Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency...Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency(RF) chains increase exponentially with the bit resolution of analog-to-digital converters(ADCs) and digital-to-analog converters(DACs). One promising solution is to employ few RF chains with low-bit ADCs and DACs. In this paper, we consider mmWave large-scale MIMO systems with low bits DACs and ADCs. Leveraging on the Bussgang theorem and the additive quantization noise model(AQNM), a closed-form expression of the achievable rate is derived to show the effect of the ADCs? and DACs? resolution. Moreover, an orthogonal matching pursuit(OMP) based hybrid precoding algorithm is proposed to increase the achievable rate. Our results show that the impact of DACs is more pronounced than the impact of ADCs. Furthermore, 5-bit ADCs and DACs are sufficient at the transceiver to operate without a significant performance loss.展开更多
Graphene is a new promising candidate for application in radio-frequency (RF) electronics due to its excellent elec- tronic properties such as ultrahigh carrier mobility, large threshold current density, and high sa...Graphene is a new promising candidate for application in radio-frequency (RF) electronics due to its excellent elec- tronic properties such as ultrahigh carrier mobility, large threshold current density, and high saturation velocity. Recently, much progress has been made in the graphene-based RF field-effect transistors (RF-FETs). Here we present for the first time the high-performance top-gated RF transistors using millimeter-scale single graphene domain on a SiO2/Si substrate through a conventional microfabrication process. A maximum cut-off frequency of 178 GHz and a peak maximum os- cillation frequency of 35 GHz are achieved in the graphene-domain-based FET with a gate length of 50 nm and 150 nm, respectively. This work shows that the millimeter-scale single graphene domain has great potential applications in RF devices and circuits.展开更多
Millimeter-wave(mm Wave) communications will be used in fifth-generation(5G) mobile communication systems, but they experience severe path loss and have high sensitivity to physical objects, leading to smaller cell ra...Millimeter-wave(mm Wave) communications will be used in fifth-generation(5G) mobile communication systems, but they experience severe path loss and have high sensitivity to physical objects, leading to smaller cell radii and complicated network architectures. A coverage extension scheme using large-scale antenna arrays(LSAAs) has been suggested and theoretically proven to be cost-efficient in combination with ultradense small cell networks. To analyze and optimize the LSAA-based network deployments, a comprehensive survey of recent advances in statistical mmWave channel modeling is first presented in terms of channel parameter estimation, large-scale path loss models, and small-scale cluster models. Next, the measurement and modeling results at two 5G candidate mmWave bands(e.g., 28 GHz and 39 GHz) are reviewed and compared in several outdoor scenarios of interest, where the propagation characteristics make crucial contributions to wireless network designs. Finally, the coverage behaviors of systems employing a large number of antenna arrays are discussed, as well as some implications on future mmWave cellular network designs.展开更多
Scaling is an important measure of multi-scale fluctuation systems. Turbulence as the most remarkable multi-scale system possesses scaling over a wide range of scales. She-Leveque (SL) hierarchical symmetry, since i...Scaling is an important measure of multi-scale fluctuation systems. Turbulence as the most remarkable multi-scale system possesses scaling over a wide range of scales. She-Leveque (SL) hierarchical symmetry, since its publication in 1994, has received wide attention. A number of experimental, numerical and theoretical work have been devoted to its verification, extension, and modification. Application to the understanding of magnetohydrodynamic turbulence, motions of cosmic baryon fluids, cosmological supersonic turbulence, natural image, spiral turbulent patterns, DNA anomalous composition, human heart variability are just a few among the most successful examples. A number of modified scaling laws have been derived in the framework of the hierarchical symmetry, and the SL model parameters are found to reveal both the organizational order of the whole system and the properties of the most significant fluctuation structures. A partial set of work related to these studies are reviewed. Particular emphasis is placed on the nature of the hierarchical symmetry. It is suggested that the SL hierarchical symmetry is a new form of the self-organization principle for multi-scale fluctuation systems, and can be employed as a standard analysis tool in the general multi-scale methodology. It is further suggested that the SL hierarchical symmetry implies the existence of a turbulence ensemble. It is speculated that the search for defining the turbulence ensemble might open a new way for deriving statistical closure equations for turbulence and other multi-scale fluctuation systems.展开更多
