Provenance of colorless and brown volcanic glass in late Pleistocene tephra layers in the Western Philippine Sea

Tephra layers in the western Philippine Sea,characterized by abundant volcanic glass shards,may provide crucial evidence on the eruption history of volcanoes and tectonic evolution of the western Pacific.A 220-ka sediment core from the Benham Rise in the western Philippine Sea offers new insights into the provenance of four intercalated tephra layers(T1–T4,in chronological order)containing either colorless or brown glass shards.Relative to primitive mantle,all glass shards are enriched in large-ion lithophile elements,such as Rb,Cs,and Pb,and depleted in high field-strength elements,such as Th,Nb,and Ta,indicating a subduction-related origin.The colorless glass shards are characterized by high SiO_(2)(>78%)and light rare earth element(LREE)contents as well as high La/Sm ratios(>9),low FeO and MgO contents(<1%),low Sr/Y(<15)and high Ba/Th ratios(>100),pointing to a rhyolitic composition and a medium-K calc-alkaline serial affinity.In contrast,the brown glass shards are characterized by lower SiO_(2)(<63%)and LREE contents,higher FeO,MgO,and CaO contents,lower La/Sm(<6)and Ba/Th(<75),and similar Sr/Y ratios(<15),indicating derivation from medium to high-K calc-alkaline andesite magma.Brown glass shards from layers T3(152 ka)and T4(172 ka)were correlated with volcanic deposits from the Taal and Laguna Caldera in the Maccolod Corridor,respectively,while the colorless glass shards from layers T1(36.5 ka)and T2(61.2 ka)were likely sourced from the Irosin Caldera in the Bicol Arc.Establishing the provenance of late Pleistocene tephra layers in the western Philippine Sea is helpful to complement a Philippine volcanic history and establish a regional tephrochronostratigraphy.

Synergistic effects of Pleistocene geological and climatic events on complex phylogeographic history of widespread sympatric species of Megaloptera in East Asia

Unraveling the phylogeographic histories of species remains a key endeavor for comprehending the evolutionary processes contributing to the rich biodiversity and high endemism found in East Asia.In this study,we explored the phylogeographic patterns and demographic histories of three endemic fishfly and dobsonfly species(Neochauliodes formosanus,Protohermes costalis,and Neoneuromus orientalis)belonging to the holometabolan order Megaloptera.These species,which share a broad and largely overlapping distribution,were analyzed using comprehensive mitogenomic data.Our findings revealed a consistent influence of vicariance on the population isolation of Neoc.formosanus and P.costalis between Hainan,Taiwan,and the East Asian mainland during the early Pleistocene,potentially hindering subsequent colonization of the later diverged Neon.orientalis to these islands.Additionally,we unveiled the dual function of the major mountain ranges in East Asia,serving both as barriers and conduits,in shaping the population structure of all three species.Notably,we demonstrated that these co-distributed species originated from Southwest,Southern,and eastern Central China,respectively,then subsequently migrated along multi-directional routes,leading to their sympatric distribution on the East Asian mainland.Furthermore,our results highlighted the significance of Pleistocene land bridges along the eastern coast of East Asia in facilitating the dispersal of mountain-dwelling insects with low dispersal ability.Overall,this study provides novel insight into the synergistic impact of Pleistocene geological and climatic events in shaping the diversity and distribution of aquatic insects in East Asia.

Biogeochemistry of sedimentary organic matter in the Yongjiang River estuary in the southern part of Hangzhou Bay,China,since the Late Pleistocene

