CW-CO2 laser nitriding technique was applied to improve the properties (such as aging property and the core loss) of grain oriented silicon steel. The samples were nitrided with regular space. Laser power density an...CW-CO2 laser nitriding technique was applied to improve the properties (such as aging property and the core loss) of grain oriented silicon steel. The samples were nitrided with regular space. Laser power density and scanning speed were chosen as 7.8×10^5W·cm^-2 and 100mm·min^-1. By some laser irradiation, Fe4N and Fe3N were formed in the nitrided zone. The nitrided samples were annealed at the temperatures ranged from 100 to 90℃. The core loss of some interested samples was tested. The results show that the core loss of the nitrided samples with different thickness of 0.23 and 0.30mm decreased by 14.9% and 9.4% respectively, and the aging property were improved up to 800℃. The mechanism of laser nitriding to improve the properties of grain oriented silicon steel is discussed.展开更多
Piezoelectric ceramics of 0.6(Bi0.9La0.1)FeO3-0.4Pb(Ti1-xMnx)O3 (BLF-PTM) for x=0, 0.01, 0.02, and 0.03 were prepared by sol-gel process combined with a solid-state reaction method. The tan? for BLF-PTM of x=0.01 is j...Piezoelectric ceramics of 0.6(Bi0.9La0.1)FeO3-0.4Pb(Ti1-xMnx)O3 (BLF-PTM) for x=0, 0.01, 0.02, and 0.03 were prepared by sol-gel process combined with a solid-state reaction method. The tan? for BLF-PTM of x=0.01 is just 0.006 at 1 kHz, drastically decreasing by using Mn dopants. The TC increases to 490 ℃ for BLF-PTM of x=0.02. Furthermore, Mn modification effectively enhances the poling state and the piezoelectric properties of BLF-PTM. The kp, Qm, d33, and g33 of 0.34, 403, and 124 pC1·N-1 and 37×10-3 Vm·N-1 are achieved for BLF-PTM of x=0.01. The results indicate that Mn modified BLF-PTM is a competitive high power and high temperature piezoelectric material with excellent piezoelectric properties.展开更多
Effect of the content of dopants in the manganese-zinc ferrites on the low power loss is studied by measuring magnetic properties and observing the grain boundary structures. The Mn0.738Zn0.206Fe2.066O4 composition po...Effect of the content of dopants in the manganese-zinc ferrites on the low power loss is studied by measuring magnetic properties and observing the grain boundary structures. The Mn0.738Zn0.206Fe2.066O4 composition powders were prepared by using conventional ceramic powder processing technique. The microstructure of grain boundary was observed by scanning electron microscope (SEM). It has been found that power loss is greatly dependent upon the content of the additives.展开更多
To fully release the potential of wide bandgap(WBG)semiconductors and achieve high energy density and efficiency,a carbonyl iron soft magnetic composite(SMC)with an easy plane-like structure is prepared.Due to this st...To fully release the potential of wide bandgap(WBG)semiconductors and achieve high energy density and efficiency,a carbonyl iron soft magnetic composite(SMC)with an easy plane-like structure is prepared.Due to this structure,the permeability of the composite increases by 3 times(from 7.5 to 21.5)at 100 MHz compared with to the spherical carbonyl iron SMC,and the permeability changes little at frequencies below 100 MHz.In addition,the natural resonance frequency of the composite shifts to higher frequencies at 1.7 GHz.The total core losses of the composites at 10,20,and 30 m T are80.0,355.3,and 810.7 m W/cm^(3),respectively,at 500 k Hz.Compared with the spherical carbonyl iron SMC,the core loss at500 k Hz is reduced by more than 60%.Therefore,this kind of soft magnetic composite with an easy plane-like structure is a good candidate for unlocking the potential of WBG semiconductors and developing the next-generation power electronics.展开更多
The dependences of the power loss per cycle on frequency f and amplitude flux density Bm have been investigated for the three main original magnetic states in five sorts of Fe-based nanocrystalline soft magnetic alloy...The dependences of the power loss per cycle on frequency f and amplitude flux density Bm have been investigated for the three main original magnetic states in five sorts of Fe-based nanocrystalline soft magnetic alloys in the ranges of 10 Hz<=f<=1000 Hz and 0.4 T<= Bm <=1.0 T. The total loss P is decomposed into the sum of the hysteresis loss Physt, the classical eddy current loss Pel and the excess loss Pexc. Physt has been found to be proportional to Bm^2 and f. The behavior