The main purpose of this work is to study doping level effects on a silicon PV cell under both moderate light concentration and normal illumination. This study also aims to compare the doping level effects under the b...The main purpose of this work is to study doping level effects on a silicon PV cell under both moderate light concentration and normal illumination. This study also aims to compare the doping level effects under the both illumination modes. The results show for both illumination modes that diffusion parameters decrease with increasing doping level. These results are in agreement with the studies of the current and the voltage which showed for the two illumination modes that doping level increase leads to a decrease in current density and an increase in voltage. It also emerges for the two illumination modes and for the doping range 10<sup>13</sup> cm<sup>-3</sup> - 10<sup>16</sup> cm<sup>-3</sup>, a decrease of maximum power and conversion efficiency. The results also show that decrease of diffusion parameters is faster under moderate concentration in comparison with normal illumination. These results predict a greater variation rate of the current, the voltage, the maximum power and the conversion efficiency under moderate concentration compared to normal illumination. Contrary to diffusion parameters study, the results show higher variation rates of parameters under normal illumination. This is explained by the fact that under moderate concentration, carriers density is close to doping level: the cell is then in high injection condition. Consequently, under moderate concentration, carriers density is less sensitive to doping level variations. The study confirms that carriers density variation with the doping level is weak under the moderate concentration compared to normal illumination.展开更多
The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we repor...The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.展开更多
A refractory gold concentrate with 19% arsenic was treated by a mixed moderately thermophiles in an airlift bioreactor through an adaptation protocol. The moderately thermophiles could respond well to 20%(w/v) pulp de...A refractory gold concentrate with 19% arsenic was treated by a mixed moderately thermophiles in an airlift bioreactor through an adaptation protocol. The moderately thermophiles could respond well to 20%(w/v) pulp density with less than 10% loss of productivity, and resist arsenic up to 15 g/L. There were a lot of jarosite, arsenolite and sulfur, but not scorodite and ferric arsenate in the bioleached residue. Jarosite passivation and lower sulfur-oxidizing activity of the cells due to the toxicity of the high concentrations of soluble arsenic and iron ions at low p H value should mainly response for the incomplete extraction at high pulp density. The initial bacterial community did not change in nature except for new found P aeruginosa ANSC, but sulfur-oxidizing microorganisms have been dominant microorganisms after a long time of adaptation. Pseudomonas aeruginosa originating from the gold concentrate should be closely relative to the metabolism of the organic matters contained in the refractory gold concentrate.展开更多
文摘The main purpose of this work is to study doping level effects on a silicon PV cell under both moderate light concentration and normal illumination. This study also aims to compare the doping level effects under the both illumination modes. The results show for both illumination modes that diffusion parameters decrease with increasing doping level. These results are in agreement with the studies of the current and the voltage which showed for the two illumination modes that doping level increase leads to a decrease in current density and an increase in voltage. It also emerges for the two illumination modes and for the doping range 10<sup>13</sup> cm<sup>-3</sup> - 10<sup>16</sup> cm<sup>-3</sup>, a decrease of maximum power and conversion efficiency. The results also show that decrease of diffusion parameters is faster under moderate concentration in comparison with normal illumination. These results predict a greater variation rate of the current, the voltage, the maximum power and the conversion efficiency under moderate concentration compared to normal illumination. Contrary to diffusion parameters study, the results show higher variation rates of parameters under normal illumination. This is explained by the fact that under moderate concentration, carriers density is close to doping level: the cell is then in high injection condition. Consequently, under moderate concentration, carriers density is less sensitive to doping level variations. The study confirms that carriers density variation with the doping level is weak under the moderate concentration compared to normal illumination.
基金the Innovation-Driven Project of Central South University(2019CX033)the National Natural Science Foundation of China(51904344 and 52172264)the Natural Science Foundation of Hunan Province of China(2021JJ10060 and 2022GK2033)。
文摘The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.
基金Project(2010CB630903)supported by the National Basic Research Program of ChinaProject(31200382)supported by the Chinese Science Foundation for Distinguished Group,China
文摘A refractory gold concentrate with 19% arsenic was treated by a mixed moderately thermophiles in an airlift bioreactor through an adaptation protocol. The moderately thermophiles could respond well to 20%(w/v) pulp density with less than 10% loss of productivity, and resist arsenic up to 15 g/L. There were a lot of jarosite, arsenolite and sulfur, but not scorodite and ferric arsenate in the bioleached residue. Jarosite passivation and lower sulfur-oxidizing activity of the cells due to the toxicity of the high concentrations of soluble arsenic and iron ions at low p H value should mainly response for the incomplete extraction at high pulp density. The initial bacterial community did not change in nature except for new found P aeruginosa ANSC, but sulfur-oxidizing microorganisms have been dominant microorganisms after a long time of adaptation. Pseudomonas aeruginosa originating from the gold concentrate should be closely relative to the metabolism of the organic matters contained in the refractory gold concentrate.