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Influence of TiO_2 Mineralizer on the Crystalline Structure of Cordierite Synthesized from Aluminum Slag 被引量:5
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作者 阮玉忠 吴任平 于岩 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第5期596-600,493,共6页
By adding small amount of TiO2, aluminum slag could be used to synthesize cor- dierite. α-Al2O3, TiO2 and dehydrated talc could generate solid solution to accelerate the solid-state reaction to form cordierite. The e... By adding small amount of TiO2, aluminum slag could be used to synthesize cor- dierite. α-Al2O3, TiO2 and dehydrated talc could generate solid solution to accelerate the solid-state reaction to form cordierite. The experimental results show that the content of cordierite increases with the increase of TiO2 added. 3.0% of TiO2 is determined to be the best amount, because all crystalline substances are converted into cordierite at this content. Philips X’pert plus software analysis shows that when the content of TiO2 is from 0 to 1.0%, cordierite has the same hexagonal structure as the single crystal and the lattice parameters change slightly; when the content of TiO2 is from 1.0 to 2.0%, the cordierite still keeps hexagonal structure but the lattice parameters change greatly; when the content of TiO2 is from 2.0 to 3.5%, the cordierite is converted from hexagonal into rhombic and the lattice parameters change accordingly. 展开更多
关键词 aluminum slag TiO2 mineralizer CORDIERITE crystalline structure
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Influence of MnO_2 Mineralizer on the Crystal Structure,Properties of SiC Kiln Furniture Bonded with Fine Silicon Powder 被引量:4
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作者 RUAN Yu-Zhong WU Wan-Guo +2 位作者 YU Yan ZHAN Hong-Bing LIN Chun-Ying(Department of Chemlcal Engineering, Fuzhou University, 350002) 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1997年第5期397-402,共6页
The properties of SiC kiln furniture bonded with fine silicon powderare related to the bonder’s crystal structure. At high temperature, it will crystallize ina-cristobalite with great bulk effect. MnO2 mineralizer ca... The properties of SiC kiln furniture bonded with fine silicon powderare related to the bonder’s crystal structure. At high temperature, it will crystallize ina-cristobalite with great bulk effect. MnO2 mineralizer can make a-cristobalite convertto a-tridymite whose bulk effect is small. The crystal structure and its amount were investigated with XRD technique. The influence of different amounts of MnO2 on thecrystal structure and polycrystal transformation, and that of crystal structure on theproperties of kiln furniture were studied. The best proportion of MnO2 added was determined to be 2.0%. 展开更多
关键词 MnO_2 mineralizer fine silicon powder SiC kiln furniture
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Chang Gao Brand Water Purifier & Mineralizer
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《China's Foreign Trade》 1994年第10期39-39,共1页
People are making excessive demands for their drinking water as they pay more and more attentions to the quality of life. Mineral water contains more calcium, magnesium and lots of trace elements than the running wate... People are making excessive demands for their drinking water as they pay more and more attentions to the quality of life. Mineral water contains more calcium, magnesium and lots of trace elements than the running water, and therefore it is good for the digestion, promotion of metabolism, prevention of cardiovascular diseases and osteoporosis, and promotion of Children growth. It has become a favourite drink for many people. 展开更多
关键词 THAN MORE Chang Gao Brand Water Purifier mineralizer
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Layered double hydroxides:Scale production and application in soil remediation as super-stable mineralizer 被引量:4
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作者 Fangqi Mao Peipei Hao +2 位作者 Yuquan Zhu Xianggui Kong Xue Duan 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2022年第1期42-48,共7页
Soil contamination by heavy metals has presented severe risks to human health through food chain.As one of the most promising remediation technologies,in-situ immobilization strategy has been widely adopted in practic... Soil contamination by heavy metals has presented severe risks to human health through food chain.As one of the most promising remediation technologies,in-situ immobilization strategy has been widely adopted in practice.However,considering the large quantities of contaminated soil,it is still a huge challenge to design low-cost amendments with strong and long-term immobilization ability.Layered double hydroxides(LDHs)have drawn tremendous attention in fundamental research and practical application because of their unique properties.Moreover,owing to its super-stable mineralization effect to heavy metal ions,LDHs have exhibited great potential in the field of soil remediation.In this work,we mainly focused on the scale production strategy of LDHs with low-cost,and its application in soil remediation.Besides,several key challenges in using LDHs as amendments for immobilization of heavy metal ions are presented.We hope that this mini-review could shed light on the sustainable development of LDHs as amendment for heavy metals in future research directions. 展开更多