of Pexc/f vs f being equivalent to P/f vs f clearly exhibits nonlinearity in the range not more than about 120 Hz, whereas the behavior of P/f vs f roughly shows linearity in the range far above 100 Hz and not more than 1000 Hz. In the range up to 1000 Hz, Physt is dominant in the original high permeability state and the state of low residual flux density, whereas Pexc in the state of high residual flux density is dominant in the wider range above about 100 Hz. The framework of the statistical theory of power loss has been used for representing the behavior of Pexc/f vs f. It has been found that the number n of the simultaneously active 'Magnetic Objects' linearly varies as n = n0 + Hexc/H0 as a function of the dynamic field Hexc in the range below about 120 Hz, whereas n approximately follows a law of the form n = n0 + (Hexc/H0)^m with 1 < m < 2 in the range far above 100 Hz and not more than 1000 Hz. The values of the field HO in principle related to the microstructure and the domain structure have been calculated for the three states.展开更多
Deep learning techniques have significantly improved image restoration tasks in recent years.As a crucial compo-nent of deep learning,the loss function plays a key role in network optimization and performance enhancem...Deep learning techniques have significantly improved image restoration tasks in recent years.As a crucial compo-nent of deep learning,the loss function plays a key role in network optimization and performance enhancement.However,the currently prevalent loss functions assign equal weight to each pixel point during loss calculation,which hampers the ability to reflect the roles of different pixel points and fails to exploit the image’s characteristics fully.To address this issue,this study proposes an asymmetric loss function based on the image and data characteristics of the image recovery task.This novel loss function can adjust the weight of the reconstruction loss based on the grey value of different pixel points,thereby effectively optimizing the network training by differentially utilizing the grey information from the original image.Specifically,we calculate a weight factor for each pixel point based on its grey value and combine it with the reconstruction loss to create a new loss function.This ensures that pixel points with smaller grey values receive greater attention,improving network recovery.In order to verify the effectiveness of the proposed asymmetric loss function,we conducted experimental tests in the image super-resolution task.The experimental results show that the model with the introduction of asymmetric loss weights improves all the indexes of the processing results without increasing the training time.In the typical super-resolution network SRCNN,by introducing asymmetric weights,it is possible to improve the peak signal-to-noise ratio(PSNR)by up to about 0.5%,the structural similarity index(SSIM)by up to about 0.3%,and reduce the root-mean-square error(RMSE)by up to about 1.7%with essentially no increase in training time.In addition,we also further tested the performance of the proposed method in the denoising task to verify the potential applicability of the method in the image restoration task.展开更多
The complex interaction between material properties in an induction heating circuit was studied by multi physics simulation and by experimental verification in a full-scale laboratory heater. The work aims to illustra...The complex interaction between material properties in an induction heating circuit was studied by multi physics simulation and by experimental verification in a full-scale laboratory heater. The work aims to illustrate the complexity of the system of interacting materials, but also to propose a method to verify properties of soft magnetic composite materials in an integrated system and to identify which properties are the most critical under different circumstances and load cases. Heat losses at different loads were primarily studied, from DC currents to AC currents at 15, 20 and 25 kHz, respectively. A FE model for magnetic simulation was correlated with a corresponding model for heat simulation. The numerical model, as well as the established input material data, could be verified through the experimental measurements. In this particular study, the current loss in the litz wire was the dominant heat source, thus making the thermal conductivity of the SMC the most important property in this material.展开更多
