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Quasistable bright dissipative holographic solitons in photorefractive two-wave mixing system 被引量:1
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作者 刘劲松 《Chinese Physics B》 SCIE EI CAS CSCD 2007年第1期165-172,共8页
The dynamical evolution of both signal and pump beams are traced by numerically solving the coupled-wave equation for a photorefractive two-wave mixing system. The direct simulations show that, when the intensity rati... The dynamical evolution of both signal and pump beams are traced by numerically solving the coupled-wave equation for a photorefractive two-wave mixing system. The direct simulations show that, when the intensity ratio of the pump beam to the signal beam is large enough, the pump beam presents a common decaying behaviour without modulational instability (MI), while the signal beam can evolve into a quasistable spatial soliton within a regime in which the pump beam is depleted slightly. The larger the ratio is, the longer the regime is. Such quasistable solitons can overcome the initial perturbations and numerical noises in the course of propagation, perform several cycles of slow oscillation in intensity and width, and persist over tens of diffraction lengths. From physical viewpoints, these solitons actually exist as completely rigorous physical objects. If the ratio is quite small, the pump beam is apt to show MI, during which the signal beam experiences strong expansion and shrinking in width and a drastic oscillation in intensity, or completely breaks up. The simulations using actual experimental parameters demonstrate that the observation of an effectively stable soliton is quite possible in the proposed system. 展开更多
关键词 spatial optical solitons photorefractive nonlinear optics two-wave mixing
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Evolution and stability of spatial solitons in a photorefractive two-wave mixing system
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作者 刘劲松 张慧蓝 +1 位作者 张光勇 王程 《Chinese Physics B》 SCIE EI CAS CSCD 2006年第2期394-402,共9页
The dynamical evolution and stability of bright dissipative holographic solitons in biased photorefractive materials in which the self-trapping beam obtains a gain from the pump beam via two-wave mixing has been inves... The dynamical evolution and stability of bright dissipative holographic solitons in biased photorefractive materials in which the self-trapping beam obtains a gain from the pump beam via two-wave mixing has been investigated numerically. Results show that these solitons are stable relative to small perturbations. Adjusting some system parameters, such as the bias field and the angle between beams, can easily control the generation of such solitons. Potential applications in optical switches or repeaters are discussed. 展开更多
关键词 spatial optical solitons photorefractive nonlinear optics two-wave mixing
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Rigidity in Subclasses of Transitive and Mixing Systems
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作者 Dawoud Ahmadi Dastjerdi Maliheh Dabbaghian Amiri 《Advances in Pure Mathematics》 2012年第6期441-445,共5页
We will present some restrictions for a rigidity sequence of a nontrivial topological dynamical system. For instance, any finite linear combination of a rigidity sequence by integers has upper Banach density zero. How... We will present some restrictions for a rigidity sequence of a nontrivial topological dynamical system. For instance, any finite linear combination of a rigidity sequence by integers has upper Banach density zero. However, there are rigidity sequences for some uniformly rigid systems whose reciprocal sums are infinite. We also show that if F is a family of subsets of natural numbers whose dual F* is filter, then a minimal F*-mixing system does not have F+-rigid factor for F∈F. 展开更多
关键词 RIGIDITY Filter mixing UPPER BANACH DENSITY DENSITY
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Effectively modulating spatial vortex four-wave mixing in a diamond atomic system
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作者 巴诺 姜明奇 +4 位作者 费金友 王丹 蒋海林 王磊 王海华 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期473-478,共6页
Due to the spatial characteristics of orbital angular momentum,vortex fields can be applied in the fields of quantum storage and quantum information.We study the realization of spatially modulated vortex fields based ... Due to the spatial characteristics of orbital angular momentum,vortex fields can be applied in the fields of quantum storage and quantum information.We study the realization of spatially modulated vortex fields based on four-wave mixing in a four-level atomic system with a diamond structure.The intensity and spiral phase of the vortex field are effectively transferred to the generated four-wave mixing field.By changing the detuning of the probe field,the phase and intensity of the generated vertex four-wave mixing field can be changed.When the probe field takes a large detuning value,the spatial distribution of the intensity and phase of the vertex four-wave mixing field can be effectively tuned by adjusting the Rabi frequency or detuning value of the coupled field.At the same time,we also provide a detailed explanation based on the dispersion relationship,and the results agree well with our simulation results. 展开更多