关键词 Heavy metals POLLUTION REMEDIATION Layered double hydroxides Scale-up Super-stable mineralization effect
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Role of nutrition in diabetes mellitus and infections
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作者 Xue-Lu Yu Li-Yun Zhou +3 位作者 Xiao Huang Xin-Yue Li Ming-Ke Wang Ji-Shun Yang 《World Journal of Clinical Cases》 SCIE 2025年第3期1-8,共8页
In this editorial,we have commented on the article that has been published in the recent issue of World Journal of Clinical Cases.The authors have described a case of unilateral thyroid cyst and have opined that the a... In this editorial,we have commented on the article that has been published in the recent issue of World Journal of Clinical Cases.The authors have described a case of unilateral thyroid cyst and have opined that the acute onset of infection may be linked to diabetes mellitus(DM).We have focused on the role of nutrition in the association between DM and infection.Patients with DM are at a high risk of infection,which could also be attributed to nutrition-related factors.Nutritional interventions for patients with diabetes are mainly based on a low-calorie diet,which can be achieved by adhering to a low-carbohydrate diet.However,dietary fiber supplementation is recommended to maintain the diversity of the gut microbiota.Furthermore,high-quality protein can prevent the increased risk of infection due to malnutrition.Supplementation of vitamins C,vitamins A,vitamins D,and folic acid improves blood sugar control and facilitates immune regulation.Mineral deficiencies augment the risk of infection,but the relationship with diabetes is mostly U-shaped and a good intake should be maintained. 展开更多
关键词 Diabetes mellitus Infection MACRONUTRIENTS VITAMINS MINERALS
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Present status and future directions:Apexification
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作者 Sachin Chauhan Radha Chauhan +1 位作者 Prashant Bhasin Bhavna G Sharaf 《World Journal of Methodology》 2025年第1期26-32,共7页
The success rate of apexification is primarily determined by multiple factors,including the material used,the size of the open apex compared to the length of the root,and the technique used in each case.The main objec... The success rate of apexification is primarily determined by multiple factors,including the material used,the size of the open apex compared to the length of the root,and the technique used in each case.The main objective of this review was to provide an update on the present management of open apex to identify factors and circumstances that may influence the success of apexification using different materials and techniques.Future research on apexification should focus on how to treat open apices with wide periapical lesions without surgery.Previously,the predictability of these parameters with non-surgical procedures was uncertain,but now,with the use of a dental operating microscope,it has become more predictable.Another reason could be that extra visits are no longer required due to major advances in the armamentarium and materials used for apexification. 展开更多
关键词 BIOCERAMICS MAGNIFICATION Biodentine Mineral trioxide aggregate APEXIFICATION Open apex
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Tracer system on halogen mineralizer from the epithermal deposits in Guizhou Province
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作者 PAN Jiayong, ZHANG Qian and SHAO Shuxun Open Laboratory of Ore Deposit Geochemistry, Geochemistry of Institute, Chinese Academy of Sciences, Guiyang 550002, China 《Chinese Science Bulletin》 SCIE EI CAS 1999年第S2期159-161,共3页
HALOGENS are typical mineralizer elements and play a very important role in remobilization and resettlement of the ore-forming mental elements in the hydrothermal deposits. Studies of tracer system on halogens mineral... HALOGENS are typical mineralizer elements and play a very important role in remobilization and resettlement of the ore-forming mental elements in the hydrothermal deposits. Studies of tracer system on halogens mineralizer include the following aspects: (i) halogens’ role as mineralizer in ore-forming action;(ii) halogens importance as tracer elements in formation and evolution of the epithermal ore deposit;(iii) halogens’ significance as guidance in looking for the buried orebodies. Guizhou is a concentrated area of epithermal Hg, Sb and Au deposits, where are distributed famousepithermal deposits such as the Wanshan Hg deposit, the Banpo Sb deposit, the Danzhai Hg-Au depositand the Lannigou Au deposit. Many researches into geological and geochemical characteristics of thesedeposits have been done, but few study on halogen mineralizer. 展开更多
关键词 TRACER SYSTEM HALOGENS mineralizer EPITHERMAL deposits Guizhou.