1 Geography Location At 16:30 on August 3rd, 2014, Ludian County, Zhaotong City, Yunnan Province (27.1°N, 103.3°E) was hit by Ms 6.5 earthquake, with the maximum intensity is 9 and epicenter depth is aro...1 Geography Location At 16:30 on August 3rd, 2014, Ludian County, Zhaotong City, Yunnan Province (27.1°N, 103.3°E) was hit by Ms 6.5 earthquake, with the maximum intensity is 9 and epicenter depth is around 12 km (Figs. 1 and 2).展开更多
We have investigated the magnetic transition and magnetocaloric effects of Mn1+xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferr...We have investigated the magnetic transition and magnetocaloric effects of Mn1+xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn (x = 0.11) gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.展开更多
The objective of this study was to establish the dielectric properties of CoFe2O4 nanoparticles with particle sizes that varied from 28.6 to 5.8 nm. CoFe2O4 nanoparticles were synthesized using a chemical coprecipitat...The objective of this study was to establish the dielectric properties of CoFe2O4 nanoparticles with particle sizes that varied from 28.6 to 5.8 nm. CoFe2O4 nanoparticles were synthesized using a chemical coprecipitation method. The particle sizes were calculated accord-ing to the Scherrer formula using X-ray diffraction (XRD) peaks, and the particle size distribution curves were constructed by using field-emission scanning electron microscopy (FESEM) images. The dielectric permittivity and loss tangents of the samples were determined in the frequency range of 1 kHz to 1 MHz and in the temperature range of 300 to 10 K. Both the dielectric permittivity and the loss tangent were found to decrease with increasing frequency and decreasing temperature. For the smallest CoFe2O4 nanoparticle size, the dielectric per-mittivity and loss tangent exhibited their highest and lowest values, respectively. This behavior is very useful for materials used in devices that operate in the microwave or radio frequency ranges.展开更多
Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywo...Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywood. Results showed that modulus of rupture (MOR) and modulus of elasticity (MOE) of hem-fir plywood declined significantly by inoculating fungi, and weight loss of sample had a modest decrease. The fungi also made a greater effect on MOR than on MOE. Of three fungi, Postia placenta caused a most significant weight loss, and Gloeophyllum trabeum resulted in a largest flexural properties loss. Substantial declines in MOR and MOE of hem-fir plywood were also observed when the plywood samples were stored under wet conditions over 15 weeks, even in the absence of fungal attack.展开更多
An inexpensive fly ash (FA), which is from a waste product, was employed to prepare fly ash/epoxy composites. The purpose of this study is to characterize the contributions of matrix viscoelasticity, hollow structur...An inexpensive fly ash (FA), which is from a waste product, was employed to prepare fly ash/epoxy composites. The purpose of this study is to characterize the contributions of matrix viscoelasticity, hollow structure characteristic (porosity), and filler/matrix interface friction to the high vibration damping capacity of such composites. The damping properties of the composites were investigated in the temperature range of-40 to 150℃ and in the frequency range of 10 to 800 Hz by using a tension-compression mode. The results indicate that the peak value of damping loss factor (tan3) for the fly ash/epoxy composites can reach 0.70-0.90 in test specification, and the attenuation of damping loss factor is inconspicuous with increasing frequency. In addition, scanning electron microscope (SEM) was used to observe the morphology of the fly ash as well as its distribution in the matrix, which will help to analyze the effect of fly ash on the damping properties of the fly ash/epoxy composites.展开更多
The rheological properties of four kinds of chocolates (Dove, Leconte, Toblerone and Cote Dor) are determined by the rheometer of MCR101. The result shows that the melt samples have shear thinning behavior and thixotr...The rheological properties of four kinds of chocolates (Dove, Leconte, Toblerone and Cote Dor) are determined by the rheometer of MCR101. The result shows that the melt samples have shear thinning behavior and thixotropic. The chocolates’ viscosities decrease with temperature increasing. The flow of melt chocolates follows Casson equation. The whole tanδ of chocolate is greater than 1, which indicates that the viscous composition is more than the elastic elements. The stress of Dove and Leconte changes rapidly compared with that of Toblerone and Cote Dor. Dove and Leconte have higher yield stress and anti-deformation ability than Toblerone and Cote Dor. The tanδ of Toblerone and Cote Dor is higher than that of the other two chocolates. This result shows that Toblerone and Cote Dor have a higher proportion of sticky ingredients. By the sensory properties, Dove and Leconte have higher overall acceptability.展开更多