关键词 coherent optical effects four-wave mixing orbital angular momentum
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Rheological properties of a multiscale granular system during mixing of cemented paste backfill:A review 被引量:2
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作者 Cuiping Li Xue Li Zhu’en Ruan 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第8期1444-1454,共11页
The technology of cemented paste backfill(CPB)is an effective method for green mining.In CPB,mixing is a vital process aiming to prepare a paste that meets the non-stratification,non-segregation,and non-bleeding requi... The technology of cemented paste backfill(CPB)is an effective method for green mining.In CPB,mixing is a vital process aiming to prepare a paste that meets the non-stratification,non-segregation,and non-bleeding requirements.As a multiscale granular system,homogenization is one of the challenges in the paste-mixing process.Due to the high shearing,high concentration,and multiscale characteristics,paste exhibits complex rheological properties in the mixing process.An overview of the mesomechanics and structural evolution is presented in this review.The effects of various influencing factors on the paste's rheological properties were investigated,and the rheological models of the paste were outlined from the macroscopic and mesoscopic levels.The results show that the mechanical effects and structural evolution are the fundamental factors affecting the rheological properties of the paste.Existing problems and future development trends are presented to change the practice where the CPB process comes first and the theory lags. 展开更多
关键词 cemented paste backfill RHEOLOGY mixing process MESOMECHANICS structural evolution
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Systematic review of mixing technology for recycling waste tailings as cemented paste backfill in mines in China 被引量:2
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作者 Liuhua Yang Jincang Li +4 位作者 Hongbin Liu Huazhe Jiao Shenghua Yin Xinming Chen Yang Yu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第8期1430-1443,共14页
The development of industry is inseparable from the support of mining.However,mining processes consume a large amount of energy,and increased tailing emissions can have a significant impact on the environment.In the p... The development of industry is inseparable from the support of mining.However,mining processes consume a large amount of energy,and increased tailing emissions can have a significant impact on the environment.In the past few decades,the mining industry developed many technologies that are related to mineral energy management,of which cemented paste backfill(CPB)is one of the representative technologies.CPB has been successfully applied to mine ground control and tailings management.In CPB technology,the mixing process is the key to achieving materials with good final quality and controlled properties.However,in the preparation process,the mixed homogeneity of the CPB is difficult to achieve because of fine tailings,high solid volume fraction,and high viscosity.Most research focused on the effect of mixing ingredients on CPB properties rather than on the preparation process of the CPB.Therefore,improving the performance and reducing the production cost of CPB by optimizing the mixing process are important.This review summarizes the current studies on the mixing technology of CPB and its application status in China.Then,it compares the advantages and disadvantages of multiple mixing equipment and discusses the latest results and research hotspots in paste preparation.Finally,it concludes the challenges and development trends of mixing technology on the basis of the relevant application cases in China to promoting cement-based material mixing technology development. 展开更多
关键词 cemented paste backfill mixed homogeneity mixing technology cement-based material
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Synergistic anionic/zwitterionic mixed surfactant system with high emulsification efficiency for enhanced oil recovery in low permeability reservoirs 被引量:1
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作者 Hai-Rong Wu Rong Tan +6 位作者 Shi-Ping Hong Qiong Zhou Bang-Yu Liu Jia-Wei Chang Tian-Fang Luan Ning Kang Ji-Rui Hou 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期936-950,共15页
Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant... Emulsification is one of the important mechanisms of surfactant flooding. To improve oil recovery for low permeability reservoirs, a highly efficient emulsification oil flooding system consisting of anionic surfactant sodium alkyl glucosyl hydroxypropyl sulfonate(APGSHS) and zwitterionic surfactant octadecyl betaine(BS-18) is proposed. The performance of APGSHS/BS-18 mixed surfactant system was evaluated in terms of interfacial tension, emulsification capability, emulsion size and distribution, wettability alteration, temperature-resistance and salt-resistance. The emulsification speed was used to evaluate the emulsification ability of surfactant systems, and the results show that mixed surfactant systems can completely emulsify the crude oil into emulsions droplets even under low energy conditions. Meanwhile,the system exhibits good temperature and salt resistance. Finally, the best oil recovery of 25.45% is achieved for low permeability core by the mixed surfactant system with a total concentration of 0.3 wt%while the molar ratio of APGSHS:BS-18 is 4:6. The current study indicates that the anionic/zwitterionic mixed surfactant system can improve the oil flooding efficiency and is potential candidate for application in low permeability reservoirs. 展开更多
关键词 Anionic/zwitterionic mixed surfactant system EMULSIFICATION Synergistic effect Low permeability reservoir Enhanced oil recovery
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Effect of aspect ratio of elliptical stirred vessel on mixing time and flow field characteristics in the absence of baffles
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作者 Yuan Yao Peiqiao Liu +5 位作者 Qian Zhang Zequan Li Benjun Xi Changyuan Tao Yundong Wang Zuohua Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期63-74,共12页
Elliptical tanks were used as an alternative to circular tanks in order to improve mixing efficiency and reduce mixing time in unbaffled stirred tanks(USTs). Five different aspect ratios of elliptical vessels were des... Elliptical tanks were used as an alternative to circular tanks in order to improve mixing efficiency and reduce mixing time in unbaffled stirred tanks(USTs). Five different aspect ratios of elliptical vessels were designed to compare their mixing time and flow field. Computational fluid dynamics(CFD) simulations were performed using the k–ε model to calculate the mixing time and simulate turbulent flow field features, such as streamline shape, velocity distribution, vortex core region distribution, and turbulent kinetic energy(TKE) transfer. Visualization was also carried out to track the tinctorial evolution of the liquid phase. Results reveal that elliptical stirred tanks can significantly improve mixing performance in USTs. Specifically, the mixing time at an aspect ratio of 2.00 is only 45.3% of the one of a circular stirred tank. Furthermore, the secondary flow is strengthened and the vortex core region increases with the increase of aspect ratio. The axial velocity is more sensitive to the aspect ratio than the circumferential and radial velocity. Additionally, the TKE transfer in elliptical vessels is altered. These findings suggest that elliptical vessels offer a promising alternative to circular vessels for enhancing mixing performance in USTs. 展开更多
关键词 mixing time CFD Stirred tank Secondary flow mixing performance
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Comparison of isotope-based linear and Bayesian mixing models in determining moisture recycling ratio
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作者 XIAO Yanqiong WANG Liwei +5 位作者 WANG Shengjie Kei YOSHIMURA SHI Yudong LI Xiaofei Athanassios A ARGIRIOU ZHANG Mingjun 《Journal of Arid Land》 SCIE CSCD 2024年第6期739-751,共13页
Stable water isotopes are natural tracers quantifying the contribution of moisture recycling to local precipitation,i.e.,the moisture recycling ratio,but various isotope-based models usually lead to different results,... Stable water isotopes are natural tracers quantifying the contribution of moisture recycling to local precipitation,i.e.,the moisture recycling ratio,but various isotope-based models usually lead to different results,which affects the accuracy of local moisture recycling.In this study,a total of 18 stations from four typical areas in China were selected to compare the performance of isotope-based linear and Bayesian mixing models and to determine local moisture recycling ratio.Among the three vapor sources including advection,transpiration,and surface evaporation,the advection vapor usually played a dominant role,and the contribution of surface evaporation was less than that of transpiration.When the abnormal values were ignored,the arithmetic averages of differences between isotope-based linear and the Bayesian mixing models were 0.9%for transpiration,0.2%for surface evaporation,and–1.1%for advection,respectively,and the medians were 0.5%,0.2%,and–0.8%,respectively.The importance of transpiration was slightly less for most cases when the Bayesian mixing model was applied,and the contribution of advection was relatively larger.The Bayesian mixing model was found to perform better in determining an efficient solution since linear model sometimes resulted in negative contribution ratios.Sensitivity test with two isotope scenarios indicated that the Bayesian model had a relatively low sensitivity to the changes in isotope input,and it was important to accurately estimate the isotopes in precipitation vapor.Generally,the Bayesian mixing model should be recommended instead of a linear model.The findings are useful for understanding the performance of isotope-based linear and Bayesian mixing models under various climate backgrounds. 展开更多