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Mineralizer constraint on gold mineralization of Ailaoshan gold belt 被引量:6
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作者 胡瑞忠 毕献武 +1 位作者 何明友 刘秉光 《Science China Earth Sciences》 SCIE EI CAS 1998年第S1期74-82,共9页
After determining that sulfur is the main mineralizer of ore forming fluid of Ailaoshan gold mineralization belt in west Yunnan Province of China, the S, He and Ar isotope compositions and geological events related to... After determining that sulfur is the main mineralizer of ore forming fluid of Ailaoshan gold mineralization belt in west Yunnan Province of China, the S, He and Ar isotope compositions and geological events related to gold mineralization are studied. It is revealed that the ore forming fluid of the belt is a mixture of high temperature S rich deep seated fluid and low temperature S depleted meteoric groundwater. That the gold mineralization occurred in early Himalayan period resulted dominantly from the mantle degassing which was associated with the crust extension at that time. The forming and evolving process of ore forming fluid can be determined as: S rich deep seated fluid ascended and added to S depleted meteogenic fluid cycling in shallow fracture systems of the belt in early Himalayan period →the S depleted meteogenic fluid converted to the mixing fluid containing sufficient S→gold in surrounding rocks was extracted by the mixing fluid, and then precipitated at a suitable place to form the gold deposits. 展开更多
关键词 Ailaoshan gold MINERALIZATION BELT S He and Ar ISOTOPES S depleted meteoric GROUNDWATER S rich deep seated fluid early HIMALAYAN period.
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A review of in situ carbon mineralization in basalt 被引量:2
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作者 Xiaomin Cao Qi Li +1 位作者 Liang Xu Yongsheng Tan 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第4期1467-1485,共19页
Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable opt... Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable option for long-term carbon storage.Basalt rich in alkaline earth elements facilitates rapid and permanent CO_(2) fixation as carbonates.However,the complex CO_(2)-fluid-basalt interaction poses challenges for assessing carbon storage potential.Under different reaction conditions,the carbonation products and carbonation rates vary.Carbon mineralization reactions also induce petrophysical and mechanical responses,which have potential risks for the long-term injectivity and the carbon storage safety in basalt reservoirs.In this paper,recent advances in carbon mineralization storage in basalt based on laboratory research are comprehensively reviewed.The assessment methods for carbon storage potential are introduced and the carbon trapping mechanisms are investigated with the identification of the controlling factors.Changes in pore structure,permeability and mechanical properties in both static reactions and reactive percolation experiments are also discussed.This study could provide insight into challenges as well as perspectives for future research. 展开更多
关键词 Carbon mineralization BASALT CO_(2)-fluid-basalt interaction Petrophysical evolution Mechanical response Carbon capture and storage(CCS)
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Mineral Geochemistry of Apatite in the Jiama PorphyrySkarn Deposit,Tibet and its Geological Significance 被引量:1
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作者 YANG Yang TANG Juxing +8 位作者 ZHANG Zebin TANG Pan XIE Fuwei RAN Fengqin YANG Zongyao YANG Huaichao BAI Yun SUN Miao QI Jing 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第2期399-415,共17页
The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemi... The Jiama deposit,a significant porphyry-skarn-type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet,China,exemplifies a typical porphyry metallogenic system.However,the mineral chemistry of its accessory minerals remains under-examined,posing challenges for resource assessment and ore prospecting.Utilizing electron microprobe analysis and LA-ICP-MS analysis,this study investigated the geochemical characteristics of apatite in ore-bearing granite and monzogranite porphyries,as well as granodiorite,quartz diorite,and dark diorite porphyries in the deposit.It also delved into the diagenetic and metallogenic information from these geochemical signatures.Key findings include:(1)The SiO_(2) content,rare earth element(REE)contents,and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries;(2)the volatile F and Cl contents in apatite,along with their ratio,indicate the Jiama deposit,formed in a collisional setting,demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment;(3)compared to non-ore-bearing rock bodies in other deposits formed in a collisional setting,apatite in the Jiama deposit exhibits lower Ce and Ga contents.This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity.Nevertheless,the marginal variation in oxygen fugacity between ore-bearing and non-ore-bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore-hosting potential of rock bodies in the Jiama deposit. 展开更多
