Two-dimensional(2D)magnet/superconductor heterostructures can promote the design of artificial materials for exploring 2D physics and device applications by exotic proximity effects.However,plagued by the low Curie te...Two-dimensional(2D)magnet/superconductor heterostructures can promote the design of artificial materials for exploring 2D physics and device applications by exotic proximity effects.However,plagued by the low Curie temperature and instability in air,it is hard to realize practical applications for the reported layered magnetic materials at present.In this paper,we developed a space-confined chemical vapor deposition method to synthesize ultrathin air-stable ε-Fe_(2)O_(3) nanosheets with Curie temperature above 350 K.The ε-Fe_(2)O_(3)/NbSe_(2) heterojunction was constructed to study the magnetic proximity effect on the superconductivity of the NbSe_(2) multilayer.The electrical transport results show that the subtle proximity effect can modulate the interfacial spin–orbit interaction while undegrading the superconducting critical parameters.Our work paves the way to construct 2D heterojunctions with ultrathin nonlayered materials and layered van der Waals(vdW)materials for exploring new physical phenomena.展开更多
In this paper, the magnetocaloric in La0.5Sm0.2Sr0.3Mn1-xFexO3 compounds with x = 0 (LSSMO) and x = 0.05 (LSSMFO) were simulated using mean field model theory. A strong consistency was observed between the theoretical...In this paper, the magnetocaloric in La0.5Sm0.2Sr0.3Mn1-xFexO3 compounds with x = 0 (LSSMO) and x = 0.05 (LSSMFO) were simulated using mean field model theory. A strong consistency was observed between the theoretical and experimental curves of magnetizations and magnetic entropy changes, −ΔSM(T). Based on the mean-field generated −ΔSM(T), the substantial Temperature-averaged Entropy Change (TEC) values reinforce the appropriateness of these materials for use in magnetic refrigeration technology within TEC (10) values of 1 and 0.57 J∙kg−1∙K−1under 1 T applied magnetic field.展开更多
Soil enzyme activities as affected by applied magnetic field were studied with three main soils (brown soil, black soil and albic soil) collected from Northeast China. Appropriate intensities of magnetic field could o...Soil enzyme activities as affected by applied magnetic field were studied with three main soils (brown soil, black soil and albic soil) collected from Northeast China. Appropriate intensities of magnetic field could obviously enhance the activities of hydrogen peroxidases, invertases, amylases and phosphatases in the three soils, although the effect varied with types and water regimes of the soils. Increasing times of magnetic treatment could multiple its good effect on the activities of hydrogen peroxidases in soils.展开更多
A study on the effect of applied magnetic field was performed with six types of soils collected fromnortheastern China. Magnetic field was found to cause changes of soil physicc-chemical properties and soilenzyme acti...A study on the effect of applied magnetic field was performed with six types of soils collected fromnortheastern China. Magnetic field was found to cause changes of soil physicc-chemical properties and soilenzyme activities. An appropriate applied magnetic field could cut down soil zeta-potential, soil specificsurface, soil water potential and soil swelling capacity; raise the charge density on soil colloids and theactivities of invertase, hydrogen peroxidase and amylase in the soils; enhance soil aggregation and improvesoil structural status and soil water-releasing capability.展开更多
Based on the closed-orbit theory, the magnetic field effect in the photodetachment of negative ion in the electric field near a metal surface is studied for the first time. The results show that the magnetic field can...Based on the closed-orbit theory, the magnetic field effect in the photodetachment of negative ion in the electric field near a metal surface is studied for the first time. The results show that the magnetic field can produce a significant effect on the photodetachment of negative ion near a metal surface. Besides the closed orbits previously found by Duet al. for the H in the electric field near a metal surface (J. Phys. B 43 035002 (2010)), some additional closed orbits are produced due to the effect of magnetic field. For a given ion surface distance and an electric field strength, the cross section depends sensitively on the magnetic field strength. As the magnetic field strength is very small, its influence can be neglected. With the increase of the magnetic field strength, the number of the closed orbits increases greatly and the oscillation in the cross section becomes much more complex. Therefore we can control the photodetachment cross section of the negative ion by changing the magnetic field strength. We hope that our results may guide future experimental studies for the photodetachment process of negative ion in the presence of external fields and surfaces.展开更多
