The functioning mechanism of groundwater and its make-up water in the process of ground subsidence was studied from such three aspects as osmotic corrasion, osmotic pressure effect and concretion effect, As to osmotic...The functioning mechanism of groundwater and its make-up water in the process of ground subsidence was studied from such three aspects as osmotic corrasion, osmotic pressure effect and concretion effect, As to osmotic corrasion, its forming conditions, mechanical mechanism and process were analyzed, As to osmotic pressure effect, it was mainly studied from hydrostatic pressurizing effect, sop softening effect and negative pressure sealing effect. Through concretion and saturation of soil, the factors of concretion settlement were analyzed. The results showed that both groundwater and its make-up water are important triggering factors to ground subsidence.展开更多
A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that...A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that remarkable mechanical coupling effects are produced in the process, and the sectional stress in rapid cooling down is found considerably larger than that in heating-up. Meanwhile, the stress and deformation of a beam mainly related to cooling rate and location are much larger than those of a column in rapid cooling, In fire fighting, the structure on the first or second floor was more dangerous than those on other floors in rapid cooling, These results could provide a theoretical reference for the design of steel structure and fire fighting.展开更多
We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 104...We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.展开更多
Electric discharge in and in contact with water can accompany ultraviolet(UV)radiation and electron impact, which can generate a large number of active species such as hydroxyl radicals(OH), oxygen radical(O), o...Electric discharge in and in contact with water can accompany ultraviolet(UV)radiation and electron impact, which can generate a large number of active species such as hydroxyl radicals(OH), oxygen radical(O), ozone(O_3) and hydrogen peroxide(H_2O_2). In this paper, a nonthermal plasma processing system was established by means of dielectric barrier discharge(DBD)arrays in water mist spray. The relationship between droplet size and water content was examined,and the effects of the concentrations of oxides in both treated water and gas were investigated under different water content and discharge time. The relative intensity of UV spectra from DBD in water mist was a function of water content. The concentrations of both O_3 and nitrogen dioxide(NO_2) in DBD room decreased with increasing water content. Moreover, the concentrations of H_2O_2, O_3 and nitrogen oxides(NOx) in treated water decreased with increasing water content,and all the ones enhanced after discharge. The experimental results were further analyzed by chemical reaction equations and commented by physical principles as much as possible. At last,the water containing phenol was tested in this system for the concentration from 100 mg/L to9.8 mg/L in a period of 35 min.展开更多
With its high strength and hardness, wear-resistant steel has become an important material in the field of construction machinery manufacturing.Given that quenching technology is a crucial component of wear-resistant ...With its high strength and hardness, wear-resistant steel has become an important material in the field of construction machinery manufacturing.Given that quenching technology is a crucial component of wear-resistant steel production, the selection of the cooling method to be used during this process is important.In this study, the feasibility of quenching wear-resistant steel by air-atomized water spray cooling was studied, and the cooling rate, microstructure, and hardness of wear-resistant steel under various cooling device structures were analyzed.The results reveal that the air-atomized water spray cooling method is an effective technique in quenching wear-resistant steel.Furthermore, martensite and uniform hardness were obtained by the air-atomized water spray cooling technique.As the space between the nozzles in each row in the device increased, the cooling rate was reduced during quenching.Meanwhile, the martensite content decreased, and more carbides were observed in the martensitic structure.A mixture comprising self-tempered martensite and bainite was formed at a large distance over a longer period of time.All these factors resulted in lower hardness and worse property uniformity.展开更多
The objective of this research is to design an effective and relatively simple method for controlled cooling of hot rolled steel channels by water spraying on the final cooling bed after continuous cast steel billets ...The objective of this research is to design an effective and relatively simple method for controlled cooling of hot rolled steel channels by water spraying on the final cooling bed after continuous cast steel billets passing through reheating furnace and sequential rolls to form channels. The need for this research arose as the channels were being cooled by forced air draft and natural convection which brought the temperature of the channels to about 270°C (518°F) at the shear stand. Steel at this temperature is too hot for convenient handling by the operators. Additional cooling by water spraying would be an acceptable solution but such cooling should be designed to enable an acceptable microstructure to be developed in the channel, as the microstructure of steel is strongly affected by nonequilibrium cooling through the eutectoid range: the mechanical properties of steel are a consequence of the microstructure. The approach followed in this investigation was first to develop a finite element method (FEM) to determine the temperature profiles in the channel subjected to cooling by water spraying and natural convection and arrive at suitable water spray rates to bring the temperature of the channel at the shear stand to levels suitable for convenient handling. PATRAN was used for preprocessing and ABAQUS for processing and post processing. Next, laboratory experiments were conducted to determine the microstructure and hardness of channels at the spray rates found suitable through FEM, to suggest the water spray rate most suitable for providing a temperature convenient for handling and for developing a desirable microstructure.展开更多