关键词 APATITE METALLOGENESIS mineral geochemistry PORPHYRY JIAMA TIBET
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Systemic modulation of skeletal mineralization by magnesium implant promoting fracture healing: Radiological exploration enhanced with PCA-based machine learning in a rat femoral model 被引量:1
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作者 Yu Sun Heike Helmholz Regine Willumeit-Römer 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第3期1009-1020,共12页
The clinical application of magnesium(Mg)and its alloys for bone fractures has been well supported by in vitro and in vivo trials.However,there were studies indicating negative effects of high dose Mg intake and susta... The clinical application of magnesium(Mg)and its alloys for bone fractures has been well supported by in vitro and in vivo trials.However,there were studies indicating negative effects of high dose Mg intake and sustained local release of Mg ions on bone metabolism or repair,which should not be ignored when developing Mg-based implants.Thus,it remains necessary to assess the biological effects of Mg implants in animal models relevant to clinical treatment modalities.The primary purpose of this study was to validate the beneficial effects of intramedullary Mg implants on the healing outcome of femoral fractures in a modified rat model.In addition,the mineralization parameters at multiple anatomical sites were evaluated,to investigate their association with healing outcome and potential clinical applications.Compared to the control group without Mg implantation,postoperative imaging at week 12 demonstrated better healing outcomes in the Mg group,with more stable unions in 3D analysis and high-mineralized bridging in 2D evaluation.The bone tissue mineral density(TMD)was higher in the Mg group at the non-operated femur and lumbar vertebra,while no differences between groups were identified regarding the bone tissue volume(TV),TMD and bone mineral content(BMC)in humerus.In the surgical femur,the Mg group presented higher TMD,but lower TV and BMC in the distal metaphyseal region,as well as reduced BMC at the osteotomy site.Principal component analysis(PCA)-based machine learning revealed that by selecting clinically relevant parameters,radiological markers could be constructed for differentiation of healing outcomes,with better performance than 2D scoring.The study provides insights and preclinical evidence for the rational investigation of bioactive materials,the identification of potential adverse effects,and the promotion of diagnostic capabilities for fracture healing. 展开更多
关键词 MAGNESIUM Implants Bone fracture MINERALIZATION Systemic modulation Principal component analysis.
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High-pressure minerals and new lunar mineral changesite-(Y) in Chang’e-5 regolith 被引量:1
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作者 Jing Yang Wei Du 《Matter and Radiation at Extremes》 SCIE EI CSCD 2024年第2期90-97,共8页
Forty-five years after the Apollo and Luna missions, China’s Chang’e-5 (CE-5) mission collected ∼1.73 kg of new lunar materials from one ofthe youngest basalt units on the Moon. The CE-5 lunar samples provide oppor... Forty-five years after the Apollo and Luna missions, China’s Chang’e-5 (CE-5) mission collected ∼1.73 kg of new lunar materials from one ofthe youngest basalt units on the Moon. The CE-5 lunar samples provide opportunities to address some key scientific questions related to theMoon, including the discovery of high-pressure silica polymorphs (seifertite and stishovite) and a new lunar mineral, changesite-(Y). Seifertitewas found to be coexist with stishovite in a silica fragment from CE-5 lunar regolith. This is the first confirmed seifertite in returned lunarsamples. Seifertite has two space group symmetries (Pnc2 and Pbcn) and formed from an α-cristobalite-like phase during “cold” compressionduring a shock event. The aftershock heating process changes some seifertite to stishovite. Thus, this silica fragment records different stagesof an impact process, and the peak shock pressure is estimated to be ∼11 to 40 GPa, which is much lower than the pressure condition forcoexistence of seifertite and stishovite on the phase diagram. Changesite-(Y), with ideal formula (Ca_(8)Y)◻Fe^(2+)(PO_(4))_(7) (where ◻ denotes avacancy) is the first new lunar mineral to be discovered in CE-5 regolith samples. This newly identified phosphate mineral is in the form ofcolumnar crystals and was found in CE-5 basalt fragments. It contains high concentrations of Y and rare earth elements (REE), reaching upto ∼14 wt. % (Y,REE)2O3. The occurrence of changesite-(Y) marks the late-stage fractional crystallization processes of CE-5 basalts combinedwith silicate liquid immiscibility. These new findings demonstrate the significance of studies on high-pressure minerals in lunar materials andthe special nature of lunar magmatic evolution. 展开更多