This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization ...This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method (LBM) can simulate the CO2 displacement processes in a two-dimensional or three-dimensional (3D) pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.展开更多
This paper deals with the problem of decentralized robustcontrol for a class of interconnected uncertain systemswith state delays.The parameter uncertainties are un-known but norm-bounded.A new sufficient condition is...This paper deals with the problem of decentralized robustcontrol for a class of interconnected uncertain systemswith state delays.The parameter uncertainties are un-known but norm-bounded.A new sufficient condition isobtained for each subsystem and overall system to be sta-bilizable via linear memoryless state feedback robust de-centralized controllers.The results depend on the size of the delays and are given in terms of linear matrix ine-qualities,so they are less conservative than those of delay-independent.Moreover,matching condition is not a necessary condition.Finally,an example is presented to illustrative the effectiveness of the proposed method.展开更多
Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analy...Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analysis of the potential value of livestock manure, the suggestion and strategy for utilization of livestock manure resources were proposed based on the actual conditions in Yangzhou city.展开更多
2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction ti...2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.展开更多
Based on the remote sensing images of algae, the present work analyzes the horizontal distribution characteristics of algal blooms in Chaohu Lake, China, which also reveals the frequency of algal blooms under differen...Based on the remote sensing images of algae, the present work analyzes the horizontal distribution characteristics of algal blooms in Chaohu Lake, China, which also reveals the frequency of algal blooms under different wind directions. Further, an unstructured-grid, three-dimensional finite-volume coastal ocean model (FVCOM) is applied to investigate the wind-induced currents and the transport pro- cess to explain the reason why algal blooms occur at the detected places. We first deduce the primary distribution of biomass from overlaid satellite images, and explain the formation mechanism by analyzing the pollution sources, and simulating the flow field and transportation process under prevailing wind over Chaohu Lake. And then, we consider the adjustment action of the wind on the corresponding day and develop a two-time scale approach to describe the whole formation process of algae horizontal distribution in Chaohu Lake. That is, on the longer time scale, i.e., during bloom season, prevailing wind determines the primary distribution of biomass by inducing the characteristic flow field; on the shorter time scale, i.e., on the day when bloom occurs, the wind force adjusts the primary distribution of biomass to form the final distribution of algal bloom.展开更多
In this paper,the nonlinear dynamic behavior of a string-beam coupled system subjected to external,parametric and tuned excitations is presented.The governing equations of motion are obtained for the nonlinear transve...In this paper,the nonlinear dynamic behavior of a string-beam coupled system subjected to external,parametric and tuned excitations is presented.The governing equations of motion are obtained for the nonlinear transverse vibrations of the string-beam coupled system which are described by a set of ordinary differential equations with two degrees of freedom.The case of 1:1 internal resonance between the modes of the beam and string,and the primary and combined resonance for the beam is considered.The method of multiple scales is utilized to analyze the nonlinear responses of the string-beam coupled system and obtain approximate solutions up to and including the second-order approximations.All resonance cases are extracted and investigated.Stability of the system is studied using frequency response equations and the phase-plane method.Numerical solutions are carried out and the results are presented graphically and discussed.The effects of the different parameters on both response and stability of the system are investigated.The reported results are compared to the available published work.展开更多
