Photocurrent-voltage characterization is a crucial method for assessing key parameters in x-ray or y-ray semiconductor detectors,especially the carrier mobility lifetime product.However,the high biases during photocur...Photocurrent-voltage characterization is a crucial method for assessing key parameters in x-ray or y-ray semiconductor detectors,especially the carrier mobility lifetime product.However,the high biases during photocurrent measurements tend to cause severe ion migration,which can lead to the instability and inaccuracy of the test results.Given the mixed electronic-ionic charac teristics,it is imperative to devise novel methods capable of precisely measuring photocurrentvoltage characteristics under high bias conditions,free from interference caused by ion migration.In this paper,pulsed bias is employed to explore the photocurrent-voltage characteristics of MAPbBr_(3) single crystals.The method yields stable photocurrent-voltage characteristics at a pulsed bias of up to 30 V,proving to be effective in mitigating ion migration.Through fitting the modified Hecht equation,we determined the mobility lifetime products of 1.0×10^(2) cm^(2)·V^(-1)for hole and 2.78×10~(-3)cm^(2)·V^(-1)for electron.This approach offers a promising solution for accurately measuring the transport properties of carriers in perovskite.展开更多
Practice experimentation that integrates the manufacturing processes and cutting-edge technologies of smart manufacturing (SM) is essential for future academic and applied engineering personnel. The broadening efficac...Practice experimentation that integrates the manufacturing processes and cutting-edge technologies of smart manufacturing (SM) is essential for future academic and applied engineering personnel. The broadening efficacy of hands-on experience in SM engineering education has been manifested. In this regard, a reference practical system is proposed in this study for hands-on training in SM crucial advancements. The system constructs a mobile robot-based production line (MRPL) to increase participants’ interest in theoretical learning and professional skills. The MRPL-based reference system includes the comprehensive principles and processes involved in modern SM factories from warehousing to logistics, processing, and testing. With key features of modularity, integrability, customizability, and open architecture, this system has a threefold objective. First, it is an interdisciplinary subject that enables students to translate classroom learning into authentic practices, thus facilitating knowledge synthesis and training involvements. Second, it offers effective support to cultivate the attributions and behavioral competencies of SM talents, such as perseverance, adaptability, and cooperation. Third, it promotes students’ capacities for critical thinking and problem solving so that they can deal with the difficulties that physical systems have and motivates them to pursue careers with new syllabi, functions, and process techno-logies. The received positive evaluations and assessments confirm that this MRPL-based reference system is beneficial for modern SM talent training in higher engineering education.展开更多
We report physics based confirmation(~1% RMS deviation), by existing experimental data, of protonprohol(proton-hole) ion product(p H) and mobilities in pure liquid water(0-100℃, 1-atm pressure) anticipated fr...We report physics based confirmation(~1% RMS deviation), by existing experimental data, of protonprohol(proton-hole) ion product(p H) and mobilities in pure liquid water(0-100℃, 1-atm pressure) anticipated from our melted-ice Hexagonal-Close-Packed(H_2O)_4Lattice Model. Five phonons are identified.(1) A propagating protonic phonon(520.9 meV from lone-pair-blue-shifted stretching mode of isolated water molecule) absorbed to generate a proton-prohol pair or detrap a tightly-bound proton.(2) Two(173.4 and 196.6 meV) bending-breathing protonic-proholic or protonic phonons absorbed during de-trapping-limited proton or proton-prohol mobilities.(3)Two propagating oxygenic-wateric Debye-Dispersive phonons(30.3 and 27.5 meV) absorbed during scatteringlimited proton or proton-prohol mobilities.展开更多
This report adds three protonic semiconductor models to explain the "abnormally" high electrical conductivity of pure liquid water characterized by the three industrial consensus parameters, the ion product(...This report adds three protonic semiconductor models to explain the "abnormally" high electrical conductivity of pure liquid water characterized by the three industrial consensus parameters, the ion product(or pH)and the two ion mobilities. Existence of long-range order in fluid water under numerous daily conditions led us to extend the 1933 Bernal-Fowler hexagonally close packed crystalline Ice Lattice to model liquid water as Melted Ice. Protonic kinetic energy band and bound(trap) pictures provide semiconductor-physics based new models of these three parameters. They are extrapolatable engineered-models for developing novel biological, chemical, electrical, mechanical and medical applications of liquid water.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No.62104234)Shanghai Explorer Program (Grant No.22TS1400100)。
文摘Photocurrent-voltage characterization is a crucial method for assessing key parameters in x-ray or y-ray semiconductor detectors,especially the carrier mobility lifetime product.However,the high biases during photocurrent measurements tend to cause severe ion migration,which can lead to the instability and inaccuracy of the test results.Given the mixed electronic-ionic charac teristics,it is imperative to devise novel methods capable of precisely measuring photocurrentvoltage characteristics under high bias conditions,free from interference caused by ion migration.In this paper,pulsed bias is employed to explore the photocurrent-voltage characteristics of MAPbBr_(3) single crystals.The method yields stable photocurrent-voltage characteristics at a pulsed bias of up to 30 V,proving to be effective in mitigating ion migration.Through fitting the modified Hecht equation,we determined the mobility lifetime products of 1.0×10^(2) cm^(2)·V^(-1)for hole and 2.78×10~(-3)cm^(2)·V^(-1)for electron.This approach offers a promising solution for accurately measuring the transport properties of carriers in perovskite.