Composite thin films of PbTiO3 nano-crystals and high transparency polymer polyetherketone (PEK-c) for application of non-linear optical devices were prepared by spin coating. The size of PbTiO3 nano-crystals was es...Composite thin films of PbTiO3 nano-crystals and high transparency polymer polyetherketone (PEK-c) for application of non-linear optical devices were prepared by spin coating. The size of PbTiO3 nano-crystals was estimated to be 30-40 nm using a transmission electron microscope. The refractive index and the mode propagation losses at 633 nm were measured using the prism coupling technique and improved photographic technique respectively. They were found to be 1.6545 and 2.00 dB cm^-1 (fundamental mode),respectively. Moreover, it is observed that this loss is increased at higher mode indices.展开更多
This paper reports that single-phase γ-Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ-Y2Si2O7 as a ...This paper reports that single-phase γ-Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ-Y2Si2O7 as a function of the temperature and frequency. The γ-Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400℃ in the range of 7.3 18 GHz. The mechanism for polarization relaxation of the as-prepared γ-Y2Si2O7 differing from that of SiO2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications.展开更多
To develop electromagnetic protection composites with integrated structure -function properties, the three-dimension (3D) braided nickel plated carbon fiber/epoxy resin (Ni-CF3D/EP) composites were prepared based on 3...To develop electromagnetic protection composites with integrated structure -function properties, the three-dimension (3D) braided nickel plated carbon fiber/epoxy resin (Ni-CF3D/EP) composites were prepared based on 3D five-directional braiding, unitary nickel plating and mold compression shaping. The electromagnetic protection properties of Ni-CF3D/EP composites including shielding effective- ness (SE) and reflection loss against plane electromagnetic wave, shielding properties against electromagnetic pulse (EMP) were investigated. The test results show that the novel composites have good electromagnetic protection properties in a wide frequency range of 14 kHz~18 GHz with SE of 42 dB~95 dB, the absorption bandwidth of –5 dB in 2 GHz~18 GHz can reach 10 GHz and the pulse peak SE against EMP is 43.7 dB which can reduce the electromagnetic energy greatly. Meanwhile, the mechanic properties were also investi- gated and the results indicate that the Ni-CF3D/EP composites can replace metal materials for loading-bearing structural applications because of their excellent mechanic properties.展开更多
The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting ...The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting the solid-state reaction method at a low temperature(910℃).The objective is to achieve matching impedances,low magnetic and dielectric losses(tanδμand tanδε,respectively),and a relatively large miniaturization factor to reduce antenna size.Experimental results indicate that the cations occupying the tetrahedral(A)and octahedral(B)ion sites are redistributed,resulting in an enhanced super-exchange interaction between the two sublattices.As a result,improved magnetization,including the increase in saturation magnetization(41.74 emu/g)and decrease in coercivity(63.75 Oe),is realized.The real part of permeability(μ')also increases with increasing concentration of Cd^(2+) ions.When x is 0.15,matching impedances with equivalent μ'and ε'values are obtained over a long frequency range(1–150MHz).Moreover,the formation of a dense microstructure guarantees that losses occur at low orders of magnitude(tanδμ≈10−2 and tanδε≈10−3).Accordingly,these properties afford wide application perspectives for the proposed compounds in the high-frequency region,i.e.,from high-frequency to very-high-frequency bands.展开更多
基金supported by the National Natural Science Foundation of China(No.50174020).