A sediment core(YJK19-02)collected from the southern outlet of Hangzhou Bay near the Yongjiang River estuary in East China was analyzed for grain size,lignin,bulk elemental composition,stable carbon isotope,and rare earth elements(REEs)to determine the sources and diagenesis of sedimentary organic matter(OM)of the estuary and adjacent areas since the Late Pleistocene.δ^(13)C values(-24.80‰–-23.60‰),total organic carbon/total nitrogen(TOC/TN)molar ratios(8.00–12.14),and light rare earth element/heavy rare earth element ratios(LREE/HREE=8.34–8.91)revealed the predominance of terrestrial sources of OM,mainly from the Changjiang(Yangtze)River.The lignin parameters of syringyl/vanillyl(S/V=0.20–0.73)and cinnamyl/vanillyl(C/V=0.03–0.19)ratios indicate the predominance of nonwoody angiosperms,and the vanillic acid/vanillin ratios[(Ad/Al)_(V)=0.32–1.57]indicate medium to high degrees of lignin degradation.An increasing trend ofΛ(total lignin in mg/100-mg OC)values from ca.14500 a BP to ca.11000 a BP reflected the increase in temperature during the Late Pleistocene.However,a time lag effect of temperature on vegetation abundance was also revealed.The relatively higher and stableΛvalues correspond to the higher temperature during the mid-Holocene from ca.8500 a BP to ca.4500 a BP.Λvalues decreased from ca.4000 a BP to the present,corresponding to historical temperature fluctuations during this time.Our results show that the vegetation abundance in the Yongjiang River Basin since the Late Pleistocene was related to the temperature fluctuation duo to climate change.

Application of 9-component S-wave 3D seismic data to study sedimentary facies and reservoirs in a biogasbearing area:A case study on the Pleistocene Qigequan Formation in Taidong area,Sanhu Depression,Qaidam Basin,NW China

To solve the problems in restoring sedimentary facies and predicting reservoirs in loose gas-bearing sediment,based on seismic sedimentologic analysis of the first 9-component S-wave 3D seismic dataset of China,a fourth-order isochronous stratigraphic framework was set up and then sedimentary facies and reservoirs in the Pleistocene Qigequan Formation in Taidong area of Qaidam Basin were studied by seismic geomorphology and seismic lithology.The study method and thought are as following.Firstly,techniques of phase rotation,frequency decomposition and fusion,and stratal slicing were applied to the 9-component S-wave seismic data to restore sedimentary facies of major marker beds based on sedimentary models reflected by satellite images.Then,techniques of seismic attribute extraction,principal component analysis,and random fitting were applied to calculate the reservoir thickness and physical parameters of a key sandbody,and the results are satisfactory and confirmed by blind testing wells.Study results reveal that the dominant sedimentary facies in the Qigequan Formation within the study area are delta front and shallow lake.The RGB fused slices indicate that there are two cycles with three sets of underwater distributary channel systems in one period.Among them,sandstones in the distributary channels of middle-low Qigequan Formation are thick and broad with superior physical properties,which are favorable reservoirs.The reservoir permeability is also affected by diagenesis.Distributary channel sandstone reservoirs extend further to the west of Sebei-1 gas field,which provides a basis to expand exploration to the western peripheral area.

Middle-Late Pleistocene Paleo-Climate and Paleo-Altimetry of the Centre of Tibetan Plateau Indicated by the Sporopollen Record of Well QZ-4

The core sample from well QZ-4 is an important climate archive for the central Tibetan Plateau in the middle-late Pleistocene. In this work, a detailed pollen analysis of it is carried out to provide a preliminary insight into the paleo-climate and paleo-altimetry change in the central Tibetan Plateau. It can be concluded that the pollen assemblage can be obviously divided into two pollen zones, Pollen zone I (251.1 - 314 m in depth, 120.0 - 345.8 ka BP.) and Pollen zone II (200 - 251.1 m in depth, 105.4 - 120 ka BP.). The paleo-climate during pollen zone I deposition period was comparatively colder and wetter than it during the pollen zone II deposition period. After Gonghe Movement, the center of Tibetan Plateau was uplifted about 300 m (from 3500 - 3700 m to 3800 - 4000 m in elevation). The wind was changed from horizontal or downward direction to upward direction, in the study area. In the central of Tibetan Plateau, the climate change seems to be mainly driven by global climate change, and that tectonic uplift may have been a subordinate influence at the middle-late Pleistocene.

