A high luminosity Circular Electron Positron Collider（CEPC） as a Higgs Factory will be helpful for precision measurements of the Higgs mass. The signal-background interference effect is carefully studied for the Hig...A high luminosity Circular Electron Positron Collider（CEPC） as a Higgs Factory will be helpful for precision measurements of the Higgs mass. The signal-background interference effect is carefully studied for the Higgs diphoton decay mode in associated Z boson production at future e^＋e^-colliders at energy 246 GeV. The mass shifts go up from about 20 MeV to 50 MeV for the experimental mass resolution ranging from 0.8 GeV to 2 GeV.展开更多
Inductively coupled plasma mass spectrometry （ICP-MS） is the most commonly used technique to deter- mine the abundances of trace elements in a wide range of geological materials. However, incomplete sample digestion...Inductively coupled plasma mass spectrometry （ICP-MS） is the most commonly used technique to deter- mine the abundances of trace elements in a wide range of geological materials. However, incomplete sample digestion, isobaric interferences and instrumental drift remain obvious problems that must be overcome in order to obtain precise and accurate results, For this reason, we have done many experi- ments and developed a set of simple, cost-effective and practical methods widely applicable for precise and rapid determination of trace element abundances in geological materials using ICP-MS. Commonly used high-pressure digestion technique is indeed effective in decomposing refractory phases, but this inevitably produces fluoride complexes that create new problems. We demonstrate that the fluoride complexes formed during high-pressure digestion can be readily re-dissolved using high-pressure vessel at 190 ℃ for only 2 h for 50 mg sample. In the case of isobaric interferences, although oxide （e.g., MO^＋/M^＋） and hydroxide （e.g., MO^＋/M^＋） productivity is variable between runs, the （MO^＋/M^＋）/（CeO^＋/Ce^＋） and （MOH^＋/M^＋）/（CeO^＋/Ce^＋） ratios remain constant, making isobaric interference correction for all other elements of interest straightforward, for which we provide an easy-to-use off-line procedure. We also show that mass-time-intensity drift curve is smooth as recognized previously, for which the correction can be readily done by analyzing a quality-control （QC） solution and using off-line Excel VBA procedure without internal standards. With these methods, we can produce data in reasonable agreement with rec- ommended values of international rock reference standards with a relative error of 〈8% and precision generally better than 5%. Importantly, compared to the widely used analytical practice, we can effectively save 〉60% of time （e.g., 〈24 h vs. 〉60 h）.展开更多
基金Supported by National Natural Science Foundation of China(11375021,11447018)New Century Excellent Talents in University(NCET)(NCET-13-0030)+1 种基金Major State Basic Research Development Program of China(2015CB856701)Fundamental Research Funds for Central Universities,Education Ministry of LiaoNing Province
文摘A high luminosity Circular Electron Positron Collider（CEPC） as a Higgs Factory will be helpful for precision measurements of the Higgs mass. The signal-background interference effect is carefully studied for the Higgs diphoton decay mode in associated Z boson production at future e^＋e^-colliders at energy 246 GeV. The mass shifts go up from about 20 MeV to 50 MeV for the experimental mass resolution ranging from 0.8 GeV to 2 GeV.
基金supported by National Natural Science Foundation of China(41130314 and 41630968)Chinese Academy of Sciences Innovation Grant(Y42217101L)+1 种基金Qingdao National Laboratory for Marine Science and Technology(2015ASKJ03)Marine Geological Process and Environment(U1606401)
文摘Inductively coupled plasma mass spectrometry （ICP-MS） is the most commonly used technique to deter- mine the abundances of trace elements in a wide range of geological materials. However, incomplete sample digestion, isobaric interferences and instrumental drift remain obvious problems that must be overcome in order to obtain precise and accurate results, For this reason, we have done many experi- ments and developed a set of simple, cost-effective and practical methods widely applicable for precise and rapid determination of trace element abundances in geological materials using ICP-MS. Commonly used high-pressure digestion technique is indeed effective in decomposing refractory phases, but this inevitably produces fluoride complexes that create new problems. We demonstrate that the fluoride complexes formed during high-pressure digestion can be readily re-dissolved using high-pressure vessel at 190 ℃ for only 2 h for 50 mg sample. In the case of isobaric interferences, although oxide （e.g., MO^＋/M^＋） and hydroxide （e.g., MO^＋/M^＋） productivity is variable between runs, the （MO^＋/M^＋）/（CeO^＋/Ce^＋） and （MOH^＋/M^＋）/（CeO^＋/Ce^＋） ratios remain constant, making isobaric interference correction for all other elements of interest straightforward, for which we provide an easy-to-use off-line procedure. We also show that mass-time-intensity drift curve is smooth as recognized previously, for which the correction can be readily done by analyzing a quality-control （QC） solution and using off-line Excel VBA procedure without internal standards. With these methods, we can produce data in reasonable agreement with rec- ommended values of international rock reference standards with a relative error of 〈8% and precision generally better than 5%. Importantly, compared to the widely used analytical practice, we can effectively save 〉60% of time （e.g., 〈24 h vs. 〉60 h）.