关键词 moisture recycling stable water isotope linear mixing model Bayesian mixing model China
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Assessing mixing uniformity in microreactors via in-line spectroscopy
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作者 Shusaku Asano Shinji Kudo +3 位作者 Taisuke Maki Yosuke Muranaka Kazuhiro Mae Jun-ichiro Hayashi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期119-124,共6页
Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasi... Mixing behavior is critical for enhancing the selectivity of fast chemical reactions in microreactors.A high Reynolds number(Re)improves the mixing rate and selectivity of the reactions,but some exceptions of increasing side product yield with the higher Re have been reported.This study investigated the mixing uniformity in microreactors with in-line UV-vis spectroscopy to clarify the relationship between reaction selectivity and chaotic mixing with the higher Re.A colorization experiment of thymolphthalein in an acidic solution was conducted with an excess acid amount to the base to indicate a non-uniformly mixed region.Non-uniformity significantly increased with Re.At the same time,the degree of mixing,which was measured by a usual decolorization experiment,showed that the mixing rate increased with Re.The in-line analysis of the Villermaux-Dushman reaction during the mixing clarified that side product yield significantly increased with Re at around 300 and then decreased at around 1100.These results suggest the compensation effect between the mixing uniformity and mixing rate on the selectivity of the mixing-sensitive reactions.Faster mixing,characterized by a larger Re,can disturb mixing uniformity and,in some cases,decrease reaction selectivity. 展开更多
关键词 MICROREACTOR Villermaux-Dushman reaction In-line analysis mixing Mass transfer UNIFORMITY
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Evaluation of Nonbreaking Wave-Induced Mixing Parameterization Schemes Based on a One-Dimensional Ocean Model
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作者 TANG Ran HUANG Chuanjiang +1 位作者 DAI Dejun WANG Gang 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第3期567-576,共10页
Surface waves have a considerable effect on vertical mixing in the upper ocean.In the past two decades,the vertical mixing induced through nonbreaking surface waves has been used in ocean and climate models to improve... Surface waves have a considerable effect on vertical mixing in the upper ocean.In the past two decades,the vertical mixing induced through nonbreaking surface waves has been used in ocean and climate models to improve the simulation of the upper ocean.Thus far,several nonbreaking wave-induced mixing parameterization schemes have been proposed;however,no quantitative comparison has been performed among them.In this paper,a one-dimensional ocean model was used to compare the performances of five schemes,including those of Qiao et al.(Q),Hu and Wang(HW),Huang and Qiao(HQ),Pleskachevsky et al.(P),and Ghantous and Babanin(GB).Similar to previous studies,all of these schemes can decrease the simulated sea surface temperature(SST),increase the subsurface temperature,and deepen the mixed layer,thereby alleviating the common thermal deviation problem of the ocean model for upper ocean simulation.Among these schemes,the HQ scheme exhibited the weakest wave-induced mixing effect,and the HW scheme exhibited the strongest effect;the other three schemes exhibited roughly the same effect.In particular,the Q and P schemes exhibited nearly the same effect.In the simulation based on observations from the Ocean Weather Station Papa,the HQ scheme exhibited the best performance,followed by the Q scheme.In the experiment with the HQ scheme,the root-mean-square deviation of the simulated SST from the observations was 0.43℃,and the mixed layer depth(MLD)was 2.0 m.As a contrast,the deviations of the SST and MLD reached 1.25℃ and 8.4 m,respectively,in the experiment without wave-induced mixing. 展开更多
关键词 wave-induced mixing surface waves sea surface temperature mixed layer depth General Ocean Turbulence Model
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Effects of cross-Kerr coupling on transmission spectrum of double-cavity optomechanical system
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作者 陈立滕 秦立国 +3 位作者 田立君 黄接辉 周南润 龚尚庆 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期390-396,共7页
We theoretically study the transmission spectrum of the cavity field in a double-cavity optomechanical system with cross-Kerr(CK) effect. The system consists of two tunneling coupling optomechanical cavities with a me... We theoretically study the transmission spectrum of the cavity field in a double-cavity optomechanical system with cross-Kerr(CK) effect. The system consists of two tunneling coupling optomechanical cavities with a mechanical resonator as a coupling interface. By doping CK medium into the mechanical resonator, CK couplings between the cavity fields and the mechanical resonator are introduced. We investigate the effects of CK coupling strength on the transmission spectrum of the cavity field, including the transmission rate, nonreciprocity and four-wave mixing(FWM). We find that the transmission spectrum of the probe field can show two obvious transparent windows, which can be widened by increasing the CK coupling strength. For the transmission between the two cavity fields, the perfect nonreciprocity and reciprocity are present and modulated by CK coupling and phase difference between two effective optomechanical couplings. In addition, the effects of the optomechanical and CK couplings on FWM show that the single peak of FWM is split into three symmetrical peaks due to the introduction of the CK effect. 展开更多
