SYNERGISTIC EFFECT OF MINERAL SURFACE CONSTITUENTS IN DEXTRIN ADSORPTION

As part of a systematic research on the interaction mechanism between polysaccharides and mineral surfaces, ive extend the studies on dextrin adsorption to real minerals such as oxides and salt-type minerals, based on previous studies of model systems {surface-modified quartz ). The minerals tested include hematite, rutile, fluorite, calcite, apatite, etc. It is observed that dextrin adsorption on these minerals is strongly pH-depen-dent, with adsorption maxima appearing at pH values around the isoelec-tric points of the minerals, indicating interactions zvith surface metal hy-droxide species. X-ray photoelectron spectroscopy (XPS) measurements re-veal electronic binding energy shifts or Auger parameter changes of miner-al surface elements after dextrin adsorption , pointing to a chemical mecha-nism of interaction. Furthermore, it is observed that the reaction of miner-als with moderate amounts of fatty acids prior to dextrin addition results in an increase in dextrin adsorption, whereas excessive fatty acids do the opposite. Combined with our previous studies, it is concluded from the ex-perimental observations that although surface hydrophobic species alone do not have any effect on dextrin adsorption, they synergistically enhance the adsorption when present together with surface metallic sites.

Characteristics of the mineral phase constituents of lacustrine deposits from the Fildes Peninsula of King George Island,Antarctica and their environmental implication

Based on analytical data of mineral phase constituents at three sections from Tern Lake, West Lake and Kitezh Lake in the Fildes Peninsula of King George Island, Antarctica, the characteristics of mineral phase constituents, material source and their environmental implication have been discussed. Research results indicate that lacustrine deposits came primarily from widespread volcanic rocks at the peninsula. Under cold and dry condition in Antarctica, the weathering process of the parent rocks in some area is mainly physical weathering with a weak chemical one. The relation curves of abundance of kaolinite and calcite against deposition age change steeply at the boundary between lacustrine and glacial deposits, indicating that the corresponding environment changes are abrupt, which may be related to different transportation fashion of both different deposits and the protection of glacial deposits.

Mineralogical Characteristics of Yellow- Red Soils Derived from Granite

Mineral constituents and their weathering in yellow-red soils derived from granite in middle and lower reaches of the Yangtze R iver were studied. Light minerals in fractions greater than silt contained over 80% quartz and feldspar, and heavy ones contained more than 60% various iron minerals and about 30% mica and hornblende. Kaolinite was the main clay mineral, the content of which was about 300 -400 g/ kg. Quartz was weathered very weakly, Ca-feldspar was weathered over 65%, and about 25% of Na-feldspar was weathered. The vermiculitisation of mica was relativly obvious, > 50% of mica being weathered to vermiculite. Weatherable minerals were also obviously weathered, the weathering being about 60%. Soil vermiculite was evolved through the process of mica→hydromica→vermiculite-chlorite→vermiculite, which was closely related to leaching situation and oxidic condition.

Origin of Quaternary Red Clay of Southern Anhui Province

The particle size distribution, heavy mineral constituents and rare earth elements (REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay. The results showed that the clay had some properties of areolian deposits, which could be compared with those of the loess in North China; and its chondrite normalized curves of REE were similar to those of the Xiashu loess, implying that they shared the same origin. It was concluded in combination with the results reported by other researchers that the Quaternary red clay of southern Anhui Province originated from aeolian deposits, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.

Log identification method in complex sand reservoirs

In order to obtain effective parameters for complex sand reservoirs,a log evaluation method for relevant reservoir parameters is established based on an analysis in the gas-bearing sandstone with high porosity and low permeability,low porosity and permeability and on various characteristics of log responses to reservoir lithologies and physical properties in the Neopleozoic sand reservoir of the Ordos basin.This log evaluation method covers the Cook method that is used to evaluate the porosity and oiliness in high porosity and low permeability reservoirs and another method in which the mineral content,derived from geochemical logs,is used to identify formation lithologies.Some areas have high calcium and low silt content,not uniformly distributed,the results of which show up in the complex formation lithologies and conventional log responses with great deviation.The reliability of the method is verified by comparison with conventional log data and core analyses.The calculation results coincide with the core analytical data and gas tests,which indicate that this log evaluation method is available,provides novel ideas for study of similar complex reservoir lithologies and has some reference value.