Impact Analysis of Microscopic Defect Types on the Macroscopic Crack Propagation in Sintered Silver Nanoparticles

Sintered silver nanoparticles(AgNPs)arewidely used in high-power electronics due to their exceptional properties.However,the material reliability is significantly affected by various microscopic defects.In this work,the three primary micro-defect types at potential stress concentrations in sintered AgNPs are identified,categorized,and quantified.Molecular dynamics(MD)simulations are employed to observe the failure evolution of different microscopic defects.The dominant mechanisms responsible for this evolution are dislocation nucleation and dislocation motion.At the same time,this paper clarifies the quantitative relationship between the tensile strain amount and the failure mechanism transitions of the three defect types by defining key strain points.The impact of defect types on the failure process is also discussed.Furthermore,traction-separation curves extracted from microscopic defect evolutions serve as a bridge to connect the macro-scale model.The validity of the crack propagation model is confirmed through tensile tests.Finally,we thoroughly analyze how micro-defect types influence macro-crack propagation and attempt to find supporting evidence from the MD model.Our findings provide a multi-perspective reference for the reliability analysis of sintered AgNPs.

Cheesy material on macroscopic on-site evaluation after endoscopic ultrasound-guided fine-needle biopsy:Don't miss the tuberculosis

Endoscopic ultrasound-guided fine-needle biopsy(EUS-FNB)is an excellent investigation to diagnose pancreatic lesions and has shown high accuracy for its use in pathologic diagnosis.Recently,macroscopic on-site evaluation(MOSE)performed by an endoscopist was introduced as an alternative to rapid on-site cytologic evaluation to increase the diagnostic yield of EUS-FNB.The MOSE of the biopsy can estimate the adequacy of the sample directly by the macroscopic evaluation of the core tissue obtained from EUS-FNB.Isolated pancreatic tuberculosis is extremely rare and difficult to diagnose because of its non-specific signs and symptoms.Therefore,this challenging diagnosis is based on endoscopy,imaging,and the bacteriological and histological examination of tissue biopsies.This uncommon presentation of tuberculosis can be revealed as pancreatic mass mimicking cancer.EUS-FNB can be very useful in providing a valuable histopathological diagnosis.A calcified lesion with a cheesy core in MOSE must be suggestive of tuberculosis,leading to the request of the GeneXpert,which can detect Mycobacterium tuberculosis deoxyribonucleic acid and resistance to rifampicin.A decent diagnostic strategy is crucial to prevent unnecessary surgical resection and to supply conservative management with antitubercular therapy.

Study of macroscopic fundamental diagram on Shanghai urban expressway network in China

The macroscopic fundamental diagram（ MFD） is studied to obtain the aggregate behavior of traffic in cities. This paper investigates the existence and the characteristics of different types of daily MFD for the Shanghai urban expressway network. The existence of MFD in the Shanghai urban expressway network is proved based on two weeks＇ data.Moreover, the hysteresis phenomena is present in most days and the network exhibits different hysteresis loops under different traffic situations. The relationship between the hysteresis phenomena and the inhomogeneity of traffic distribution is verified. The MFDs in the years of 2009 and 2012 are compared. The hysteresis loop still exists in 2012, which further verifies the existence of the hysteresis phenomenon. The direct relationship between the length of the hysteresis loop（ ΔO） and the congestion is proved based on sufficient data. The width of the hysteresis loop, i. e., the drop in network flow（ ΔQ） has no relationship with the congestion, and it varies from day to day under different traffic situations.

Formation law and criterion of nebulous macroscopic segregation in ZL205A alloy castings

The appearance of macroscopic segregation in ZL205A alloy castings bears a super resemblance to theappearance of shrinkage porosity, and the chemical composition of the segregation is Al2Cu whose microstructure isin the form of dentrite or skeleton crystal. According to the characteristic of nebulous segregation, the formationprocess could be divided into two steps by the eutectic temperature of Al2Cu. Then a criterion for each of the twosteps is brought forward on the basis of the shrinkage porosity criterion of low pressure casting.

Effect of electromagnetic stirring in mold on the macroscopic quality of high carbon steel billet

An industrial plant trial for optimizing the process parameters in a round billet continuous casting mold with electromagnetic stirring （M-EMS） was performed, in which the influences of stirring parameters with M-EMS on the solidification macrostructure of high carbon steel were investigated. The results show that the billet quality is not well controlled under the condition of working current and frequency with EMS, in which the subsurface crack of grade 1.0-2.0 ups to 38.09%, the central pipe of grade 1.0-1.5 reaches to 14.28%, and the central porosity of grade 1.5 is 14.29%. The parameters of current 260 A and frequency 8 Hz as the final optimum scheme has a remarkable effect for improving the macroscopic quality of billet, in which the subsurface crack, central pipe and skin blowhole are all disappeared, and the central porosity and carbon segregation are also well improved.