The formation of mineral scale is a complex problem during the oilfield operations. Scale inhibitors are widely used to prevent salt precipitation within reservoirs, in downhole equipment, and in production facilities...The formation of mineral scale is a complex problem during the oilfield operations. Scale inhibitors are widely used to prevent salt precipitation within reservoirs, in downhole equipment, and in production facilities. The scale inhibitors not only must have high effectiveness to prevent scale formation, but also have good adsorption- desorption characteristics, which determine the operation duration of the scale inhibitors. This work is focused on the development of a new scale inhibitor for preventing cal- cium carbonate formation in three different synthetic for- mation waters. Scale inhibition efficiency, optical density of the solution, induction time of calcium carbonate for- mation, corrosion activity, and adsorption-desorption ability were investigated for the developed scale inhibitor. The optimum concentration of hydrochloric acid in the inhibitor was determined by surface tension measurement on the boundary layer between oil and the aqueous scale inhibitor solution. The results show that the optimum mass percentage of 5 % hydrochloric acid solution in the inhi- bitor was in the range of 8 % to 10 %. The new scale inhibitor had high efficiency at a concentration of 30 mg/L. The results indicate that the induction period for calcium carbonate nucleation in the presence of the new inhibitor was about 3.5 times longer than the value in the absence of the inhibitors. During the desorption process at reservoir conditions, the number of pore volumes injected into the carbonate core for the developed inhibitor was significantly greater than the volume of a tested industrial inhibitor, showing better adsorption/desorption capacity.展开更多
The Bohai Bay Basin is a typical oil-prone basin, in which natural gas geological reserves have a small proportion. In this basin, the gas source rock is largely medium-deep lake mudstone with oil-prone type Ⅱ2-Ⅱ1 k...The Bohai Bay Basin is a typical oil-prone basin, in which natural gas geological reserves have a small proportion. In this basin, the gas source rock is largely medium-deep lake mudstone with oil-prone type Ⅱ2-Ⅱ1 kerogens, and natural gas preservation conditions are poor due to active late tectonic movements. The formation conditions of large natural gas fields in the Bohai Bay Basin have been elusive. Based on the exploration results of Bohai Bay Basin and comparison with large gas fields in China and abroad, the formation conditions of conventional large-scale natural gas reservoirs in the Bohai Bay Basin were examined from accumulation dynamics, structure and sedimentation. The results show that the formation conditions of conventional large natural gas reservoirs in Bohai Bay Basin mainly include one core element and two key elements. The core factor is the strong sealing of Paleogene "quilt-like" overpressure mudstone. The two key factors include the rapid maturation and high-intensity gas generation of source rock in the late stage and large scale reservoir. On this basis, large-scale nature gas accumulation models in the Bohai Bay Basin have been worked out, including regional overpressure mudstone enriching model, local overpressure mudstone depleting model, sand-rich sedimentary subsag depleting model and late strongly-developed fault depleting model. It is found that Bozhong sag, northern Liaozhong sag and Banqiao sag have favorable conditions for the formation of large-scale natural gas reservoirs, and are worth exploring. The study results have important guidance for exploration of large scale natural gas reservoirs in the Bohai Bay Basin.展开更多
The multi-fractal ity over China are studied behaviors of relative humid using the multi-fractal de trended fluctuation analysis (DFA) method. Three multi fractal parameters (the spectrum width Aa, the asymmetry Aa...The multi-fractal ity over China are studied behaviors of relative humid using the multi-fractal de trended fluctuation analysis (DFA) method. Three multi fractal parameters (the spectrum width Aa, the asymmetry Aaas, and the long-range correlation exponent a0) of the singularity spectrum are introduced to quantify the multi-fractal behaviors. The results show that multi-frac tality exists in daily humidity records over most stations in China and is mainly due to the broad distribution of the probability density of the sequence values. Strong multi fractal behaviors over some stations in the Yunnan, Guangdong, and Inner Mongolia provinces are obvious. These behaviors are mainly caused by different long range correlations between large and small fluctuations. The asymmetry of the singularity of relative humidity records is weak, except for a small number of stations in the far east and west of China, where the singularity spec trum is left-skewed. Finally, the long-range correlations in North China are stronger than those in South China, which indicates better predictability in North China. By studying the parameters of the multi-fractal spectrum, various data of long-range power law correlations of the relative humidity records are obtained, which may pro vide theoretical support for climate prediction.展开更多
