期刊文献+
共找到6篇文章
< 1 >
每页显示 20 50 100
Fixed-Bed Column Adsorption Modeling of MnO4- Ions from Acidic Aqueous Solutions on Activated Carbons Prepared with the Biomass
1
作者 Charly Mve Mfoumou Francis Ngoye +3 位作者 Pradel Tonda-Mikiela Mbouiti Lionel Berthy Bouassa Mougnala Spenseur Guy Raymond Feuya Tchouya 《Open Journal of Inorganic Chemistry》 CAS 2023年第2期25-42,共18页
Activated carbons calcined at 400˚C and 600˚C (AC-400 and AC-600), prepared using palm nuts, collected in the town of Franceville in Gabon, were used to study the dynamic adsorption of MnO<sub>4</sub>-<... Activated carbons calcined at 400˚C and 600˚C (AC-400 and AC-600), prepared using palm nuts, collected in the town of Franceville in Gabon, were used to study the dynamic adsorption of MnO<sub>4</sub>-</sup> ions in acidic media on fixed bed column and on the kinetic modeling of experimental data of breakthrough curves of  MnO<sub>4</sub>-</sup> ions obtained. Results on the adsorption of MnO<sub>4</sub>-</sup>  ions in fixed-bed dynamics obtained on AC-400 and AC-600 adsorbents beds indicated that the AC-400 bed appears to be the most efficient in removing MnO<sub>4</sub>-</sup>  ions in acidic media. Indeed, the adsorbed amounts, the adsorbed capacities at saturation and the elimination percentage of MnO<sub>4</sub>-</sup>  ions obtained with AC-400 (31.24 mg;52.06 mg·g<sup>-1</sup> and 41.65% respectively) were higher compared to those obtained with AC-600 (9.87 mg;16.45 mg·g<sup>-1</sup> and 17.79% respectively). The breakthrough curves kinetic modeling revealed that the Thomas model and the pseudo-first-order kinetic model were the most suitable models to describe the adsorption of MnO<sub>4</sub>-</sup>  ions on adsorbents studied in our experimental conditions. The results of the intraparticle diffusion model showed that intraparticle diffusion was involved in the adsorption mechanism of MnO<sub>4</sub>-</sup>  ions on investigated adsorbents and was not the limiting step and the only process controlling MnO<sub>4</sub>-</sup>  ions adsorption. In contrast to AC-400, the intraparticle diffusion on AC-600 bed plays an important role in the adsorption mechanism of MnO<sub>4</sub>-</sup>  ions. 展开更多
关键词 Acidic Media MnO4 style=margin-left:-6px >- BIOMASS activated carbon Dynamic Adsorption Kinetics Models
下载PDF
微粒子活性炭-丝裂霉素(CH-MMC)在直肠癌根治术中的导向性研究
2
作者 谢波 钱军 《山西医科大学学报》 CAS 2013年第4期301-303,共3页
目的探讨微粒子活性炭-丝裂霉素(CH-MMC)在直肠癌根治性手术中的应用。方法选取直肠癌患者60例,随机分为两组:标记组34例,术前1-7 d通过纤维结肠镜在肿瘤附近正常肠管黏膜下多点注射CH-MMC;对照组26例,未注射CH-MMC。所有患者均行直肠... 目的探讨微粒子活性炭-丝裂霉素(CH-MMC)在直肠癌根治性手术中的应用。方法选取直肠癌患者60例,随机分为两组:标记组34例,术前1-7 d通过纤维结肠镜在肿瘤附近正常肠管黏膜下多点注射CH-MMC;对照组26例,未注射CH-MMC。所有患者均行直肠癌根治性手术,术中常规清除各站淋巴结。比较两组病理标本所检出的淋巴结数量。结果标记组平均清除淋巴结(18.41±2.45)枚,明显高于对照组(15.12±1.47)枚(P<0.01)。标记组平均清扫≤5 mm淋巴结数目(12.65±1.63)枚,明显高于对照组(6.03±1.22)枚(P<0.01)。标记组19例淋巴结转移患者中平均清扫转移淋巴结(10.03±1.59)枚,明显高于对照组12例淋巴结转移患者中平均清扫转移淋巴结(5.93±1.06)枚。标记组黑染淋巴结中发生转移率高于未黑染淋巴结中的转移率(40.22%vs 19.77%,P<0.01)。结论术前多点注射微粒子活性炭-丝裂霉素(CH-MMC)在直肠癌手术中有一定的导向作用,提高了区域淋巴结的清除及检出率。 展开更多
关键词 活性炭-丝裂霉素 直肠癌 淋巴结
下载PDF
微粒子活性炭-丝裂霉素用于大肠癌淋巴结清除术的临床研究 被引量:2
3
作者 王佾 黄卫 宝荣 《中国药业》 CAS 2008年第9期54-55,共2页
