This paper reports that the film composed of flower-like ZnO micro-spheres, which consists of nano-sheets, is fab- ricated by chemical bath deposition. By adding hydrogen fluoride (HF) into the reaction solution, wh...This paper reports that the film composed of flower-like ZnO micro-spheres, which consists of nano-sheets, is fab- ricated by chemical bath deposition. By adding hydrogen fluoride (HF) into the reaction solution, which contains zinc nitrate hexahydrate and hexamethylenetetramine, the ZnO crystal growth process is changed and the film composed by ZnO micro-spheres is obtained after keeping the reaction solution at 95 ℃ for 2 h. The morphology, crystal phase and wettahility of the sample axe characterized by scanning electron microscope, x-ray diffraction and contact angle meter, respectively. The results show that the filrrl has the micro-nano compound structure. After modification with heptadecafluorodecyltrimethoxy-silane, the wettability of the film changed from superhydrophilicity to superhydropho-bicity, on which water contact angle and the sliding angle are 154° and less than 5° for 8-μL water droplet, respectively. Additionally, the formation mechanism of the ZnO micro-sphere is also discussed.展开更多
Since natural restoration combined with artificial auxiliary measures may achieve a relatively rapid restoration effect at a lower cost, it has become an essential measure for the ecological restoration of rock slopes...Since natural restoration combined with artificial auxiliary measures may achieve a relatively rapid restoration effect at a lower cost, it has become an essential measure for the ecological restoration of rock slopes. Previous studies have focused heavily on the relationship between substrate nutrients and water conditions and the development of mosses on the rock surface, but quantitative characterization of substantial effect of rock surface texture(e.g., microrelief) on moss growth is absent. The undulating microrelief on the rock surface can increase the heterogeneity of the microhabitat, which may be an important factor affecting the development of mossdominated biocrusts. In this study, the roughness of rock surfaces, moss coverage and biomass, weight and major nutrient contents of soils within the biocrusts were measured in the western mountainous area of Sichuan Province, Southwest China to further examine the role of rock surface microrelief in the biocrusts. The results showed that three main factors affecting the development of the biocrusts were bryophyte emergence, soil accumulation, and lithology. The presence of moss accelerates soil formation on rock surfaces and lead to the accumulation of nutrients so that all parts of the moss-dominated biocrusts system can develop synergistically. It was found that a microrelief structure with a roughness between 1.5 and 2.5 could gather soil and bryophyte propagules effectively, which may have a strong relationship with the angle of repose. When the roughness is 1.5, the corresponding undulation angle is very close to the theoretical minimum value of the undulation angle calculated according to the relationships between the undulation angle of the protrusion, slope and angle of repose.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 50872129)Natural Science Foundation of Anhui Province of China (Grant No. 070414187)
文摘This paper reports that the film composed of flower-like ZnO micro-spheres, which consists of nano-sheets, is fab- ricated by chemical bath deposition. By adding hydrogen fluoride (HF) into the reaction solution, which contains zinc nitrate hexahydrate and hexamethylenetetramine, the ZnO crystal growth process is changed and the film composed by ZnO micro-spheres is obtained after keeping the reaction solution at 95 ℃ for 2 h. The morphology, crystal phase and wettahility of the sample axe characterized by scanning electron microscope, x-ray diffraction and contact angle meter, respectively. The results show that the filrrl has the micro-nano compound structure. After modification with heptadecafluorodecyltrimethoxy-silane, the wettability of the film changed from superhydrophilicity to superhydropho-bicity, on which water contact angle and the sliding angle are 154° and less than 5° for 8-μL water droplet, respectively. Additionally, the formation mechanism of the ZnO micro-sphere is also discussed.
基金supported by the Project of Assessment on Post-quake Ecosystem and Environment Recovery in Jiuzhaigou under Grant 5132202020000046the National Key Research and Development Programme of China under Grant 2017YFC0504902。
文摘Since natural restoration combined with artificial auxiliary measures may achieve a relatively rapid restoration effect at a lower cost, it has become an essential measure for the ecological restoration of rock slopes. Previous studies have focused heavily on the relationship between substrate nutrients and water conditions and the development of mosses on the rock surface, but quantitative characterization of substantial effect of rock surface texture(e.g., microrelief) on moss growth is absent. The undulating microrelief on the rock surface can increase the heterogeneity of the microhabitat, which may be an important factor affecting the development of mossdominated biocrusts. In this study, the roughness of rock surfaces, moss coverage and biomass, weight and major nutrient contents of soils within the biocrusts were measured in the western mountainous area of Sichuan Province, Southwest China to further examine the role of rock surface microrelief in the biocrusts. The results showed that three main factors affecting the development of the biocrusts were bryophyte emergence, soil accumulation, and lithology. The presence of moss accelerates soil formation on rock surfaces and lead to the accumulation of nutrients so that all parts of the moss-dominated biocrusts system can develop synergistically. It was found that a microrelief structure with a roughness between 1.5 and 2.5 could gather soil and bryophyte propagules effectively, which may have a strong relationship with the angle of repose. When the roughness is 1.5, the corresponding undulation angle is very close to the theoretical minimum value of the undulation angle calculated according to the relationships between the undulation angle of the protrusion, slope and angle of repose.
文摘CT血管造影(computed tomography angiography,CTA)作为一种无创、检测精确较高的辅助诊断方法,尚急需能有效消除冠脉目标附近干扰噪声并寻求可全自动快速准确追踪目标的新算法以大幅减轻医生阅片压力、辅助其进行可靠诊断与治疗。提出了一种特征融合的误差最小平方和(minimum output sum of squared error,MOSSE)冠脉目标追踪新算法,通过提取冠脉血管多个特征,将其融合加入现有的MOSSE追踪方法,实现全自动准确快速追踪冠脉目标。使用河北大学附属医院9位患者(5男4女,均龄65岁,其中6位有冠心病史)的CTA数据进行了算法验证,并与文献已报道基于中心线提取和基于区域生长的现有冠脉目标提取算法进行了处理结果对比分析。结果表明,新算法处理追踪一例患者切片数据仅需耗时0.02 s,多个病例的平均准确度达94.30%,性能优于上述现有冠脉目标提取算法,能实现全自动准确高效追踪到形态变化剧烈的冠脉目标,可为冠心病的临床诊治起到更为高效的辅助作用。