A millimeter scale butterfly-shaped reactor was proposed based on sizing-up strategy and fabricated via femtosecond laser engraving. An improvement of mixing performance and residence time distribution was realized by...A millimeter scale butterfly-shaped reactor was proposed based on sizing-up strategy and fabricated via femtosecond laser engraving. An improvement of mixing performance and residence time distribution was realized by means of contraction and expansion of the reaction channel. The liquid holdup was greatly increased through connection of multiple mixing units. Structure optimization of the reactor was carried out by computational fluid dynamics simulation, from which the effect of reactor internals on mixing and the influence of parallel branching structure on heat transfer were discussed. The UV–vis absorption spectroscopy was used to determine the residence time distribution in the reactor, and characteristic parameters such as skewness and dimensionless variance were obtained. Further, a chained stagnant flow model was proposed to precisely describe the trailing phenomenon caused by fluid stagnation and laminar flow in small scale reactors, which enables a better fit for the experimental results of the asymmetric residence time distribution. In addition, the heat transfer performance of the reactor was investigated, and the overall heat transfer coefficient was 110–600 W m^(-2)K-1in the flow rate range of 10–40 m L/min.展开更多
基金supported in part by the National Key R&D Program of China (No. 2016YFE0200900)Major Projects of Beijing Municipal Science and Technology Commission (No. Z181100003218010)+3 种基金National Natural Science Foundation of China (Nos. 61601020, 61725101 and U1834210)the Beijing Natural Science Foundation (Nos. 4182049, L171005 and L172020)the open research fund of National Mobile Communications Research Laboratory, Southeast University (No. 2018D04)Key Laboratory of Optical Communication and Networks (No. KLOCN2018002)
文摘Millimeter wave(mmWave) and large-scale multiple input multiple output(MIMO) are two emerging technologies in fifth-generation wireless communication systems. The power consumption and hardware cost of radio frequency(RF) chains increase exponentially with the bit resolution of analog-to-digital converters(ADCs) and digital-to-analog converters(DACs). One promising solution is to employ few RF chains with low-bit ADCs and DACs. In this paper, we consider mmWave large-scale MIMO systems with low bits DACs and ADCs. Leveraging on the Bussgang theorem and the additive quantization noise model(AQNM), a closed-form expression of the achievable rate is derived to show the effect of the ADCs? and DACs? resolution. Moreover, an orthogonal matching pursuit(OMP) based hybrid precoding algorithm is proposed to increase the achievable rate. Our results show that the impact of DACs is more pronounced than the impact of ADCs. Furthermore, 5-bit ADCs and DACs are sufficient at the transceiver to operate without a significant performance loss.
基金supported by the National Basic Research Program of China(Grant Nos.2011CBA00600,2011CBA00601,and 2013CBA01604)the National Natural Science Foundation of China(Grant No.60625403)the National Science and Technology Major Project of China(Grant No.2011ZX02707)
文摘Graphene is a new promising candidate for application in radio-frequency (RF) electronics due to its excellent elec- tronic properties such as ultrahigh carrier mobility, large threshold current density, and high saturation velocity. Recently, much progress has been made in the graphene-based RF field-effect transistors (RF-FETs). Here we present for the first time the high-performance top-gated RF transistors using millimeter-scale single graphene domain on a SiO2/Si substrate through a conventional microfabrication process. A maximum cut-off frequency of 178 GHz and a peak maximum os- cillation frequency of 35 GHz are achieved in the graphene-domain-based FET with a gate length of 50 nm and 150 nm, respectively. This work shows that the millimeter-scale single graphene domain has great potential applications in RF devices and circuits.
基金supported in part by the National Natural Science Foundation of China under Grant No.61671145the Key R&D Program of Jiangsu Province of China under Grant BE2018121
文摘Millimeter-wave(mm Wave) communications will be used in fifth-generation(5G) mobile communication systems, but they experience severe path loss and have high sensitivity to physical objects, leading to smaller cell radii and complicated network architectures. A coverage extension scheme using large-scale antenna arrays(LSAAs) has been suggested and theoretically proven to be cost-efficient in combination with ultradense small cell networks. To analyze and optimize the LSAA-based network deployments, a comprehensive survey of recent advances in statistical mmWave channel modeling is first presented in terms of channel parameter estimation, large-scale path loss models, and small-scale cluster models. Next, the measurement and modeling results at two 5G candidate mmWave bands(e.g., 28 GHz and 39 GHz) are reviewed and compared in several outdoor scenarios of interest, where the propagation characteristics make crucial contributions to wireless network designs. Finally, the coverage behaviors of systems employing a large number of antenna arrays are discussed, as well as some implications on future mmWave cellular network designs.