Accumulation of float coal dust(FCD)in underground mines is an explosion hazard that affects all underground coal mine workers.While this hazard is addressed by the application of rock dust,inadequate rock dusting pra...Accumulation of float coal dust(FCD)in underground mines is an explosion hazard that affects all underground coal mine workers.While this hazard is addressed by the application of rock dust,inadequate rock dusting practices can leave miners exposed to an explosion risk.Researchers at the National Institute for Occupational Safety and Health(NIOSH)have focused on developing a water curtain that removes FCD from the airstream,thereby reducing the buildup of FCD in mine airways.In this study,the number and spacing of the active sprays in the water curtain were varied to determine the optimal configuration to obtain peak knockdown efficiency(KE)while minimizing water consumption.展开更多
Calcium fluoride(CaF_(2))is an ideal adsorbent for the dehydration of gaseous hydrogen fluoride(HF)containing water vapor.In this work,a novel CaF_(2)absorbent,spherical CaF_(2)nanoaggregates(NAs)with a closely packed...Calcium fluoride(CaF_(2))is an ideal adsorbent for the dehydration of gaseous hydrogen fluoride(HF)containing water vapor.In this work,a novel CaF_(2)absorbent,spherical CaF_(2)nanoaggregates(NAs)with a closely packed structure,was proposed and efficiently fabricated by spray drying technology.As the building blocks of CaF_(2)NAs,the CaF_(2)nanoparticles(NPs)were prepared by the addition of excess calcium ions(Ca^(2+))or fluorine ions(F−)in the synthesis.The results indicated that the CaF_(2)NPs synthesized by excess Ca^(2+)and the corresponding NAs exhibited much better water vapor adsorption properties than their counterparts by excess F−,owing to higher zeta potentials.More importantly,whether excess Ca^(2+)or F^(−),CaF_(2)NAs had further enhanced water vapor adsorption capacity compared to primary CaF_(2)NPs,possibly owing to their unique nano-micro secondary structures and higher surface areas.This work has great potential in the development of high-performance absorbents for separating moisture from corrosive gas HF.展开更多
This paper reports the chemical synthesis of tungsten carbide/cobalt (WC/Co) nanocomposite powders via a unique chemical processing technique, involving the using of all water soluble solution of W-, Co- and C-precurs...This paper reports the chemical synthesis of tungsten carbide/cobalt (WC/Co) nanocomposite powders via a unique chemical processing technique, involving the using of all water soluble solution of W-, Co- and C-precursors. In the actual synthesis, large quantities of commercial-scale WC-Co nanocomposite powders are made by an unique combination of converting a molecularly mixed W-, Co-, and C-containing solutions into a complex inorganic polymeric powder precursor, conversion of the inorganic polymeric precursor powder into a W-Co-C-O containing powder intermediates using a belt furnace with temperature at about 500°C - 600°C in an inert atmosphere, followed by carburization in a rotary furnace at temperature less than 1000°C in nitrogen. Liquid phase sintering technique is used to consolidate the WC/Co nanocomposite powder into sintered bulk parts. The sintered parts have excellent hardness in excess of 93 HRA, with WC grains in the order of 200 - 300 nm, while Co phase is uniformly distributed on the grain boundaries of the WC nanoparticles. We also report the presence of cobalt Co precipitates inside tungsten carbide WC nanograins in the composites of the consolidated bulk parts. EDS is used to identify the presence of these precipitates and micro-micro-diffraction technique is employed to determine the nature of these precipitates.展开更多
Phenolic-metal complexation coatings have been discovered to be a universal route for the deposition of multifunctional coatings. However, most complexation coatings have been prepared by the immersion method, which l...Phenolic-metal complexation coatings have been discovered to be a universal route for the deposition of multifunctional coatings. However, most complexation coatings have been prepared by the immersion method, which limits their practical large-scale application. Herein, we describe a facile and green engineering strategy that involves spraying phenolic compound and metal ions on substrate to form in-situ complexation coating with different coordination states. The coating is formed within minutes and it can be achieved in large scale by the spray method. The pyrogallol-Fem complexation coating is prepared at pH 7.5, which consists predominantly of biscoordination complexation with a small amount of tris-coordination complexation. It displays that the water contact angle is near zero due to the generation of rough hierarchical structures and massive hydroxyl groups. The superhydrophilic cotton resulting from the deposition of the pyrogallol-Fe^Ⅲ complexation can separate oil/water mixtures and surfactant-stabilized oil-in-water emulsions with high separation efficiency. The formation of the phenolic-metal complexation coating by using spray technique constitutes a cost-effective and environmentally friendly, strategy with potential to be applied for large-scale surface engineering processes and green oil/water separation.展开更多