关键词 cross-Kerr transmission rate NONRECIPROCITY four-wave mixing
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A strategy for strengthening chaotic mixing of dual shaft eccentric mixers by changing non-Newtonian fluids kinetic energy distribution
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作者 Songsong Wang Tong Meng +4 位作者 Qian Zhang Changyuan Tao Yundong Wang Zequan Li Zuohua Liu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第5期122-134,共13页
Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier ... Efficiently modulating the velocity distribution and flow pattern of non-Newtonian fluids is a critical challenge in the context of dual shaft eccentric mixers for process intensification,posing a significant barrier for the existing technologies.Accordingly,this work reports a convenient strategy that changes the kinetic energy to controllably regulate the flow patterns from radial flow to axial flow.Results showed that the desired velocity distribution and flow patterns could be effectively obtained by varying the number and structure of baffles to change kinetic energy,and a more uniform velocity distribution,which could not be reached normally in standard baffle dual shaft mixers,was easily obtained.Furthermore,a comparative analysis of velocity and shear rate distributions is employed to elucidate the mechanism behind the generation of flow patterns in various dual-shaft eccentric mixers.Importantly,there is little difference in the power number of the laminar flow at the same Reynolds number,meaning that the baffle type has no effect on the power consumption,while the power number of both unbaffle and U-shaped baffle mixing systems decreases compared with the standard baffle mixing system in the transition flow.Finally,at the same rotational condition,the dimensionless mixing time of the U-shaped baffle mixing system is 15.3%and 7.9%shorter than that of the standard baffle and the unbaffle mixing system,respectively,which shows the advantage of the U-shaped baffle in stirring rate. 展开更多
关键词 Dual shaft “U-shaped”baffle Flow pattern mixing time Power demand
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Mineral Chemistry,Trace Elements,Isotopic Analysis and Zircon U-Pb Dating in the Hesar Pluton,Northern UDMA,Iran:Implications for Pre-Collisional Magma Mixing
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作者 Kazem KAZEMI Soroush MODABBERI +3 位作者 Parisa GHARIBNEJAD XIAO Yilin Fatemeh SARJOUGHIAN Ali KANANIAN 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2024年第3期657-678,共22页
The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested th... The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km. 展开更多
关键词 ENCLAVE magma mixing zircon U-Pb dating Urumieh-Dokhtar magmatic arc
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Experimental study on secondary air mixing along the bed height in a circulating fluidized bed with a multitracer-gas method
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作者 Qingyu Zhang Leming Cheng +3 位作者 Kun Li Qixun Kang Qiang Guo Chaogang Wu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第6期54-62,共9页
A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Expe... A multitracer-gas method was proposed to study the secondary air(SA)mixing along the bed height in a circulating fluidized bed(CFB)using carbon monoxide(CO),oxygen(O_(2)),and carbon dioxide(CO_(2))as tracer gases.Experiments were carried out on a cold CFB test rig with a cross-section of 0.42 m×0.73 m and a height of 5.50 m.The effects of superficial velocity,SA ratio,bed inventory,and particle diameter on the SA mixing were investigated.The results indicate that there are some differences in the measurement results obtained using different tracer gases,wherein the deviation between CO and CO_(2) ranges from 42%to 66%and that between O_(2) and CO_(2) ranges from 45%to 71%in the lower part of the fluidized bed.However,these differences became less pronounced as the bed height increased.Besides,the high solid concentration and fine particle diameter in the CFB may weaken the difference.The measurement results of different tracer gases show the same trends under the variation of operating parameters.Increasing superficial velocity and SA ratio and decreasing particle diameter result in better mixing of the SA.The effect of bed inventory on SA mixing is not monotonic. 展开更多
关键词 Circulating fluidized bed Secondary air injection Gas mixing Multitracer-gas method
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Cooperative structure of Li/Ni mixing and stacking faults for achieving high-capacity Co-free Li-rich oxides
