Two new complexes [Mn(DHTA)(PLQ)]n(1) and{[Co2(DHTA)(phen)2(H2 O)6]· DHTA}n(2)(H2 DHTA = 2,5-dihydroxy-1,4-benzenedicarboxylic acid, PLQ = 1,10-phenanthroline-5,6-quinone, phen = 1,10-phenanthroline) have been hy...Two new complexes [Mn(DHTA)(PLQ)]n(1) and{[Co2(DHTA)(phen)2(H2 O)6]· DHTA}n(2)(H2 DHTA = 2,5-dihydroxy-1,4-benzenedicarboxylic acid, PLQ = 1,10-phenanthroline-5,6-quinone, phen = 1,10-phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, fluorescence spectrum, single-crystal and power X-ray diffraction. Complex 1 exhibits a two-dimensional(2 D) network, which was stabilized through O–H···O hydrogen bonding interactions. Complex 2 shows a zero-dimensional structure, which was further extended into a three-dimensional supramolecular structure through O–H···O hydrogen bonds and π-π interactions.展开更多
The crystal structure of one novel Mn（II） complex, [Mn（pmta）_3]_2[Mn（H_2O）_6]·4H_2O（1）, is reported（Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid）. In the title compound, the asymmetric ...The crystal structure of one novel Mn（II） complex, [Mn（pmta）_3]_2[Mn（H_2O）_6]·4H_2O（1）, is reported（Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid）. In the title compound, the asymmetric unit consists of a [Mn（pmta_）3]ˉ anion, half [Mn（H_2O）_6]^（2＋） counter cation and two lattice H_2O molecules, and the intra- and intermolecular hydrogen bonds connect the complex into a supramolecular structure. The liquid-state fluorescence spectra of complex 1 have been determined. Hirshfeld surface analysis was also studied. The main intermolecular interactions in the complex are O···H and H···H contacts.展开更多
A coordination polymer [Mn2（ctpt）2（aic）2]n （1, ctpt = 2-（4-chloro-phenyl）-1H- 1,3,7,8-tetraaza-cyclopenta[l]phenanthrene, H2aic = 5-amino-isophthalic acid） was hydrother- mally designed and synthesized. The co...A coordination polymer [Mn2（ctpt）2（aic）2]n （1, ctpt = 2-（4-chloro-phenyl）-1H- 1,3,7,8-tetraaza-cyclopenta[l]phenanthrene, H2aic = 5-amino-isophthalic acid） was hydrother- mally designed and synthesized. The complex was characterized by elemental analysis, IR spectro- scopy, single-crystal X-ray diffraction, and thermogravimetric analysis （TGA）. Each Mn（II） atom is linked by the aic ligands with neighbor Mn（II） atoms, forming an infinite one-dimensional （1D） double-chain structure. Complex 1 crystallizes in monoclinic, space group C2/c, with a = 18.23（1）, b = 17.27（1）, c = 16.69（1） ？, V = 4814.0（7） ？3, C27H16ClMnN5O4, Mr = 564.84, Dc = 1.559 g/cm3, μ（MoKα） = 0.706 mm-1, F（000） = 2296, Z = 8, the final R = 0.0487 and wR = 0.1269 （I 〉 2σ（I））. The 1D chain structure of complex 1 is stable below 458 ℃. In addition, to elucidate the essential electronic characters of this complex, theoretical calculation analysis of 1 was performed by the PBE0/LANL2DZ method in Gaussian 03 Program.展开更多
A new complex associated with Mn ion,[Mn（Hbibm）（SO4）]·0.5H2O（1,Hbibm= 2,2＇-bibenzimidazole）,was prepared under solvothermal conditions,and characterized by single-crystal X-ray diffraction,elemental analys...A new complex associated with Mn ion,[Mn（Hbibm）（SO4）]·0.5H2O（1,Hbibm= 2,2＇-bibenzimidazole）,was prepared under solvothermal conditions,and characterized by single-crystal X-ray diffraction,elemental analysis and IR spectra.The complex belongs to the triclinic system,space group P1 with a=8.9250（5）,b=12.8022（8）,c=13.3505（8）,α=66.614（2）,β= 72.567（2）,γ=80.627（2）°,V=1334.1（1）3,Z=1,Dc=1.565 g/cm3,S=0.996,μ=0.628 mm-1,F（000）=644,R=0.0447 and wR=0.0586 for 5155 observed reflections（Ⅰ〉 2σ（Ⅰ））.Complex 1 is a mononuclear Mn（II） complex.The π-π interactions and interchain hydrogen-bonding interactions further extend the mononuclear for 1,generating a 3D supramolecular architecture.Complex 1 shows strong blue fluorescent emissions in the solid state upon 395 nm photo-excitation at room temperature.展开更多
Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-toly...Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-tolyl)-2,2′:6′,2″-terpyridine, salen = N,N?-ethylenebis-(salicylideneaminato)dianion). Single-crystal X-ray diffraction analysis shows complex 1 crystallizes in orthorhombic Pbca space group and the asymmetric unit of 1 contains one[-NC-RuⅡ(ttpy)(CN)(m-CN)-Mn Ⅲ-(salen)-] molecule. In the structure of 1, each [Ru Ⅱ(ttpy)(CN)3]-connects two [MnⅢ(salen)]+ with two cyanide groups in a cis-conformation, and in turn each[MnⅢ(salen)]+ unit links two [RuⅡ(ttpy)(CN)3]-building blocks in a trans-conformation, resulting in a 1D [-NC-RuⅡ-CN-MnⅢ-]n chain. Furthermore, the electronic absorption spectra and luminescence spectroscopy of complex 1 have also been studied.展开更多
基金supported by the Science and Technology development plan of Jilin Province(2015052006JH)
文摘Two new complexes [Mn(DHTA)(PLQ)]n(1) and{[Co2(DHTA)(phen)2(H2 O)6]· DHTA}n(2)(H2 DHTA = 2,5-dihydroxy-1,4-benzenedicarboxylic acid, PLQ = 1,10-phenanthroline-5,6-quinone, phen = 1,10-phenanthroline) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, fluorescence spectrum, single-crystal and power X-ray diffraction. Complex 1 exhibits a two-dimensional(2 D) network, which was stabilized through O–H···O hydrogen bonding interactions. Complex 2 shows a zero-dimensional structure, which was further extended into a three-dimensional supramolecular structure through O–H···O hydrogen bonds and π-π interactions.