Considering the actual magnetic field configuration in a Hall thruster, the effect of magnetic mirror on the radial profile of near-wall conductivity (NWC) is studied in this paper. The plasma electron dynamic proce...Considering the actual magnetic field configuration in a Hall thruster, the effect of magnetic mirror on the radial profile of near-wall conductivity (NWC) is studied in this paper. The plasma electron dynamic process is described by the test particle method. The Monte Carlo scheme is used to solve this model. The radial profile of electron mobility is obtained and the role of magnetic mirror in NWC is analysed both theoretically and numerically. The numerical results show that the electron mobility peak due to NWC is inversely proportional to the magnetic mirror ratio and the asymmetry of electron mobility along the radial direction gets greater when the magnetic mirror is considered. This effect indicates that apart from the disparity in the magnetic field strength, the difference in the magnetic mirror ratio near the inner and outer walls would actually augment the asymmetry of the radial profile of NWC in Hall thrusters.展开更多
In this paper, we review the magnetic properties and magnetocaloric effects(MCE) of binary R–T(R = Pr, Gd, Tb,Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu) intermetallic compounds(including RGa series, RNi series, R_(12...In this paper, we review the magnetic properties and magnetocaloric effects(MCE) of binary R–T(R = Pr, Gd, Tb,Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu) intermetallic compounds(including RGa series, RNi series, R_(12)Co_7 series, R_3 Co series and RCu_2series), which have been investigated in detail in the past several years. The R–T compounds are studied by means of magnetic measurements, heat capacity measurements, magnetoresistance measurements and neutron powder diffraction measurements. The R–T compounds show complex magnetic transitions and interesting magnetic properties.The types of magnetic transitions are investigated and confirmed in detail by multiple approaches. Especially, most of the R–T compounds undergo more than one magnetic transition, which has significant impact on the magnetocaloric effect of R–T compounds. The MCE of R–T compounds are calculated by different ways and the special shapes of MCE peaks for different compounds are investigated and discussed in detail. To improve the MCE performance of R–T compounds,atoms with large spin(S) and atoms with large total angular momentum(J) are introduced to substitute the related rare earth atoms. With the atom substitution, the maximum of magnetic entropy change(?SM), refrigerant temperature width(Twidth)or refrigerant capacity(RC) is enlarged for some R–T compounds. In the low temperature range, binary R–T(R = Pr, Gd,Tb, Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu) intermetallic compounds(including RGa series, RNi series,R_(12)Co_7 series, R_3 Co series and RCu_2series) show excellent performance of MCE, indicating the potential application for gas liquefaction in the future.展开更多
Two-dimensional(2D)magnetic materials have aroused tremendous interest due to the 2D confinement of magnetism and potential applications in spintronic and valleytronic devices.However,most of the currently 2D magnetic...Two-dimensional(2D)magnetic materials have aroused tremendous interest due to the 2D confinement of magnetism and potential applications in spintronic and valleytronic devices.However,most of the currently 2D magnetic materials are achieved by the exfoliation from their bulks,of which the thickness and domain size are difficult to control,limiting the practical device applications.Here,we demonstrate the realization of thickness-tunable rhombohedral Cr_(2)Se_(3)nanosheets on different substrates via the chemical vapor deposition route.The magnetic transition temperature at about 75 K is observed.Furthermore,van der Waals heterostructures consisting of Cr_(2)Se_(3)nanosheets and monolayer WS2 are constructed.We observe the magnetic proximity effect in the heterostructures,which manifests the manipulation of the valley polarization in monolayer WS2.Our work contributes to the vapor growth and applications of 2D magnetic materials.展开更多
The magnetic field effects (MFEs) are studied on photocatalytic degradation of methylene blue (MB) solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and t...The magnetic field effects (MFEs) are studied on photocatalytic degradation of methylene blue (MB) solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and the dependence of the reaction rate on the initial dye concentration and settling duration is studied under UV light irradiation. It is found that the MFEs exist on the heterogeneous reaction systems for both ZnO and TiO2 powders and that the extraordinary phenomenon is reproducible. For ZnO powder, the results are in good agreement with the second-order reaction kinetics following the Langmuir-Hinshelwood (L-H) model, while the reaction for TiO2 follows first-order kinetics. It enhances the photodegradation for ZnO, while it reduces or enhances the reaction for TiO2 depending on the initial dye concentrations. The MFEs become small or negligible when the same photodecomposition experiment is carried out after settling the MB solution for more than three hours for both ZnO and TiO2. It is suggested that the key factors of MFEs on photocatalytic degradation is the condition of the MB solution as well as the characteristics of photocatalysts. The alteration of the MFEs ascribed to the solution condition caused by variation of the settling time.展开更多