关键词 evolution MINERALS BASALT
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Genesis of the Nuri Cu-W-Mo Deposit,Tibet,China:Constraints from in situ Trace Elements and Sr Isotopic Analysis of Scheelite 被引量:1
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作者 WANG Yiyun WU Zhishan +8 位作者 CHEN Wenqing DU Qing’an TANG Liwei SHI Hongzhao MA Guotao ZHANG Zhi LIANG Wei WU Bo MIAO Hengyi 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第1期117-131,共15页
The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controver... The Nuri deposit is the only Cu-W-Mo polymetallic deposit with large-scale WO3 resources in the eastern section of the Gangdese metallogenic belt,Tibet,China.However,the genetic type of this deposit has been controversial since its discovery.Based on a study of the geological characteristics of the deposit,this study presents mineralization stages,focusing on the oxide stage and the quartz-sulfide stage where scheelite is mainly formed,referred to as Sch-A and Sch-B,respectively.Through LA-ICP-MS trace element and Sr isotope analyses,the origin,evolutionary process of the oreforming fluid and genesis of the ore deposit are investigated.Scanning Electron Microscope-Cathodoluminescence(SEMCL)observations reveal that Sch-A consists of three generations,with dark gray homogenous Sch-A1 being replaced by relatively lighter and homogeneous Sch-A2 and Sch-A3,with Sch-A2 displaying a gray CL image color with vague and uneven growth bands and Sch-A3 has a light gray CL image color with hardly any growth band.In contrast,Sch-B exhibits a‘core-rim’structure,with the core part(Sch-B1)being dark gray and displaying a uniform growth band,while the rim part(Sch-B2)is light gray and homogeneous.The normalized distribution pattern of rare earth elements in scheelite and Sr isotope data suggest that the early ore-forming fluid in the Nuri deposit originated from granodiorite porphyry and,later on,some country rock material was mixed in,due to strong water-rock interaction.Combining the O-H isotope data further indicates that the ore-forming fluid in the Nuri deposit originated from magmatic-hydrothermal sources,with contributions from metamorphic water caused by water-rock interaction during the mineralization process,as well as later meteoric water.The intense water-rock interaction likely played a crucial role in the precipitation of scheelite,leading to varying Eu anomalies in different generations of scheelite from the oxide stage to the quartz-sulfide stage,while also causing a gradual decrease in oxygen fugacity(fO2)and a slow rise in pH value.Additionally,the high Mo and low Sr contents in the scheelite are consistent with typical characteristics of magmatic-hydrothermal scheelite.Therefore,considering the geological features of the deposit,the geochemical characteristics of scheelite and the O-H isotope data published previously,it can be concluded that the genesis of the Nuri deposit belongs to porphyry-skarn deposit. 展开更多
关键词 trace elements in situ Sr isotopes tungsten mineralization Gangdese metallogenic belt TIBET
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Imaging the Architecture of Mineral Systems and the Pathways of Ore-forming Fluids across Mongolia with Magnetotellurics
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作者 Matthew J.COMEAU Rafael RIGAUD +4 位作者 Erdenechimeg BATMAGNAI Shoovdor TSERENDUG Sodnomsambuu DEMBEREL Michael BECKEN Alexey KUVSHINOV 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第S01期11-13,共3页
In the framework of a mineral system approach,a combination of components is required to develop a mineral system.This includes the whole-lithosphere architecture,which controls the transport of ore-forming fluids,and... In the framework of a mineral system approach,a combination of components is required to develop a mineral system.This includes the whole-lithosphere architecture,which controls the transport of ore-forming fluids,and favorable tectonic and geodynamic processes,occurring at various spatial and temporal scales,that influence the genesis and evolution of ore-forming fluids(Huston et al.,2016;Groves et al.,2018;Davies et al.,2020).Knowledge of the deep structural framework can advance the understanding of the development of a mineral system and the emplacement of mineral deposits.Deep geophysical exploration carried out with this aim is increasingly important for targeting new ore deposits in unexplored and underexplored regions(Dentith et al.,2018;Dentith,2019). 展开更多
关键词 MAGNETOTELLURICS electrical resistivity mineral exploration mineral emplacement ORE fluids fluid transport
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Research progress of CO_(2) capture and mineralization based on natural minerals