Palynological Evidence of Late Pleistocene Soft-sediment Deformation Event in the Northeastern Margin of the Tibetan Plateau

The northeastern margin of the Tibetan Plateau is the youngest part of the Tibetan Plateau where tectonic activity is intense and climate change is complex.In this study,combined with field investigations,we explored accelerator mass spectrometry 14C and optically stimulated luminescence dating and palynological analysis of the sedimentary sequence in the Qingshuihe Basin to explain the origin of soft-sediment deformation layer.Dating and palynological results from the Sanchahe section in the basin revealed a detailed history of vegetation variation and associated climate change from~18 to~5 ka BP.The results indicate that the permafrost developed at~18–11.7 ka BP,and the soft-sediment deformation structures formed at~11.7–5 ka BP.Together with the characteristics of the deformation(meter-scale,continuous symmetrical wave)and paleoclimate,we suggest that the soft-sediment deformation layer in the late Pleistocene was cryoturbated under climatic conditions.The discovery of a series of cryoturbations in the Qingshuihe Basin has further enriched the regional distribution of periglacial phenomena in the west of the Ordos Plateau,expanded the distribution range of periglacial phenomena,and provided evidence for exploring the temporal and spatial changes in permafrost in northern China at the end of the late Pleistocene.

A Middle Pleistocene Glaciation Record from Lacustrine Sediments in the Western Tibetan Plateau and Discussion on Climate Change

The Tibetan Plateau is an important area for studying global climate change,but the answers to many scientific problems remain unknown.Here,we present new information from the lacustrine sedimentary record in the western Tibetan Plateau,related to the third most-recent glaciations.Continuous sediment data,including sporopollen,particle size,total organic carbon,mass susceptibility,CaCO_(3),CaSO_(4),BaSO_(4)contents and chronological data,were reconstructed and revealed that climate and environmental conditions obviously and distinctly changed between 600 and 700 thousand years ago.In comparison,the data obtained from the Guliya ice core in this area also corresponds to the global glacial climatic characteristics recorded in basin sediments in the eastern and southeastern regions of the plateau and to the information obtained from ice cores in the Antarctic and Arctic regions.In this study,we conclude that the main reason for the glaciations and new tectonic movement must be a geomagnetic polarity reversal 774 thousand years ago(from Matuyama to Brunhes).Indeed,the results of this study suggest that the described reversal event might have influenced the current global climate pattern and will continue to impact climatic changes in the future.

Percutaneous microwave ablation and transcatheter arterial chemoembolization for serum tumor markers and prognostics of middle-late primary hepatic carcinoma

BACKGROUND Primary hepatic carcinoma(PHC)has an insidious onset and is usually diagnosed in the middle and late stages.Although transcatheter arterial chemoembolization(TACE)is the preferred option for treating middle-and advanced-stage PHC,it has limited efficacy in killing tumor cells and poor long-term efficacy.TACE plus percutaneous microwave coagulation therapy(PMCT)is more effective than interventional therapy alone and can improve survival time.However,there are few reports on the effects of TACE and PMCT on serum marker levels and the prognosis of patients with advanced PHC.AIM To investigate the effect of PMCT+TACE on serum tumor markers and the prognosis of middle-late PHC.METHODS This retrospective study included 150 patients with middle-late PHC admitted to Zhongshan People’s Hospital between March 2018 and February 2021.Patients were divided into a single group(treated with TACE,n=75)and a combined group(treated with TACE+PMCT,n=75).Before and after treatment,the clinical efficacy and serum tumor marker levels[carbohydrate antigen 19-9(CA19-9),alpha-fetoprotein(AFP),and carcinoembryonic antigen(CEA)]of both groups were observed.The 1-year survival rates and prognostic factors of the two groups were analyzed.RESULTS The combined group had 21 and 35 cases of complete remission(CR)and partial remission(PR),respectively.The single group had 13 and 25 cases of CR and PR,decreased,with the decrease in the combined group being more significant(P<0.05).The 1-year survival rate of the combined group(80.00%)was higher than that of the single group(60.00%)(P<0.05).The average survival time within 1 year in the combined group was 299.38±61.13 d,longer than that in the single group(214.41±72.97 d,P<0.05).COX analysis revealed that tumor diameter,tumor number,and the treatment method were prognostic factors for patients with middle-late PHC(P<0.05).CONCLUSION TACE+PMCT is effective in treating patients with mid-late PHC.It reduces the levels of tumor markers,prolongs survival,and improves prognosis.