Detecting stress concentration, especially critical stress state leading to structure damage or failure, is one of the most important tasks of equipment diagnosis. Metal magnetic memory technique needs further researc...Detecting stress concentration, especially critical stress state leading to structure damage or failure, is one of the most important tasks of equipment diagnosis. Metal magnetic memory technique needs further research to evaluate stress concentration quantitatively due to ambiguous physical mechanism, though it has potential to detect early defects in ferromagnetic materials. Mild Q235 steel defective specimens in demagnetization state were loaded in tension up to visible necking, with magnetic memory signals measurement made at increasing stress levels. Magnetic signals varied greatly under first several loadings and subsequently tended to stability in the elastic region, which showed that the magnetization always approaches the anhysteretic magnetization curve and was explained by the theory of magnetomechanical effect. In the plastic stage, an abnormal wave occurred in the stress concentration zone and its height value was sensitive to plastic deformation levels and dependent on the distance between the probe and defect, in accordance with the simulation results based on the magnetic dipole model. Different magnetic signal characteristics in the elastic-plastic region indicate that the magnetic memory technique can identify macroyielding and early damage, which is of profound significance for ensuring safe operation of equipment in service.展开更多
In this paper,a reflection magnet to be installed in the EAST neutral beam injection system is simulated and designed.The field intensity of reflection magnet of 42-cm maximum bending radius is about 1.539×10-1 T...In this paper,a reflection magnet to be installed in the EAST neutral beam injection system is simulated and designed.The field intensity of reflection magnet of 42-cm maximum bending radius is about 1.539×10-1 T for 100 keV deuterium beam.The shielding cage is formed by rods.Using the ANSOFT software,the magnetic shielding effect was estimated at about 3% at the magnet pole region.展开更多
The lattice parameter and magnetocaloric properties of three samples of LaFe11.2Co0.7Si1.1-xGax with x = 0, 0.03 and 0.05 have been investigated by X-ray powder diffraction and magnetization measurements. The lattice ...The lattice parameter and magnetocaloric properties of three samples of LaFe11.2Co0.7Si1.1-xGax with x = 0, 0.03 and 0.05 have been investigated by X-ray powder diffraction and magnetization measurements. The lattice parameter increases slightly and the Curie temperature increases somewhat with increasing gallium content. However, a small amount of Ga doping into the sample decreases the magnetic entropy change of the sample. All the samples remain in the first-order magnetic phase transition. The most striking effect of the Ga doping is that the cooling capacity in the samples increases significantly. The maximum magnetic entropy change, ASM and the cooling capacity of the sample LaFe11.2Co0.7Si1.07Ga0.03 are 11.9 J·kg^-1·K^-1 and 254.8 J·kg^-1, respectively.展开更多
The magnetocaloric effect(MCE) of RT Si and RT Al systems with R = Gd–Tm, T = Fe–Cu and Pd, which have been widely investigated in recent years, is reviewed. It is found that these RT X compounds exhibit various c...The magnetocaloric effect(MCE) of RT Si and RT Al systems with R = Gd–Tm, T = Fe–Cu and Pd, which have been widely investigated in recent years, is reviewed. It is found that these RT X compounds exhibit various crystal structures and magnetic properties, which then result in different MCE. Large MCE has been observed not only in the typical ferromagnetic materials but also in the antiferromagnetic materials. The magnetic properties have been studied in detail to discuss the physical mechanism of large MCE in RT X compounds. Particularly, some RT X compounds such as Er Fe Si,Ho Cu Si, Ho Cu Al exhibit large reversible MCE under low magnetic field change, which suggests that these compounds could be promising materials for magnetic refrigeration in a low temperature range.展开更多
The magnetocaloric properties of the GdsGe2.025Si1.925In0.05 compound have been studied by x-ray diffraction, magnetic and heat capacity measurements. Powder x-ray diffraction measurement shows that the compound has a...The magnetocaloric properties of the GdsGe2.025Si1.925In0.05 compound have been studied by x-ray diffraction, magnetic and heat capacity measurements. Powder x-ray diffraction measurement shows that the compound has a dominant phase of monoclinic Cd5Ge2Si2-type structure and a small quantity of Gds(Ge,Si)3-type phase at room temperature. At about 270 K, this compound shows a first order phase transition. The isothermal magnetic entropy change (△SM) is calculated from the temperature and magnetic field dependences of the magnetization and the temperature dependence of MCE in terms of adiabatic temperature change (△Tad) is calculated from the isothermal magnetic entropy change and the temperature variation in zero-field heat-capacity data. The maximum △SM is -13.6 J·kg^-1.K^- 1 and maximum ATad is 13 K for the magnetic field change of 0 5 T. The Debye temperature (θD) of this compound is 149 K and the value of DOS at the Fermi level is 1.6 states/eV.atom from the low temperature zero-field heat-capacity data. A considerable isothermal magnetic entropy change and adiabatic temperature change under a field change of 0-5 T jointly make the Gd5Ge2.025Si1.925In0.05 compound an attractive candidate for a magnetic refrigerant.展开更多
Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer (MR-WPT) system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic pe...Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer (MR-WPT) system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic performance in engineering. In this study, the shielding effectiveness of a two-coil MR-WPT system for different material shields is analyzed in theory using Moser's formula and Schelkunoff's formula. On this basis a candidate magnetic-shielding scheme with a double-layer structure is determined, which has better shielding effectiveness and coils coupling coefficient. Finally, some finite element simulation results validate the correctness of the theoretical analysis, and the shielding effectiveness with the double-layer shield in maximum is 30?dB larger than the one with the single-layer case.展开更多
The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys ...The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys also have been measured. It was found that a sharp Hopkinson peak appeared at the Curie point for each amorphous and crystalline alloy but there was no Hopkinson peak for the nanocrystalline alloy at the Curie point of the residual amorphous phase. This phenomenon has been explained in terms of the characteristic temperature dependence of the effective magnetic anisotropy.展开更多
The magnetocaloric effect in the A-site doping colossal magnetoresistance material (La_(0.6)Dy_(0.1))Sr_(0.3)MnO_3 was studied. From the measurement and calculation of isothermal magnetization (M-H) curves under vario...The magnetocaloric effect in the A-site doping colossal magnetoresistance material (La_(0.6)Dy_(0.1))Sr_(0.3)MnO_3 was studied. From the measurement and calculation of isothermal magnetization (M-H) curves under various temperatures, a large magnetocaloric effect with ferromagnetic-paramagnetic transition, additional magnetism exchange action introduces additional magnetic entropy change was discovered. This result suggests that (La_(0.6)Dy_(0.1))Sr_(0.3)MnO_3 is a suitable candidate as working substance at room temperature in magnetic refrigeration technology.展开更多
The phases and the magnetocaloric effect in the alloys R(Co1-xSnx)2 with X = 0, 0.025, 0.050, 0.075, and 0.100 were investigated by X-ray diffraction analysis and magnetization measurement. The substitution of Sn in...The phases and the magnetocaloric effect in the alloys R(Co1-xSnx)2 with X = 0, 0.025, 0.050, 0.075, and 0.100 were investigated by X-ray diffraction analysis and magnetization measurement. The substitution of Sn in RCo2 is limited. The cubic MgCu2-type structure for the alloys of RCo2 was confirmed by X-ray powder diffraction and the remaining alloys mainly consisted of the RCo2 phase, along with some RCo3 and R5Sn3 impurity phases. The impurity phases increase with the increase of Sn content. The Tc of the alloys is not very sensitive to the Sn substitution for Dy(Co1-xSnx)2 and Tb(Co1-xSnx)2, whereas in Gd(Co1-xSnx)2, the Curie temperatures significantly increase. The maximum magnetic entropy changes in the alloys Dy(Co1-xSnx)2 (x = 0, 0.025, 0.050, 0.075) are 5.78, 5.43, 3.88, and 2.98 J·kg^-1·K^-1, respectively, and those in the Tb(Co1-xSnx)2 (x = 0, 0.025) are 3.44, and 2.29 J·kg^-1·K^-1 respectively in the applied field change of 0-2.0 T.展开更多
The phases and magnetocaloric effect in the alloys (Gd1-xNdx)Co2 with x = 0, 0.1, 0.2, 0.3, and 0.4 were investigated by X-ray diffraction analysis and magnetization measurement. The samples are single phase with a ...The phases and magnetocaloric effect in the alloys (Gd1-xNdx)Co2 with x = 0, 0.1, 0.2, 0.3, and 0.4 were investigated by X-ray diffraction analysis and magnetization measurement. The samples are single phase with a cubic MgCu2-type structure. The To decreases obviously with increasing Nd content from 404 K of the alloy with x = 0 to 272 K of the alloy with x = 0.4; forx = 0.3, the To is 296 K, which is near room temperature. In the samples (Gd1-xNdx)Co2 with x = 0.0, 0.1, 0.2, 0.3, and 0.4, the maximum magnetic entropy change is 1.471, 1.228, 1.280, 1.381 and 1.610 J·kg^-1·K^-1, respectively, in the applied field range of 0-2.0 T. The results of Arrott plots confirmed that the transition type were second order magnetic transition forx = 0, 0.3, and 0.4.展开更多
The first-order phase transition in GdsSi2Ge2 is sensitive to both magnetic field and pressure. It may indicate that the influences of the magnetic field and the pressure on the phase transition are virtually equivale...The first-order phase transition in GdsSi2Ge2 is sensitive to both magnetic field and pressure. It may indicate that the influences of the magnetic field and the pressure on the phase transition are virtually equivalent. Moreover, theoretical analyses reveal that the total entropy change is almost definite at a certain Curie temperature no matter whether the applied external field is a magnetic field or a pressure. The entropy change curve can be broadened dramatically under pressure, and the refrigerant capacity is improved from 284.7 J/kg to 447.0 J/kg.展开更多
基金The work is supported by the National Key Research and Development Program of China(Grant No.2022YFA1204104)the National Natural Science Foundation of China(Grant No.61888102)the Chinese Academy of Sciences(Grant Nos.ZDBS-SSW-WHC001 and XDB33030100).
