Electrospun ZnSnO_(3)/PVDF‑HFP Nanofibrous Triboelectric Films for Efficient Mechanical Energy Harvesting

Nowadays,triboelectric nanogenerators(TENGs)are one of the most emerging technologies owing to their easy and costeffective device structure.TENGs can harvest mechanical energy from our living environment.Herein,we synthesized dielectric zinc tin oxide(ZnSnO_(3))nanoparticles(NPs)by a hydrothermal technique.The ZnSnO_(3)NPs provide a dielectric and piezoelectric effect,which can efficiently enhance the output electrical performance of the proposed TENG.The prepared ZnSnO_(3)NPs were embedded into a polyvinylidene fluoride hexafluoropropylene(PVDF-HFP)polymer to prepare ZnSnO_(3)/PVDF-HFP nanofibrous films to fabricate a TENG.The output performance of TENG was investigated and optimized by varying the loading concentration of ZnSnO_(3)NPs in PVDF-HFP fibrous films.The highest voltage,current,charge density,and power density from the fabricated TENG were achieved as~138 V,~5μA,~52μC/m2,and~1.6 W/m2,respectively.Additionally,the robustness of the TENG was studied via the long-term mechanical stability test.Finally,the practical and real-time application of the TENG was demonstrated by harvesting mechanical energy to power low-power portable electronic devices.Furthermore,the materials used in the TENG were combined into a skipping rope to harvest biomechanical/mechanical energy while exercising.

Performances of a Stinger PDC cutter breaking granite: Cutting force and mechanical specific energy in single cutter tests

The Stinger PDC cutter has high rock-breaking efficiency and excellent impact and wear resistance, which can significantly increase the rate of penetration (ROP) and extend PDC bit life for drilling hard and abrasive formation. The knowledge of force response and mechanical specific energy (MSE) for the Stinger PDC cutter is of great importance for improving the cutter's performance and optimizing the hybrid PDC bit design. In this paper, 87 single cutter tests were conducted on the granite. A new method for precisely obtaining the rock broken volume was proposed. The influences of cutting depth, cutting angle, and cutting speed on cutting force and MSE were analyzed. Besides, a phenomenological cutting force model of the Stinger PDC cutter was established by regression of experimental data. Moreover, the surface topography and fracture morphology of the cutting groove and large size cuttings were measured by a 3D profilometer and a scanning electron microscope (SEM). Finally, the rock-breaking mechanism of the Stinger PDC cutter was illustrated. The results indicated that the cutting depth has the greatest influence on the cutting force and MSE, while the cutting speed has no obvious effects, especially at low cutting speeds. As the increase of cutting depth, the cutting force increases linearly, and MSE reduces with a quadratic polynomial relationship. When the cutting angle raises from 10° to 30°, the cutting force increases linearly, and the MSE firstly decreases and then increases. The optimal cutting angle for breaking rock is approximately 20°. The Stinger PDC cutter breaks granite mainly by high concentrated point loading and tensile failure, which can observably improve the rock breaking efficiency. The key findings of this work will help to reveal the rock-breaking mechanisms and optimize the cutter arrangement for the Stinger PDC cutter.

A novel improvement strategy and a comprehensive mechanism insight for α-MnO_(2) energy storage in rechargeable aqueous zinc-ion batteries

Aqueous zinc-ion batteries have been regarded as the most potential candidate to substitute lithium-ion batteries.However,many serious challenges such as suppressing zinc dendrite growth and undesirable reactions,and achieving fully accepted mechanism also have not been solved.Herein,the commensal composite microspheres withα-MnO_(2) nano-wires and carbon nanotubes were achieved and could effectively suppress ZnSO_(4)·3Zn(OH)_(2)·nH_(2)O rampant crystallization.The electrode assembled with the microspheres delivered a high initial capacity at a current density of 0.05 A g^(-1) and maintained a significantly prominent capacity retention of 88%over 2500 cycles.Furthermore,a novel energy-storage mechanism,in which multivalent manganese oxides play a synergistic effect,was comprehen-sively investigated by the quantitative and qualitative analysis for ZnSO_(4)·3Zn(OH)_(2)·nH_(2)O.The capacity contribution of multivalent manganese oxides and the crystal structure dissection in the transformed processes were completely identified.Therefore,our research could provide a novel strategy for designing improved electrode structure and a comprehensive understanding of the energy storage mechanism of α-MnO_(2) cathodes.