In this paper,a method composed of gelation of basic skeleton(first step)and skeleton reinforcement process(second step)was introduced to synthesize silica powder with high pore volume through the reaction between wat...In this paper,a method composed of gelation of basic skeleton(first step)and skeleton reinforcement process(second step)was introduced to synthesize silica powder with high pore volume through the reaction between water glass and sulfuric acid.No organic solvents were involved in the entire preparation process and the final product was collected by spray drying.The effect of concentration of base solution,gelation point p H value and skeleton reinforcement time on the BET specific surface area and pore volume of the prepared silica powder were investigated intensively.The results show that,a basic skeleton with good dispersibility and high porosity was obtained when the concentration of base solution was 0.1 mol·L^(-1) and the gelation p H value reached 6.5.Then the basic skeleton grew into a more uniform porous structure after 30 min skeleton reinforcement.Under these optimum conditions,silica powder prepared by skeleton reinforcement method had a BET specific surface area of 358.0 m^(2)·g^(-1),and its pore volume reached 2.18 cm^(3)·g^(-1),which was much higher than that of prepared by skeleton-free method(1.62 cm^(3)·g^(-1))and by direct gelation method(0.31 cm^(3)·g^(-1)).展开更多
High-speed planing crafts have successfully evolved through developments in the last several decades.Classical approaches such as inviscid potential flow–based methods and the empirically based Savitsky method provid...High-speed planing crafts have successfully evolved through developments in the last several decades.Classical approaches such as inviscid potential flow–based methods and the empirically based Savitsky method provide general understanding for practical design.However,sometimes such analyses suffer inaccuracies since the air–water interface effects,especially in the transition phase,are not fully accounted for.Hence,understanding the behaviour at the transition speed is of fundamental importance for the designer.The fluid forces in planing hulls are dominated by phenomena such as flow separation at various discontinuities viz.,knuckles,chines and transom,with resultant spray generation.In such cases,the application of potential theory at high speeds introduces limitations.This paper investigates the simulation of modelling of the pre-planing behaviour with a view to capturing the air–water interface effects,with validations through experiments to compare the drag,dynamic trim and wetted surface area.The paper also brings out the merits of gridding strategies to obtain reliable results especially with regard to spray generation due to the air–water interface effects.The verification and validation studies serve to authenticate the use of the multi-gridding strategies on the basis of comparisons with simulations using model tests.It emerges from the study that overset/chimera grids give better results compared with single unstructured hexahedral grids.Two overset methods are investigated to obtain reliable estimation of the dynamic trim and drag,and their ability to capture the spray resulting from the air–water interaction.The results demonstrate very close simulation of the actual flow kinematics at steady-speed conditions in terms of spray at the air–water interface,drag at the pre-planing and full planing range and dynamic trim angles.展开更多
Owing to the increasing worldwide demand for natural gas,the development of a large submerged combustion vaporizer is required.Its burner is equipped with a water spray nozzle to reduce nitrogen oxides,and a practi-ca...Owing to the increasing worldwide demand for natural gas,the development of a large submerged combustion vaporizer is required.Its burner is equipped with a water spray nozzle to reduce nitrogen oxides,and a practi-cal simulation method is required for the optimal design.The non-adiabatic flamelet approach can predict the combustion emissions and is useful for reducing simulation costs.However,as the number of control variables increases,the database requires larger memory and cannot be dealt with by general computers.In this study,an artificial neural network(ANN)model based on a five-dimensional flamelet database,which includes the effects of heat loss and vapor concentration by sprayed water evaporation,is developed.Furthermore,large eddy sim-ulations(LESs)for turbulent combustion fields with and without water spray are conducted employing flamelet generated manifold(FGM)approach with this ANN model,and the validity is investigated.For comparison,a lab-scale burner equipped with a water spray nozzle is manufactured,and combustion experiments with and without water spray are conducted.The results show that CO,NO,temperature,and reaction rate of progress variable predicted by the present ANN model are in good agreement with those of a five-dimensional flamelet database.In the condition without water spray,the flame behavior predicted by the LES employing the FGM/ANN ap-proach is in good agreement with that employing the conventional FGM approach,while indicating much lower memory,although there appeared some quantitative discrepancies in the temperature against the experiment probably partially because of the insufficiency of the FGM approach for the present complex flame structure.In the condition with water spray,the LES employing the FGM/ANN approach is able to capture the effect of the water spray on the flame behavior in the experiment,such that the water spray decreases the temperature,which causes the decrease in NO but increase in CO.展开更多