A Mini Review on Nanocarbon-Based 1D Macroscopic Fibers:Assembly Strategies and Mechanical Properties

Nanocarbon-based materials, such as carbon nanotubes(CNTs) and graphene have been attached much attention by scientific and industrial community. As two representative nanocarbon materials, one-dimensional CNTs and twodimensional graphene both possess remarkable mechanical properties. In the past years, a large amount of work have been done by using CNTs or graphene as building blocks for constructing novel, macroscopic, mechanically strong fibrous materials. In this review, we summarize the assembly approaches of CNT-based fibers and graphene-based fibers in chronological order, respectively. The mechanical performances of these fibrous materials are compared, and the critical influences on the mechanical properties are discussed. Personal perspectives on the fabrication methods of CNT-and graphene-based fibers are further presented.

Perimeter traffic control strategy based on macroscopic fundamental diagrams

A perimeter traffic signal control strategy is proposed based on the macroscopic fundamental diagram theory(MFD)to solve the signal control problem in oversaturated states.First,the MFD of a specific regional network can be derived using VSS IM simulation software.Secondly,the maximum number of cumulative vehicles that the network can accommodate is determined based on the MFD.Then,through monitoring the influx flow,the number of vehicles existing in and exiting from the network,a perimeter traffic control model is proposed to optimize the signal timing of the boundary intersections.Finally,a virtual network simulation model is established and three different kinds o f traffic demand are loaded into the network.Simulation results show that a fer the strategy implementation,the number o f vehicles accumulating in the network can be kept near the optimal value,while the number o f both entering and exiting vehicles increases significantly and the road network can be maintained at a large capacity.Simultaneously,the queue length at the approach of the border intersections is reasonably controlled and vehicles entering and exiting the network can maintain a more efficient and stable speed.The network performance indices such as the average traffic delay and average number of stops can be improved to a certain degree,thus verifying the effectiveness and feasibility of the perimeter control strategy.

Effect of inhibitors on macroscopical oxidation kinetics of calcium sulfite

In the presence of inhibitors, the macroscopical oxidation kinetics of calcium sulfite, the main byproduct in wet limestone scrubbing, was studied for the first time by adding different inhibitors and varying pH, concentration of calcium sulfite, oxygen partial pressure, concentration of inhibitors and temperature. The mathematical model about the general oxidation reaction was established, which was controlled by three steps involving dissolution of calcium sulfite, mass transfer of oxygen and chemical reaction in the solution. It was concluded that the general reaction was controlled by mass transfer of oxygen under uncatalyzed conditions, while it was controlled by dissolution of calcium sulfite after adding three kinds of inhibitors. Thus, the theory was provided for investigating the mechanism and oxidation kinetics of sulfite. The beneficial references were also supplied for design of oxidation technics in the wet limestone scrubbing.

NON-LOCAL MODELING ON MACROSCOPIC DOMAIN PATTERNS IN PHASE TRANSFORMATION OF NiTi TUBES

Recent experiments revealed many new phenomena of the macroscopic domain patterns in the stress-induced phase transformation of a superelastic polycrystalline NiTi tube during tensile loading. The new phenomena include deformation instability with the formation of a helical domain, domain topology transition from helix to cylinder, domain-front branching and loading-path dependence of domain patterns. In this paper, we model the polycrystal as an elastic continuum with nonconvex strain energy and adopt the non-local strain gradient energy to account for the energy of the diffusive domain front. We simulate the equilibrium domain patterns and their evolution in the tubes under tensile loading by a non-local Finite Element Method （FEM）. It is revealed that the observed loading-path dependence and topology transition of do- main patterns are due to the thermodynamic metastability of the tube system. The computation also shows that the tube-wall thickness has a significant effect on the domain patterns： with fixed material properties and interfacial energy density, a large tube-wall thickness leads to a long and slim helical domain and a severe branching of the cylindrical-domain front.

Review to better understand the macroscopic subtypes and histogenesis of intrahepatic cholangiocarcinoma

Intrahepatic cholangiocarcinoma is macroscopically classified into three subtypes, mass-forming-type, periductal infiltrating-type, and intraductal growth-type. Each subtype should be preoperatively differentiated to perform the valid surgical resection. Recent researches have revealed the clinical, radiologic, pathobiological characteristics of each subtype. We reviewed recently published studies covering various aspects of intrahepatic cholangiocarcinoma(ICC), focusing especially on the macroscopic subtypes and stem cell features to better understand the pathophysiology of ICC and to establish the valid therapeutic strategy.