The calculation of mechanical energy loss for incompressible steady pipe flow of homogeneous fluid

The calculation of the mechanical energy loss is one of the fundamental problems in the field of Hydraulics and Engineering Fluid Mechanics. However, for a non-uniform flow the relation between the mechanical energy loss in a volume of fluid and the kinematical and dynamical characteristics of the flow field is not clearly established. In this paper a new mechanical energy equation for the incompressible steady non-uniform pipe flow of homogeneous fluid is derived, which includes the variation of the mean turbulent kinetic energy, and the formula for the calculation of the mechanical energy transformation loss for the non-uniform flow between two cross sections is obtained based on this equation. This formula can be simplified to the Darcy-Weisbach formula for the uniform flow as widely used in Hydraulics. Furthermore, the contributions of the mechanical energy loss relative to the time averaged velocity gradient and the dissipation of the turbulent kinetic energy in the turbulent uniform pipe flow are discussed, and the contributions of the mechanical energy loss in the viscous sublayer, the buffer layer and the region above the buffer layer for the turbulent uniform flow are also analyzed.

The mechanical energy equation for total flow in open channels

The mechanical energy equation is a fundamental equation of a 1-D mathematical model in Hydraulics and Engineering Fluid Mechanics. This equation for the total flow used to be deduced by extending the Bernoulli＇s equation for the ideal fluid in the streamline to a stream tube, and then revised by considering the viscous effect and integrated on the cross section. This derivation is not rigorous and the effect of turbulence is not considered. In this paper, the energy equation for the total flow is derived by using the Navier-Stokes equations in Fluid Mechanics, the results are as follows：（1） A new energy equation for steady channel flows of incompressible homogeneous liquid is obtained, which includes the variation of the turbulent kinetic energy along the channel, the formula for the mechanical energy loss of the total flow can be determined directly in the deduction process.（2） The theoretical solution of the velocity field for laminar flows in a rectangular open channel is obtained and the mechanical energy loss in the energy equation is calculated. The variations of the coefficient of the mechanical energy loss against the Reynolds number and the width-depth ratio are obtained.（3） The turbulent flow in a rectangular open channel is simulated using 3-D Reynolds averaged equations closed by the Reynolds stress model（RSM）, and the variations of the coefficient of the mechanical energy loss against the Reynolds number and the width-depth ratio are discussed.

Theoretical analysis and numerical simulation of mechanical energy loss and wall resistance of steady open channel flow

The mechanical energy loss and the wall resistance are very important in practical engineering. These problems are investigated through theoretical analysis and numerical simulation in this paper, The results are as follows. （1） A new mechanical energy equation for the total flow is obtained, and a general formula for the calculation of the mechanical energy loss is proposed. （2） The general relationship between the wall resistance and the mechanical energy loss for the steady channel flow is obtained, the simplified form of which for the steady uniform channel flow is in consistent with the formula used in Hydraulics deduced by 7r theorem and dimensional analysis. （3） The steady channel flow over a backward facing step with a small expansion ratio is numerica- lly simulated, and the mechanical energy loss, the wall resistance as well as the relationship between the wall resistance and the mechanical energy loss are calculated and analyzed.