文摘CW-CO2 laser nitriding technique was applied to improve the properties (such as aging property and the core loss) of grain oriented silicon steel. The samples were nitrided with regular space. Laser power density and scanning speed were chosen as 7.8×10^5W·cm^-2 and 100mm·min^-1. By some laser irradiation, Fe4N and Fe3N were formed in the nitrided zone. The nitrided samples were annealed at the temperatures ranged from 100 to 90℃. The core loss of some interested samples was tested. The results show that the core loss of the nitrided samples with different thickness of 0.23 and 0.30mm decreased by 14.9% and 9.4% respectively, and the aging property were improved up to 800℃. The mechanism of laser nitriding to improve the properties of grain oriented silicon steel is discussed.
基金financially supported by National Nature Science Foundation of China(No.50872080)Shanghai Special Foundation of Nanotechnology(No.1052nm07300)+2 种基金Shanghai Education Development Foundation(No.08SG41)Shanghai Leading Academic Disciplines(No.S30107)Innovational Foundation of Shanghai University
文摘Piezoelectric ceramics of 0.6(Bi0.9La0.1)FeO3-0.4Pb(Ti1-xMnx)O3 (BLF-PTM) for x=0, 0.01, 0.02, and 0.03 were prepared by sol-gel process combined with a solid-state reaction method. The tan? for BLF-PTM of x=0.01 is just 0.006 at 1 kHz, drastically decreasing by using Mn dopants. The TC increases to 490 ℃ for BLF-PTM of x=0.02. Furthermore, Mn modification effectively enhances the poling state and the piezoelectric properties of BLF-PTM. The kp, Qm, d33, and g33 of 0.34, 403, and 124 pC1·N-1 and 37×10-3 Vm·N-1 are achieved for BLF-PTM of x=0.01. The results indicate that Mn modified BLF-PTM is a competitive high power and high temperature piezoelectric material with excellent piezoelectric properties.
基金Project supported by National High-Technology Research and De-velopment Program(Grant No .2001AA3250380)
文摘Effect of the content of dopants in the manganese-zinc ferrites on the low power loss is studied by measuring magnetic properties and observing the grain boundary structures. The Mn0.738Zn0.206Fe2.066O4 composition powders were prepared by using conventional ceramic powder processing technique. The microstructure of grain boundary was observed by scanning electron microscope (SEM). It has been found that power loss is greatly dependent upon the content of the additives.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11574122 and 51731001)Joint Fund of Equipment Pre-Research and Ministry of Education,China(Grant No.6141A02033242)。
文摘To fully release the potential of wide bandgap(WBG)semiconductors and achieve high energy density and efficiency,a carbonyl iron soft magnetic composite(SMC)with an easy plane-like structure is prepared.Due to this structure,the permeability of the composite increases by 3 times(from 7.5 to 21.5)at 100 MHz compared with to the spherical carbonyl iron SMC,and the permeability changes little at frequencies below 100 MHz.In addition,the natural resonance frequency of the composite shifts to higher frequencies at 1.7 GHz.The total core losses of the composites at 10,20,and 30 m T are80.0,355.3,and 810.7 m W/cm^(3),respectively,at 500 k Hz.Compared with the spherical carbonyl iron SMC,the core loss at500 k Hz is reduced by more than 60%.Therefore,this kind of soft magnetic composite with an easy plane-like structure is a good candidate for unlocking the potential of WBG semiconductors and developing the next-generation power electronics.