文摘Two-dimensional(2D)magnet/superconductor heterostructures can promote the design of artificial materials for exploring 2D physics and device applications by exotic proximity effects.However,plagued by the low Curie temperature and instability in air,it is hard to realize practical applications for the reported layered magnetic materials at present.In this paper,we developed a space-confined chemical vapor deposition method to synthesize ultrathin air-stable ε-Fe_(2)O_(3) nanosheets with Curie temperature above 350 K.The ε-Fe_(2)O_(3)/NbSe_(2) heterojunction was constructed to study the magnetic proximity effect on the superconductivity of the NbSe_(2) multilayer.The electrical transport results show that the subtle proximity effect can modulate the interfacial spin–orbit interaction while undegrading the superconducting critical parameters.Our work paves the way to construct 2D heterojunctions with ultrathin nonlayered materials and layered van der Waals(vdW)materials for exploring new physical phenomena.
文摘In this paper, the magnetocaloric in La0.5Sm0.2Sr0.3Mn1-xFexO3 compounds with x = 0 (LSSMO) and x = 0.05 (LSSMFO) were simulated using mean field model theory. A strong consistency was observed between the theoretical and experimental curves of magnetizations and magnetic entropy changes, −ΔSM(T). Based on the mean-field generated −ΔSM(T), the substantial Temperature-averaged Entropy Change (TEC) values reinforce the appropriateness of these materials for use in magnetic refrigeration technology within TEC (10) values of 1 and 0.57 J∙kg−1∙K−1under 1 T applied magnetic field.
文摘Soil enzyme activities as affected by applied magnetic field were studied with three main soils (brown soil, black soil and albic soil) collected from Northeast China. Appropriate intensities of magnetic field could obviously enhance the activities of hydrogen peroxidases, invertases, amylases and phosphatases in the three soils, although the effect varied with types and water regimes of the soils. Increasing times of magnetic treatment could multiple its good effect on the activities of hydrogen peroxidases in soils.
文摘A study on the effect of applied magnetic field was performed with six types of soils collected fromnortheastern China. Magnetic field was found to cause changes of soil physicc-chemical properties and soilenzyme activities. An appropriate applied magnetic field could cut down soil zeta-potential, soil specificsurface, soil water potential and soil swelling capacity; raise the charge density on soil colloids and theactivities of invertase, hydrogen peroxidase and amylase in the soils; enhance soil aggregation and improvesoil structural status and soil water-releasing capability.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 11074104 and 10604045)the University Science and Technology Planning Program of Shandong Province of China (Grant No. J09LA02)
文摘Based on the closed-orbit theory, the magnetic field effect in the photodetachment of negative ion in the electric field near a metal surface is studied for the first time. The results show that the magnetic field can produce a significant effect on the photodetachment of negative ion near a metal surface. Besides the closed orbits previously found by Duet al. for the H in the electric field near a metal surface (J. Phys. B 43 035002 (2010)), some additional closed orbits are produced due to the effect of magnetic field. For a given ion surface distance and an electric field strength, the cross section depends sensitively on the magnetic field strength. As the magnetic field strength is very small, its influence can be neglected. With the increase of the magnetic field strength, the number of the closed orbits increases greatly and the oscillation in the cross section becomes much more complex. Therefore we can control the photodetachment cross section of the negative ion by changing the magnetic field strength. We hope that our results may guide future experimental studies for the photodetachment process of negative ion in the presence of external fields and surfaces.