基金the National Natural Science Foundation(90716008)MOST 973 project (2009CB724100)
文摘Scaling is an important measure of multi-scale fluctuation systems. Turbulence as the most remarkable multi-scale system possesses scaling over a wide range of scales. She-Leveque (SL) hierarchical symmetry, since its publication in 1994, has received wide attention. A number of experimental, numerical and theoretical work have been devoted to its verification, extension, and modification. Application to the understanding of magnetohydrodynamic turbulence, motions of cosmic baryon fluids, cosmological supersonic turbulence, natural image, spiral turbulent patterns, DNA anomalous composition, human heart variability are just a few among the most successful examples. A number of modified scaling laws have been derived in the framework of the hierarchical symmetry, and the SL model parameters are found to reveal both the organizational order of the whole system and the properties of the most significant fluctuation structures. A partial set of work related to these studies are reviewed. Particular emphasis is placed on the nature of the hierarchical symmetry. It is suggested that the SL hierarchical symmetry is a new form of the self-organization principle for multi-scale fluctuation systems, and can be employed as a standard analysis tool in the general multi-scale methodology. It is further suggested that the SL hierarchical symmetry implies the existence of a turbulence ensemble. It is speculated that the search for defining the turbulence ensemble might open a new way for deriving statistical closure equations for turbulence and other multi-scale fluctuation systems.
基金The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China (Grant Nos. 51374213 and 51674251), the State Key Research Development Program of China (Grant No. 2016YFC0600705), the National Natural Science Fund for Distinguished Young Scholars of China (Grant No. 51125017), the Fund for Innovative Research and Development Group Program of Jiangsu Province (Grant No. 2014- 27), the Science Fund for Creative Research Groups of the National Natural Science Foundation of China (Grant No. 51421003), and the Priority Academic Program Development of the Jiangsu Higher Education Institutions (PAPD 2014).
文摘This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method (LBM) can simulate the CO2 displacement processes in a two-dimensional or three-dimensional (3D) pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.
基金China Postdoctotral Foundation and Shanghai Postdoctoral Foundation
文摘This paper deals with the problem of decentralized robustcontrol for a class of interconnected uncertain systemswith state delays.The parameter uncertainties are un-known but norm-bounded.A new sufficient condition isobtained for each subsystem and overall system to be sta-bilizable via linear memoryless state feedback robust de-centralized controllers.The results depend on the size of the delays and are given in terms of linear matrix ine-qualities,so they are less conservative than those of delay-independent.Moreover,matching condition is not a necessary condition.Finally,an example is presented to illustrative the effectiveness of the proposed method.
基金Cultivated Land Quality Monitoring Special Funds in Jiangsu Province,Jiangsu Agricultural Three Engineerings(sx(2010)229)Yangzhou Agricultural Science and Technology Project(YZ2010059)Aid
文摘Based on surveying the conditions of large -scale farms and commercial manure in the each county of Yangzhou city, the situations and problems for utilization of livestock manure resources were grasped. After an analysis of the potential value of livestock manure, the suggestion and strategy for utilization of livestock manure resources were proposed based on the actual conditions in Yangzhou city.
