Aging Characteristics of Lithium-Ion Battery Under Fast Charging Based on Electrochemical-thermalmechanical Coupling Model

The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.

Evaluation of Serum Anti-Müllerian Hormone (AMH) Values for 28,016 Bulgarian Women: Prognostic Statistical Model of Age Specific AMH Declining

The present study aims to establish a relationship between serum AMH levels and age in a large group of women living in Bulgaria, as well as to establish reference age-specific AMH levels in women that would serve as an initial estimate of ovarian age. A total of 28,016 women on the territory of the Republic of Bulgaria were tested for serum AMH levels with a median age of 37.0 years (interquartile range 32.0 to 41.0). For women aged 20 - 29 years, the Bulgarian population has relatively high median levels of AMH, similar to women of Asian origin. For women aged 30 - 34 years, our results are comparable to those of women living in Western Europe. For women aged 35 - 39 years, our results are comparable to those of women living in the territory of India and Kenya. For women aged 40 - 44 years, our results were lower than those for women from the Western European and Chinese populations, close to the Indian and higher than Korean and Kenya populations, respectively. Our results for women of Bulgarian origin are also comparable to US Latina women at age 30, 35 and 40 ages. On the base on constructed a statistical model to predicting the decline in AMH levels at different ages, we found non-linear structure of AMH decline for the low AMH 3.5) the dependence of the decline of AMH on age was confirmed as linear. In conclusion, we evaluated the serum level of AMH in Bulgarian women and established age-specific AMH percentile reference values based on a large representative sample. We have developed a prognostic statistical model that can facilitate the application of AMH in clinical practice and the prediction of reproductive capacity and population health.

A Hierarchical Modeling Framework for Electrochemical Behaviors in Lithium-Ion Batteries with Detailed Structures

The accurate representation of lithium plating and aging phenomena has posed a persistent challenge within the battery research community.Empirical evidence underscores the pivotal role of cell structure in influencing aging behaviors and lithium plating within lithium-ion batteries(LIBs).Available lithium-ion plating models often falter in detailed description when integrating the structural intricacies.To address this challenge,this study proposes an innovative hierarchical model that intricately incorporates the layered rolling structure in cells.Notably,our model demonstrates a remarkable capacity to predict the non-uniform distribution of current density and overpotential along the rolling direction of LIBs.Subsequently,we delve into an insightful exploration of the structural factors that influence lithium plating behavior,leveraging the foundation laid by our established model.Furthermore,we easily update the hierarchical model by considering aging factors.This aging model effectively anticipates capacity fatigue and lithium plating tendencies across individual layers of LIBs,all while maintaining computational efficiency.In light of our findings,this model yields novel perspectives on capacity fatigue dynamics and local lithium plating behaviors,offering a substantial advancement compared to existing models.This research paves the way for more efficient and tailored LIB design and operation,with broad implications for energy storage technologies.

The effects of population aging on industrial structure upgrading:Empirical analysis of provincial and threshold characteristics in China

Global population aging trends are intensifying,presenting multifaceted economic and social challenges for countries worldwide.As the world’s largest developing country,China has entered a phase of extreme demographic aging,posing significant questions about its impact on the ongoing upgrading of industrial structures.How does this demographic shift influence the upgrading of industrial structures,and does technological innovation mitigate or exacerbate this impact?The empirical results indicate that population aging impedes upgrading the industrial structure,while technological innovation positively affects the relationship between the two.Moreover,using technological innovation as a threshold variable,the impact of population aging on industrial structure upgrading evolves in a“gradient”manner from“impediment”to“insignificant”to“promotion”as the technological innovation levels increase.These findings offer practical guidance for tailoring industrial policies to different stages of technological advancement.

Hopf Bifurcation of Nonresident Computer Virus Model with Age Structure and Two Delays Effects

This paper constructed and studied a nonresident computer virus model with age structure and two delays effects. The non-negativity and boundedness of the solution of the model have been discussed, and then gave the basic regeneration number, and obtained the conditions for the existence and the stability of the virus-free equilibrium and the computer virus equilibrium. Theoretical analysis shows the conditions under which the model undergoes Hopf bifurcation in three different cases. The numerical examples are provided to demonstrate the theoretical results.

Anti-Interference Study on Radiographic Bone Age Estimation Based on Artificial Intelligence Model

In this paper, the interferences of X-ray image noise on a bone age model, Xception model, were studied. We conduct a comparative experiment test according to the output performance of the neural network model using both the original image training and noise-added (Gaussian noise plus salt-pepper noise) training, and analyze the anti-interference ability of the Xception model, hoping to improve it through noise enhancement training and generalize the application ability of the model. The results show that the model trained with noise-added (Gaussian noise plussalt-pepper noise) images can make predictions that are more robust and less affected by the image disturbances, such as image noise.

