The electrode process of Y^(3+)ion on molybdenum and nickel electrodes has been studied by cyclic voltammetry and chronopotentiometry in the YCl_3-NaCl-KCl melt.The overall charge transfer process is a two-step reacti...The electrode process of Y^(3+)ion on molybdenum and nickel electrodes has been studied by cyclic voltammetry and chronopotentiometry in the YCl_3-NaCl-KCl melt.The overall charge transfer process is a two-step reaction:Y^(3+)+e=Y^(2+);Y^(2+)+2e=Y.Yttrium reduced on the nickel electrode can form a series of Ni-Y alloys.X-ray diffraction analysis was employed to determine the alloy compositions formed under different con- ditions.展开更多
文摘The electrode process of Y^(3+)ion on molybdenum and nickel electrodes has been studied by cyclic voltammetry and chronopotentiometry in the YCl_3-NaCl-KCl melt.The overall charge transfer process is a two-step reaction:Y^(3+)+e=Y^(2+);Y^(2+)+2e=Y.Yttrium reduced on the nickel electrode can form a series of Ni-Y alloys.X-ray diffraction analysis was employed to determine the alloy compositions formed under different con- ditions.