基金National Amorphous and Nanocrystalline Alloy Engineering Researeh Cease
文摘The dependences of the power loss per cycle on frequency f and amplitude flux density Bm have been investigated for the three main original magnetic states in five sorts of Fe-based nanocrystalline soft magnetic alloys in the ranges of 10 Hz<=f<=1000 Hz and 0.4 T<= Bm <=1.0 T. The total loss P is decomposed into the sum of the hysteresis loss Physt, the classical eddy current loss Pel and the excess loss Pexc. Physt has been found to be proportional to Bm^2 and f. The behavior of Pexc/f vs f being equivalent to P/f vs f clearly exhibits nonlinearity in the range not more than about 120 Hz, whereas the behavior of P/f vs f roughly shows linearity in the range far above 100 Hz and not more than 1000 Hz. In the range up to 1000 Hz, Physt is dominant in the original high permeability state and the state of low residual flux density, whereas Pexc in the state of high residual flux density is dominant in the wider range above about 100 Hz. The framework of the statistical theory of power loss has been used for representing the behavior of Pexc/f vs f. It has been found that the number n of the simultaneously active 'Magnetic Objects' linearly varies as n = n0 + Hexc/H0 as a function of the dynamic field Hexc in the range below about 120 Hz, whereas n approximately follows a law of the form n = n0 + (Hexc/H0)^m with 1 < m < 2 in the range far above 100 Hz and not more than 1000 Hz. The values of the field HO in principle related to the microstructure and the domain structure have been calculated for the three states.
基金supported by the National Natural Science Foundation of China(62201618).
文摘Deep learning techniques have significantly improved image restoration tasks in recent years.As a crucial compo-nent of deep learning,the loss function plays a key role in network optimization and performance enhancement.However,the currently prevalent loss functions assign equal weight to each pixel point during loss calculation,which hampers the ability to reflect the roles of different pixel points and fails to exploit the image’s characteristics fully.To address this issue,this study proposes an asymmetric loss function based on the image and data characteristics of the image recovery task.This novel loss function can adjust the weight of the reconstruction loss based on the grey value of different pixel points,thereby effectively optimizing the network training by differentially utilizing the grey information from the original image.Specifically,we calculate a weight factor for each pixel point based on its grey value and combine it with the reconstruction loss to create a new loss function.This ensures that pixel points with smaller grey values receive greater attention,improving network recovery.In order to verify the effectiveness of the proposed asymmetric loss function,we conducted experimental tests in the image super-resolution task.The experimental results show that the model with the introduction of asymmetric loss weights improves all the indexes of the processing results without increasing the training time.In the typical super-resolution network SRCNN,by introducing asymmetric weights,it is possible to improve the peak signal-to-noise ratio(PSNR)by up to about 0.5%,the structural similarity index(SSIM)by up to about 0.3%,and reduce the root-mean-square error(RMSE)by up to about 1.7%with essentially no increase in training time.In addition,we also further tested the performance of the proposed method in the denoising task to verify the potential applicability of the method in the image restoration task.
文摘The complex interaction between material properties in an induction heating circuit was studied by multi physics simulation and by experimental verification in a full-scale laboratory heater. The work aims to illustrate the complexity of the system of interacting materials, but also to propose a method to verify properties of soft magnetic composite materials in an integrated system and to identify which properties are the most critical under different circumstances and load cases. Heat losses at different loads were primarily studied, from DC currents to AC currents at 15, 20 and 25 kHz, respectively. A FE model for magnetic simulation was correlated with a corresponding model for heat simulation. The numerical model, as well as the established input material data, could be verified through the experimental measurements. In this particular study, the current loss in the litz wire was the dominant heat source, thus making the thermal conductivity of the SMC the most important property in this material.
文摘1 Geography Location At 16:30 on August 3rd, 2014, Ludian County, Zhaotong City, Yunnan Province (27.1°N, 103.3°E) was hit by Ms 6.5 earthquake, with the maximum intensity is 9 and epicenter depth is around 12 km (Figs. 1 and 2).
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 50701022,51001019,and 50831006)the Program for New Century Excellent Talents of China (Grant No. NCET-08-0278)
文摘We have investigated the magnetic transition and magnetocaloric effects of Mn1+xCo1-xGe alloys by tuning the ratio of Mn/Co. With increasing Mn content, a series of first-order magnetostructural transitions from ferromagnetic to paramagnetic states with large changes of magnetization are observed at room temperature. Further increasing the content of Mn (x = 0.11) gives rise to a single second-order magnetic transition. Interestingly, large low-field magnetic entropy changes with almost zero magnetic hysteresis are observed in these alloys. The effects of Mn/Co ratio on magnetic transition and magnetocaloric effects are discussed in this paper.