Effect of pre-deformation on aging creep of Al-Li-S4 alloy and its constitutive modeling

A set of uniaxial tensile creep tests at different pre-deformations, aging temperatures and stress levels were carried out for Al-Li-S4 alloy, and the creep behavior and the effects of pre-deformation on mechanical properties and microstructures were determined under basic thermodynamics conditions of aging forming. The results show that pre-deformation shortens the time of primary creep and raises the second steady-state creep rate. Then, the total creep strain is greater, but in the range of test parameters it is still smaller than that without pre-deformation. In addition, transmission electron microscopy（TEM） observation shows that pre-deformation promotes the formation of T1 phase and θ′ phase and makes them distribute more dispersively, while inhibits the generation of δ′ phase, which leads to the improvement of mechanical properties of the alloy. A unified constitutive model reflecting the effects of aging mechanism, stress levels and different pre-deformations was established. The fitting results agree with the experimental data well.

Development of a modified Mooney-Rivlin constitutive model for rubber to investigate the effects of aging and marine corrosion on seismic isolated bearings

In this study, aging and marine corrosion tests of a large number of rubber material and rubber bearings have been carried out. The constitutive Mooney-Rivlin model parameters for a rubber isolated bearing have been determined. By applying the least-square method to the experimental data, the relationships between the aging time and the marine corrosion time with the constants in the constitutive model for a rubber beating have been derived. Next, the Mooney-Rivlin model has been modified accordingly. Further, using the modified Mooney-Rivlin model and the Abaqus software, the performance of the rubber isolated bearings has been simulated. The simulation results have been compared to the experimental results so as to verify the accuracy of the modified model. The comparison shows that the maximum errors for the vertical and horizontal stiffnesses are 16.8% and 0.49%, respectively. Since these errors are considered acceptable, the accuracy of the modified constitutive model can be considered verified. The results of this study can provide theoretical support for the performance study on rubber isolated bearings under the complex ocean environment and the life-cycle performance evaluation of bridges and other offshore structures.

Modeling of whole process of ageing precipitation and strengthening in Al-Cu-Mg-Ag alloys with high Cu-to-Mg mass ratio

A physically based numerical model to predict the microstructure evolution and yield strength of high Cu-to-Mg mass ratio Al-Cu-Mg-Ag alloys during the whole ageing process was developed.A thermodynamically-based precipitation model,employing the classical nucleation and growth theories,was adapted to deal with the precipitation kinetics (evolution of radius and volume fraction of precipitates for Ω phase) of aged Al-Cu-Mg-Ag alloys.The model gives an estimation of the precipitation kinetics (evolution of radius and density of precipitates for both θ' and Ω phases) of the alloy.The strengthening model based on Orowan mechanism was deduced.The microstructural development and strength predictions of the model are generally in good agreement with the experimental data.

Non-linear creep damage model of sandstone under freeze-thaw cycle

To study rock damage characteristics under long-term freeze-thaw cycles and loads,rock freeze-thaw and creep damage factors were defined based on nuclear magnetic resonance porosity and volume strain,respectively.The damage factor is introduced into the basic rheological element,and the non-linear creep damage constitutive model and freeze-thaw rock equation are established to describe non-linear creep characteristics under a constant load.Simultaneously,the creep test of freeze-thaw rock under step loading is performed.Based on the test data,the applicability and accuracy of the creep damage freeze-thaw rock model are analyzed and verified.The results show that freeze-thaw cycles result in continuous rock pore structure damage and deterioration,and nuclear magnetic resonance porosity enhancement.The constant load induces increasing rock plastic deformation,volume,and creep aging damage.As the loading stress increases,the instantaneous rock elastic parameters increase,and the rheological elastic and viscosity parameters decrease.Furthermore,the damage degradation of freeze-thaw cycles weakens the rock viscoplasticity,resulting in a rapid decrease in the viscosity parameter with an increase in freeze-thaw cycles.Generally,the continuous damage of the rock is degraded,and the long-term strength decreases continuously.

Constitutive modeling and springback prediction of stress relaxation age forming of pre-deformed 2219 aluminum alloy

Stress relaxation ageing behavior of pre-deformed AA2219 is studied through stress relaxation age experiments and finite element(FE) simulation. The results show that the stress can promote the process of ageing precipitation, and shorten the time to reach the peak strength. Meanwhile,the residual stress and yield strength increase along with the increase in the initial stress. Based on microstructure evolution and ageing strengthening theory,a unified constitutive model is established and incorporated into the FE simulation model through a user subroutine. It is found that the relative error of the radius is 3.6% compared with the experimental result and the springback is 16.8%. This indicates that the proposed stress relaxation ageing constitutive model provides a good prediction on the springback of such stiffened panel during its ageing process.

