SURFACE MODIFICATION OF POLYPROPYLENE MICROFIBRE BY PLASMA-INDUCED VAPOR GRAFTING WITH ACRYLIC ACID

The hydrophilicity, dyeing and antistatic ability of polypropylene microfibre (PPMF) were improved by plasma-induced vapor grafting with acrylic acid. The effects of plasma discharge time, power, liquid phase acrylic acid temperature and environmental temperature on grafting yield were investigated. The existence of grafted polyacrylic acid (PAA) was verified by ESCA and ATR FT-IR. The morphology of grafted PAA was directly observed by SEM. The wicking test shows that the hydrophilicity of modified PPMF is greatly enhanced. The dyeability test of modified PPMF was carried out using Dispersion Yellow. It was found that the dye uptake ratio is linear to the weight percent of grafting. The antistatic ability was indicated by specific resistance. The specific resistance of modified PPMF was reduced to 10(6) similar to 10(7) Ohm . cm, thus the antistatic ability was considerably improved.

竹材动态杨氏模量影响因子的分析

用共振法分别测出同种竹材不同高度的动态杨氏模量,分析其与竹节长、密度和纤丝角的关系。结果表明,随着竹节高度增大,竹材的密度增大,动态杨氏模量也增大,而竹材的内耗则不断下降;同时,竹节高度增大,竹材的纤丝角变小,动态杨氏模量变大,而内耗变小。因此,影响同种竹材不同部位的动态杨氏模量的主要因素是密度和纤丝角。

竹材的动切变模量与密度及纤丝角的关系

运用动态法测出毛竹和孝顺竹两种不同竹种的动切变模量 ,分析了其与密度和纤丝角的关系。分别用扭摆、X射线衍射仪和电子密度仪测出竹材试样的动切变模量、纤丝角和密度。结果表明 ,两竹种的动切变弹性模量随密度和纤丝角余弦的增大而增大 ,动切变耗散模量也随密度增大而增大 ,但与纤丝角的余弦关系不大。而耗散角随密度和纤丝角余弦的增大而减小。

林分密度对南方型杨树木材性质的影响

就林分密度对南方型杨树材性的影响进行研究。研究结果表明：①林分密度对各无性系木材的纤维素含量影响规律不明显；②随林分密度增大，纤维长度有所增长，各级纤维频率趋于均匀，林分密度对纤维宽度与长宽比影响不显著；③林分密度对Ｓ_２层微纤丝角有显著影响，Ｓ_２层微纤丝角随着林分密度的增大而减少；④木材相对结晶度随林分密度的增大而增大；⑤随着林分密度的增大，木材的冲击韧性降低，而气干密度逐渐增大。在４ｍ×４ｍ、５ｍ×５ｍ和６ｍ×６ｍ株行距的林分中，随林分密度增加其抗弯强度和弹性模量增大。而对木材的抗压强度影响不明显。