Mechanical Energy and Kinematics of Double Poling Technique Performed at Different Inclines by World-Level Cross-Country Skiers During World Cup Races

Purpose To analyze the inter-limb coordination patterns and energy recovery of elite cross-country skiers performing double poling(DP).Methods Thirty-three elite athletes in three track sections of FIS-WC races,with different slopes(2°,0°and−1.5°).Stereo vision capture system(50 Hz cameras)and 3D analysis were used to extract:kinematic parameters(center of gravity,veloc-ity);joint angles and angular velocities;energy(potential and kinetic)and energy recovery indices R% and R(t)during the entire DP cycle and within poling(R_(pol))and swing phase(R_(swi)).Results Average race velocity of the centre of gravity(V_(ave))significantly varied according to slopes(5.4,7.3 and 8.3 m/s).This correlated with differences in the angular velocities of the most relevant joints.Elbow flexion angular velocity in the early portion of poling phase was higher according to the slope variations(−137,−171 and−202 deg/s,for the slopes 2°,0°and−1.5°,respectively),indicating the possible modulation of muscular stretch shortening cycle(SSC).A similar trend was observed for shoulder angular velocity which increased during poling phase,and for knee extension velocity during swing phase,and for knee extension velocity during swing phase.R%decreased significantly for the−1.5°slope(32%and 24%vs.15%);R(t)was higher for the Rswi.Significant differences were observed in trunk-elbow,trunk-shoulder,trunk-knee and elbow-shoulder patterns for the−1.5°slope with respect to the others.Conclusions Despite the modest variation of the track’s slope,the effects on propulsion and recovery strategies were different.

Preface for Special Issue on“Key Mechanical Problems of Marine Energy Development Equipment”

There are abundant energy reserves such as oil,natural gas,hydrate,and wind energy in the ocean.Countries around the globe are competing to advance their marine energy development technologies.The exploitation of marine resources relies on cutting-edge industrial equipment.After decades of R&D endeavors,China has obtained most of the key technologies for the design,production,testing,and field application of marine energy development equipment(Xie and Zeng,2021).

Methylene blue intercalated vanadium oxide with synergistic energy storage mechanism for highly efficient aqueous zinc ion batteries

With the rise of aqueous multivalent rechargeable batteries,inorganic-organic hybrid cathodes have attracted more and more attention due to the complement of each other’s advantages.Herein,a strategy of designing hybrid cathode is adopted for high efficient aqueous zinc-ion batteries(AZIBs).Methylene blue(MB)intercalated vanadium oxide(HVO-MB)was synthesized through sol-gel and ion exchange method.Compared with other organic-inorganic intercalation cathode,not only can the MB intercalation enlarge the HVO interlayer spacing to improve ion mobility,but also provide coordination reactions with the Zn^(2+)to enhance the intrinsic electrochemical reaction kinetics of the hybrid electrode.As a key component for the cathode of AZIBs,HVO-MB contributes a specific capacity of 418 mA h g^(-1) at 0.1 A g^(-1),high rate capability(243 mA h g^(-1) at 5 A g^(-1))and extraordinary stability(88%of capacity retention after 2000cycles at a high current density of 5 A g^(-1))in 3 M Zn(CF_(3)SO_(3))_(2) aqueous electrolyte.The electrochemical kinetics reveals HVO-MB characterized with large pseudocapacitance charge storage behavior due to the fast ion migration provided by the coordination reaction and expanded interlayer distance.Furthermore,a mixed energy storage mechanism involving Zn^(2+)insertion and coordination reaction is confirmed by various ex-situ characterization.Thus,this work opens up a new path for constructing the high performance cathode of AZIBs through organic-inorganic hybridization.