文摘The objective of this study was to establish the dielectric properties of CoFe2O4 nanoparticles with particle sizes that varied from 28.6 to 5.8 nm. CoFe2O4 nanoparticles were synthesized using a chemical coprecipitation method. The particle sizes were calculated accord-ing to the Scherrer formula using X-ray diffraction (XRD) peaks, and the particle size distribution curves were constructed by using field-emission scanning electron microscopy (FESEM) images. The dielectric permittivity and loss tangents of the samples were determined in the frequency range of 1 kHz to 1 MHz and in the temperature range of 300 to 10 K. Both the dielectric permittivity and the loss tangent were found to decrease with increasing frequency and decreasing temperature. For the smallest CoFe2O4 nanoparticle size, the dielectric per-mittivity and loss tangent exhibited their highest and lowest values, respectively. This behavior is very useful for materials used in devices that operate in the microwave or radio frequency ranges.
基金This research was supported by Forest Research Labora-tory, Oregon State University
文摘Hem-fir plywood were exposed to two brown rot fungi, Gloeophyllum trabeum and Postia placenta, and one white rot fungus, Trametes versicolor, to investigate the effect of fungal decay on mechanical properties of plywood. Results showed that modulus of rupture (MOR) and modulus of elasticity (MOE) of hem-fir plywood declined significantly by inoculating fungi, and weight loss of sample had a modest decrease. The fungi also made a greater effect on MOR than on MOE. Of three fungi, Postia placenta caused a most significant weight loss, and Gloeophyllum trabeum resulted in a largest flexural properties loss. Substantial declines in MOR and MOE of hem-fir plywood were also observed when the plywood samples were stored under wet conditions over 15 weeks, even in the absence of fungal attack.
文摘An inexpensive fly ash (FA), which is from a waste product, was employed to prepare fly ash/epoxy composites. The purpose of this study is to characterize the contributions of matrix viscoelasticity, hollow structure characteristic (porosity), and filler/matrix interface friction to the high vibration damping capacity of such composites. The damping properties of the composites were investigated in the temperature range of-40 to 150℃ and in the frequency range of 10 to 800 Hz by using a tension-compression mode. The results indicate that the peak value of damping loss factor (tan3) for the fly ash/epoxy composites can reach 0.70-0.90 in test specification, and the attenuation of damping loss factor is inconspicuous with increasing frequency. In addition, scanning electron microscope (SEM) was used to observe the morphology of the fly ash as well as its distribution in the matrix, which will help to analyze the effect of fly ash on the damping properties of the fly ash/epoxy composites.
文摘The rheological properties of four kinds of chocolates (Dove, Leconte, Toblerone and Cote Dor) are determined by the rheometer of MCR101. The result shows that the melt samples have shear thinning behavior and thixotropic. The chocolates’ viscosities decrease with temperature increasing. The flow of melt chocolates follows Casson equation. The whole tanδ of chocolate is greater than 1, which indicates that the viscous composition is more than the elastic elements. The stress of Dove and Leconte changes rapidly compared with that of Toblerone and Cote Dor. Dove and Leconte have higher yield stress and anti-deformation ability than Toblerone and Cote Dor. The tanδ of Toblerone and Cote Dor is higher than that of the other two chocolates. This result shows that Toblerone and Cote Dor have a higher proportion of sticky ingredients. By the sensory properties, Dove and Leconte have higher overall acceptability.
基金Founded by the National Natural Science Foundation (Nos. 60377016 and 60476020) the "863" National Plan (No. 2002AA313070) of China.