To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried o...To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried out on three kinds of plant shellfibers to test their crystallinity.The aging process of the composites was conducted under 2 different conditions.One was artificial seawater immersion and xenon lamp irradiation,and the other one was deionized water spray and xenon lamp irradiation.The mechanical properties(tensile strength,flexural strength,impact strength),changes in color,water absorption,Fourier transform infrared spectroscopy(FTIR),and microstructures of the composites before and after the two aging experiments were analyzed.The results showed that the chestnut shell had the highest crystallinity,which was 42%.The chestnut shell/PVC composites had the strongest interface bonding,the least internal defects,and the best general mechanical properties among the three composites.Its tensile strength,bending strength and impact strength were 23.81 MPa,34.12 MPa,and 4.32 KJ·m^(-2),respectively.Comparing the two aging conditions,artificial seawater immersion and xenon lamp irradiation destroyed the quality of the combination of plant shellfibers and PVC,making the internal defects of the composites increase.This made the water absorption ability and changes in the color of the composites more obvious and led to a great decrease in the mechanical properties.The general mechanical properties of the chestnut shell/PVC composites were the best,but their water absorption ability changed more obviously.展开更多
The task of studying the process of icing is important due to the operation of large ships and fishing vessels in the seas of the Arctic Ocean.In this paper the ice accretion simulation for fishing vessel has been don...The task of studying the process of icing is important due to the operation of large ships and fishing vessels in the seas of the Arctic Ocean.In this paper the ice accretion simulation for fishing vessel has been done at different Reynolds and Froude numbers.A hybrid approach was used for modeling:first,the approach based on Reynolds-averaged Navier-Stokes(RANS)model and volume of fluid(VOF)method with interDyMFoam solver was used for ship modelling in waves,second,RANS model and Euler-Lagrangian approach with iceFoam solver for ice accretion process modelling for ship with hull was applied.The k-ωSST turbulence model with wall functions was used for the RANS model.With the help of the interDyMFoam solver,the position of water jet and liquid droplets in space were determined during the movement of the ship and taking into account the waves in the sea.With the help of iceFoam solver,the process of ice accretion on the surface of the vessel was modeled.The calculations were run for different number Reynolds,Froude.The analysis of mesh convergency was done.The distribution of ice thickness and water film on the ship’s surface is obtained.The simulations were performed on a high-performance cluster in parallel mode.展开更多
This study evaluated corn(Zea mays var.indentata)canopy vigor and temperature variations using small unmanned aerial system(UAS)based spatiotemporal imagery data.The key objective was to develop understanding on site-...This study evaluated corn(Zea mays var.indentata)canopy vigor and temperature variations using small unmanned aerial system(UAS)based spatiotemporal imagery data.The key objective was to develop understanding on site-specific suitability of the Mid Elevation Spray Application(MESA)and Low Elevation Spray Application(LESA)sprinkler systems in irrigating corn crop and potential water as well as energy savings.Aerial data was collected through small UAS flights at 100m height above ground level and on 49,59,65,77,105,114,134 days after planting(DAP).Small UAS had 5-band multispectral and radiometric thermal imager on-board the platform.Custom image processing algorithms were developed to extract various vegetation indices(Normalized difference vegetation index[NDVI],Green NDVI[GNDVI]and Normalized difference red edge[NDRE])and canopy temperature maps from the imagery data.Two sample T-test was performed on extracted data to understand significant difference,at 5%level,within the LESA and MESA treatments.For both the irrigation techniques,the crop vigor increased in the early growth stage(49,65 DAP),peaked in the mid growth stage(77,105,114 DAP)and then decreased in the late growth stage(134 DAP).The MESA irrigated sections had higher vigor(NDVI,GNDVI,NDRE),but not significant,compared to LESA throughout the season.Similarly,the MESA irrigated areas had significantly(0.61–2.07C)cooler canopies than LESA.Such results were anticipated,in part due to the issues with the sprinkler heads used in LESA.The heads were being pulled off in the corn field,causing the weighted hose to damage the crop.A different kind of sprinkler head was used after this incident.However,some strips of corn had already been damaged.Overall,this study results confirm suitability of aerial imagery data in evaluating pertinent irrigation treatments.Additional season’s data would be needed to clearly understand which technique(LESA or MESA)is more suitable for irrigating corn crop in the central part of state of Washington.展开更多
基金financially supported by the National Nature Science Foundation of China (No.50490271)the National Key Technologies R & D Program of China (No.2004BA615A-18).