Tiêu Equation Experimentation of Understanding by Energy Transfer Quantum Mechanics

Background: The Tiêu equation has a ground roots approach to the process of Quantum Biology and goes deeper through the incorporation of Quantum Mechanics. The process can be measured in plant, animal, and human usage through a variety of experimental or testing forms. Animal studies were conducted for which, in the first day of the study all the animals consistently gained dramatic weight, even as a toxic substance was introduced as described in the introduction of the paper to harm animal subjects which induced weight loss through toxicity. Tests can be made by incorporating blood report results. Human patients were also observed to show improvement to their health as administration of the substance was introduced to the biological mechanism and plants were initially exposed to the substance to observe results. This is consistent with the Tiêu equation which provides that wave function is created as the introduction of the substance to the biological mechanism which supports Quantum Mechanics. The Tiêu equation demonstrates that Quantum Mechanics moves a particle by temperature producing energy thru the blood-brain barrier for example. Methods: The methods for the Tiêu equation incorporate animal studies to include the substance administered through laboratory standards using Good Laboratory Practices under Title 40 C.F.R. § 158. Human patients were treated with the substance by medical professionals who are experts in their field and have knowledge to the response of patients. Plant applications were acquired for observation and guidance of ongoing experiments of animals’ representative for the biologics mechanism. Results: The animal studies along with patient blood testing results have been an impressive line that has followed the Tiêu equation to consistently show improvement in the introduction of the innovation to biologic mechanisms. The mechanism responds to the substance by producing energy to the mechanism with efficient effect. For plant observations, plant organisms responded, and were seen as showing improvement thru visual observation.

Piezoionics:Mechanical-to-ionic transduction for sensing,biointerface,and energy harvesting

Piezoionic materials consisting of a polymer matrix and mobile ions can produce an electrical output upon an applied pressure inducing an ion concentration gradient.Distinct from charges generated by the piezoelectric or triboelectric effects,the use of generated mobile ions to carry a signal closely resembles many ionic biological processes.Due to this similarity to biology,the piezoionic effect has great potential to enable seamless integration with biological systems,which accelerates the advancement of medical devices and personalized medicine.In this review,a comprehensive description of the piezoionic mechanism,methods,and applications are presented,with the aim to facilitate a dialogue among relevant scientific communities.First,the piezoionic effect is briefly introduced,then the development of mechanistic understanding over time is surveyed.Next,different types of piezoionic materials are reviewed and methods to enhance the piezoionic output via materials properties,electrode interfaces,and device architectures are detailed.Finally,applications,challenges,and outlooks are provided.With its novel properties,piezoionics is expected to play a key role in the overcoming of grand challenges in the areas of sensing,biointerfaces,and energy harvesting.

Revealing the role of calcium ion intercalation of hydrated vanadium oxides for aqueous zinc-ion batteries

Exploring suitable high-capacity V_(2)O_(5)-based cathode materials is essential for the rapid advancement of aqueous zinc ion batteries(ZIBs).However,the typical problem of slow Zn^(2+)diffusion kinetics has severely limited the feasibility of such materials.In this work,unique hydrated vanadates(CaVO,BaVO)were obtained by intercalation of Ca^(2+)or Ba^(2+)into hydrated vanadium pentoxide.In the CaVO//Zn and BaVO//Zn batteries systems,the former delivered up to a 489.8 mAh g^(-1)discharge specific capacity at 0.1 A g^(-1).Moreover,the remarkable energy density of 370.07 Wh kg^(-1)and favorable cycling stability yard outperform BaVO,pure V_(2)O_(5),and many reported cathodes of similar ionic intercalation compounds.In addition,pseudocapacitance analysis,galvanostatic intermittent titration(GITT)tests,and Trasatti analysis revealed the high capacitance contribution and Zn^(2+)diffusion coefficient of CaVO,while an in-depth investigation based on EIS elucidated the reasons for the better electrochemical performance of CaVO.Notably,ex-situ XRD,XPS,and TEM tests further demonstrated the Zn^(2+)insertion/extraction and Zn-storage mechanism that occurred during the cycle in the CaVO//Zn battery system.This work provides new insights into the intercalation of similar divalent cations in vanadium oxides and offers new solutions for designing cathodes for high-capacity aqueous ZIBs.

