The polymeric surfactant can be used as an efficient agent for enhanced oil recovery(EOR)because of its large bulk viscosity and good interfacial activity.However,there is a sparse understanding of its matching relati...The polymeric surfactant can be used as an efficient agent for enhanced oil recovery(EOR)because of its large bulk viscosity and good interfacial activity.However,there is a sparse understanding of its matching relationship with reservoirs and emulsification occurrence conditions,which may affect its migration and EOR efficiency.One intermolecular association molecule polymeric surfactant(IAM)was synthesized by micellar polymerization and characterized with 1 H NMR,FTIR,and TGA.The matching relationship between IAM and reservoirs was evaluated by comparing the viscosity retention rate of effluent in the core flow experiments.Moreover,the effect of the matching relationship on EOR in the heterogeneous reservoir was clarified with parallel core displacement experiments by considering different flow abilities of IAM in the high-permeability layer.The occurrence conditions of in-situ emulsification of IAM were evaluated via oil-water co-injection experiments under the different injection rates and oil-water ratios.Microscopic visualization displacement was carried out to compare the micro EOR mechanisms of different chemical systems.The results show that IAM features thickening,shearing resistance,viscoelasticity,thermal stability,and interfacial activity.The matching relationship between cores and IAM could be divided as hardly injected,flow limited,and flow smoothly,corresponding to the viscosity retention ratio of<20%,20%-80%,and>80%,respectively.IAM could gain better EOR efficiency(17.69%)when its matching relationship to the high permeability layer was“flow limited”.The defined mixture capillary number shows that only when it is greater than 1×10^(3),the in-situ emulsions can be generated.Compared to HPAM,IAM could reduce IFT and form vortices to more effectively displace film and corner remaining oils by stripping and peeling off crude oil.The formed emulsion accumulated at the pore throat could further increase flow resistance,which benefits swept area enlargement.This work could provide theoretical and data support for the parameters design in the polymeric surfactant practical application.展开更多
Vegetation cover derived from remote sensing image is widely used for soil erosion risk assessment, but there is no clear guideline to select the most appropriate temporal satellite data. It is common practice that sa...Vegetation cover derived from remote sensing image is widely used for soil erosion risk assessment, but there is no clear guideline to select the most appropriate temporal satellite data. It is common practice that satellite data during growing season are randomly selected and used in soil erosion risk assessment. However, the effectiveness of vegetation in protecting the soil is quite different even if it is the same growing season since vegetation covers change as they grow. This article aims to provide a method of choosing optimal vegetation cover for studying soil erosion risk using remote sensing, that is, the vegetation cover in the most appropriate temporal period. Based on the temporal relationship of the two most active impact factors, rainfall and vegetation, an index of RV is developed and used to indicate the relative erosion risk during the year. The results show that annual variation of rainfall is significant, and vegetation is relatively stable, resulting in their matching relationship is different in each year. The correlation coefficient reaches 0.89 between RV and real sediment transport during the period when rainfall can cause soil erosion. In other words, RV is a good indicator of soil erosion. Therefore, there is a good correlation between RV maximum and the optimal vegetation cover, which can help facilitate erosion research in the future, showing good potential for successful application in other places.展开更多
The technology of cold pressure welding was adopted to achieve the bonding of Al/Cu(limited soluble and forming compounds), Ag/Ni (hardly mutual soluble), and the relative state of interface was tested by HREM. The re...The technology of cold pressure welding was adopted to achieve the bonding of Al/Cu(limited soluble and forming compounds), Ag/Ni (hardly mutual soluble), and the relative state of interface was tested by HREM. The results indicate that stable interface is always corresponding to the low interfacial energy value; the stable interface is not coherent but partly-coherent because of the twisting of grain boundary caused by pressure, meanwhile existing dislocation. Namely, the interfacial match and other states under the condition of cold pressure welding are different from the situation that under the condition of thermal action. Moreover, theoretical analyses and calculation on the base of thermodynamics, crystallogeny, solid physics etc, were discussed.展开更多
基金The work was supported by the National Natural Science Foundation of China(Grant 52074318)the Science Foundation of China University of Petroleum,Beijing(No.2462022BJRC005)+2 种基金Ningbo 2025 Project(2019B10138)the China Scholarship Council(No.202106440061)China University of Petroleum,Beijing,and the University of Alberta.