Macroscopic appearance of TypeⅣand giant Type Ⅲ is a high risk for a poor prognosis in pathological stage Ⅱ/Ⅲ advanced gastric cancer with postoperative adjuvant chemotherapy

AIM To evaluate whether a high risk macroscopic appearance(Type Ⅳ and giant Type Ⅲ) is associated with a dismal prognosis after curative surgery, because its prognostic relevance remains elusive in pathological stage Ⅱ/Ⅲ(p Stage Ⅱ/Ⅲ) gastric cancer.METHODS One hundred and seventy-two advanced gastric cancer(defined as pT2 or beyond) patients with p Stage Ⅱ/Ⅲ who underwent curative surgery plus adjuvant S1 chemotherapy were evaluated, and the prognostic relevance of a high-risk macroscopic appearance was examined. RESULTS Advanced gastric cancers with a high-risk macroscopic appearance were retrospectively identified by preoperative recorded images. A high-risk macroscopic appearance showed a significantly worse relapse free survival(RFS)(35.7%) and overall survival(OS)(34%) than an average risk appearance(P = 0.0003 and P < 0.0001, respectively). A high-risk macroscopic appearance was significantly associated with the 13^(th) Japanese Gastric Cancer Association(JGCA) pT(P = 0.01), but not with the 13^(th) JGCA pN. On univariate analysis for RFS and OS, prognostic factors included 13^(th) JGCA p Stage(P < 0.0001)and other clinicopathological factors including macroscopic appearance. A multivariate Cox proportional hazards model for univariate prognostic factors identified highrisk macroscopic appearance(P = 0.036, HR = 2.29 for RFS and P = 0.021, HR = 2.74 for OS) as an independent prognostic indicator. CONCLUSION A high-risk macroscopic appearance was associated with a poor prognosis, and it could be a prognostic factor independent of 13^(th) JGCA stage in p Stage Ⅱ/Ⅲ advanced gastric cancer.

Evolution and distribution of macroscopic gas channels in an overburden strata

The evolution of gas bearing channels in the roof,and their spatial distribution,was studied.A complete consideration of gas flow changes through the stress-strain changes in the roof near a working face is made.The theoretical abutment pressure distribution using displacement monitors and borehole visual recording instruments allow a theoretical analysis.Field test research determined the conditions for formation of macroscopic gas channels.These appear along the working face roof,normally distributed to it.These results show that the coal rock stratification becomes a macroscopic gas channel boundary if its deformation is less than the lower layer,or greater than the layer above it.At the same time the stability is greater than the distance from the roof for hanging dew conditions.The working face advances and the roof gas channels experience a cycle of development.Microscopic channels dominate the initial stage then macroscopic gas channels form,develop,and close.The evolution of the macroscopic channels depends on the ratio between the distances from the new compaction area in the goaf to the initial stress area in front of the working face.The amount of daily advance of the face also affects channel development.The experimental observations in one mining area showed that the main gas channels are located about 2 and 6.2 m above the lower surface of the roof and that they have an evolution period 7 to 11 days long.

Macroscopic resonant tunneling in an rf-SQUID flux qubit

We have observed the macroscopic resonant tunneling of magnetic flux between macroscopically distinct quantum states in a superconducting flux qubit. The dependences of the macroscopic resonant tunneling on the barrier height of the potential well, the flux bias and the initial state are investigated. Detailed measurements of the tunneling rate as a function of the flux bias reveal the feature of the quantum noise in the superconducting flux qubit.

A macroscopic traffic model based on weather conditions

A traffic model based on the road surface conditions during adverse weather is presented. The surface of a road is affected by snow, compacted snow, and ice, which affects the traffic behavior. In this paper, a new macroscopic traffic flow model based on the transition velocity distribution is proposed which characterizes traffic alignment under adverse weather conditions. Two examples are considered to illustrate the effect of the transition velocity behavior on traffic velocity and density. Simulation results are presented which show that this model provides a more accurate characterization of traffic flow behavior than the well known Payne-Whitham model. The proposed model can be used to reduce accidents and improve road safety during adverse weather conditions.

Fluorination Increases Hydrophobicity at the Macroscopic Level but not at the Microscopic Level

Hydrophobic interactions have been studied before in detail based on hydrophobic polymers,such as polystyrene(PS).Because fluorinated materials have relatively low surface energy,they often show both oleophobicity and hydrophobicity at the macroscopic level.However,it remains unknown how fluorination of hydrophobic polymer influences hydrophobicity at the microscopic level.We synthesized PS and fluorine-substituted PS(FPS)by employing the reversible addition-fragmentation chain transfer polymerization method.Contact angle measurements confirmed that FPS is more hydrophobic than PS at the macroscopic level due to the introduction of fluorine.However,single molecule force spectroscopy experiments showed that the forces required to unfold the PS and FPS nanoparticles in water are indistinguishable,indicating that the strength of the hydrophobic effect that drives the self-assembly of PS and FPS nanoparticles is the same at the microscopic level.The divergence of hydrophobic effect at the macroscopic and microscopic level may hint different underlying mechanisms:the hydrophobicity is dominated by the solvent hydration at the microscopic level and the surface-associated interaction at the macroscopic level.