基金The work was supported by the“New Engineering”Research and Practice Project,China(Grant No.E-ZNZZ20201214)China Postdoctoral Science Foundation(Grant No.2019M650179)+1 种基金Guangdong Innovative and Entrepreneurial Research Team Program,China(Grant No.2019ZT08Z780)Guangdong HUST Industrial Technology Research Institute,Guangdong Provincial Key Laboratory of Digital Manufacturing Equipment,China(Grant No.2020B1212060014).
文摘Practice experimentation that integrates the manufacturing processes and cutting-edge technologies of smart manufacturing (SM) is essential for future academic and applied engineering personnel. The broadening efficacy of hands-on experience in SM engineering education has been manifested. In this regard, a reference practical system is proposed in this study for hands-on training in SM crucial advancements. The system constructs a mobile robot-based production line (MRPL) to increase participants’ interest in theoretical learning and professional skills. The MRPL-based reference system includes the comprehensive principles and processes involved in modern SM factories from warehousing to logistics, processing, and testing. With key features of modularity, integrability, customizability, and open architecture, this system has a threefold objective. First, it is an interdisciplinary subject that enables students to translate classroom learning into authentic practices, thus facilitating knowledge synthesis and training involvements. Second, it offers effective support to cultivate the attributions and behavioral competencies of SM talents, such as perseverance, adaptability, and cooperation. Third, it promotes students’ capacities for critical thinking and problem solving so that they can deal with the difficulties that physical systems have and motivates them to pursue careers with new syllabi, functions, and process techno-logies. The received positive evaluations and assessments confirm that this MRPL-based reference system is beneficial for modern SM talent training in higher engineering education.
文摘We report physics based confirmation(~1% RMS deviation), by existing experimental data, of protonprohol(proton-hole) ion product(p H) and mobilities in pure liquid water(0-100℃, 1-atm pressure) anticipated from our melted-ice Hexagonal-Close-Packed(H_2O)_4Lattice Model. Five phonons are identified.(1) A propagating protonic phonon(520.9 meV from lone-pair-blue-shifted stretching mode of isolated water molecule) absorbed to generate a proton-prohol pair or detrap a tightly-bound proton.(2) Two(173.4 and 196.6 meV) bending-breathing protonic-proholic or protonic phonons absorbed during de-trapping-limited proton or proton-prohol mobilities.(3)Two propagating oxygenic-wateric Debye-Dispersive phonons(30.3 and 27.5 meV) absorbed during scatteringlimited proton or proton-prohol mobilities.
基金funded by the National Natural Science Foundation of China
文摘This report adds three protonic semiconductor models to explain the "abnormally" high electrical conductivity of pure liquid water characterized by the three industrial consensus parameters, the ion product(or pH)and the two ion mobilities. Existence of long-range order in fluid water under numerous daily conditions led us to extend the 1933 Bernal-Fowler hexagonally close packed crystalline Ice Lattice to model liquid water as Melted Ice. Protonic kinetic energy band and bound(trap) pictures provide semiconductor-physics based new models of these three parameters. They are extrapolatable engineered-models for developing novel biological, chemical, electrical, mechanical and medical applications of liquid water.