基金funded by the National Natural Science Foundation of China(Nos.21991103,21991104,22008074,22008072)Natural Science Foundation of Shanghai(No.20ZR1415700)China Postdoctoral Science Foundation(Nos.2020M671025,2019TQ0093)。
文摘2-Hydroxycarbazole and 4-hydroxycarbazole are important chemicals with extensive applications in optoelectronic materials and pharmaceutical field.State of the art yield of 2-hydroxycarbazole is~30%and the reaction time is typically in hours or days.Herein,we developed a green route for the continuous and high-throughput synthesis of 2-hydroxycarbazole and 4-hydroxycarbazole via photochemical intramolecular cyclization of 3–hydroxy-2–chloro-diphenylamine using a self-designed millimeter scale photoreactor,which was designed based on sizing-up and numbering-up strategies for a decent liquid holdup(6.8 m L)and fabricated via femtosecond laser engraving technique.The photochemical synthesis was carried out continuously under the illumination of 365 nm UV-LED with dimethyl sulfoxide as solvent and potassium t-butoxide as catalyst.It was found that under optimized conditions a 2-hydroxycarbazole yield of 31.6%and a 4-hydroxycarbazole yield of 11.1%were obtained with a residence time of 1 min.Compared to semibatch operations,the reaction time was shortened by 1–2 orders of magnitude.As a result,a throughput of 11.3 g/day 2-hydroxycarbazole and 4.0 g/day 4-hydroxycarbazole can be achieved from the photoreactor.It was proposed that the short reaction time and high product yield are resulted from higher photon transfer rates and more uniform photon distribution provided by the millimeter scale photoreactor,which enhances the reaction rates and mitigates overreaction.
基金supported by the Hundred Talents Program of Chinese Academy of Sciencesthe National Natural Science Fundation of China for Distinguished Young Scholar(10825211)
文摘Based on the remote sensing images of algae, the present work analyzes the horizontal distribution characteristics of algal blooms in Chaohu Lake, China, which also reveals the frequency of algal blooms under different wind directions. Further, an unstructured-grid, three-dimensional finite-volume coastal ocean model (FVCOM) is applied to investigate the wind-induced currents and the transport pro- cess to explain the reason why algal blooms occur at the detected places. We first deduce the primary distribution of biomass from overlaid satellite images, and explain the formation mechanism by analyzing the pollution sources, and simulating the flow field and transportation process under prevailing wind over Chaohu Lake. And then, we consider the adjustment action of the wind on the corresponding day and develop a two-time scale approach to describe the whole formation process of algae horizontal distribution in Chaohu Lake. That is, on the longer time scale, i.e., during bloom season, prevailing wind determines the primary distribution of biomass by inducing the characteristic flow field; on the shorter time scale, i.e., on the day when bloom occurs, the wind force adjusts the primary distribution of biomass to form the final distribution of algal bloom.
文摘In this paper,the nonlinear dynamic behavior of a string-beam coupled system subjected to external,parametric and tuned excitations is presented.The governing equations of motion are obtained for the nonlinear transverse vibrations of the string-beam coupled system which are described by a set of ordinary differential equations with two degrees of freedom.The case of 1:1 internal resonance between the modes of the beam and string,and the primary and combined resonance for the beam is considered.The method of multiple scales is utilized to analyze the nonlinear responses of the string-beam coupled system and obtain approximate solutions up to and including the second-order approximations.All resonance cases are extracted and investigated.Stability of the system is studied using frequency response equations and the phase-plane method.Numerical solutions are carried out and the results are presented graphically and discussed.The effects of the different parameters on both response and stability of the system are investigated.The reported results are compared to the available published work.
文摘The formation of mineral scale is a complex problem during the oilfield operations. Scale inhibitors are widely used to prevent salt precipitation within reservoirs, in downhole equipment, and in production facilities. The scale inhibitors not only must have high effectiveness to prevent scale formation, but also have good adsorption- desorption characteristics, which determine the operation duration of the scale inhibitors. This work is focused on the development of a new scale inhibitor for preventing cal- cium carbonate formation in three different synthetic for- mation waters. Scale inhibition efficiency, optical density of the solution, induction time of calcium carbonate for- mation, corrosion activity, and adsorption-desorption ability were investigated for the developed scale inhibitor. The optimum concentration of hydrochloric acid in the inhibitor was determined by surface tension measurement on the boundary layer between oil and the aqueous scale inhibitor solution. The results show that the optimum mass percentage of 5 % hydrochloric acid solution in the inhi- bitor was in the range of 8 % to 10 %. The new scale inhibitor had high efficiency at a concentration of 30 mg/L. The results indicate that the induction period for calcium carbonate nucleation in the presence of the new inhibitor was about 3.5 times longer than the value in the absence of the inhibitors. During the desorption process at reservoir conditions, the number of pore volumes injected into the carbonate core for the developed inhibitor was significantly greater than the volume of a tested industrial inhibitor, showing better adsorption/desorption capacity.