基金supported by Changjiang Scholars and Innovative Research Team in University of China (PCSIRT)(No.IRT0520)National Natural Science Foundation of China (No.60671012)
文摘Considering the actual magnetic field configuration in a Hall thruster, the effect of magnetic mirror on the radial profile of near-wall conductivity (NWC) is studied in this paper. The plasma electron dynamic process is described by the test particle method. The Monte Carlo scheme is used to solve this model. The radial profile of electron mobility is obtained and the role of magnetic mirror in NWC is analysed both theoretically and numerically. The numerical results show that the electron mobility peak due to NWC is inversely proportional to the magnetic mirror ratio and the asymmetry of electron mobility along the radial direction gets greater when the magnetic mirror is considered. This effect indicates that apart from the disparity in the magnetic field strength, the difference in the magnetic mirror ratio near the inner and outer walls would actually augment the asymmetry of the radial profile of NWC in Hall thrusters.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11274357,51501005,51590880,and 11674008)the Fundamental Research Funds for the Central Universities,China(Grant No.FRF-TP-15-010A1)+1 种基金the China Postdoctoral Science Foundation(Grant No.2016M591071)the Key Research Program of the Chinese Academy of Sciences(Grant No.KJZD-EW-M05)
文摘In this paper, we review the magnetic properties and magnetocaloric effects(MCE) of binary R–T(R = Pr, Gd, Tb,Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu) intermetallic compounds(including RGa series, RNi series, R_(12)Co_7 series, R_3 Co series and RCu_2series), which have been investigated in detail in the past several years. The R–T compounds are studied by means of magnetic measurements, heat capacity measurements, magnetoresistance measurements and neutron powder diffraction measurements. The R–T compounds show complex magnetic transitions and interesting magnetic properties.The types of magnetic transitions are investigated and confirmed in detail by multiple approaches. Especially, most of the R–T compounds undergo more than one magnetic transition, which has significant impact on the magnetocaloric effect of R–T compounds. The MCE of R–T compounds are calculated by different ways and the special shapes of MCE peaks for different compounds are investigated and discussed in detail. To improve the MCE performance of R–T compounds,atoms with large spin(S) and atoms with large total angular momentum(J) are introduced to substitute the related rare earth atoms. With the atom substitution, the maximum of magnetic entropy change(?SM), refrigerant temperature width(Twidth)or refrigerant capacity(RC) is enlarged for some R–T compounds. In the low temperature range, binary R–T(R = Pr, Gd,Tb, Dy, Ho, Er, Tm; T = Ga, Ni, Co, Cu) intermetallic compounds(including RGa series, RNi series,R_(12)Co_7 series, R_3 Co series and RCu_2series) show excellent performance of MCE, indicating the potential application for gas liquefaction in the future.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.52022029,91850116,51772084,62090035,and U19A2090)Hunan Provincial Natural Science Foundation of China(Grant Nos.2018RS3051 and 2018WK4004)the Key Program of the Hunan Provincial Science and Technology Department(Grant No.2019XK2001).
文摘Two-dimensional(2D)magnetic materials have aroused tremendous interest due to the 2D confinement of magnetism and potential applications in spintronic and valleytronic devices.However,most of the currently 2D magnetic materials are achieved by the exfoliation from their bulks,of which the thickness and domain size are difficult to control,limiting the practical device applications.Here,we demonstrate the realization of thickness-tunable rhombohedral Cr_(2)Se_(3)nanosheets on different substrates via the chemical vapor deposition route.The magnetic transition temperature at about 75 K is observed.Furthermore,van der Waals heterostructures consisting of Cr_(2)Se_(3)nanosheets and monolayer WS2 are constructed.We observe the magnetic proximity effect in the heterostructures,which manifests the manipulation of the valley polarization in monolayer WS2.Our work contributes to the vapor growth and applications of 2D magnetic materials.
文摘The magnetic field effects (MFEs) are studied on photocatalytic degradation of methylene blue (MB) solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and the dependence of the reaction rate on the initial dye concentration and settling duration is studied under UV light irradiation. It is found that the MFEs exist on the heterogeneous reaction systems for both ZnO and TiO2 powders and that the extraordinary phenomenon is reproducible. For ZnO powder, the results are in good agreement with the second-order reaction kinetics following the Langmuir-Hinshelwood (L-H) model, while the reaction for TiO2 follows first-order kinetics. It enhances the photodegradation for ZnO, while it reduces or enhances the reaction for TiO2 depending on the initial dye concentrations. The MFEs become small or negligible when the same photodecomposition experiment is carried out after settling the MB solution for more than three hours for both ZnO and TiO2. It is suggested that the key factors of MFEs on photocatalytic degradation is the condition of the MB solution as well as the characteristics of photocatalysts. The alteration of the MFEs ascribed to the solution condition caused by variation of the settling time.