文摘The functioning mechanism of groundwater and its make-up water in the process of ground subsidence was studied from such three aspects as osmotic corrasion, osmotic pressure effect and concretion effect, As to osmotic corrasion, its forming conditions, mechanical mechanism and process were analyzed, As to osmotic pressure effect, it was mainly studied from hydrostatic pressurizing effect, sop softening effect and negative pressure sealing effect. Through concretion and saturation of soil, the factors of concretion settlement were analyzed. The results showed that both groundwater and its make-up water are important triggering factors to ground subsidence.
基金supported by the National Natural Science Foundation of China (51478002)
文摘A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that remarkable mechanical coupling effects are produced in the process, and the sectional stress in rapid cooling down is found considerably larger than that in heating-up. Meanwhile, the stress and deformation of a beam mainly related to cooling rate and location are much larger than those of a column in rapid cooling, In fire fighting, the structure on the first or second floor was more dangerous than those on other floors in rapid cooling, These results could provide a theoretical reference for the design of steel structure and fire fighting.
文摘We conducted a transient experimental investigation of steam–water direct contact condensation in the absence of noncondensible gas in a laboratory-scale column with the inner diameter of 325 mm and the height of 1045 mm. We applied a new analysis method for the steam state equation to analyze the molar quantity change in steam over the course of the experiment and determined the transient steam variation. We also investigated the influence of flow rates and temperatures ofcooling water on the efficiency ofsteam condensation. Our experimental results show that appropriate increasing of the cooling water flow rate can significantly accelerate the steam condensation. We achieved a rapid increase in the total volumetric heat transfer coefficient by increasing the flow rate of cooling water, which indicated a higher thermal convection between the steam and the cooling water with higher flow rates. We found that the temperature ofcooling water did not play an important role on steam condensation. This method was confirmed to be effective for rapid recovering ofsteam.
基金supported by National Natural Science Foundation of China(Nos.11274092,51107033,11404092,11274091)the Nantong Science and Technology Project,China(No.BK2014024)+1 种基金the Open Project of Jiangsu Province Key Laboratory of Environmental Engineering,China(No.KF2014001)the Fundamental Research Funds for the Central Universities,China(No.2014B11414)
文摘Electric discharge in and in contact with water can accompany ultraviolet(UV)radiation and electron impact, which can generate a large number of active species such as hydroxyl radicals(OH), oxygen radical(O), ozone(O_3) and hydrogen peroxide(H_2O_2). In this paper, a nonthermal plasma processing system was established by means of dielectric barrier discharge(DBD)arrays in water mist spray. The relationship between droplet size and water content was examined,and the effects of the concentrations of oxides in both treated water and gas were investigated under different water content and discharge time. The relative intensity of UV spectra from DBD in water mist was a function of water content. The concentrations of both O_3 and nitrogen dioxide(NO_2) in DBD room decreased with increasing water content. Moreover, the concentrations of H_2O_2, O_3 and nitrogen oxides(NOx) in treated water decreased with increasing water content,and all the ones enhanced after discharge. The experimental results were further analyzed by chemical reaction equations and commented by physical principles as much as possible. At last,the water containing phenol was tested in this system for the concentration from 100 mg/L to9.8 mg/L in a period of 35 min.
文摘With its high strength and hardness, wear-resistant steel has become an important material in the field of construction machinery manufacturing.Given that quenching technology is a crucial component of wear-resistant steel production, the selection of the cooling method to be used during this process is important.In this study, the feasibility of quenching wear-resistant steel by air-atomized water spray cooling was studied, and the cooling rate, microstructure, and hardness of wear-resistant steel under various cooling device structures were analyzed.The results reveal that the air-atomized water spray cooling method is an effective technique in quenching wear-resistant steel.Furthermore, martensite and uniform hardness were obtained by the air-atomized water spray cooling technique.As the space between the nozzles in each row in the device increased, the cooling rate was reduced during quenching.Meanwhile, the martensite content decreased, and more carbides were observed in the martensitic structure.A mixture comprising self-tempered martensite and bainite was formed at a large distance over a longer period of time.All these factors resulted in lower hardness and worse property uniformity.
文摘The objective of this research is to design an effective and relatively simple method for controlled cooling of hot rolled steel channels by water spraying on the final cooling bed after continuous cast steel billets passing through reheating furnace and sequential rolls to form channels. The need for this research arose as the channels were being cooled by forced air draft and natural convection which brought the temperature of the channels to about 270°C (518°F) at the shear stand. Steel at this temperature is too hot for convenient handling by the operators. Additional cooling by water spraying would be an acceptable solution but such cooling should be designed to enable an acceptable microstructure to be developed in the channel, as the microstructure of steel is strongly affected by nonequilibrium cooling through the eutectoid range: the mechanical properties of steel are a consequence of the microstructure. The approach followed in this investigation was first to develop a finite element method (FEM) to determine the temperature profiles in the channel subjected to cooling by water spraying and natural convection and arrive at suitable water spray rates to bring the temperature of the channel at the shear stand to levels suitable for convenient handling. PATRAN was used for preprocessing and ABAQUS for processing and post processing. Next, laboratory experiments were conducted to determine the microstructure and hardness of channels at the spray rates found suitable through FEM, to suggest the water spray rate most suitable for providing a temperature convenient for handling and for developing a desirable microstructure.