基金Supported by the China National Science and Technology Major Project (2016ZX05024-003)
文摘The Bohai Bay Basin is a typical oil-prone basin, in which natural gas geological reserves have a small proportion. In this basin, the gas source rock is largely medium-deep lake mudstone with oil-prone type Ⅱ2-Ⅱ1 kerogens, and natural gas preservation conditions are poor due to active late tectonic movements. The formation conditions of large natural gas fields in the Bohai Bay Basin have been elusive. Based on the exploration results of Bohai Bay Basin and comparison with large gas fields in China and abroad, the formation conditions of conventional large-scale natural gas reservoirs in the Bohai Bay Basin were examined from accumulation dynamics, structure and sedimentation. The results show that the formation conditions of conventional large natural gas reservoirs in Bohai Bay Basin mainly include one core element and two key elements. The core factor is the strong sealing of Paleogene "quilt-like" overpressure mudstone. The two key factors include the rapid maturation and high-intensity gas generation of source rock in the late stage and large scale reservoir. On this basis, large-scale nature gas accumulation models in the Bohai Bay Basin have been worked out, including regional overpressure mudstone enriching model, local overpressure mudstone depleting model, sand-rich sedimentary subsag depleting model and late strongly-developed fault depleting model. It is found that Bozhong sag, northern Liaozhong sag and Banqiao sag have favorable conditions for the formation of large-scale natural gas reservoirs, and are worth exploring. The study results have important guidance for exploration of large scale natural gas reservoirs in the Bohai Bay Basin.
基金supported by the National Natural Science Foundation of China (40975027)
文摘The multi-fractal ity over China are studied behaviors of relative humid using the multi-fractal de trended fluctuation analysis (DFA) method. Three multi fractal parameters (the spectrum width Aa, the asymmetry Aaas, and the long-range correlation exponent a0) of the singularity spectrum are introduced to quantify the multi-fractal behaviors. The results show that multi-frac tality exists in daily humidity records over most stations in China and is mainly due to the broad distribution of the probability density of the sequence values. Strong multi fractal behaviors over some stations in the Yunnan, Guangdong, and Inner Mongolia provinces are obvious. These behaviors are mainly caused by different long range correlations between large and small fluctuations. The asymmetry of the singularity of relative humidity records is weak, except for a small number of stations in the far east and west of China, where the singularity spec trum is left-skewed. Finally, the long-range correlations in North China are stronger than those in South China, which indicates better predictability in North China. By studying the parameters of the multi-fractal spectrum, various data of long-range power law correlations of the relative humidity records are obtained, which may pro vide theoretical support for climate prediction.
基金funded by the National Natural Science Foundation of China (Nos. 21991103, 21991104, 22008074, 22008072)Natural Science Foundation of Shanghai (No. 20ZR1415700)China Postdoctoral Science Foundation (Nos. 2020M671025,2019TQ0093)。
文摘A millimeter scale butterfly-shaped reactor was proposed based on sizing-up strategy and fabricated via femtosecond laser engraving. An improvement of mixing performance and residence time distribution was realized by means of contraction and expansion of the reaction channel. The liquid holdup was greatly increased through connection of multiple mixing units. Structure optimization of the reactor was carried out by computational fluid dynamics simulation, from which the effect of reactor internals on mixing and the influence of parallel branching structure on heat transfer were discussed. The UV–vis absorption spectroscopy was used to determine the residence time distribution in the reactor, and characteristic parameters such as skewness and dimensionless variance were obtained. Further, a chained stagnant flow model was proposed to precisely describe the trailing phenomenon caused by fluid stagnation and laminar flow in small scale reactors, which enables a better fit for the experimental results of the asymmetric residence time distribution. In addition, the heat transfer performance of the reactor was investigated, and the overall heat transfer coefficient was 110–600 W m^(-2)K-1in the flow rate range of 10–40 m L/min.