Late Pleistocene glaciation of the Hulifang Massif of Gongwang mountains in Yunnan Province

Late Pleistocene glaciation was restricted to only a few high mountains in eastern China. The Gongwang mountains constitute one of the typical places once glaciated. Geomorphic mapping of the area and the TL dating provides evidence for at least four distinct glaciations. YJT-Ⅰ glacial advance occurred about 100 ka BP and two TL absolute ages （101,100 ± 7780 a BP; 104,000± 8300 a BP） indicate this advance happened during the Penultimale Glaciation. The early stage glacial advance （YJT-Ⅱ advance） during the last glaciation occurred about 40,920 ± 3400 a BP. The last glacial maximum advance （YJT-Ⅲ advance） about 18-25 ka BP, which sustained by two TL ages （18,230 ±1420 a BP; 25,420 ± 2110 a BP）. The Penultimale and the early stage glaciations were more extensive and the last glacial maximum （LGM） and the late-glacial period （YJT-Ⅳ advance, 10 ka BP） were progressively less extensive. Correlated with the other mountains in eastern China, these glacial advances in the Gongwang mountains just like the advances in the western part such as Diancang mountains, Yulong mountains of Yunnan Province and the glacier series are more complete than the adjacent mid-latitude regions such as Taibai mountain and Taiwan mountains and are roughly representative of climate changes during the last glacial cycle in Yunnan Province.

Late Pleistocene aeolian activity in Haitan Island, Southeast China: Insights from optically stimulated luminescence dating of coastal dunes on marine terraces

The 'Old Red Sand' is a type of semicemented medium-fine sandy sediment that is red(10R_4/8) or brown red(2.5YR_4/8) in colour and is found in late Quaternary deposits. The sediments have distinctive characteristics and are a critical archive for understanding climatic changes in the coastal areas of East Asia. The ages of the late Quaternary aeolian sand dunes from Haitan Island in the coastal area of South China are still in debate. In this study, three sets of marine terraces were identified in the northern region of Haitan Island. Aeolian dune sands are well preserved on the top of these terraces. Quartz Optically Stimulated Luminescence dating and the distribution of the formation ages demonstrated that the palaeo-dunes are deposits from the middle-late period of the Late Pleistocene(Q_3^(2-3)). The period may be divided into three stages, 100-90 ka, 70-60 ka, and 40-20 ka, in which the palaeo-dunes of the first two stages are more widespread and were formed separately during a low-sea level period of the Marine Isotope Stages 5 b and 4. Several depositional palaeo-flood event records were preserved during the last stage due to the increasing gradient of mountain gullies formed during the Last Glacial Maximum.

Environmental evolution in the salt-water intrusion area south of Laizhou Bay since late Pleistocene