文摘Accumulation of float coal dust(FCD)in underground mines is an explosion hazard that affects all underground coal mine workers.While this hazard is addressed by the application of rock dust,inadequate rock dusting practices can leave miners exposed to an explosion risk.Researchers at the National Institute for Occupational Safety and Health(NIOSH)have focused on developing a water curtain that removes FCD from the airstream,thereby reducing the buildup of FCD in mine airways.In this study,the number and spacing of the active sprays in the water curtain were varied to determine the optimal configuration to obtain peak knockdown efficiency(KE)while minimizing water consumption.
基金supported by the National Key Research and Development Program of China(grant No.2021YFA1201301)the National Natural Science Foundation of China(grant No.22288102).
文摘Calcium fluoride(CaF_(2))is an ideal adsorbent for the dehydration of gaseous hydrogen fluoride(HF)containing water vapor.In this work,a novel CaF_(2)absorbent,spherical CaF_(2)nanoaggregates(NAs)with a closely packed structure,was proposed and efficiently fabricated by spray drying technology.As the building blocks of CaF_(2)NAs,the CaF_(2)nanoparticles(NPs)were prepared by the addition of excess calcium ions(Ca^(2+))or fluorine ions(F−)in the synthesis.The results indicated that the CaF_(2)NPs synthesized by excess Ca^(2+)and the corresponding NAs exhibited much better water vapor adsorption properties than their counterparts by excess F−,owing to higher zeta potentials.More importantly,whether excess Ca^(2+)or F^(−),CaF_(2)NAs had further enhanced water vapor adsorption capacity compared to primary CaF_(2)NPs,possibly owing to their unique nano-micro secondary structures and higher surface areas.This work has great potential in the development of high-performance absorbents for separating moisture from corrosive gas HF.
文摘This paper reports the chemical synthesis of tungsten carbide/cobalt (WC/Co) nanocomposite powders via a unique chemical processing technique, involving the using of all water soluble solution of W-, Co- and C-precursors. In the actual synthesis, large quantities of commercial-scale WC-Co nanocomposite powders are made by an unique combination of converting a molecularly mixed W-, Co-, and C-containing solutions into a complex inorganic polymeric powder precursor, conversion of the inorganic polymeric precursor powder into a W-Co-C-O containing powder intermediates using a belt furnace with temperature at about 500°C - 600°C in an inert atmosphere, followed by carburization in a rotary furnace at temperature less than 1000°C in nitrogen. Liquid phase sintering technique is used to consolidate the WC/Co nanocomposite powder into sintered bulk parts. The sintered parts have excellent hardness in excess of 93 HRA, with WC grains in the order of 200 - 300 nm, while Co phase is uniformly distributed on the grain boundaries of the WC nanoparticles. We also report the presence of cobalt Co precipitates inside tungsten carbide WC nanograins in the composites of the consolidated bulk parts. EDS is used to identify the presence of these precipitates and micro-micro-diffraction technique is employed to determine the nature of these precipitates.
基金the National Natural Science Foundation of China (U1703351 and 51663021)the Bingtuan Excellent Young Scholars (CZ027205).
文摘Phenolic-metal complexation coatings have been discovered to be a universal route for the deposition of multifunctional coatings. However, most complexation coatings have been prepared by the immersion method, which limits their practical large-scale application. Herein, we describe a facile and green engineering strategy that involves spraying phenolic compound and metal ions on substrate to form in-situ complexation coating with different coordination states. The coating is formed within minutes and it can be achieved in large scale by the spray method. The pyrogallol-Fem complexation coating is prepared at pH 7.5, which consists predominantly of biscoordination complexation with a small amount of tris-coordination complexation. It displays that the water contact angle is near zero due to the generation of rough hierarchical structures and massive hydroxyl groups. The superhydrophilic cotton resulting from the deposition of the pyrogallol-Fe^Ⅲ complexation can separate oil/water mixtures and surfactant-stabilized oil-in-water emulsions with high separation efficiency. The formation of the phenolic-metal complexation coating by using spray technique constitutes a cost-effective and environmentally friendly, strategy with potential to be applied for large-scale surface engineering processes and green oil/water separation.
