In this paper,we report a total synthesis of a naturally occurring pyrrolo[2,3-d]pyrimidine nucleoside, mycalisine A.Our synthetic strategy uses D-xylose as the starting material and Vorbr（u｜¨）ggen glycosylati...In this paper,we report a total synthesis of a naturally occurring pyrrolo[2,3-d]pyrimidine nucleoside, mycalisine A.Our synthetic strategy uses D-xylose as the starting material and Vorbr（u｜¨）ggen glycosylation as the key step.Mycalisine A was synthesized in 11 steps with a 15%overall yield.展开更多
基金NSFC(Nos.20962009 and 21062006)NCET(No.11- 1000)+1 种基金the Training Project of Jiangxi Youth Scientists,Education Department of Jiangxi Province(Nos.GJJ1 1223 and GJJ12583)Bureau of Science & Technology of Nanchang City for financial support
文摘In this paper,we report a total synthesis of a naturally occurring pyrrolo[2,3-d]pyrimidine nucleoside, mycalisine A.Our synthetic strategy uses D-xylose as the starting material and Vorbr（u｜¨）ggen glycosylation as the key step.Mycalisine A was synthesized in 11 steps with a 15%overall yield.