The design and engineering strategies of metal tellurides for advanced metal-ion batteries

Owning various crystal structures and high theoretical capacity,metal tellurides are emerging as promising electrode materials for high-performance metal-ion batteries(MBs).Since metal telluride-based MBs are quite new,fundamental issues raise regarding the energy storage mechanism and other aspects affecting electrochemical performance.Severe volume expansion,low intrinsic conductivity and slow ion diffusion kinetics jeopardize the performance of metal tellurides,so that rational design and engineering are crucial to circumvent these disadvantages.Herein,this review provides an in-depth discussion of recent investigations and progresses of metal tellurides,beginning with a critical discussion on the energy storage mechanisms of metal tellurides in various MBs.In the following,recent design and engineering strategies of metal tellurides,including morphology engineering,compositing,defect engineering and heterostructure construction,for high-performance MBs are summarized.The primary focus is to present a comprehensive understanding of the structural evolution based on the mechanism and corresponding effects of dimension control,composition,electron configuration and structural complexity on the electrochemical performance.In closing,outlooks and prospects for future development of metal tellurides are proposed.This work also highlights the promising directions of design and engineering strategies of metal tellurides with high performance and low cost.

Energy evolution mechanism and failure criteria of jointed surrounding rock under uniaxial compression

The object of this article is to investigate the energy evolution mechanism and failure criteria of cross-jointed samples containing an opening during deformation and failure based on the uniaxial compression test and rock energy principle.The results show that the energy evolution characteristics of the samples correspond to a typical progressive damage mode.The peak total energy,peak elastic energy,and total input energy of the samples all first decrease and then increase with an increase of half of the included angle,reaching their minimum values when this angle is 45°,while the dissipated energy generally increases with this angle.The existence of the opening and cross joints can obviously weaken the energy storage capacity of the rock,and the change in the included angle of the cross joint has a great influence on the elastic energy ratio of the sample before the peak stress,which leads to some differences in the distribution laws of the input energy.The continuous change and the subsequent sharp change in the rate of change in the energy consumption ratio can be used as the criteria of the crack initiation and propagation and the unstable failure of the sample,respectively.

Recent advances in energy storage mechanism of aqueous zinc-ion batteries

Aqueous rechargeable zinc-ion batteries(ZIBs)have recently attracted increasing research interest due to their unparalleled safety,fantastic cost competitiveness and promising capacity advantages compared with the commercial lithium ion batteries.However,the disputed energy storage mechanism has been a confusing issue restraining the development of ZIBs.Although a lot of efforts have been dedicated to the exploration in battery chemistry,a comprehensive review that focuses on summarizing the energy storage mechanisms of ZIBs is needed.Herein,the energy storage mechanisms of aqueous rechargeable ZIBs are systematically reviewed in detail and summarized as four types,which are traditional Zn^(2+)insertion chemistry,dual ions co-insertion,chemical conversion reaction and coordination reaction of Zn^(2+)with organic cathodes.Furthermore,the promising exploration directions and rational prospects are also proposed in this review.

Experimental investigation on the energy evolution of dry and water-saturated red sandstones

In order to investigate the effect of water content on the energy evolution of red sandstone, the axial loading–unloading experiments on dry and water-saturated sandstone samples were conducted, and the distribution and evolution of elastic energy and dissipated energy within the rock were measured.The results show that the saturation process from dry to fully-saturated states reduces the strength, rigidity and brittleness of the rock by 30.2%, 25.5% and 16.7%, respectively. The water-saturated sample has larger irreversible deformation in the pre-peak stage and smaller stress drop in the post-peak stage.The saturation process decreases the accumulation energy limit by 38.9%, but increases the dissipated energy and residual elastic energy density, thus greatly reducing the magnitude and rate of energy release. The water-saturated sample has lower conversion efficiency to elastic energy by 3% in the prepeak region; moreover, the elastic energy ratio falls with a smaller range in the post-peak stage.Therefore, saturation process can greatly reduce the risk of dynamic disaster, and heterogeneous water content can lead to dynamic disaster possibly on the other hand.