基金supported by National Natural Science Foundation of China(Grant No. 10772061)Heilongjiang Provincial Natural Science Foundation of China(Grant No. A200907)Specialized Research Fundfor the Doctoral Program of Higher Education of China(Grant No.20092322120001)
文摘Detecting stress concentration, especially critical stress state leading to structure damage or failure, is one of the most important tasks of equipment diagnosis. Metal magnetic memory technique needs further research to evaluate stress concentration quantitatively due to ambiguous physical mechanism, though it has potential to detect early defects in ferromagnetic materials. Mild Q235 steel defective specimens in demagnetization state were loaded in tension up to visible necking, with magnetic memory signals measurement made at increasing stress levels. Magnetic signals varied greatly under first several loadings and subsequently tended to stability in the elastic region, which showed that the magnetization always approaches the anhysteretic magnetization curve and was explained by the theory of magnetomechanical effect. In the plastic stage, an abnormal wave occurred in the stress concentration zone and its height value was sensitive to plastic deformation levels and dependent on the distance between the probe and defect, in accordance with the simulation results based on the magnetic dipole model. Different magnetic signal characteristics in the elastic-plastic region indicate that the magnetic memory technique can identify macroyielding and early damage, which is of profound significance for ensuring safe operation of equipment in service.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences:the study and simulation on beam interaction with background particles in neutralization area for NBI,and the key technical and physical problems study for neutral beam steady-state operationsupported by National Natural Science Foundation of China under Grant No.10875146
文摘In this paper,a reflection magnet to be installed in the EAST neutral beam injection system is simulated and designed.The field intensity of reflection magnet of 42-cm maximum bending radius is about 1.539×10-1 T for 100 keV deuterium beam.The shielding cage is formed by rods.Using the ANSOFT software,the magnetic shielding effect was estimated at about 3% at the magnet pole region.
基金the Opening Foun-dation of Guangxi Key Laboratory for the Advance Materi-als and New Preparation Technology
文摘The lattice parameter and magnetocaloric properties of three samples of LaFe11.2Co0.7Si1.1-xGax with x = 0, 0.03 and 0.05 have been investigated by X-ray powder diffraction and magnetization measurements. The lattice parameter increases slightly and the Curie temperature increases somewhat with increasing gallium content. However, a small amount of Ga doping into the sample decreases the magnetic entropy change of the sample. All the samples remain in the first-order magnetic phase transition. The most striking effect of the Ga doping is that the cooling capacity in the samples increases significantly. The maximum magnetic entropy change, ASM and the cooling capacity of the sample LaFe11.2Co0.7Si1.07Ga0.03 are 11.9 J·kg^-1·K^-1 and 254.8 J·kg^-1, respectively.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.5137102611274357+1 种基金and 51327806)the Fundamental Research Funds for the Central Universities(Grant Nos.FRF-TP-14-011A2 and FRF-TP-15-002A3)
文摘The magnetocaloric effect(MCE) of RT Si and RT Al systems with R = Gd–Tm, T = Fe–Cu and Pd, which have been widely investigated in recent years, is reviewed. It is found that these RT X compounds exhibit various crystal structures and magnetic properties, which then result in different MCE. Large MCE has been observed not only in the typical ferromagnetic materials but also in the antiferromagnetic materials. The magnetic properties have been studied in detail to discuss the physical mechanism of large MCE in RT X compounds. Particularly, some RT X compounds such as Er Fe Si,Ho Cu Si, Ho Cu Al exhibit large reversible MCE under low magnetic field change, which suggests that these compounds could be promising materials for magnetic refrigeration in a low temperature range.
基金supported by Ankara University Research Funds (Grand Number:BAP 06B4343004)
文摘The magnetocaloric properties of the GdsGe2.025Si1.925In0.05 compound have been studied by x-ray diffraction, magnetic and heat capacity measurements. Powder x-ray diffraction measurement shows that the compound has a dominant phase of monoclinic Cd5Ge2Si2-type structure and a small quantity of Gds(Ge,Si)3-type phase at room temperature. At about 270 K, this compound shows a first order phase transition. The isothermal magnetic entropy change (△SM) is calculated from the temperature and magnetic field dependences of the magnetization and the temperature dependence of MCE in terms of adiabatic temperature change (△Tad) is calculated from the isothermal magnetic entropy change and the temperature variation in zero-field heat-capacity data. The maximum △SM is -13.6 J·kg^-1.K^- 1 and maximum ATad is 13 K for the magnetic field change of 0 5 T. The Debye temperature (θD) of this compound is 149 K and the value of DOS at the Fermi level is 1.6 states/eV.atom from the low temperature zero-field heat-capacity data. A considerable isothermal magnetic entropy change and adiabatic temperature change under a field change of 0-5 T jointly make the Gd5Ge2.025Si1.925In0.05 compound an attractive candidate for a magnetic refrigerant.