The south coastal plain of Laizhou Bay is one of the typical salt-water intrusion areas in China, the occurrence and development of which was closely related with the palaeoenvironment evolution. Systematic analyses of pollen, foraminifera and grain size composition based on ^14C and luminescence dating from two sediment cores were performed for the purpose of understanding the salt-water intrusion in the coastal plain of Laizhou Bay from the perspective of environmental evolution since late Pleistocene. It could be classified into seven evolution stages since 120 kaBP： 120-85 kaBP was a transition period from cold to warm; 85-76 kaBP was a period with warm and wet climate having swamp lakes developed in the lower reaches of the Weihe River, south coastal plain of Laizhou Bay; 76-50 kaBP was characterized by grassland vegetation and coarse sediments in terrestrial environment, which was the early stage of Dali Ice-Age; 50-24 kaBP was a period with alternate sea deposition in the south coastal plain of Laizhou Bay; 24-10 kaBP was the late stage of Dali Ice-Age with coldest period of Quaternary, the south coastal plain of Laizhou Bay was dry grassland and loess deposition environment; 10-4 kaBP was another warm and wet climate period, sea level was high and regressed at 4 kaBP; and has been the modern sedimentary environment since 4 kaBP. Among the three warm stages, including 85-76 kaBP, 50-24 kaBP and 10-4 kaBP, corresponded to late Yangkou, Guangrao and Kenli seawater transgression respectively. The duration of the latter one in south coastal plain of Laizhou Bay was longer than that in west coast of Bohai Sea and east coast of Laizhou Bay. The three periods of seawater transgression formed the foundation of salt-water intrusion in this area.

A New Mid Early Pleistocene Mammalian FaunaDiscovered in Choukoutien，China and Its Application in Biostratigraphy

This paper deals with a new Early Pleistocene micromammalian fauna found in Choukonden (Zhoukoudian) and its application in biostratigraphy.The new locality (east cave ), discovered in 1985,is located on the north slope of the Taipingshan Hill, about 2 km northeast of the Loc.1 in Choukoutien and is about 140-150m in altitude. At this locality,abundant fossil mammals are found in thick cave-fissure deposit. This fauna comprises 30mammalian taxa. Based on the comparison of the fauna, as Well as the sporo-pollen, climate events and paleomagnetic polarity section with those in other areas,we come to the conclusion that the sediments (Taipingshan Formation) in east cave were formed during the Period about from 1.67 Ma B. P. to 0.97 Ma B. P., and the fauna is about 1.20 Ma B. P. in ags.

An Updated Review of the Middle-Late Jurassic Yanliao Biota: Chronology,Taphonomy,Paleontology and Paleoecology

The northeastern Chinese Yanliao Biota （sometimes called the Daohugou Biota） comprises numerous, frequently spectacular fossils of non-marine organisms, occurring in Middle-Upper Jurassic strata in western Liaoning, northern Hebei, and southeastern Inner Mongolia. The biota lasted for about 10 million years, divided into two phases： the Bathonian-Callovian Daohugou phase （about 168-164 million years ago） and the Oxfordian Linglongta phase （164-159 million years ago）. The Yanliao fossils are often taphonomically exceptional （many vertebrate skeletons, for example, are complete and accompanied by preserved integumentary features）, and not only are taxonomically diverse but also include the oldest known representatives of many groups of plants, invertebrates, and vertebrates. These fossils have provided significant new information regarding the origins and early evolution of such clades as fleas, birds, and mammals, in addition to the evolution of some major biological structures such as feathers, and have demonstrated the existence of a complex terrestrial ecosystem in northeast China around the time of the Middle-Late Jurassic boundary.

Sediment distribution and provenance since Late Pleistocene in Laizhou Bay,Bohai Sea,China

There are three transgression-regression events and evolutions of the sedimentary environment by sea level changes since the Pleistocene in the southern section of the Bohai Sea, China. It is obvious that a multi-source fluvial delta sedimentary system may be more dominant in a sedimentary environment. Based on previous research and survey or historical data, we carried out studies on the division of sedimentary units, sedimentary facies analysis and strata division and comparison, which aim to establish the sedimentary stratigraph of Laizhou Bay. We focus on the sedimentary procession of the Laizhou Bay since the early Late Pleistocene. It can be divided into two glacial periods and three interglacial periods, corresponding to two regression and three transgression events in Laizhou Bay since Late Pleistocene. In 124.6-72.0 ka BP, 60.0-24.4 ka BP and 10.2-4.0 ka BP, three times warm-wet periods occurred, respectively corresponding to the Cangzhou transgression, Xianxian transgression, and Huanghua transgression. In 72.0-60.0 ka BP and 24.4-10.2 ka BP, two dry and cold periods, it was the continental sedimentary environment, corresponding to Wurm early glacier and Wurm late glacier. The results show:(1) Sediments have the characteristics of phase and stage under the terrestrial input of the Yellow River and middle-small rivers in the southern section of the Bohai Sea.(2) PI moved towards coastal in Cangzhou transgression strata in early Late Pleistocene. PI moved northward from land in Xianxian transgression strata in the late Pleistocene. PI moved further north in the Huanghua transgression strata in Holocene.(3) During the regressive period, the land source input increased and the estuarine or lagoon sedimentation developed, which manifested as progradational superposition.(4) During the transgressive period, it mainly developed shallow coastal sediment and transitionally formed regressive deposition to the south in delta/tidal flat deposition.