文摘The polymeric surfactant can be used as an efficient agent for enhanced oil recovery(EOR)because of its large bulk viscosity and good interfacial activity.However,there is a sparse understanding of its matching relationship with reservoirs and emulsification occurrence conditions,which may affect its migration and EOR efficiency.One intermolecular association molecule polymeric surfactant(IAM)was synthesized by micellar polymerization and characterized with 1 H NMR,FTIR,and TGA.The matching relationship between IAM and reservoirs was evaluated by comparing the viscosity retention rate of effluent in the core flow experiments.Moreover,the effect of the matching relationship on EOR in the heterogeneous reservoir was clarified with parallel core displacement experiments by considering different flow abilities of IAM in the high-permeability layer.The occurrence conditions of in-situ emulsification of IAM were evaluated via oil-water co-injection experiments under the different injection rates and oil-water ratios.Microscopic visualization displacement was carried out to compare the micro EOR mechanisms of different chemical systems.The results show that IAM features thickening,shearing resistance,viscoelasticity,thermal stability,and interfacial activity.The matching relationship between cores and IAM could be divided as hardly injected,flow limited,and flow smoothly,corresponding to the viscosity retention ratio of<20%,20%-80%,and>80%,respectively.IAM could gain better EOR efficiency(17.69%)when its matching relationship to the high permeability layer was“flow limited”.The defined mixture capillary number shows that only when it is greater than 1×10^(3),the in-situ emulsions can be generated.Compared to HPAM,IAM could reduce IFT and form vortices to more effectively displace film and corner remaining oils by stripping and peeling off crude oil.The formed emulsion accumulated at the pore throat could further increase flow resistance,which benefits swept area enlargement.This work could provide theoretical and data support for the parameters design in the polymeric surfactant practical application.
文摘Vegetation cover derived from remote sensing image is widely used for soil erosion risk assessment, but there is no clear guideline to select the most appropriate temporal satellite data. It is common practice that satellite data during growing season are randomly selected and used in soil erosion risk assessment. However, the effectiveness of vegetation in protecting the soil is quite different even if it is the same growing season since vegetation covers change as they grow. This article aims to provide a method of choosing optimal vegetation cover for studying soil erosion risk using remote sensing, that is, the vegetation cover in the most appropriate temporal period. Based on the temporal relationship of the two most active impact factors, rainfall and vegetation, an index of RV is developed and used to indicate the relative erosion risk during the year. The results show that annual variation of rainfall is significant, and vegetation is relatively stable, resulting in their matching relationship is different in each year. The correlation coefficient reaches 0.89 between RV and real sediment transport during the period when rainfall can cause soil erosion. In other words, RV is a good indicator of soil erosion. Therefore, there is a good correlation between RV maximum and the optimal vegetation cover, which can help facilitate erosion research in the future, showing good potential for successful application in other places.
文摘The technology of cold pressure welding was adopted to achieve the bonding of Al/Cu(limited soluble and forming compounds), Ag/Ni (hardly mutual soluble), and the relative state of interface was tested by HREM. The results indicate that stable interface is always corresponding to the low interfacial energy value; the stable interface is not coherent but partly-coherent because of the twisting of grain boundary caused by pressure, meanwhile existing dislocation. Namely, the interfacial match and other states under the condition of cold pressure welding are different from the situation that under the condition of thermal action. Moreover, theoretical analyses and calculation on the base of thermodynamics, crystallogeny, solid physics etc, were discussed.