Instability energy mechanism of super-large section crossing chambers in deep coal mines

The stress concentration and failure at chamber intersections in coal mine are intense,especially in deepburied,super-large section conditions.In this paper,the plastic radius of super-large section chamber under unequal pressure was corrected on the basis of the size effect.Then,stress and failure evolution of intersections under different crossing angles and equivalent angular bisectors were revealed.Furthermore,2 trajectory curves of failure and stress were analytically expressed,which divided the intersection into 5 influencing zones in the light of stress superposition degree.After determining instability trigger point and instability path,instability energy criterion of intersection can be obtained as K>1,which means that the external energy is greater than the sum of energy consumed by surrounding rock instability and supporting structure failure.Taking coal-gangue separation system of Longgu Coal Mine as example,it was found that there was instability risk under original parameters.For long-term stability,an optimization design method was proposed by considering safety factor,and optimal support scheme was obtained.Field monitoring showed intersections deformations were relatively small with the maximum of 125 mm,which verified the rationality of theoretical analysis.This study provides guidance for the stability control of the intersections under the same or similar conditions.

CFD Simulation and Experimental Study of a New Elastic Blade Wave Energy Converter

Small moving vehicles represent an important category of marine engineering tools and devices(equipment)typically used for ocean resource detection and maintenance of marine rights and interests.The lack of efficient power supply modes is one of the technical bottlenecks restricting the effective utilisation of this type of equipment.In this work,the performance characteristics of a new type of elastic-blade/wave-energy converter(EBWEC)and its core energy conversion component(named wave energy absorber)are comprehensively studied.In particular,computational fluid dynamics(CFD)simulations and experiments have been used to analyze the hydrodynamics and performance characteristics of the EBWEC.The pressure cloud diagrams relating to the surface of the elastic blade were obtained through two-way fluid-solid coupling simulations.The influence of blade thickness and relative speed on the performance characteristics of EBWEC was analyzed accordingly.A prototype of the EBWEC and its bucket test platform were also developed.The power characteristics of the EBWEC were analyzed and studied by using the blade thickness and motion cycle as control variables.The present research shows that the EBWEC can effectively overcome the performance disadvantages related to the transmission shaft torque load and power curve fluctuations of rigid blade wave energy converters(RBWEC).

A comprehensive review of miniatured wind energy harvesters

Following the current rapid development of the Internet of Things(IoT)and wireless condition monitoring systems,energy harvesters which use ambient energy have become a key part of achieving an energy-autonomous system.Miniature wind energy harvesters have attracted widespread attention because of their great potential of power density as well as the rich availability of wind energy in many possible areas of application.This article provides readers with a glimpse into the state-of-the-art of miniature wind energy harvesters.The crucial factors for them to achieve high working efficiency under lower operational wind speed excitation are analyzed.Various potential energy coupling mechanisms are discussed in detail.Design approaches for broadening operational wind-speed-range given a variety of energy coupling mechanisms are also presented,as observed in the literature.Performance enhancement mechanisms including hydrodynamic configuration optimization,and non-linear vibration pick-up structure are reviewed.Conclusions are drawn and the outlook for each coupling mechanisms is presented.

Study on Nano-structured WC-Co Composite Powders Made by Mechanical Milling

Nano structured WC Co composite powders were prepared by high energy mechanical milling. The microstructure of as milled WC Co composite powders (including grain size, lattice strain, Co distribution and lattice defects) was investigated by X ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and energy dispersive X ray spectroscopy (EDS). Nano structured WC co vered and separated by cobalt thin layers with average grain size less than 10 nm was obtained by high energy mechanical milling. The morphology of WC grains is almost spherical. High energy mechanical milling could also bring about a large number of lattice defects in WC grains.