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作者 Zhen Wu Yu-Han Zhang +9 位作者 Hao Wang Zewen Liu Xudong Zhang Xin Dai Kunyang Zou Xiaoming Lou Xuechen Hu Lijing Ma Yan Liu Yongning Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期315-324,I0007,共11页
Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high capacity.However,they commonly face severe structural instability and poor electroche... Co-free Li-rich layered oxides(LLOs)are emerging as promising cathode materials for Li-ion batteries due to their low cost and high capacity.However,they commonly face severe structural instability and poor electrochemical activity,leading to diminished capacity and voltage performance.Herein,we introduce a Co-free LLO,Li_(1.167)Ni_(0.222)Mn_(0.611)O_(2)(Cf-L1),which features a cooperative structure of Li/Ni mixing and stacking faults.This structure regulates the crystal and electronic structures,resulting in a higher discharge capacity of 300.6 mA h g^(-1)and enhanced rate capability compared to the typical Co-free LLO,Li_(1.2)Ni_(0.2)Mn_(0.6)O_(2)(Cf-Ls).Density functional theory(DFT)indicates that Li/Ni mixing in LLOs leads to increased Li-O-Li configurations and higher anionic redox activities,while stacking faults further optimize the electronic interactions of transition metal(TM)3d and non-bonding O 2p orbitals.Moreover,stacking faults accommodate lattice strain,improving electrochemical reversibility during charge/discharge cycles,as demonstrated by the in situ XRD of Cf-L1 showing less lattice evolution than Cf-Ls.This study offers a structured approach to developing Co-free LLOs with enhanced capacity,voltage,rate capability,and cyclability,significantly impacting the advancement of the next-generation Li-ion batteries. 展开更多
关键词 Co-free Li-rich oxides Li/Ni mixing Stacking faults Electronic structure
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Accurate estimation of Li/Ni mixing degree of lithium nickel oxide cathode materials
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作者 陈鹏浩 徐磊 +1 位作者 禹习谦 李泓 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期631-635,共5页
Li/Ni mixing negatively influences the discharge capacity of lithium nickel oxide and high-nickel ternary cathode materials.However,accurately measuring the Li/Ni mixing degree is difficult due to the preferred orient... Li/Ni mixing negatively influences the discharge capacity of lithium nickel oxide and high-nickel ternary cathode materials.However,accurately measuring the Li/Ni mixing degree is difficult due to the preferred orientation of labbased XRD measurements using Bragg–Brentano geometry.Here,we find that employing spherical harmonics in Rietveld refinement to eliminate the preferred orientation can significantly decrease the measurement error of the Li/Ni mixing ratio.The Li/Ni mixing ratio obtained from Rietveld refinement with spherical harmonics shows a strong correlation with discharge capacity,which means the electrochemical capacity of lithium nickel oxide and high-nickel ternary cathode can be estimated by the Li/Ni mixing degree.Our findings provide a simple and accurate method to estimate the Li/Ni mixing degree,which is valuable to the structural analysis and screening of the synthesis conditions of lithium nickel oxide and high-nickel ternary cathode materials. 展开更多
关键词 lithium nickel oxide high-nickel ternary cathode Li/Ni mixing spherical harmonics function discharge capacity
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Effect of droplet characteristics on liquid-phase distribution in spray zone of internal mixing air-mist nozzle
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作者 Wei-li Wu Chang-gui Cheng +2 位作者 Yang Li Shi-fa Wei De-li Chen 《China Foundry》 SCIE EI CAS CSCD 2024年第2期185-196,共12页
In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In ord... In continuous casting production,droplet characteristics are important parameters for evaluating the nozzle atomization quality,and have a significant impact on the secondary cooling effect and the slab quality.In order to study the behavior of atomized droplets after reaching the slab surface and to optimize the spray cooling effect,the influence of droplet diameter and droplet velocity on the migration behavior of droplets in the secondary cooling zone was analyzed by FLUENT software.Results show that the droplets in the spray zone and on the slab surface are mainly concentrated in the center,thus,the liquid volume fraction in the center is higher than that of either side.As the droplet diameter increases,the region of high liquid volume fraction on the slab surface becomes wider,and the liquid phase distribution in the slab width direction becomes uneven.Although increasing the droplet velocity at the nozzle exit has little effect on droplet diffusion in the spray zone,the distribution becomes more uneven due to more liquid reaches the slab surface per unit time.A prediction formula of the maximum water flow rate on the slab surface for specific droplet characteristics was proposed based on dimensionless analysis and validated by simulated data.A nozzle spacing of 210 mm was recommended under the working conditions in this study,which ensures effective coverage of the spray water over the slab surface and enhances the distribution uniformity of water flow rate in the transverse direction. 展开更多