MACROSCOPIC REGULARITY FOR THE BOLTZMANN EQUATION

The regularity of solutions to the Boltzmann equation is a fundamental problem in the kinetic theory. In this paper, the case with angular cut-off is investigated. It is shown that the macroscopic parts of solutions to the Boltzmann equation, i.e., the density, momentum and total energy are continuous functions of （x, t） in the region R3 × （0, ＋∞）. More precisely, these macroscopic quantities immediately become continuous in any positive time even though they are initially discontinuous and the discontinuities of solutions propagate only in the microscopic level. It should be noted that such kind of phenomenon can not hap- pen for the compressible Navier-Stokes equations in which the initial discontinuities of the density never vanish in any finite time, see [22]. This hints that the Boltzmann equation has better regularity effect in the macroscopic level than compressible Navier-Stokes equations.

Vehicle emissions calculation for urban roads based on the Macroscopic Fundamental Diagram method and real-time traffic information

Vehicle emissions calculation methods mostly use ownership information or annual road monitoring data as the activity level to calculate air pollutant emissions,but it is hard to reflect either the emissions intensity under different conditions or the spatiotemporal characteristics in various sections based on such approaches.This paper presents a method based on the Macroscopic Fundamental Diagram and real-time traffic data to calculate vehicle emissions,which could reflect the operation conditions and emission characteristics of vehicles.Following the‘Technical Guide for the Compiling of Road Vehicle Air Pollutant Emissions Inventories’,the emissions of three roads with different lane numbers and road grades in Beijing were estimated and verified using this method.Compared with monitoring data,the average deviations of the traffic flow on the Fifth Expressway,Jingfu National Highway,and Jingzhou Provincial Highway were?25.5%,?26.5%,and?13.4%,respectively,and the average deviations of nitrogen oxides emissions were?27.7%,?12.9%,and?12%,respectively.This method showed good application potentials to construct the emissions inventory applied to the block-scale model and analyze the spatiotemporal distribution characteristics of motor vehicle emissions in urban areas.

Macroscopic Young’s Elastic Modulus Model of Particle Packing Rock Layers

Based on the Hertzian granular contact mechanics model, the paper built up a Macroscopic Young’s Elastic Modulus of particle/granular packing rock layers, and built up a ties to connecting Young’s Elastic Modulus of sand particle in Meso and the Macroscopic Young’s Modulus of granular packing rock layers. The Macroscopic Young’s Modulus of granular packing rock layers is far less than the Young’s Modulus of sand particle. The Macroscopic Young’s Modulus of granular packing rock layers is proportioned to the powers of 1/3 of the vertical contact force of sand particles. The Macroscopic Young’s Modulus is inversely proportional to particle diameter. The paper calculated the vertical contact force of five types aligning mode of the particles. When equal stress, the increased of the coordination number lead to the decrease of the contact force fn, this lead to the coordination number is an inverse proportion to Macroscopic Young’s Modulus. But the larger coordination number change only means very little Macroscopic Young’s Modulus change.

Laser-Manipulating Macroscopic Quantum States of a Bose-Einstein Condensate Held in a Kronig-Penny Potential

We investigate the boundary vaJue problem （BVP） of a quasi-one-dimensional Gross-Pitaevskii equation with the Kronig-Penney potential （KPP） of period d, which governs a repulsive Bose-Einstein condensate. Under the zero and periodic boundary conditions, we show how to determine n exact stationary eigenstates {Rn} corresponding to different chemical potentials {μn} from the known solutions of the system. The n-th eigenstate P~ is the Jacobian elliptic function with period 2din for n = 1,2,…, and with zero points containing the potential barrier positions. So Rn is differentiable at any spatial point and R2 describes n complete wave-packets in each period of the KPP. It is revealed that one can use a laser pulse modeled by a 5 potential at site xi to manipulate the transitions from the states of {Rn} with zero Point x≠xi to the states of {Rn＇} with zero Point x= Xi. The results suggest an experimental scheme for applying BEC to test the BVP and to observe the macroscopic quantum transitions.

Electromagnetically induced transparency and quadripartite macroscopic entanglement generated in a ring cavity

We propose a feasible scheme to generate electromagnetically induced transparency（EIT） and quadripartite macroscopic entanglement in an optomechanical system with one fixed mirror and three movable perfectly reflecting mirrors.We explore the EIT phenomena in this optomechanical system.Results show the appearance of EIT dips in the output field.Moreover,we demonstrate how steady-state quadripartite entanglement can be generated via radiation pressure.We also quantify the bipartite entanglement in each field-mirror subsystem and in the mirror-mirror subsystem.Findings show that a high intensity of entanglement between two subsystems can be achieved.