基金financially supported by the National Natural Science Foundation of China (21838003, 91834301, 21878092)the Shanghai Scientific and Technological Innovation Project (18JC1410600)+2 种基金the Social Development Program of Shanghai(17DZ1200900, 18DZ2252400)the Innovation Program of Shanghai Municipal Education Commissionthe Fundamental Research Funds for the Central Universities (222201718002)
文摘In this paper,a method composed of gelation of basic skeleton(first step)and skeleton reinforcement process(second step)was introduced to synthesize silica powder with high pore volume through the reaction between water glass and sulfuric acid.No organic solvents were involved in the entire preparation process and the final product was collected by spray drying.The effect of concentration of base solution,gelation point p H value and skeleton reinforcement time on the BET specific surface area and pore volume of the prepared silica powder were investigated intensively.The results show that,a basic skeleton with good dispersibility and high porosity was obtained when the concentration of base solution was 0.1 mol·L^(-1) and the gelation p H value reached 6.5.Then the basic skeleton grew into a more uniform porous structure after 30 min skeleton reinforcement.Under these optimum conditions,silica powder prepared by skeleton reinforcement method had a BET specific surface area of 358.0 m^(2)·g^(-1),and its pore volume reached 2.18 cm^(3)·g^(-1),which was much higher than that of prepared by skeleton-free method(1.62 cm^(3)·g^(-1))and by direct gelation method(0.31 cm^(3)·g^(-1)).
文摘High-speed planing crafts have successfully evolved through developments in the last several decades.Classical approaches such as inviscid potential flow–based methods and the empirically based Savitsky method provide general understanding for practical design.However,sometimes such analyses suffer inaccuracies since the air–water interface effects,especially in the transition phase,are not fully accounted for.Hence,understanding the behaviour at the transition speed is of fundamental importance for the designer.The fluid forces in planing hulls are dominated by phenomena such as flow separation at various discontinuities viz.,knuckles,chines and transom,with resultant spray generation.In such cases,the application of potential theory at high speeds introduces limitations.This paper investigates the simulation of modelling of the pre-planing behaviour with a view to capturing the air–water interface effects,with validations through experiments to compare the drag,dynamic trim and wetted surface area.The paper also brings out the merits of gridding strategies to obtain reliable results especially with regard to spray generation due to the air–water interface effects.The verification and validation studies serve to authenticate the use of the multi-gridding strategies on the basis of comparisons with simulations using model tests.It emerges from the study that overset/chimera grids give better results compared with single unstructured hexahedral grids.Two overset methods are investigated to obtain reliable estimation of the dynamic trim and drag,and their ability to capture the spray resulting from the air–water interaction.The results demonstrate very close simulation of the actual flow kinematics at steady-speed conditions in terms of spray at the air–water interface,drag at the pre-planing and full planing range and dynamic trim angles.
基金The temperature measurements and PIA were supported by Prof.M.Nishioka of University of Tsukuba and Prof.K.Nishino of Yokohama National University,respectively.This work was partially supported by MEXT as"Program for Promoting Researches on the Supercomputer Fu-gaku"(Digital Twins of Real World’s Clean Energy Systems with Inte-grated Utilization of Super-simulation and AI).
文摘Owing to the increasing worldwide demand for natural gas,the development of a large submerged combustion vaporizer is required.Its burner is equipped with a water spray nozzle to reduce nitrogen oxides,and a practi-cal simulation method is required for the optimal design.The non-adiabatic flamelet approach can predict the combustion emissions and is useful for reducing simulation costs.However,as the number of control variables increases,the database requires larger memory and cannot be dealt with by general computers.In this study,an artificial neural network(ANN)model based on a five-dimensional flamelet database,which includes the effects of heat loss and vapor concentration by sprayed water evaporation,is developed.Furthermore,large eddy sim-ulations(LESs)for turbulent combustion fields with and without water spray are conducted employing flamelet generated manifold(FGM)approach with this ANN model,and the validity is investigated.For comparison,a lab-scale burner equipped with a water spray nozzle is manufactured,and combustion experiments with and without water spray are conducted.The results show that CO,NO,temperature,and reaction rate of progress variable predicted by the present ANN model are in good agreement with those of a five-dimensional flamelet database.In the condition without water spray,the flame behavior predicted by the LES employing the FGM/ANN ap-proach is in good agreement with that employing the conventional FGM approach,while indicating much lower memory,although there appeared some quantitative discrepancies in the temperature against the experiment probably partially because of the insufficiency of the FGM approach for the present complex flame structure.In the condition with water spray,the LES employing the FGM/ANN approach is able to capture the effect of the water spray on the flame behavior in the experiment,such that the water spray decreases the temperature,which causes the decrease in NO but increase in CO.