文摘Composite thin films of PbTiO3 nano-crystals and high transparency polymer polyetherketone (PEK-c) for application of non-linear optical devices were prepared by spin coating. The size of PbTiO3 nano-crystals was estimated to be 30-40 nm using a transmission electron microscope. The refractive index and the mode propagation losses at 633 nm were measured using the prism coupling technique and improved photographic technique respectively. They were found to be 1.6545 and 2.00 dB cm^-1 (fundamental mode),respectively. Moreover, it is observed that this loss is increased at higher mode indices.
基金Project supported by the National Natural Science Foundation of China (Grant No. 50872159)the National Defense Pre-research Foundation of China (Grant Nos. 513180303 and A2220061080)
文摘This paper reports that single-phase γ-Y2Si2O7 is prepared via a sufficient blending and cold-pressed sintering technique from Y2O3 powder and SiO2 nanopowder. It studies the dielectric properties of γ-Y2Si2O7 as a function of the temperature and frequency. The γ-Y2Si2O7 exhibits low dielectric loss and non-Debye relaxation behaviour from 25 to 1400℃ in the range of 7.3 18 GHz. The mechanism for polarization relaxation of the as-prepared γ-Y2Si2O7 differing from that of SiO2 is explained. Such particular dielectric properties could potentially make specific attraction for extensive practical applications.
基金Project supported by Equipment Pre-research Foundation of China (9140A31030110JB3403)
文摘To develop electromagnetic protection composites with integrated structure -function properties, the three-dimension (3D) braided nickel plated carbon fiber/epoxy resin (Ni-CF3D/EP) composites were prepared based on 3D five-directional braiding, unitary nickel plating and mold compression shaping. The electromagnetic protection properties of Ni-CF3D/EP composites including shielding effective- ness (SE) and reflection loss against plane electromagnetic wave, shielding properties against electromagnetic pulse (EMP) were investigated. The test results show that the novel composites have good electromagnetic protection properties in a wide frequency range of 14 kHz~18 GHz with SE of 42 dB~95 dB, the absorption bandwidth of –5 dB in 2 GHz~18 GHz can reach 10 GHz and the pulse peak SE against EMP is 43.7 dB which can reduce the electromagnetic energy greatly. Meanwhile, the mechanic properties were also investi- gated and the results indicate that the Ni-CF3D/EP composites can replace metal materials for loading-bearing structural applications because of their excellent mechanic properties.
基金This work was supported by National Key Scientific Instrument and Equipment Development Project No.51827802by Major Science and Technology projects in Sichuan Province Nos.2019ZDZX0026 and 20ZDYF2818+1 种基金by the National Natural Science Foundation of China No.51872041by Foundation for University Teacher of Education of China No.ZYGX2019J011.
文摘The effects of Cd^(2+) ions on the microstructure,magnetic properties,and dielectric properties of Bi_(2)O_(3)-added MgFe_(2)O_(4) ferrites(Cd_(x)Mg_(1-x)Fe_(2)O_(4),x=0.00,0.15,0.30 and 0.45)are obtained by adopting the solid-state reaction method at a low temperature(910℃).The objective is to achieve matching impedances,low magnetic and dielectric losses(tanδμand tanδε,respectively),and a relatively large miniaturization factor to reduce antenna size.Experimental results indicate that the cations occupying the tetrahedral(A)and octahedral(B)ion sites are redistributed,resulting in an enhanced super-exchange interaction between the two sublattices.As a result,improved magnetization,including the increase in saturation magnetization(41.74 emu/g)and decrease in coercivity(63.75 Oe),is realized.The real part of permeability(μ')also increases with increasing concentration of Cd^(2+) ions.When x is 0.15,matching impedances with equivalent μ'and ε'values are obtained over a long frequency range(1–150MHz).Moreover,the formation of a dense microstructure guarantees that losses occur at low orders of magnitude(tanδμ≈10−2 and tanδε≈10−3).Accordingly,these properties afford wide application perspectives for the proposed compounds in the high-frequency region,i.e.,from high-frequency to very-high-frequency bands.