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作者 Chenguang Qian Chunquan Li +5 位作者 Peng Huang Jialin Liang Xin Zhang Jifa Wang Jianbing Wang Zhiming Sun 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第6期1208-1227,共20页
Natural minerals,such as kaolinite,halloysite,montmorillonite,attapulgite,bentonite,sepiolite,forsterite,and wollastonite,have considerable potential for use in CO_(2) capture and mineralization due to their abundant ... Natural minerals,such as kaolinite,halloysite,montmorillonite,attapulgite,bentonite,sepiolite,forsterite,and wollastonite,have considerable potential for use in CO_(2) capture and mineralization due to their abundant reserves,low cost,excellent mechanical prop-erties,and chemical stability.Over the past decades,various methods,such as those involving heat,acid,alkali,organic amine,amino sil-ane,and ionic liquid,have been employed to enhance the CO_(2) capture performance of natural minerals to attain high specific surface area,a large number of pore structures,and rich active sites.Future research on CO_(2) capture by natural minerals will focus on the full utiliza-tion of the properties of natural minerals,adoption of suitable modification methods,and preparation of composite materials with high specific surface area and rich active sites.In addition,we provide a summary of the principle and technical route of direct and indirect mineralization of CO_(2) by natural minerals.This process uses minerals with high calcium and magnesium contents,such as forsterite(Mg_(2)SiO_(4)),serpentine[Mg_(3)Si_(2)O(OH)_(4)],and wollastonite(CaSiO_(3)).The research status of indirect mineralization of CO_(2) using hydro-chloric acid,acetic acid,molten salt,and ammonium salt as media is also introduced in detail.The recovery of additives and high-value-added products during the mineralization process to increase economic benefits is another focus of future research on CO_(2) mineralization by natural minerals. 展开更多
关键词 natural mineral carbon dioxide capture MODIFICATION composite material carbon dioxide mineralization
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Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review
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作者 Shi-min Zhen Da-zhao Wang +2 位作者 Zhong-jian Zha Hai-jun Bai Jiang Wang 《China Geology》 CAS CSCD 2024年第3期533-550,共18页
The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization origi... The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit. 展开更多
关键词 Mineralization and alteration Alkaline intrusion Au deposit Physicochemical conditions Metallogenic model Oxygen fugacity Sulfur fugacity Mechanisms of mineral precipitation Fluid boiling Fluorine-enriched fluid Dongping gold deposit North China Craton Mineral exploration engineering
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Geochemistry, mineral paragenesis and geothermal conditions of oreforming fluids from the Ain El Bey Cu–Fe deposit: potential occurrence of native gold and precious metal traces (North African orogenic belt, Northern Tunisia)
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作者 Rania Ben Aissa Wiem Ben Aissa +2 位作者 Said Tlig Lassaad Ben Aissa Abdessalem Ben Haj Amara 《Acta Geochimica》 EI CAS CSCD 2024年第2期366-384,共19页
The Ain El Bey abandoned mine, in North-West Tunisia, fits into the geodynamic context of the European and African plate boundary. Ore deposit corresponds to veins and breccia of multiphase Cu–Fe-rich mineralization ... The Ain El Bey abandoned mine, in North-West Tunisia, fits into the geodynamic context of the European and African plate boundary. Ore deposit corresponds to veins and breccia of multiphase Cu–Fe-rich mineralization related to various hydrothermal fluid circulations. Petromineralogical studies indicate a rich mineral paragenesis with a minimum of seven mineralization phases and, at least, six pyrite generations. As is also the case for galena and native silver, native gold is observed for the first time as inclusion in quartz which opens up, thus, new perspectives for prospecting and evaluating the potential for noble metals associated with the mineralization. Scanning Electron Microscope--Energy Dispersive Spectroscopy and Transmission electron microscopy analyses show, in addition, a large incorporation of trace elements, including Ag and Au, in mineral structures such as fahlores(tetrahedrite-tennantite) and chalcopyrite ones. The mineral/mineral associations, used as geothermometers, gave estimated temperatures for the mineralizing fluids varying from 254 to 330 ℃ for phase Ⅲ, from 254 to 350 ℃ for phase Ⅳ, and from 200 to 300 ℃ for phases Ⅴ and Ⅵ. The seventh and last identified mineralization phase, marked by a deposit of native gold, reflects a drop in the mineralizing fluid’s temperature(< 200 ℃) compatible with boiling conditions. Such results open up perspectives for the development of precious metal research and the revaluation of the Cu–Fe ore deposit at the Ain El Bey abandoned mine, as well as at the surrounding areas fitting in the geodynamic framework of the Africa-Europe plate boundary. 展开更多