基金This study was supported by the financial support of Natural Science Research Projects in Higher Education Institutions in Jiangsu Province(No.18KJD430002).
文摘To make full use of plant shellfibers(rice husk,walnut shell,chestnut shell),three kinds of wood-plastic com-posites of plant shellfibers and polyvinyl chloride(PVC)were prepared.X-ray diffraction analysis was carried out on three kinds of plant shellfibers to test their crystallinity.The aging process of the composites was conducted under 2 different conditions.One was artificial seawater immersion and xenon lamp irradiation,and the other one was deionized water spray and xenon lamp irradiation.The mechanical properties(tensile strength,flexural strength,impact strength),changes in color,water absorption,Fourier transform infrared spectroscopy(FTIR),and microstructures of the composites before and after the two aging experiments were analyzed.The results showed that the chestnut shell had the highest crystallinity,which was 42%.The chestnut shell/PVC composites had the strongest interface bonding,the least internal defects,and the best general mechanical properties among the three composites.Its tensile strength,bending strength and impact strength were 23.81 MPa,34.12 MPa,and 4.32 KJ·m^(-2),respectively.Comparing the two aging conditions,artificial seawater immersion and xenon lamp irradiation destroyed the quality of the combination of plant shellfibers and PVC,making the internal defects of the composites increase.This made the water absorption ability and changes in the color of the composites more obvious and led to a great decrease in the mechanical properties.The general mechanical properties of the chestnut shell/PVC composites were the best,but their water absorption ability changed more obviously.
基金This work was supported by the Russian Foundation for Basic Research(Grant No.19-29-13016).
文摘The task of studying the process of icing is important due to the operation of large ships and fishing vessels in the seas of the Arctic Ocean.In this paper the ice accretion simulation for fishing vessel has been done at different Reynolds and Froude numbers.A hybrid approach was used for modeling:first,the approach based on Reynolds-averaged Navier-Stokes(RANS)model and volume of fluid(VOF)method with interDyMFoam solver was used for ship modelling in waves,second,RANS model and Euler-Lagrangian approach with iceFoam solver for ice accretion process modelling for ship with hull was applied.The k-ωSST turbulence model with wall functions was used for the RANS model.With the help of the interDyMFoam solver,the position of water jet and liquid droplets in space were determined during the movement of the ship and taking into account the waves in the sea.With the help of iceFoam solver,the process of ice accretion on the surface of the vessel was modeled.The calculations were run for different number Reynolds,Froude.The analysis of mesh convergency was done.The distribution of ice thickness and water film on the ship’s surface is obtained.The simulations were performed on a high-performance cluster in parallel mode.
基金This project was funded in part by State ofWashingtonWater Research Center and USDA National Institute for Food and Agriculture Projects#WNP00745 and WNP0839.Authors would like to acknowledge help of Rajeev Sinha,Haitham Bahlol and Azeem Khan in completion of this study.
文摘This study evaluated corn(Zea mays var.indentata)canopy vigor and temperature variations using small unmanned aerial system(UAS)based spatiotemporal imagery data.The key objective was to develop understanding on site-specific suitability of the Mid Elevation Spray Application(MESA)and Low Elevation Spray Application(LESA)sprinkler systems in irrigating corn crop and potential water as well as energy savings.Aerial data was collected through small UAS flights at 100m height above ground level and on 49,59,65,77,105,114,134 days after planting(DAP).Small UAS had 5-band multispectral and radiometric thermal imager on-board the platform.Custom image processing algorithms were developed to extract various vegetation indices(Normalized difference vegetation index[NDVI],Green NDVI[GNDVI]and Normalized difference red edge[NDRE])and canopy temperature maps from the imagery data.Two sample T-test was performed on extracted data to understand significant difference,at 5%level,within the LESA and MESA treatments.For both the irrigation techniques,the crop vigor increased in the early growth stage(49,65 DAP),peaked in the mid growth stage(77,105,114 DAP)and then decreased in the late growth stage(134 DAP).The MESA irrigated sections had higher vigor(NDVI,GNDVI,NDRE),but not significant,compared to LESA throughout the season.Similarly,the MESA irrigated areas had significantly(0.61–2.07C)cooler canopies than LESA.Such results were anticipated,in part due to the issues with the sprinkler heads used in LESA.The heads were being pulled off in the corn field,causing the weighted hose to damage the crop.A different kind of sprinkler head was used after this incident.However,some strips of corn had already been damaged.Overall,this study results confirm suitability of aerial imagery data in evaluating pertinent irrigation treatments.Additional season’s data would be needed to clearly understand which technique(LESA or MESA)is more suitable for irrigating corn crop in the central part of state of Washington.