Transverse relaxation characteristic and stress relaxation model considering molecular chains of HTPB coating based on pre-strained thermal aging

In order to accurately describe the transverse relaxation characteristic and stress relaxation modulus of HTPB coating during pre-strain thermal aging process,a one month thermal aging test was carried out at70C with pre-strain of 0%,3%,6%and 9%,respectively.The low-field1 H NMR and stress relaxation modulus tests were carried out for HTPB coating at different aging stages.The stress relaxation model considering the molecular chains was proposed according to the changes of crosslinking chain and dangling chain of HTPB coating during pre-strain aging.The results showed that with the increase of aging time,the decay rate of transverse relaxation curve became faster,the transverse relaxation time decreased,the value of combined parameter q Mrl increased,the proportion of crosslinking chain decreased,while the proportion of dangling chain increased.Moreover,the stress relaxation modulus increased,the crosslinking network structure of HTPB coating became denser and the degree of crosslinking increased.At the initial aging stage,the pre-strain will destroy the crosslinking network structure of HTPB coating to a certain extent.With the increase of aging time,the effect of pre-strain will gradually weaken and the influence of aging on materials will gradually increase.The correlations between the stress relaxation model considering the molecular chains and the test results were more than 0.9950,which can accurately describe the stress relaxation modulus of HTPB coating during the pre-strain thermal aging process.

Parameter fitting of constitutive model and FEM analysis of solder joint thermal cycle reliability for lead-free solder Sn-3.5Ag

The experimental tests of tensile for lead-flee solder Sn-3.5Ag were performed for the general work temperatures range from 11 to 90 ℃ and strain rate range from 5 × 10^-5 to 2 × 10^-2s^-1, and its stress--strain curves were compared to those of solder Sn-37Pb. The parameters in Anand model for solder Sn-3.5Ag were fitted based on experimental data and nonlinear fitting method, and its validity was checked by means of experimental data. Furthermore, the Anand model was used in the FEM analysis to evaluate solder joint thermal cycle reliability. The results show that solder Sn-3.5Ag has a better creep resistance than solder Sn-37Pb. The maximum stress is located at the upper right comer of the outmost solder joint from the symmetric center, and thermal fatigue life is predicted to be 3.796 × 10^4 cycles under the calculated conditions.

Growth simulation and yield prediction for perennial jujube fruit tree by integrating age into the WOFOST model

Mathematical models have been widely employed for the simulation of growth dynamics of annual crops,thereby performing yield prediction,but not for fruit tree species such as jujube tree(Zizyphus jujuba).The objectives of this study were to investigate the potential use of a modified WOFOST model for predicting jujube yield by introducing tree age as a key parameter.The model was established using data collected from dedicated field experiments performed in 2016-2018.Simulated growth dynamics of dry weights of leaves,stems,fruits,total biomass and leaf area index(LAI) agreed well with measured values,showing root mean square error(RMSE) values of 0.143,0.333,0.366,0.624 t ha^-1 and 0.19,and R2 values of 0.947,0.976,0.985,0.986 and 0.95,respectively.Simulated phenological development stages for emergence,anthesis and maturity were 2,3 and 3 days earlier than the observed values,respectively.In addition,in order to predict the yields of trees with different ages,the weight of new organs(initial buds and roots) in each growing season was introduced as the initial total dry weight(TDWI),which was calculated as averaged,fitted and optimized values of trees with the same age.The results showed the evolution of the simulated LAI and yields profiled in response to the changes in TDWI.The modelling performance was significantly improved when it considered TDWI integrated with tree age,showing good global(R2≥0.856,RMSE≤0.68 t ha^-1) and local accuracies(mean R2≥0.43,RMSE≤0.70 t ha^-1).Furthermore,the optimized TDWI exhibited the highest precision,with globally validated R2 of 0.891 and RMSE of 0.591 t ha^-1,and local mean R2 of 0.57 and RMSE of 0.66 t ha^-1,respectively.The proposed model was not only verified with the confidence to accurately predict yields of jujube,but it can also provide a fundamental strategy for simulating the growth of other fruit trees.

Anti-apoptotic treatment in mouse models of age-related hearing loss

Age-related hearing loss (AHL), or presbycusis, is the most common neurodegenerative disorder and top communication deficit of the aged population. Genetic predisposition is one of the major factors in the development of AHL. Generally, AHL is associated with an age-dependent loss of sensory hair cells, spiral ganglion neurons and stria vascularis cells in the inner ear. Although the mechanisms leading to genetic hearing loss are not completely understood, caspase-family proteases function as important signals in the inner ear pathology. It is now accepted that mouse models are the best tools to study the mechanism of genetic hearing loss or AHL. Here, we provide a brief review of recent studies on hearing improvement in mouse models of AHL by anti-apoptotic treatment.