关键词 Ore-formingfluids Mineral geochemistry Mineral geothermometers Native silver-gold Ain El Bey Ore deposit North Tunisia
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Basalt Petrology, Water Chemistry, and Their Impact on the CO_(2) Mineralization Simulation at Leizhou Peninsula Sites, Southern China
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作者 Jinglian Jiang Pengchun Li +4 位作者 Changyou Xia Jianxin Cai Muxin Liu Yongbin Jin Xi Liang 《哈尔滨工程大学学报(英文版)》 CSCD 2024年第3期583-598,共16页
Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest ... Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula. 展开更多
关键词 CO_(2)mineralization Mineral carbonation Basalt carbonation Geochemistry simulation Leizhou Peninsula
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Geology and mineralization of the Hongqiling large magmatic nickel-copper-cobalt deposit(22×10^(4)t)in Jilin Province,China:A review
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作者 Cong Chen Yu-chao Gu +14 位作者 Di Zhang Tao-tao Wu Ai Li Yun-sheng Ren Qing-qing Shang Jian Zhang Xiong-fei Bian Fei Su Jia-lin Yang Qiu-shi Sun Xiao-hai Li Wan-zhen Liu Zhen-ming Sun Sen Zhang Yu-hui Feng 《China Geology》 CAS CSCD 2024年第4期762-796,共35页
The Hongqiling large nickel-copper-cobalt deposit(hereafter referred to as the Hongqiling deposit),a typical mafic-ultramafic copper-nickel deposit in China,boasts proven Ni(Ni)resources of approximately 22×10^(4... The Hongqiling large nickel-copper-cobalt deposit(hereafter referred to as the Hongqiling deposit),a typical mafic-ultramafic copper-nickel deposit in China,boasts proven Ni(Ni)resources of approximately 22×10^(4)t,associated copper resources of 2×10^(4)t,and associated cobalt(Co)resources of 0.5×10^(4)t,with Ni reserves ranking 10th among China's magmatic nickel deposits.Geotectonically,the Hongqiling deposit is situated in the superimposed zone between the Xing'an-Mongolian orogenic belt and the circum-Western Pacific's active continental margin belt.Its ore-bearing plutons occur within the metamorphic rocks of the Ordovician Hulan Group,with the emplacement of plutons and the locations of orebodies governed by the deep-seated Huifahe fault and its secondary NW-trending Fujia-Hejiagou-Beixinglong-Changsheng fault zone.In the deposit,the rock assemblages of ore-bearing plutons predominantly encompass gabbro-pyroxenite-olivine pyroxenite-pyroxene peridotite(pluton No.1)and norite-orthopyroxenite-harzburgite(pluton No.7),with ore-bearing lithofacies consisting primarily of olivine pyroxenite and pyroxenite facies.The Hongqiling deposit hosts stratoid,overhanging lentoid,veined,and pure-sulfide veined orebodies.Its ores principally contain metallic minerals including pyrrhotite,pentlandite,chalcopyrite,violarite,and pyrite.Despite unidentified magma sources of ore-bearing mafic-ultramafic rocks,it is roughly accepted that the magmatic evolution in the Hongqiling deposit primarily involved fractional crystallization and crustal contamination.The ore-forming materials were primarily derived from the upper mantle,mixed with minor crustal materials.The ore-bearing mafic-ultramafic rocks in the deposit,primarily emplaced during the Indosinian(208-239 Ma),were formed in an intense extension setting followed by the collisional orogeny between the North China Plate and the Songnen-Zhangguangcai Range Block during the Middle-Late Triassic.From the perspective of the metallogenic geological setting,surrounding rocks,ore-controlling structures,and rock assemblages,this study identified one favorable condition and seven significant indicators for prospecting for Hongqiling-type nickel deposits and developed a prospecting model of the Hongqiling deposit.These serve as valuable references for exploring similar nickel deposits in the region,as well as the deep parts and margins of the Hongqiling deposit. 展开更多
关键词 Nickel-copper-cobalt deposit Fractional crystallization Crustal contamination MAGMATIC MINERALIZATION Re-Os isotopic age Sulfur isotopic Metallogenic mode Prospecting model Western Pacific’s active continental margin Mineral exploration engineering Hongqiling Jilin
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Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization
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作者 Liqiang Zhang Xilian Chen +3 位作者 Shaohao Zou Deru Xu Xuena Wang Hua Wang 《Acta Geochimica》 EI CAS CSCD 2024年第2期280-295,共16页
The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassi... The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration. 展开更多
关键词 TONALITE Zircon APATITE Mineralization potential Dongga area Gangdese belt
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