Evolution of a Late Pleistocene palaeolake in Dali Nor area of southeastern Inner Mongolia Plateau,China

Lithological,geochronological,granulometric,and scanning electron microscope(SEM)analyses of eight lacustrine outcrops indicate the existence of a large palaeolake in Dali Nor area during 149-24.6 ka(MIS5-3)and a small one in upstream of the Xilamulun River during 12.96-11.69 ka.The large palaeolake recorded its highest water level above 1300 m during the MIS3 and covered the whole Dali Nor basin and upstream of the Xilamulun River within an area of about 3000 km^2.However,the small palaeolake with a highest water level above 1200 m,covered an area of about 600 km^2.Besides the reconstruction of palaeolake areas,this study also looked into the evolutionary process of the palaeolake during the Late Pleistocene.Our data provide insights on the timing of appearance of the large palaeolakes and a better understanding of the mechanism responsible for variations in the environment conditions of dry lands in middle latitudes.

Tectonic Uplift of the Yili Basin during the Last Stage of the Late Pleistocene: Evidence from ESR and OSL Dating of Sediments in the Huocheng Area, Xinjiang

The Quaternary sediments in the Yili Basin can serve as archives for studying the Cenozoic basin-mountain relationship. In this study, based on typical natural sections and boreholes, the surficial sediments of the Huocheng area were studied, and their sedimentary ages were obtained using the optically stimulated luminescence(OSL) and electron spin resonance(ESR) dating methods. These dates, combined with changes in the sedimentary facies, provided details of the neotectonic movement in the Yili Basin and adjacent areas. By dating sediments from five sections and three boreholes, we determined that the surficial sediments of the Huocheng area were mainly formed in the Late Pleistocene, with scattered instances of Holocene sediments. The surficial sediments mainly consisted of alluvial fan facies, fluvial facies, lacustrine facies, and desert facies. Based on the activity on the Hongshanzui fault and the northern margin fault of the Wusun Mountains, the Huocheng area was uplifted synchronously with the Tianshan Mountains during the last stage of the Late Pleistocene, causing the desert facies sediments to be superimposed on the former paleo-lake sediments.

ENVIRONMENTAL CHANGES SINCE LATE PLEISTOCENE IN ESTUARINE PLAIN OF JIULONG RIVER, FUJIAN PROVINCE

Based on the evidences of lithostratigraphy, palynology, micropaleontolopy and geochronology, paleoenvironments since the Late Pleistocene in the study area have been reconstructed. One of the most important inferences is that two marine transgressions have occurred, one in Wurm Sub-interglacial and the other Postglacial. The former had caused the study area to be in an estuary-bay envirment over the transgression maximum, with a sea level of no less than 10 m below present; foe latter reached its maximum over the Atlantic stage, with sedimentary environments of estuary-bay, hay or shallow sea, and the sea level arrived at the highest elevation in about 6 - 5 ka B.P. Furthermore, it is notable that, during the Late Wurm Glacial, the study area area had principally been in an estuary-bay environment, although the climate, like many other areas, turned cold and dry, It reflects a general trend of crustal subduction in Jiulong Estudrine Plain over this pened.

