The promotion effect of CO in methane dehydroaromatization was investigated using ^13CO probe molecules. By alternative injection of ^13CO to the methane feed, the distribution of ^13CxC6-xH6（x= 0-3） products change...The promotion effect of CO in methane dehydroaromatization was investigated using ^13CO probe molecules. By alternative injection of ^13CO to the methane feed, the distribution of ^13CxC6-xH6（x= 0-3） products changed significantly, confirming the participation of ^13CO in the reaction network. The addition of ^13CO did not change the conversion of CH4 but improved slightly the durability of the methane dehydroaromatization （MDA） reaction, which might be caused by the interaction of the dissociated oxygen species and the deposited carbon species. The ratio of ^13CxC6-xH6 （x = 0-3） varied with the time on stream, which was determined by the competitive reactions of methane decomposition and ^13CO dissociation.展开更多
基金supported by the National Basic Research Program of China (2005CB221400)x
文摘The promotion effect of CO in methane dehydroaromatization was investigated using ^13CO probe molecules. By alternative injection of ^13CO to the methane feed, the distribution of ^13CxC6-xH6（x= 0-3） products changed significantly, confirming the participation of ^13CO in the reaction network. The addition of ^13CO did not change the conversion of CH4 but improved slightly the durability of the methane dehydroaromatization （MDA） reaction, which might be caused by the interaction of the dissociated oxygen species and the deposited carbon species. The ratio of ^13CxC6-xH6 （x = 0-3） varied with the time on stream, which was determined by the competitive reactions of methane decomposition and ^13CO dissociation.
基金a research grant from the Natural Science and Engineering Research Council of Canadaan equipment grant from the Canada Foundation for Innovationfunding from the Canada Research Chair pro-gram