基金supported by the National Natural Science Foundation of China(No.20801012)New Energy Technology Co.Ltd.of Ai Naji of Jiangsu Province(No.8507040091)
文摘The crystal structure of one novel Mn（II） complex, [Mn（pmta）_3]_2[Mn（H_2O）_6]·4H_2O（1）, is reported（Hpmta = 5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid）. In the title compound, the asymmetric unit consists of a [Mn（pmta_）3]ˉ anion, half [Mn（H_2O）_6]^（2＋） counter cation and two lattice H_2O molecules, and the intra- and intermolecular hydrogen bonds connect the complex into a supramolecular structure. The liquid-state fluorescence spectra of complex 1 have been determined. Hirshfeld surface analysis was also studied. The main intermolecular interactions in the complex are O···H and H···H contacts.
基金supported by the National Natural Science Foundation of China(No.21406085)
文摘A coordination polymer [Mn2（ctpt）2（aic）2]n （1, ctpt = 2-（4-chloro-phenyl）-1H- 1,3,7,8-tetraaza-cyclopenta[l]phenanthrene, H2aic = 5-amino-isophthalic acid） was hydrother- mally designed and synthesized. The complex was characterized by elemental analysis, IR spectro- scopy, single-crystal X-ray diffraction, and thermogravimetric analysis （TGA）. Each Mn（II） atom is linked by the aic ligands with neighbor Mn（II） atoms, forming an infinite one-dimensional （1D） double-chain structure. Complex 1 crystallizes in monoclinic, space group C2/c, with a = 18.23（1）, b = 17.27（1）, c = 16.69（1） ？, V = 4814.0（7） ？3, C27H16ClMnN5O4, Mr = 564.84, Dc = 1.559 g/cm3, μ（MoKα） = 0.706 mm-1, F（000） = 2296, Z = 8, the final R = 0.0487 and wR = 0.1269 （I 〉 2σ（I））. The 1D chain structure of complex 1 is stable below 458 ℃. In addition, to elucidate the essential electronic characters of this complex, theoretical calculation analysis of 1 was performed by the PBE0/LANL2DZ method in Gaussian 03 Program.
基金Supported by the NNSFC (No. 51062016)the NSF of the Education Committee of Guangxi Province (No. 200911MS199)
文摘A new complex associated with Mn ion,[Mn（Hbibm）（SO4）]·0.5H2O（1,Hbibm= 2,2＇-bibenzimidazole）,was prepared under solvothermal conditions,and characterized by single-crystal X-ray diffraction,elemental analysis and IR spectra.The complex belongs to the triclinic system,space group P1 with a=8.9250（5）,b=12.8022（8）,c=13.3505（8）,α=66.614（2）,β= 72.567（2）,γ=80.627（2）°,V=1334.1（1）3,Z=1,Dc=1.565 g/cm3,S=0.996,μ=0.628 mm-1,F（000）=644,R=0.0447 and wR=0.0586 for 5155 observed reflections（Ⅰ〉 2σ（Ⅰ））.Complex 1 is a mononuclear Mn（II） complex.The π-π interactions and interchain hydrogen-bonding interactions further extend the mononuclear for 1,generating a 3D supramolecular architecture.Complex 1 shows strong blue fluorescent emissions in the solid state upon 395 nm photo-excitation at room temperature.
基金Supported by the Science and Technology Research Project of Hubei Provincial Department of Education(China,No.Q20174302)the Scientific Research Foundation of Jingchu University of Technology(No.QN201602)National college students innovation and entrepreneurship training program(No.201811336003,China)
文摘Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-tolyl)-2,2′:6′,2″-terpyridine, salen = N,N?-ethylenebis-(salicylideneaminato)dianion). Single-crystal X-ray diffraction analysis shows complex 1 crystallizes in orthorhombic Pbca space group and the asymmetric unit of 1 contains one[-NC-RuⅡ(ttpy)(CN)(m-CN)-Mn Ⅲ-(salen)-] molecule. In the structure of 1, each [Ru Ⅱ(ttpy)(CN)3]-connects two [MnⅢ(salen)]+ with two cyanide groups in a cis-conformation, and in turn each[MnⅢ(salen)]+ unit links two [RuⅡ(ttpy)(CN)3]-building blocks in a trans-conformation, resulting in a 1D [-NC-RuⅡ-CN-MnⅢ-]n chain. Furthermore, the electronic absorption spectra and luminescence spectroscopy of complex 1 have also been studied.
基金supported by the National Natural Science Foundation of China(No.21973086,No.22203083)the Ministry of Science and Technology of China(No.2021YFA1200103)the Fundamental Research Funds for the Central Universities(No.WK2060000018)。