Uranium Series Chronology of the Late Pleistocene Basalt from the Longgang Volcanoes, Jilin Province

The Longgang volcanic cluster located in Jilin Province belongs to one of the active volcanic regions in northeast China, and has been active in modern times. In view of the multiple eruptions in history, it is very important to determine the age of each eruption for evaluating the volcanic hazards. Two alkaline basalt samples taken from Dayizishan and Diaoshuihu were analyzed with the U-series component dating after magnetic separation. The ages of the two samples are (71±9) ka and (106±13) ka B.P., respectively. These data indicate that there existed intensive eruption activities during the late Pleistocene.

Petrography, Geochemistry and Petrogensis of Pleistocene Basaltic Flow from Northwest Atarous Area, Central Jordan

Fifteen basaltic rock samples were collected from central Jordan at the Atarous volcanism basaltic flow area. The samples cover about 8 km2 from the Atarous Basalt flow (AB). The AB flow was introduced in the Miocene to Pleistocene periods. The samples analyze major and trace elements by using XRF. Petrography, Geochemistry and Petrogensis have investigation to carried out for the AB. The petrography analyses of the AB rocks show they are composed of plagioclase (labradorite and bytownite), pyroxene (augite), and olivine (forsterite);accessory minerals include apatite and secondary minerals magnetite, ilmenite, spinel and iddingsite. The AB is classified within alkaline to sub-alkaline and tholeiitic to Calc-Alkaline basalt. The Mg# range between 0.39 and 0.49 of basalt samples exhibits different degrees of fractionation with a low degree of melting < 15% as indicated from the varying concentration of incompatible trace elements Ba, Rb, Sr. Trace elements of primary magna show low variable abundances of compatible and incompatible elements, which reflecs a homogenous source. Geochemical parameters such as Mg# and high Ti contents indicate that the corresponding magmas are of primary origin. The tectonic setting of AB is explained by using discrimination diagrams, Ti-Zr-Sr and Nb-Zr-Y and Ti-Zr-Y, the AB plotted within the plate basalt, alkali basalt and Calk alkaline basalt field, respectively. The spider diagram shows the samples AB enrichment of the Ba, K, Nb and Ce, depletion of Nb and Y. The AB exhibited positive Nb, Ce and Ti anomalies, and negative anomalies of Ba, Sr, and P. It is attributed to the fractionation of feldspar for Ba and Sr and apatite for P depletion. The spider diagram showed a positive Nb peak, which conforms to the tertiary and to recent continental alkali basalt provinces and indicates that the AB is the product of lithosphere from upwelling asthenosphere mantle.

Geochemistry and environment evolution of Core E in the Laizhou Bay since last stage of Middle Pleistocene

Geochemistry analysis has been done on Core E (37 07' N, 118 55' E; depth: 82.1 m) taken from the Laizhou Bay in 1994. Nine kinds of invariable elements, 15 kinds of microelements and the content of lime carbonate are measured by means of ICP. The results indicate that most of the invariable elements and microelements in Core E show significant changes in the boundary stratotype, and the ratios between elements (Mn/Fe, Sr/Ba, Ti/Al) in particular. So they can be used as characteristic indicator to stratigraphic division of Quaternary. The changes of invariable elements are primarily controlled by the host minerals, and they mainly indicate the provenance as well as the sedimentation and depositional environment. Several elements, such as Fe, Al, Ca, Mg, Mn and Ti, are very sensitive to the provenance and environment. The distribution of microelements differs in four depositional periods: last stage of Middle Pleistocene, last interglacial period, last glacial period and Recent epoch, and especially in the 'cold period' and 'warm period'. The loops in the cycle curves of the most microelements correspond with the sand bed sediments, among which there are six sand units representing 'warm period' sediments, and one representing 'cold period' sediments. The carbonate is on the high side in the aeolian silt sediments formed in the glacial lowering of sea level in Core E, but on the low side in the transgressive sand beds formed in the interglacial period. The content variation of carbonate has a direct bearing on the grain size and the styles of sediments, and is a good indicator to the climate, environment and stratigraphic division.