Insights into enhanced electrochemiluminescence of a multiresonance thermally activated delayed fluorescence molecule

The electrochemiluminescence(ECL)behavior of a multiresonance thermally activated delayed fluorescence molecule has been investigated for the first time by means of ECL‐voltage curves,newly designed ECL‐time observatory,and ECL spectroscopy.The compound,Mes3DiKTa,shows complex ECL behavior,including a delayed onset time of 5 ms for ECL generation in both the annihilation pathway and the coreactant route,which we attribute to organic long‐persistent ECL(OLECL).Triplet‐triplet annihilation,thermally activated delayed fluorescence and uncompensated solution resistance cannot be ruled out as contributing mechanisms to the ECL.A very long ECL emission decay was attributed to OLECL as well.The absolute ECL efficiencies of Mes3DiKTa were enhanced and reached 0.0013%in annihilation route and 1.1%for the coreactant system,which are superior to those of most other organic ECL materials.It is plausible that ECL materials with comparable behavior as Mes3DiKTa are desirable in applications such as ECL sensing,imaging,and light‐emitting devices.

Stochastic Multiresonance for a Fractional Linear Oscillator with Quadratic Trichotomous Noise

The stochastic multiresonance behavior for a fractional linear oscillator with random system frequency is investigated. The fluctuation of the system frequency is a quadratic trichotomous noise, the memory kernel of the fractional oscillator is modeled as a Mittag Lemer function. Based on linear system theory, applying Laplace transform and the definition of fractional derivative, the expression of the system output amplitude （SPA） is obtained. Stochastic multiresonanee phenomenon is found on the curves of SPA versus the memory time and the memory exponent of the fractional oscillator, as well as versus the trichotomous noise amplitude. The SPA depends non-monotonically on the stationary probability of the trichotomous noise, on the viscous damping coefficient and system characteristic frequency of the oscillator, as well as on the driving frequency of external force.

Intensity Correlation Time of a Single-Mode Laser Driven by Two Coloured Noises with Coloured Cross-Correlation with Bias Signal Modulation

The intensity correlation time T is studied by employing a gain-noise model of a single-mode laser driven by coloured pump noise τ1 and coloured quantum noise τ2 with coloured cross-correlation τ3 with a bias signal modulation. By using the linear approximation method, we detect that a maximum （i.e. resonance） exists in the curves of the intensity correlation time T versus the noise intensities D and Q when the noise correlation coefficient A is positive; and a minimum （i.e. suppression） exists in the T - D and T - Q curves when A is negative. When A is zero, T increases monotonously with increase of D and decreases monotonically with increase of Q. Furthermore, the curve of T versus the pump noise self-correlation time τ1 is also studied. Our study shows that, no matter what the value of A is, there exist one maximum and one minimum in the T - τ1 curve.

3D printed labyrinth multiresonant composite metastructure for broadband and strong microwave absorption

Microwave absorbers(MAs)with broadband and strong microwave absorption capacities are urgently required to meet the demands of complex electromagnetic(EM)environments.Herein,a novel labyrinth multiresonant metastructure composed of a polyether-ether-ketone/flaky carbonyl iron(PEEK/CIP)magnetic composite was proposed and fabricated via 3D printing technology.A complex multiresonant cavity design was introduced,and the resonant loss area was significantly improved.Both broadband and high-efficiency microwave absorption performances were achieved.The multilayer labyrinth multiresonant metastructure was designed with gradient impedance.The effects of structural parameters on the absorbing properties were investigated and optimized.Experiments and simulations demonstrated the effectiveness of the design strategy.The designed metastructure with a 10 mm thickness exhibited a-10 dB absorption bandwidth at a frequency of 3.78–40 GHz and an absorption bandwidth below-15 dB at 7.5–36.5 GHz.Moreover,an excellent wide-angle absorption performance was observed for different polarization states,including transverse electric(TE)and transverse magnetic(TM)modes.The combination of a complex multiresonant metastructure design and 3D printing fabrication provides a facile route to considerably extend the absorption bandwidth and strength of electromagnetic absorbers.This work is expected to provide a promising strategy for further enhancing microwave absorption performance,and the designed metastructure possesses great application potential in stealth and electromagnetic compatibility technologies.

Regulation and Control of Electromagnetic Field in Radio-Frequency Circuits and Systems

Since the first demonstrations of radio-frequency(RF)circuits,the physics of the electromagnetic(EM)field and its regulation and control with codesigned circuits,have become essential competencies of RF circuit designers.Leveraging advanced regulation or control methods,numerous high-performance circuits have been developed at RF and millimeter-wave(mm-wave)frequencies.Three main methods of electromagnetic regulation have been widely utilized,namely,the separation of electric and magnetic coupling paths,the manipulation of electromagnetic energy through the coupling of multiple tanks or multiple resonators,and the regulation of electromagnetic fields in air cavities or meta-substrates.The separated coupling paths of electric and magnetic fields provide guidance for designing a high-performance filter topology with a quasielliptical response through additional zeros.The manipulation of the EM field through electrical and magnetic intercouplings of multitanks or multiresonators,such as are used in oscillators,power amplifiers(PAs),etc.,results in remarkable power efficiency,size reduction,and wide bandwidth.The regulation of electromagnetism through an air cavity,patterned substrate,or metasubstrate reduces dielectric losses and size,especially when using a substrate integrated suspended line(SISL)platform.Many excellent circuits have been reported based on SISL with low loss,high integration,and self-packaging.Here,we present state-of-the-art cases that demonstrate the benefits of EM field regulation and control.

Ultrawideband chromatic aberration-free meta-mirrors

Chromatic aberration-free meta-devices(e.g.,achromatic meta-devices and abnormal chromatic meta-devices)play an essential role in modern science and technology.However,current efforts suffer the issues of low efficiency,narrow operating band,and limited wavefront manipulation capability.We propose a general strategy to design chromatic aberration-free meta-devices with high-efficiency and ultrabroadband properties,which is realized by satisfying the key criteria of desirable phase dispersion and high reflection amplitudes at the target frequency interval.The phase dispersion is tuned successfully based on a multiresonant Lorentz model,and high reflection is guaranteed by the presence of the metallic ground.As proof of the concept,two microwave meta-devices are designed,fabricated,and experimentally characterized.An achromatic meta-mirror is proposed within 8 to 12 GHz,and another abnormal chromatic meta-mirror can tune the reflection angle as a linear function.Both meta-mirrors exhibit very high efficiencies(85%to 94%in the frequency band).Our findings open a door to realize chromatic aberration-free meta-devices with high efficiency and wideband properties and stimulate the realizations of chromatic aberration-free metadevices with other functionalities or working at higher frequency.