关键词 continuous casting secondary cooling zone internal mixing air-mist nozzle droplet characteristics liquid phase distribution water flow rate
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Persistent mixing bursts in the equatorial Pacific thermocline induced by persistent equatorial waves
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作者 Jingjing ZHANG Chuanyu LIU +1 位作者 Xiang GONG Fan WANG 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2024年第2期492-510,共19页
A recent study by Liu et al.(2020)suggested that due to the saturation of equatorially trapped planetary waves with different dynamical types,temporal periods,meridional and baroclinic modes,complex layer structures o... A recent study by Liu et al.(2020)suggested that due to the saturation of equatorially trapped planetary waves with different dynamical types,temporal periods,meridional and baroclinic modes,complex layer structures of vertical velocity shear and hence turbulent mixing could frequently occur in the thermocline of the eastern equatorial Pacific.We investigated the occurrence of the interior turbulent mixing as indicated by shear instabilities,above the Equatorial Undercurrent(EUC)core at three equatorial sites along 140°W,170°W,and 165°E,respectively,based mainly on data from the Tropical Atmosphere and Ocean(TAO)mooring array.We found that turbulent mixing bursts persisted in the thermocline of all three sites.Specifically,the interior turbulent mixing layers(ITMLs)could occur in probability of approximately 68%,53%,and 48%at the three sites,respectively.The overall occurrence probability shows obvious and similar biannual variations at 140°W and 170°W,which is higher in boreal from late summer to winter and lower in spring.Vertically,the ITMLs are primarily located above the EUC core and prevail in deeper(shallower)layers from late summer to winter(spring).Most ITMLs(70%)lasted for hours to 3 days,and a few of them(15%)for more than 7 days.The thicknesses of ITMLs were concentrated between 15 and 55 m.At 165°E,the vertical distribution of ITML occurrence probability was different from that at 140°W and 170°W,as it did not show a preference for depths;the durations of ITMLs are short(also from hours to several days)and their thicknesses were between 5 and 25 m.These properties,particularly the high occurrence probability,and short durations demonstrated the persistence of thermocline mixing in the western to eastern equatorial Pacific thermocline and confirmed the generation mechanism by persistent equatorial waves as well. 展开更多
关键词 interior turbulent mixing layer(ITML) weakly sheared layer(WSL) Equatorial Undercurrent(EUC)core occurrence probability SEASONALITY
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Effect of the mixing of s-wave and chiral p-wave pairings on electrical shot noise properties of normal metal/superconductor tunnel junctions
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作者 胡雨辰 胡梁宾 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第7期538-545,共8页
We study theoretically the electrical shot noise properties of tunnel junctions between a normal metal and a superconductor with the mixture of singlet s-wave and chiral triplet p-wave pairing due to broken inversion ... We study theoretically the electrical shot noise properties of tunnel junctions between a normal metal and a superconductor with the mixture of singlet s-wave and chiral triplet p-wave pairing due to broken inversion symmetry. We investigate how the shot noise properties vary as the relative amplitude between the two parity components in the pairing potential is changed. It is demonstrated that some characteristics of the electrical shot noise properties of such tunnel junctions may depend sensitively on the relative amplitude between the two parity components in the pairing potential, and some significant changes may occur in the electrical shot noise properties when the relative amplitude between the two parity components is varied from the singlet s-wave pairing dominated regime to the chiral triplet p-wave pairing dominated regime. In the chiral triplet p-wave pairing dominated regime, the ratio of noise power to electric current is close to 2e both in the in-gap and in the out-gap region. In the singlet s-wave pairing dominated regime, the value of this ratio is close to 4e in the inner gap region but may reduce to about 2e in the outer gap region as the relative amplitude of the chiral triplet pairing component is increased. The variations of the differential shot noise with the bias voltage also exhibit some significantly different features in different regimes. Such different features can serve as useful diagnostic tools for the determination of the relative magnitude of the two parity components in the pairing potential. 展开更多
关键词 normal metal/superconductor tunnel junctions shot noise mixing of s-wave and chiral p-wave pairing spin–orbit coupling
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