THE PERIODIC SOLUTIONS FOR TIME DEPENDENT AGE-STRUCTURED POPULATION MODELS

In this paper, the existence of periodic solutions for a time dependent age-structured population model is studied. The averaged net reproductive number is introduced as the main parameter to determine the dynamical behaviors of the model. The existence of a global parameterized branch of periodic solutions of the model is obtained by using the contracting mapping theorem in a periodic and continuous function space. The global stability of the trivial equilibrium is studied and a very practical stability criteria for the model is obtained. The dynamics of the linear time-periodic model is similar to that of the linear model.

Cross-linking density and aging constitutive model of HTPB coating under prestrain thermal accelerated aging

In order to study the cross-linking density and aging constitutive relationship of HTPB coating during storage,the thermal accelerated aging tests at 0%,3%,6%and 9%prestrains were carried out.The crosslinking density of HTPB coating at different aging stages were tested using low-field^1 H NMR and the variation of cross-linking density was analyzed.The aging model of cross-linking density considering the chemical aging and the physical stretching factors was established.The uniaxial tensile tests were carried out on HTPB coating at different aging stages and the cross-linking density was introduced into Ogden hyperelastic constitutive model as a characterization parameter of correction coefficient.Combined with uniaxial tensile test results,a prestrain aging constitutive model of HTPB coating was established.The results show that the cross-linking density of HTPB coating increases rapidly at first and then slowly with the increase of thermal accelerated aging time without prestrain.Under prestrain conditions,the crosslinking density of HTPB coating decreases at the early stage,and increases rapidly at first and then slowly at the middle and late stages of thermal accelerated aging.The correlation coefficients of aging model of cross-linking density and aging constitutive model with test results are R>0.9500 and R>0.9900 respectively,which can be used to accurately describe the cross-linking density and aging constitutive relationship of HTPB coating under prestrain accelerated thermal aging conditions.

The Model for Linear Magnetoresistance of Two-Dimensional Metal-Semiconductor Composites with Interfacial Shells

A metal-semiconductor composite with the interracial shells is investigated theoretically for the large linear mag- netoresistance effect of high doping Ag2＋δ Se and Ag2＋δ te materials. The magnetoresistance （MR） of composites is a function of the magnetic field, temperature, the conductivities of two phases without magnetic field, and the thickness and conductivity of the interracial shells. The MR increases with the increase of the magnetic field and with the decrease of temperature, and no saturation is found even under the high magnetic field. Moreover, it is interestingly found that the interracial shell is an important factor for the MR of the composites. The MR increases with the thickness and the conductivity of the interfacial shells. Lastly, the theoretical results on the MR are compared with the experimental data. It is found that the value of the MR of the composite with the interfacial shell is larger than that without the interfacial shell.

Integrating Universal Design Standards and Building Information Modeling at the Conceptual Design Stage of Buildings

A projection of the Canadian population shows that in 2024 one in five Canadians will be over 65 years old. This shift forces designers to consider the entire lifetime of occupants during the design of new buildings. Universal Design (UD), which is a design that accommodates all people to the greatest extent possible and aging in place design that is deeply rooted in the principles of UD, aim to house people irrespective of their age, ability, and chronic health conditions. Building Information Modeling (BIM) significantly helps advance the development of the Architecture, Engineering, and Construction (AEC) industry in a more collaborative and automated way. Integrating BIM and UD allows designers to incorporate UD standards easily and efficiently at the conceptual design stage of buildings by using the functionalities and capabilities of BIM tools. Therefore, this study presents the development of an automated computer model to facilitate the adoption of UD standards and processes. The novelty highlighted in this model resides in the creation of an automated method that employs a newly created plug-in and databases to assist designers to incorporate UD standards at the conceptual stage in a timely and cost-effective manner. Furthermore, the study introduces the methodology consisting of collecting, categorizing, and storing data from various universal design and accessible design guidelines in the developed databases and developing new plug-ins in BIM tool to link the developed databases in order to automate the process of retrieving necessary information and components to help designers and owners select optimal design alternatives based on their predefined criteria.

Genetic Worth Effect Models for Boreal Conifers and Their Utility When Integrated into Density Management Decision-Support Systems

Based on approaches deduced from previous research findings and empirical observations from density control experiments, genetic worth effect response models were developed for black spruce (Picea mariana (Mill) BSP.) and jack pine (Pinus banksiana Lamb.) plantations. The models accounted for the increased rate of stand development arising from the planting of genetically-improved stock through temporal adjustments to the species-specific site-based mean dominant height-age functions. The models utilized a relative height growth modifier based on known estimates of genetic gain. The models also incorporated a phenotypic juvenile age-mature age correlation function in order to account for the intrinsic temporal decline in the magnitude of genetic worth effects throughout the rotation. Integrating the functions into algorithmic variants of structural stand density management models produced stand development patterns that were consistent with axioms of even-aged stand dynamics.