用于液态LBE的数值模拟方法,给出了可靠的利用雷诺时均方法的湍流模型与湍流普朗特数模型,阐释了利用四方程模型数值模拟的原理与优势;系统总结了应用于PCHE中的S-CO_(2)传热关联式,LBE与S-CO_(2)耦合换热研究现状与存在的问题。目前LBE与S-CO_(2)直接耦合换热的研究成果较缺乏,仍无成熟结论明确哪种换热器结构最合适,哪种数值模型有最优的可靠性与最小的偏差值,仍需针对不同应用场景具体考虑。本文明晰了铅铋-超临界二氧化碳耦合换热应用研究的方向与困难所在,对其他类似的新型多工质耦合换热系统的开发也具有重要指导意义。展开更多
基金financially supported by the National Natural Science Foundation of China (Nos. 51564015 and 51674126)the Graduate Student Innovation Special Fund of Jiangxi Province (YC2015-B064)+2 种基金the Science and Technology Research Project of Jiangxi Department of Education (GJJ150664)the Outstanding Doctoral Dissertation Project Fund of JXUST (YB2016007)the Scientific Research Fund of JXUST (NSFJ2014-G09)
文摘Metal Sm has been widely used in making Al–Sm magnet alloy materials. Conventional distillation technology to produce Sm has the disadvantages of low productivity, high costs, and pollution generation. The objective of this study was to develop a molten salt electrolyte system to produce Al–Sm alloy directly, with focus on the electrical conductivity and optimal operating conditions to minimize the energy consumption. The continuously varying cell constant(CVCC) technique was used to measure the conductivity for the Na3AlF6–AlF3–LiF–MgF2–Al2O3–Sm2O3electrolysis medium in the temperature range from 905 to 1055°C. The temperature(t) and the addition of Al2O3(W(Al2O3)), Sm2O3(W(Sm2O3)), and a combination of Al2O3and Sm2O3into the basic fluoride system were examined with respect to their effects on the conductivity(κ) and activation energy. The experimental results showed that the molten electrolyte conductivity increases with increasing temperature(t) and decreases with the addition of Al2O3or Sm2O3or both. We concluded that the optimal operation conditions for Al–Sm intermediate alloy production in the Na3AlF6–AlF3–LiF–MgF2–Al2O3–Sm2O3system are W(Al2O3) + W(Sm2O3) = 3wt%, W(Al2O3):W(Sm2O3) = 7:3, and a temperature of 965 to 995°C, which results in satisfactory conductivity, low fluoride evaporation losses, and low energy consumption.
基金the National Key Technology R&D Program for the 11th Five-Year Plan(2006BAE04B01 ,2006BAE04B04) the National Basic Research Program ("973") of China (2007CB613705)
文摘The preparation techniques of Mg-mischmetal intermediate alloy and the effects of the mischmetal addition ranging from 0.45% to 1.04% on the microstructure and properties of AZ91D alloy prepared by die casting were investigated. The Mg-MM intermediate alloy was prepared by permanent mold casting and then was extruded into the bars. The microstructure and analytical studies were carried out using optical microscopy and differential scanning calorimetry (DSC). Testing results shows the Mg-MM intermediate alloy could melt easily down at die casting temperature of 680 ℃ that was lower than the melting point of lanthanum (918 ℃) and that of cerium (798 ℃). This was propitious to protection the alloy from the oxidation at high temperatures. Then magnesium alloy test bars were produced under conventional cold chamber die casting condition with addition of different weight of the Mg-MM intermediate alloy. Observation and analysis indicated that the microstructures of the alloy were refined and RE containing Al phase was formed with increasing RE addition. The data obtained by tensile tests showed that alloying with mischmetal improved the tensile property of the AZ91D magnesium die casting alloy at ambient temperature.
文摘The standard heat treatment of cast nickel base superalloy K403 is the solid solution treatment of 1210℃/4h, air cooling. It is very difficult to meet the requirements of Aviation Standard HB5155, in which the stress rupture life at 750℃ and 645MPa is longer than 50h. The results showed that the intermediate temperature stress rupture properties impaired by treatment of 1210℃/4h were due to precipitation of too small γ′ phase(<0.2μm) in grains and absence of the secondary carbides at grain boundaries. Microstructure containing the intergranular M6C carbides with envelope of γ′ and the residual coarse γ′ was obtained by means of 1180℃/4h treatment, therefore the stress rupture life was obviously increased to meet the demand of HB5155. The effect of γ′ size was also discussed from the view point of deformation mechanism in this paper.
基金supported by the National Natural Science Foundation
文摘A TTT diagram for th ie precipitation formed at some intermediate temperatures through cooling from high lemperalure parenl phase in a Cu-27 27Zn-3.73Al allay is established by means of dilatormetric measurement.The morphology and structure of transformation products formed at some intermediate tem peratures isothermally through cooling from high temperature parent phase and up-quenching from DO_(3) parent phase are studied by metallographic.X-ray and electron microscopy analyses.Three regions in the two separate C curves are obtained according to different morphology of precipitate:rod-like a,plate-like bainite and a rods,and bainite plates.Prolonged aging makes bainite plate change gradually into a whose lattice parameters are no different from that of a formed equilibriumly from parent phase.The structure is almost orthorhombic long period structure for bainites formed from B_(2) and DO_(3) parent phase,but monoclinic for martensite from DO_(3).They correspond to the overlapping and separating of(1210)and(2010)diffraction peaks respectively,showing the lower degree of ordering in bainite.
文摘For the purpose of improving the defects of the conventional friction welding method, the new friction welding technology has been examined. That is, the aim of the study is producing the joint of dissimilar materials evaluated to be difficult for friction welding and non-round shape joints. In this process, after the intermediate material generates the independent friction heat on every side of the specimens, it is removed instantaneously and upset process begins to weld the specimens for a joint. In this study, similar joint of A2017 aluminum alloy and one of S45C steel were examined. On the other hand, thermal elastic-plastic stress analysis by the finite element method was carried out using ANSYS mechanical.