基金Supported by the National Natural Science Foundation of China under Grant No 51377185
文摘Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer (MR-WPT) system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic performance in engineering. In this study, the shielding effectiveness of a two-coil MR-WPT system for different material shields is analyzed in theory using Moser's formula and Schelkunoff's formula. On this basis a candidate magnetic-shielding scheme with a double-layer structure is determined, which has better shielding effectiveness and coils coupling coefficient. Finally, some finite element simulation results validate the correctness of the theoretical analysis, and the shielding effectiveness with the double-layer shield in maximum is 30?dB larger than the one with the single-layer case.
基金National Natural Science Foundation of China! under grant No. 59871013.
文摘The μi-T curves of the alloy Fe73.5Cu1 Nb3Si13.5B9 in the amorphous state and in the nanocrys-talline state have been investigated. For comparison, μi-T curves of the other two kinds of typical soft magnetic alloys also have been measured. It was found that a sharp Hopkinson peak appeared at the Curie point for each amorphous and crystalline alloy but there was no Hopkinson peak for the nanocrystalline alloy at the Curie point of the residual amorphous phase. This phenomenon has been explained in terms of the characteristic temperature dependence of the effective magnetic anisotropy.
基金Project supported by the National Science Foundation of China (10334090) and the National Key Fundamental Research De velopment Program (001CB610604)
文摘The magnetocaloric effect in the A-site doping colossal magnetoresistance material (La_(0.6)Dy_(0.1))Sr_(0.3)MnO_3 was studied. From the measurement and calculation of isothermal magnetization (M-H) curves under various temperatures, a large magnetocaloric effect with ferromagnetic-paramagnetic transition, additional magnetism exchange action introduces additional magnetic entropy change was discovered. This result suggests that (La_(0.6)Dy_(0.1))Sr_(0.3)MnO_3 is a suitable candidate as working substance at room temperature in magnetic refrigeration technology.
基金The work was financially supported by the National Natural Science Foundation of China (No. 50371058).
文摘The phases and the magnetocaloric effect in the alloys R(Co1-xSnx)2 with X = 0, 0.025, 0.050, 0.075, and 0.100 were investigated by X-ray diffraction analysis and magnetization measurement. The substitution of Sn in RCo2 is limited. The cubic MgCu2-type structure for the alloys of RCo2 was confirmed by X-ray powder diffraction and the remaining alloys mainly consisted of the RCo2 phase, along with some RCo3 and R5Sn3 impurity phases. The impurity phases increase with the increase of Sn content. The Tc of the alloys is not very sensitive to the Sn substitution for Dy(Co1-xSnx)2 and Tb(Co1-xSnx)2, whereas in Gd(Co1-xSnx)2, the Curie temperatures significantly increase. The maximum magnetic entropy changes in the alloys Dy(Co1-xSnx)2 (x = 0, 0.025, 0.050, 0.075) are 5.78, 5.43, 3.88, and 2.98 J·kg^-1·K^-1, respectively, and those in the Tb(Co1-xSnx)2 (x = 0, 0.025) are 3.44, and 2.29 J·kg^-1·K^-1 respectively in the applied field change of 0-2.0 T.
基金the National Natu-ral Science Foundation of China (No. 50371058)
文摘The phases and magnetocaloric effect in the alloys (Gd1-xNdx)Co2 with x = 0, 0.1, 0.2, 0.3, and 0.4 were investigated by X-ray diffraction analysis and magnetization measurement. The samples are single phase with a cubic MgCu2-type structure. The To decreases obviously with increasing Nd content from 404 K of the alloy with x = 0 to 272 K of the alloy with x = 0.4; forx = 0.3, the To is 296 K, which is near room temperature. In the samples (Gd1-xNdx)Co2 with x = 0.0, 0.1, 0.2, 0.3, and 0.4, the maximum magnetic entropy change is 1.471, 1.228, 1.280, 1.381 and 1.610 J·kg^-1·K^-1, respectively, in the applied field range of 0-2.0 T. The results of Arrott plots confirmed that the transition type were second order magnetic transition forx = 0, 0.3, and 0.4.
基金Projected supported by the National Natural Science Foundation of China (Grant Nos. 50801015 and 50921003)the Fundamental Research Funds for the Central Universities,China (Grant No. YWF-11-03-Q-003)
文摘The first-order phase transition in GdsSi2Ge2 is sensitive to both magnetic field and pressure. It may indicate that the influences of the magnetic field and the pressure on the phase transition are virtually equivalent. Moreover, theoretical analyses reveal that the total entropy change is almost definite at a certain Curie temperature no matter whether the applied external field is a magnetic field or a pressure. The entropy change curve can be broadened dramatically under pressure, and the refrigerant capacity is improved from 284.7 J/kg to 447.0 J/kg.