目的探讨微粒子活性炭吸附丝裂霉素(CH-MMC)在大肠癌根治术中的应用。方法将83例大肠癌患者,随机分为两组,试验组(50例)术前经肠镜注射CH-MMC混悬液,对照组33例,两组均行大肠癌根治加淋巴结清扫术。结果大肠癌根治术中,试验组平均每例... 目的探讨微粒子活性炭吸附丝裂霉素(CH-MMC)在大肠癌根治术中的应用。方法将83例大肠癌患者,随机分为两组,试验组(50例)术前经肠镜注射CH-MMC混悬液,对照组33例,两组均行大肠癌根治加淋巴结清扫术。结果大肠癌根治术中,试验组平均每例清扫淋巴结(19±6)枚,明显高于对照组的(11±5)枚。结论阿霉素被活性炭吸附后癌周注射能靶向进入淋巴结,较有针对性地治疗大肠癌淋巴结转移,具有一定的临床应用价值。 展开更多
关键词 大肠癌 微粒子活性炭-丝裂霉素 临床研究
下载PDF
活性碳吸附丝裂霉素C腹腔化疗的临床实验研究 被引量:18
4
作者 梁寒 王殿昌 +4 位作者 孙慧 王晨 蒋会留 吴洁 李雯 《中国肿瘤临床》 CAS CSCD 北大核心 2000年第12期897-901,共5页
目的:通过动物实验及临床应用,证实活性碳吸附丝裂霉素C腹腔化疗能治疗和预防进展期胃癌术后腹腔复发,从而提高患者的生存率。方法:利用人胃癌裸鼠模型进行活性碳(CH)吸附MMC腹腔化疗的动物实验,共分4组,每组8只荷瘤裸... 目的:通过动物实验及临床应用,证实活性碳吸附丝裂霉素C腹腔化疗能治疗和预防进展期胃癌术后腹腔复发,从而提高患者的生存率。方法:利用人胃癌裸鼠模型进行活性碳(CH)吸附MMC腹腔化疗的动物实验,共分4组,每组8只荷瘤裸鼠。实验组腹腔给予CH-MMC,腹腔化疗组腹腔给予MMC,静脉化疗组经内眦静脉给予MMC,对照组腹腔注入等容量生理盐水。 展开更多
关键词 胃癌 腹腔化疗 活性碳 丝裂霉素C
下载PDF
Thermodynamic evaluation of reaction abilities of structural units in Fe-C binary melts based on atom-molecule coexistence theory
5
作者 Xue-min Yang Jin-yan Li +2 位作者 Dong-ping Duan Fang-jia Yan Jian Zhang 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2018年第1期37-56,共20页
The reaction abilities of structural units in Fe-C binary melts over a temperature range above the liquidus lines have been evaluated by a thermodynamic model for calculating the mass action concentrations Ni of struc... The reaction abilities of structural units in Fe-C binary melts over a temperature range above the liquidus lines have been evaluated by a thermodynamic model for calculating the mass action concentrations Ni of structural units in Fe-C binary melts based on the atom-molecule coexistence theory (AMCT), i.e., the AMCT-N/model, through comparing with the predicted activities aR.i of both C and Fe by 14 collected models from the literature at four temperatures of 1833, 1873, 1923, and 1973 K. Furthermore, the Raoultian activity coefficient γC0 of in infinitely dilute Fe-C binary melts and the standard molar Gibbs free energy change △solG%m,Cdis(1)→[C]W[C]=1.0 of dissolved liquid C for forming w[C] as 1.0 in Fe-C binary melts referred to 1 mass% of C as reference state have also been determined to be valid. The determined activity coefficient In γC of C and activity coefficient In TEe of Fe including temperature effect for Fe-C binary melts can be described by a quadratic polynomial function and a cubic polynomial function, respectively. 展开更多
关键词 Fe-C binary melt carbon activity Iron activity Thermodynamic evaluation Thermodynamic model Mass action concentration - Atom-molecule coexistence theory (AMCT)
原文传递
改性活性炭负载FeCl_3催化一锅法合成多芳基咪唑 被引量:5
6
作者 肖立伟 高红杰 +3 位作者 孔洁 刘光仙 李玲玲 段敬丹 《有机化学》 SCIE CAS CSCD 北大核心 2014年第12期2511-2516,共6页
制备了一种新型改性活性炭负载氯化铁催化剂(MAC-Fe Cl3),通过红外光谱及等离子体发射光谱进行了表征.在MAC-Fe Cl3催化下,以乙酸铵为氮源,苯偶酰与芳醛以及伯胺作用,一锅法合成了一系列2,4,5-三芳基咪唑和1,2,4,5-四芳基咪唑.催化剂后... 制备了一种新型改性活性炭负载氯化铁催化剂(MAC-Fe Cl3),通过红外光谱及等离子体发射光谱进行了表征.在MAC-Fe Cl3催化下,以乙酸铵为氮源,苯偶酰与芳醛以及伯胺作用,一锅法合成了一系列2,4,5-三芳基咪唑和1,2,4,5-四芳基咪唑.催化剂后处理简单,重复使用4次仍保持较高活性.该方法收率较高、对环境友好、操作简单. 展开更多
关键词 改性活性炭负载FeCl3 2 4 5-三芳基咪唑 1 2 4 5-四芳基咪唑 一锅法 异相催化 modified active carbon surported FECL3
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部